JP2007503522A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2007503522A5 JP2007503522A5 JP2006532804A JP2006532804A JP2007503522A5 JP 2007503522 A5 JP2007503522 A5 JP 2007503522A5 JP 2006532804 A JP2006532804 A JP 2006532804A JP 2006532804 A JP2006532804 A JP 2006532804A JP 2007503522 A5 JP2007503522 A5 JP 2007503522A5
- Authority
- JP
- Japan
- Prior art keywords
- po3g
- alumina
- silica
- carbon
- palladium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 claims description 20
- 238000005984 hydrogenation reaction Methods 0.000 claims description 14
- 241001550224 Apha Species 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 claims description 6
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 4
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims description 4
- 239000000376 reactant Substances 0.000 claims description 4
- 238000006068 polycondensation reaction Methods 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 16
- 239000000377 silicon dioxide Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- 239000005751 Copper oxide Substances 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 239000007868 Raney catalyst Substances 0.000 description 2
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 2
- 229910000564 Raney nickel Inorganic materials 0.000 description 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- DSVGQVZAZSZEEX-UHFFFAOYSA-N [C].[Pt] Chemical compound [C].[Pt] DSVGQVZAZSZEEX-UHFFFAOYSA-N 0.000 description 2
- XCVKVYNICFBSJQ-UHFFFAOYSA-N [Re].[C] Chemical compound [Re].[C] XCVKVYNICFBSJQ-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 229910000423 chromium oxide Inorganic materials 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 229910000431 copper oxide Inorganic materials 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 229910021472 group 8 element Inorganic materials 0.000 description 2
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 2
- DZQBLSOLVRLASG-UHFFFAOYSA-N iridium;methane Chemical compound C.[Ir] DZQBLSOLVRLASG-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- UKVIEHSSVKSQBA-UHFFFAOYSA-N methane;palladium Chemical compound C.[Pd] UKVIEHSSVKSQBA-UHFFFAOYSA-N 0.000 description 2
- RPNNPZHFJPXFQS-UHFFFAOYSA-N methane;rhodium Chemical compound C.[Rh] RPNNPZHFJPXFQS-UHFFFAOYSA-N 0.000 description 2
- NCPHGZWGGANCAY-UHFFFAOYSA-N methane;ruthenium Chemical compound C.[Ru] NCPHGZWGGANCAY-UHFFFAOYSA-N 0.000 description 2
- VMWYVTOHEQQZHQ-UHFFFAOYSA-N methylidynenickel Chemical compound [Ni]#[C] VMWYVTOHEQQZHQ-UHFFFAOYSA-N 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 229910000018 strontium carbonate Inorganic materials 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- PWGQHOJABIQOOS-UHFFFAOYSA-N copper;dioxido(dioxo)chromium Chemical compound [Cu+2].[O-][Cr]([O-])(=O)=O PWGQHOJABIQOOS-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US46822703P | 2003-05-06 | 2003-05-06 | |
| US10/634,612 US7342142B2 (en) | 2003-05-06 | 2003-08-05 | Hydrogenation of polytrimethylene ether glycol |
| PCT/US2004/014045 WO2004101471A2 (en) | 2003-05-06 | 2004-05-05 | Hydrogenation of polytrimethylene ether glycol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2007503522A JP2007503522A (ja) | 2007-02-22 |
| JP2007503522A5 true JP2007503522A5 (enExample) | 2007-07-05 |
Family
ID=33423710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006532804A Pending JP2007503522A (ja) | 2003-05-06 | 2004-05-05 | ポリトリメチレンエーテルグリコールの水素化 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7342142B2 (enExample) |
| EP (1) | EP1620379A2 (enExample) |
