JP2008073628A - 酸素吸収組成物及びその製造方法 - Google Patents
酸素吸収組成物及びその製造方法 Download PDFInfo
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- JP2008073628A JP2008073628A JP2006256854A JP2006256854A JP2008073628A JP 2008073628 A JP2008073628 A JP 2008073628A JP 2006256854 A JP2006256854 A JP 2006256854A JP 2006256854 A JP2006256854 A JP 2006256854A JP 2008073628 A JP2008073628 A JP 2008073628A
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- oxygen
- antioxidant
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- oxidation
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- 229910052707 ruthenium Inorganic materials 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
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- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
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- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
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- 230000007704 transition Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- ILLOBGFGKYTZRO-UHFFFAOYSA-N tris(2-ethylhexyl) phosphite Chemical compound CCCCC(CC)COP(OCC(CC)CCCC)OCC(CC)CCCC ILLOBGFGKYTZRO-UHFFFAOYSA-N 0.000 description 1
- JZNDMMGBXUYFNQ-UHFFFAOYSA-N tris(dodecylsulfanyl)phosphane Chemical compound CCCCCCCCCCCCSP(SCCCCCCCCCCCC)SCCCCCCCCCCCC JZNDMMGBXUYFNQ-UHFFFAOYSA-N 0.000 description 1
- QQBLOZGVRHAYGT-UHFFFAOYSA-N tris-decyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OCCCCCCCCCC QQBLOZGVRHAYGT-UHFFFAOYSA-N 0.000 description 1
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Images
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- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
【解決手段】 アリル水素および/または3級炭素と結合した水素を分子中に有する被酸化性化合物(A)と、酸化防止剤(B)0.005重量%〜0.35重量%と、酸化促進成分(C)0.0001重量%〜10重量%とからなる酸素吸収組成物。
【選択図】 なし
Description
[1]被酸化性化合物(A)
[2]酸化防止剤(B)
[3]酸化促進成分(C)
[4]その他の成分
[5]酸素吸収組成物の製造方法
[5−1]工程(X)
[5−2]工程(Y)
[5−3]工程(Z)
[6]酸素吸収組成物の形態
<酸化防止剤(B)の定量方法>
<飽和酸素吸収量(Vos)>
<誘導期間>
<被酸化性化合物(A)>
<酸化防止剤(B)>
<酸化促進成分(C)>
CAT2:関東化学社製、酸化鉄(III)。融点1538℃。上述の群Pの物質。
CAT3:関東化学社製、鉄、融点1536℃。上述の群Pの物質。
CAT4:関東化学社製、ステアリン酸亜鉛。融点140℃。上述の群Qの物質。
CAT5:関東化学社製、酸化亜鉛。融点1975℃。上述の群Qの物質。
CAT6:関東化学社製、アントラキノン。融点286℃。上述の群Qの物質。
CAT7:関東化学社製、酸化銀(I)。222℃で銀と酸素に分解する(融点200℃以上)。
CAT8:和光純薬工業社製、ナフテン酸鉄(II)ミネラルスピリット溶液(Fe:5重量%)、常温23℃で液体(融点23℃以下)。
CAT9:関東化学社製、硫酸銅(II)。融点600℃以上。上述の群Pの物質。
[実施例1]
[比較例1]
[実施例2]
[実施例3]
[実施例4]
[比較例2]
[実施例5]
[実施例6〜11]
[実施例12]
Claims (3)
- アリル水素および/または3級炭素と結合した水素を分子中に有する被酸化性化合物(A)と、酸化防止剤(B)0.005重量%〜0.35重量%と、酸化促進成分(C)0.0001重量%〜10重量%とからなる酸素吸収組成物。
- 前記酸化促進成分(C)が、融点が150℃以上の遷移金属化合物であることを特徴とする請求項1に記載の酸素吸収組成物。
- アリル水素および/または3級炭素と結合した水素を分子中に有する被酸化性化合物(A)と、酸化防止剤(B)0.05重量%〜1重量%と、酸化促進成分(C)0.0001重量%〜10重量%と、水0.1重量%〜10重量%とを混合する工程、ベント口を備えた押出機を用いて、加熱溶融状態において50kPa以下まで減圧脱気しながら加熱溶融押出する工程、その後冷却する工程を順次経ることを特徴とする酸素吸収組成物の製造方法。
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH105584A (ja) * | 1996-06-21 | 1998-01-13 | Sumitomo Chem Co Ltd | 酸素吸収シートおよびその製造法 |
JP2005186060A (ja) * | 2003-12-04 | 2005-07-14 | Nippon Zeon Co Ltd | 酸素吸収剤 |
WO2005123248A1 (ja) * | 2004-06-18 | 2005-12-29 | Kuraray Co., Ltd. | 酸素吸収性組成物および包装材 |
WO2006095640A1 (ja) * | 2005-03-07 | 2006-09-14 | Asahi Kasei Chemicals Corporation | 粉状酸素吸収材及びその製造法 |
-
2006
- 2006-09-22 JP JP2006256854A patent/JP2008073628A/ja active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH105584A (ja) * | 1996-06-21 | 1998-01-13 | Sumitomo Chem Co Ltd | 酸素吸収シートおよびその製造法 |
JP2005186060A (ja) * | 2003-12-04 | 2005-07-14 | Nippon Zeon Co Ltd | 酸素吸収剤 |
WO2005123248A1 (ja) * | 2004-06-18 | 2005-12-29 | Kuraray Co., Ltd. | 酸素吸収性組成物および包装材 |
WO2006095640A1 (ja) * | 2005-03-07 | 2006-09-14 | Asahi Kasei Chemicals Corporation | 粉状酸素吸収材及びその製造法 |
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