JP2007519625A5 - - Google Patents
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- Publication number
- JP2007519625A5 JP2007519625A5 JP2006546051A JP2006546051A JP2007519625A5 JP 2007519625 A5 JP2007519625 A5 JP 2007519625A5 JP 2006546051 A JP2006546051 A JP 2006546051A JP 2006546051 A JP2006546051 A JP 2006546051A JP 2007519625 A5 JP2007519625 A5 JP 2007519625A5
- Authority
- JP
- Japan
- Prior art keywords
- substituted
- alkyl
- branched
- cyclic
- sch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003153 chemical reaction reagent Substances 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 11
- 125000004122 cyclic group Chemical group 0.000 claims description 11
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 238000007239 Wittig reaction Methods 0.000 claims description 5
- 150000001728 carbonyl compounds Chemical class 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 3
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
- 238000000034 method Methods 0.000 claims 7
- 150000003222 pyridines Chemical class 0.000 claims 4
- 239000003054 catalyst Substances 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 238000002360 preparation method Methods 0.000 claims 2
- 238000007363 ring formation reaction Methods 0.000 claims 2
- 238000003786 synthesis reaction Methods 0.000 claims 2
- DHJDPIHFALRNER-OWOJBTEDSA-N (e)-4-amino-1,1,1-trifluorobut-3-en-2-one Chemical compound N\C=C\C(=O)C(F)(F)F DHJDPIHFALRNER-OWOJBTEDSA-N 0.000 claims 1
- IKHLLNMSMFVTLP-UHFFFAOYSA-N 4-(trifluoromethyl)-1h-pyridin-2-one Chemical compound OC1=CC(C(F)(F)F)=CC=N1 IKHLLNMSMFVTLP-UHFFFAOYSA-N 0.000 claims 1
- 238000006546 Horner-Wadsworth-Emmons reaction Methods 0.000 claims 1
- 229910021536 Zeolite Inorganic materials 0.000 claims 1
- 230000002378 acidificating effect Effects 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 150000003018 phosphorus compounds Chemical class 0.000 claims 1
- 239000010457 zeolite Substances 0.000 claims 1
- 238000006052 Horner reaction Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- -1 phosphorus compound Chemical class 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 3
- 150000002900 organolithium compounds Chemical class 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 150000004678 hydrides Chemical class 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- XPYGGHVSFMUHLH-UUSULHAXSA-N falecalcitriol Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@@H](CCCC(O)(C(F)(F)F)C(F)(F)F)C)=C\C=C1\C[C@@H](O)C[C@H](O)C1=C XPYGGHVSFMUHLH-UUSULHAXSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- JILPJDVXYVTZDQ-UHFFFAOYSA-N lithium methoxide Chemical class [Li+].[O-]C JILPJDVXYVTZDQ-UHFFFAOYSA-N 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- AZVCGYPLLBEUNV-UHFFFAOYSA-N lithium;ethanolate Chemical compound [Li+].CC[O-] AZVCGYPLLBEUNV-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000004714 phosphonium salts Chemical class 0.000 description 1
- 150000003017 phosphorus Chemical class 0.000 description 1
- 239000003880 polar aprotic solvent Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US53161403P | 2003-12-23 | 2003-12-23 | |
| EP03029730.3 | 2003-12-23 | ||
| US60/531,614 | 2003-12-23 | ||
| EP03029730 | 2003-12-23 | ||
| PCT/EP2004/014590 WO2005063780A1 (en) | 2003-12-23 | 2004-12-22 | Process for the preparation of pyridine derivatives |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012139429A Division JP2012214487A (ja) | 2003-12-23 | 2012-06-21 | ピリジン誘導体の調製方法 |
| JP2012229144A Division JP2013047245A (ja) | 2003-12-23 | 2012-10-16 | ピリジン誘導体の調製方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2007519625A JP2007519625A (ja) | 2007-07-19 |