| JP (1) | JP2007503522A (enExample) |
| KR (1) | KR20060015578A (enExample) |
| BR (1) | BRPI0410512A (enExample) |
| CA (1) | CA2522776A1 (enExample) |
| MX (1) | MXPA05011833A (enExample) |
| WO (1) | WO2004101471A2 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7084311B2 (en) * | 2003-05-06 | 2006-08-01 | E. I. Du Pont De Nemours And Company | Hydrogenation of chemically derived 1,3-propanediol |
| US7074969B2 (en) * | 2004-06-18 | 2006-07-11 | E.I. Du Pont De Nemours And Company | Process for preparation of polytrimethylene ether glycols |
| US20060189711A1 (en) * | 2005-02-23 | 2006-08-24 | Ng Howard C | Silicon-containing polytrimethylene homo- or copolyether composition |
| US7629396B2 (en) | 2005-02-23 | 2009-12-08 | E.I. Du Pont De Nemours And Company | Silicon-containing polytrimethylene homo- for copolyether composition |
| US7413677B2 (en) * | 2005-02-25 | 2008-08-19 | E. I. Du Pont De Nemours And Company | Process for heat transfer utilizing a polytrimethylene homo- or copolyether glycol based heat transfer fluid |
| US7476344B2 (en) * | 2005-02-25 | 2009-01-13 | E.I. Du Pont De Nemours | Electrical apparatuses containing polytrimethylene homo- or copolyether glycol based electrical insulation fluids |
| US7282159B2 (en) * | 2005-02-25 | 2007-10-16 | E.I. Dupont De Nemours And Company | Process for heat transfer utilizing a polytrimethylene ether glycol or polytrimethylene ether ester glycol based heat transfer fluid |
| US7244790B2 (en) * | 2005-05-02 | 2007-07-17 | E.I. Du Pont De Nemours And Company | Thermoplastic elastomer blend, method of manufacture and use thereof |
| US7157607B1 (en) * | 2005-08-16 | 2007-01-02 | E. I. Du Pont De Nemours And Company | Manufacture of polytrimethylene ether glycol |
| US7357985B2 (en) * | 2005-09-19 | 2008-04-15 | E.I. Du Pont De Nemours And Company | High crimp bicomponent fibers |
| US20070203371A1 (en) * | 2006-01-23 | 2007-08-30 | Sunkara Hari B | Process for producing polytrimethylene ether glycol |
| US20080242831A1 (en) * | 2007-03-27 | 2008-10-02 | Yanhui Niu | Lower-color polytrimethylene ether glycol using zero-valent metals |
| US7714174B2 (en) * | 2007-03-27 | 2010-05-11 | E. I. Du Pont De Nemours And Company | Lower-color polytrimethylene ether glycol using hydride compounds |
| EP2205659B1 (en) * | 2007-11-01 | 2014-06-04 | E. I. du Pont de Nemours and Company | Preparation of polytrimethylene ether glycol or copolymers thereof |
Family Cites Families (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5346907A (en) * | 1976-10-08 | 1978-04-27 | Kuraray Co Ltd | Improvement of quality of polyoxyalkylene compounds |
| US4213000A (en) * | 1979-05-29 | 1980-07-15 | E. I. Du Pont De Nemours And Company | Reducing color formers in 1,4-butanediol |
| DE3112065A1 (de) * | 1981-03-27 | 1982-10-07 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von polytetramethylenether-glykol oder -glykoldiester mit niedriger farbzahl |
| JPS61166832A (ja) * | 1985-01-17 | 1986-07-28 | Taiyo Kagaku Kk | ポリグリセリンの精製法 |
| US4885410A (en) * | 1987-11-27 | 1989-12-05 | Gaf Corporation | Hydrogenation catalyst |
| DE3926136A1 (de) * | 1989-08-08 | 1991-02-14 | Degussa | Verfahren zur herstellung von 1,3-propandiol |
| DE3935750A1 (de) * | 1989-10-27 | 1991-05-02 | Basf Ag | Verfahren zur herstellung von hochreinen polymerisaten des tetrahydrofurans |
| DE4038192A1 (de) * | 1990-11-30 | 1992-06-04 | Degussa | Verfahren zur herstellung von 1,3-propandiol |
| JPH0825939B2 (ja) * | 1991-07-10 | 1996-03-13 | 日揮株式会社 | ポリグリセリンの精製方法 |