| JP2007519625A5 true JP2007519625A5 (cg-RX-API-DMAC7.html) | 2012-12-06 |
| JP5160092B2 JP5160092B2 (ja) | 2013-03-13 |
Family
ID=34923925
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006546051A Expired - Lifetime JP5160092B2 (ja) | 2003-12-23 | 2004-12-22 | ピリジン誘導体の調製方法 |
| JP2012139429A Pending JP2012214487A (ja) | 2003-12-23 | 2012-06-21 | ピリジン誘導体の調製方法 |
| JP2012229144A Pending JP2013047245A (ja) | 2003-12-23 | 2012-10-16 | ピリジン誘導体の調製方法 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012139429A Pending JP2012214487A (ja) | 2003-12-23 | 2012-06-21 | ピリジン誘導体の調製方法 |
| JP2012229144A Pending JP2013047245A (ja) | 2003-12-23 | 2012-10-16 | ピリジン誘導体の調製方法 |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US7687632B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP1723156B1 (cg-RX-API-DMAC7.html) |
| JP (3) | JP5160092B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR101164694B1 (cg-RX-API-DMAC7.html) |
| CN (1) | CN1898255B (cg-RX-API-DMAC7.html) |
| AR (1) | AR046775A1 (cg-RX-API-DMAC7.html) |
| AU (1) | AU2004309054B2 (cg-RX-API-DMAC7.html) |
| BR (1) | BRPI0418047B8 (cg-RX-API-DMAC7.html) |
| CA (1) | CA2550693C (cg-RX-API-DMAC7.html) |
| DK (1) | DK1723156T3 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2528716T3 (cg-RX-API-DMAC7.html) |
| IL (1) | IL176472A (cg-RX-API-DMAC7.html) |
| IN (2) | IN2012DN02546A (cg-RX-API-DMAC7.html) |
| PL (1) | PL1723156T3 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2005063780A1 (cg-RX-API-DMAC7.html) |
| ZA (1) | ZA200605471B (cg-RX-API-DMAC7.html) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2611018T3 (es) * | 2004-04-08 | 2017-05-04 | Dow Agrosciences Llc | Sulfoximinas N-sustituidas insecticidas |
| WO2006012320A1 (en) * | 2004-06-25 | 2006-02-02 | Dow Agrosciences Llc | Process for the preparation of 4-trifluoromethyl-2(1h)-pyridinone |
| TW201309635A (zh) * | 2006-02-10 | 2013-03-01 | Dow Agrosciences Llc | 殺蟲性之ｎ-取代（６-鹵烷基吡啶-３-基）烷基磺醯亞胺（二） |
| TWI381811B (zh) * | 2006-06-23 | 2013-01-11 | Dow Agrosciences Llc | 用以防治可抵抗一般殺蟲劑之昆蟲的方法 |
| EP2338884A1 (en) * | 2006-09-01 | 2011-06-29 | Dow AgroSciences LLC | Insecticidal N-substituted (2-substituted-1,3-thiazol) alkyl sulfoximines |
| TWI387585B (zh) * | 2006-09-01 | 2013-03-01 | Dow Agrosciences Llc | 殺蟲性之ｎ-取代（雜芳基）烷基烴基硫亞胺 |
| TWI395737B (zh) * | 2006-11-08 | 2013-05-11 | Dow Agrosciences Llc | 作為殺蟲劑之雜芳基（取代的）烷基ｎ-取代的磺醯亞胺 |
| US7709648B2 (en) * | 2007-02-09 | 2010-05-04 | Dow Agrosciences Llc | Process for the preparation of 2-substituted-5-(1-alkylthio)alkylpyridines |
| AR066366A1 (es) * | 2007-05-01 | 2009-08-12 | Dow Agrosciences Llc | Mezclas sinergicas plaguicidas |
| ATE523083T1 (de) * | 2007-07-20 | 2011-09-15 | Dow Agrosciences Llc | Erhöhte pflanzenvitalität |
| EP2268615B1 (en) * | 2008-03-03 | 2016-08-17 | Dow AgroSciences LLC | Pesticides |
| CN102875548A (zh) * | 2011-07-14 | 2013-01-16 | 中国科学院大连化学物理研究所 | 一类基于肟的通过[2+2+2]环加成合成吡啶衍生物的方法 |
| EP2607343A1 (en) | 2011-12-22 | 2013-06-26 | Solvay Sa | Process for the manufacture of halogenated precursors of alkenones and of alkenones |
| US10961248B2 (en) * | 2016-12-01 | 2021-03-30 | Syngenta Participations Ag | Pesticidally active heterocyclic derivatives with sulfur containing substituents |
| EP3902785A1 (en) | 2018-12-27 | 2021-11-03 | Corteva Agriscience LLC | Preparation of sulfonamide herbicide process intermediates |
| ES2939695T3 (es) | 2018-12-27 | 2023-04-26 | Corteva Agriscience Llc | Preparación de intermedios de un proceso de herbicidas de sulfonamida |