| DE4132663C2 (de) * | 1991-10-01 | 1993-10-14 | Degussa | Verfahren zum Herstellen von 1,3-Propandiol durch Hydrieren von Hydroxypropionaldehyd |
| DE4138981A1 (de) * | 1991-11-27 | 1993-06-03 | Degussa | Verfahren zur herstellung von 3-hydroxyalkanalen |
| DE4138982A1 (de) * | 1991-11-27 | 1993-06-03 | Degussa | Verfahren zur herstellung von 3-hydroxyalkanalen |
| DE4218282A1 (de) * | 1992-06-03 | 1993-12-09 | Degussa | Verfahren zur Herstellung von 1,3-Propandiol |
| DE4222708A1 (de) | 1992-07-10 | 1994-01-13 | Degussa | Verfahren zur Herstellung von 1,3-Propandiol |
| US6342484B1 (en) * | 1993-06-30 | 2002-01-29 | Board Of Regents, The University Of Texas Systems | Method and compositions for promotion of wound treatment |
| US5527973A (en) * | 1994-12-16 | 1996-06-18 | Kelsey; Donald R. | Purification of 1,3-propanediol |
| JPH08333448A (ja) * | 1995-06-08 | 1996-12-17 | Kao Corp | 色相の優れたポリエーテル重合体の製造方法 |
| US6111137A (en) * | 1996-12-20 | 2000-08-29 | Mitsui Chemicals, Inc. | Purification process of lactic acid |
| DE19703383A1 (de) * | 1997-01-30 | 1998-08-06 | Degussa | Verfahren zur Herstellung von 1,3-Propandiol |
| US5962745A (en) * | 1997-02-14 | 1999-10-05 | E. I. Du Pont De Nemours And Company | Process for preparing 3-hydroxyalkanals |
| DE69817356T2 (de) * | 1997-06-18 | 2004-07-08 | E.I. Du Pont De Nemours And Co., Wilmington | Verfahren zur herstellung von 1,3-propandiol durch hydrierung von 3-hydroxypropanal |
| US5986145A (en) * | 1997-08-22 | 1999-11-16 | Shell Oil Company | Purification of 3-hydroxy-propanal |
| JP4328026B2 (ja) * | 1998-09-04 | 2009-09-09 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | ３−ヒドロキシプロパナールの接触水素化による１，３−プロパンジオールの二段階製造法 |
| US6191321B1 (en) * | 1998-09-30 | 2001-02-20 | Shell Oil Company | Process for preparing 1,3-propanediol from methyl 3-hydroxypropionate |
| US5945570A (en) | 1998-10-29 | 1999-08-31 | Arhancet; Juan Pedro | Catalyst and process for preparing 1,3-propanediol |
| US6350895B1 (en) * | 1999-03-26 | 2002-02-26 | E. I. Du Pont De Nemours And Company | Transesterification process using yttrium and samarium compound catalystis |
| US6331264B1 (en) * | 1999-03-31 | 2001-12-18 | E. I. Du Pont De Nemours And Company | Low emission polymer compositions |
| US6277289B1 (en) * | 1999-07-01 | 2001-08-21 | E. I. Du Pont De Nemours And Company | Treatment of aqueous aldehyde waste streams |
| US6284930B1 (en) * | 1999-07-30 | 2001-09-04 | E.I. Du Pont De Nemours And Company | Process for the preparation of 3-hydroxypropanal |
| US6342646B1 (en) * | 1999-07-30 | 2002-01-29 | E. I. Du Pont De Nemours And Company | Catalytic hydrogenation of 3-hydroxypropanal to 1,3-propanediol |
| JP5283298B2 (ja) * | 1999-08-25 | 2013-09-04 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | ジ（１，３−プロピレングリコール）低レベル含有ポリ（トリメチレンテレフタレート）の調製 |
| EP1246861B1 (en) * | 1999-12-17 | 2006-05-17 | E.I. Du Pont De Nemours And Company | Production of polytrimethylene ether glycol and copolymers thereof |
| AU2270901A (en) * | 1999-12-17 | 2001-06-25 | E.I. Du Pont De Nemours And Company | Continuous process for the preparation of polytrimethylene ether glycol |
| US6255442B1 (en) * | 2000-02-08 | 2001-07-03 | E. I. Du Pont De Nemours And Company | Esterification process |
| US6353062B1 (en) | 2000-02-11 | 2002-03-05 | E. I. Du Pont De Nemours And Company | Continuous process for producing poly(trimethylene terephthalate) |
| US6353082B1 (en) * | 2000-10-26 | 2002-03-05 | Eastman Kodak Company | Highly branched polyesters through one-step polymerization process |
| AU2003248676A1 (en) * | 2002-06-15 | 2003-12-31 | Enteromed, Inc. | Treatment of non-alcoholic fatty liver disease |