| CN115286568B (zh) * | 2022-08-24 | 2023-12-12 | 常州沃腾化工科技有限公司 | 一种2-羟基-4-三氟甲基吡啶的制备方法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE611728A (fr) * | 1960-07-12 | 1962-06-19 | American Cyanamid Co | Perfectionnements aux compositions contenant des antibiotiques à base de tétracycline |
| US3993656A (en) * | 1974-11-19 | 1976-11-23 | Merck & Co., Inc. | 1,8-Naphthyridine compounds |
| JPS5221196A (en) * | 1975-08-12 | 1977-02-17 | Fujio Hashimoto | Device for removing red tide |
| JPS53127490A (en) * | 1977-04-13 | 1978-11-07 | Yamanouchi Pharmaceut Co Ltd | Novel nitrogen-containing heterocyclic compound |
| JPS5384990A (en) * | 1976-12-29 | 1978-07-26 | Yamanouchi Pharmaceut Co Ltd | Novel nitrogen-containing heterocyclic compound and its preparation |
| JPS53121764A (en) * | 1977-03-31 | 1978-10-24 | Yamanouchi Pharmaceut Co Ltd | Heterocyclic compounds and process for their preparation |
| JPS55104266A (en) * | 1979-02-02 | 1980-08-09 | Yamanouchi Pharmaceut Co Ltd | Novel pyridone derivative |
| JPS6210087A (ja) * | 1985-07-03 | 1987-01-19 | Shionogi & Co Ltd | ４，７−ジヒドロチエノ〔２，３−ｂ〕ピリジン誘導体，その製造法および循環器系疾患治療剤 |
| JPS6413065A (en) * | 1987-07-06 | 1989-01-17 | Mitsubishi Chem Ind | Peptide derivative of beta-chloro-l-(z)- dehydroglutamic acid |
| DK177191D0 (da) * | 1991-10-23 | 1991-10-23 | Novo Nordisk As | Heterocyclic compounds and their preparation and use |
| US5391745A (en) * | 1992-07-23 | 1995-02-21 | Sloan-Kettering Institute For Cancer Research | Methods of preparation of camptothecin analogs |
| US5858924A (en) | 1996-09-24 | 1999-01-12 | Dow Agrosciences Llc | N-( 1, 2, 4! triazoloazinyl) benzenesulfonamide and pyridinesulfonamide compounds and their use as herbicides |
| WO1999065897A1 (en) * | 1998-06-19 | 1999-12-23 | Chiron Corporation | Inhibitors of glycogen synthase kinase 3 |
| EP1301483A1 (de) * | 2000-07-18 | 2003-04-16 | Basf Aktiengesellschaft | 1-aryl-4-halogenalkyl-2-(1h)-pyridone und ihre verwendung als herbizide |
| US6399781B1 (en) | 2000-10-10 | 2002-06-04 | Boehringer Ingelheim Chemicals, Inc. | Process for making 3-amino-2-chloro-4-methylpyridine |
| WO2006012320A1 (en) * | 2004-06-25 | 2006-02-02 | Dow Agrosciences Llc | Process for the preparation of 4-trifluoromethyl-2(1h)-pyridinone |
-
2004
- 2004-12-11 ZA ZA200605471A patent/ZA200605471B/en unknown
- 2004-12-22 WO PCT/EP2004/014590 patent/WO2005063780A1/en not_active Ceased
- 2004-12-22 PL PL04804186T patent/PL1723156T3/pl unknown
- 2004-12-22 IN IN2546DEN2012 patent/IN2012DN02546A/en unknown
- 2004-12-22 US US10/584,354 patent/US7687632B2/en not_active Expired - Lifetime
- 2004-12-22 DK DK04804186.7T patent/DK1723156T3/en active
- 2004-12-22 AU AU2004309054A patent/AU2004309054B2/en not_active Expired
- 2004-12-22 EP EP04804186.7A patent/EP1723156B1/en not_active Expired - Lifetime
- 2004-12-22 CN CN2004800388844A patent/CN1898255B/zh not_active Expired - Lifetime
- 2004-12-22 BR BRPI0418047A patent/BRPI0418047B8/pt not_active IP Right Cessation
- 2004-12-22 IN IN2545DEN2012 patent/IN2012DN02545A/en unknown
- 2004-12-22 ES ES04804186.7T patent/ES2528716T3/es not_active Expired - Lifetime
- 2004-12-22 CA CA2550693A patent/CA2550693C/en not_active Expired - Lifetime
- 2004-12-22 JP JP2006546051A patent/JP5160092B2/ja not_active Expired - Lifetime
- 2004-12-22 KR KR1020067012653A patent/KR101164694B1/ko not_active Expired - Lifetime
- 2004-12-22 AR ARP040104854A patent/AR046775A1/es active IP Right Grant
-
2006
- 2006-06-21 IL IL176472A patent/IL176472A/en active IP Right Grant
-
2012
- 2012-06-21 JP JP2012139429A patent/JP2012214487A/ja active Pending
- 2012-10-16 JP JP2012229144A patent/JP2013047245A/ja active Pending
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