| US6972346B2 (en) * | 2002-11-01 | 2005-12-06 | Shell Oil Company | Solid acid catalyzed reactive stripping of impurities formed during the production of 1, 3-propanediol |
| DK176022B1 (da) | 2003-03-07 | 2005-12-19 | Lindberg As | Apparat, fikstur samt fremgangsmåde til fiksering af brilleglas for uindfattede briller |
| US20040211729A1 (en) * | 2003-04-25 | 2004-10-28 | Sunkara Hari Babu | Processes for recovering oligomers of glycols and polymerization catalysts from waste streams |
| US7323539B2 (en) | 2003-05-06 | 2008-01-29 | E. I. Du Pont De Nemours And Company | Polytrimethylene ether glycol and polytrimethylene ether ester with excellent quality |
| US7009082B2 (en) * | 2003-05-06 | 2006-03-07 | E.I. Du Pont De Nemours And Company | Removal of color bodies from polytrimethylene ether glycol polymers |
| US7084311B2 (en) | 2003-05-06 | 2006-08-01 | E. I. Du Pont De Nemours And Company | Hydrogenation of chemically derived 1,3-propanediol |
| JP3933605B2 (ja) * | 2003-05-12 | 2007-06-20 | 有限会社新城製作所 | ピアスナットの製造方法 |
-
2003
- 2003-08-05 US US10/634,612 patent/US7342142B2/en not_active Expired - Fee Related
-
2004
- 2004-05-05 MX MXPA05011833A patent/MXPA05011833A/es active IP Right Grant
- 2004-05-05 EP EP04760883A patent/EP1620379A2/en not_active Withdrawn
- 2004-05-05 KR KR1020057020959A patent/KR20060015578A/ko not_active Withdrawn
- 2004-05-05 BR BRPI0410512-5A patent/BRPI0410512A/pt not_active IP Right Cessation
- 2004-05-05 WO PCT/US2004/014045 patent/WO2004101471A2/en not_active Ceased
- 2004-05-05 CA CA002522776A patent/CA2522776A1/en not_active Abandoned
- 2004-05-05 JP JP2006532804A patent/JP2007503522A/ja active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2007500214A5 (enExample) | ||
| JP2007500215A5 (enExample) | ||
| ATE13177T1 (de) | Verfahren zur herstellung von cyclohexylaminen durch hydrierung von aromatischen aminen. | |
| CN1332914C (zh) | 在载体催化剂存在下芳香族化合物的加氢方法 | |
| EP1857177A3 (en) | Metal modified Pd/Ni catalysts | |
| EP1816145A4 (en) | POLYMER POLYMERIZATION CATALYZER BASED ON CONJUGATED SERVES, METHOD FOR THE PREPARATION OF POLYMER BASED ON CONJUGATED SERVES THEREWITH, RUBBER COMPOSITION FOR ROLLING AND RUBBER COMPOSITION FOR GOLFBALL | |
| JP2005500987A5 (enExample) | ||
| BR0010993A (pt) | Processo para hidrogenação de ligações duplas etilenicamente insaturadas em polìmeros p,dispersão aquosa de polìmero,e,composição aquosa de revestimento | |
| ATE546224T1 (de) | Verfahren zur herstellung von aminen | |
| TW200700152A (en) | Hydrogenation catalyst and hydrogenation method | |
| JP5987041B2 (ja) | ブロックコポリマーを選択的に水素化する方法およびその組成物 | |
| IN2003CH00040A (enExample) | ||
| BR0005880A (pt) | Modificação de um catalisador de hidrogenação | |
| DE50010580D1 (de) | Farbzahlverbesserung von mehrwertigen alkoholen durch hydrierung | |
| WO2004101471A3 (en) | Hydrogenation of polytrimethylene ether glycol | |
| ES2181957T3 (es) | Catalizador multimetalico y procedimiento para la preparacion de aminas aromaticas sustituidas. | |
| KR910011757A (ko) | N.n-디메틸 아민의 제조공정 | |
| IL126443A (en) | Process for preparing cyano group containing aromatic methylamines | |
| EP0588060B1 (en) | Method for preparing aromatic secondary amino compound | |
| CN120737312B (zh) | 一种制备环氧树脂固化剂的方法 | |
| KR950032589A (ko) | 수소처리된 탄화수소 공급원료의 수소화분해 방법 | |
| TH72834A (th) | การเติมไฮโดรเจนของ 1,3-โพรเพนไดออลที่ได้มาทางชีวเคมี | |
| CN120718246A (zh) | 一种环氧树脂固化剂 | |
| JP2980161B2 (ja) | 第二級アミンを製造するためのアミンの不均化 | |
| EP3312202A1 (en) | Method for hydrogenating polymer and hydrogenated polymer thereof |