JP2007262472A - 金色装飾品およびその製造方法 - Google Patents
金色装飾品およびその製造方法 Download PDFInfo
- Publication number
- JP2007262472A JP2007262472A JP2006087940A JP2006087940A JP2007262472A JP 2007262472 A JP2007262472 A JP 2007262472A JP 2006087940 A JP2006087940 A JP 2006087940A JP 2006087940 A JP2006087940 A JP 2006087940A JP 2007262472 A JP2007262472 A JP 2007262472A
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- JP
- Japan
- Prior art keywords
- coating
- tin
- film
- gradient
- gold
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims description 15
- 238000000576 coating method Methods 0.000 claims abstract description 237
- 239000011248 coating agent Substances 0.000 claims abstract description 234
- 125000004429 atom Chemical group 0.000 claims abstract description 142
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 137
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 110
- 229910052737 gold Inorganic materials 0.000 claims abstract description 103
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 96
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 51
- 125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 38
- 229910001020 Au alloy Inorganic materials 0.000 claims abstract description 33
- 239000011261 inert gas Substances 0.000 claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 15
- 239000012298 atmosphere Substances 0.000 claims abstract description 6
- 239000010931 gold Substances 0.000 claims description 159
- 239000010936 titanium Substances 0.000 claims description 159
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 82
- 238000007747 plating Methods 0.000 claims description 81
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 79
- 238000001704 evaporation Methods 0.000 claims description 65
- 230000008020 evaporation Effects 0.000 claims description 51
- 229910052751 metal Inorganic materials 0.000 claims description 47
- 239000002184 metal Substances 0.000 claims description 47
- 229910001873 dinitrogen Inorganic materials 0.000 claims description 39
- 230000015572 biosynthetic process Effects 0.000 claims description 20
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 229910045601 alloy Inorganic materials 0.000 claims description 9
- 239000000956 alloy Substances 0.000 claims description 9
- 150000002739 metals Chemical class 0.000 claims description 4
- 239000000203 mixture Substances 0.000 abstract description 7
- 239000010408 film Substances 0.000 description 199
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 64
- 239000007789 gas Substances 0.000 description 42
- 238000012360 testing method Methods 0.000 description 34
- 229910052786 argon Inorganic materials 0.000 description 32
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 25
- 239000010410 layer Substances 0.000 description 16
- 238000005260 corrosion Methods 0.000 description 14
- 230000007797 corrosion Effects 0.000 description 14
- 229910052763 palladium Inorganic materials 0.000 description 14
- 238000005299 abrasion Methods 0.000 description 12
- 239000011247 coating layer Substances 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 9
- 238000000151 deposition Methods 0.000 description 9
- 230000008021 deposition Effects 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 239000001301 oxygen Substances 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 230000007423 decrease Effects 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- 238000007733 ion plating Methods 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000003353 gold alloy Substances 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 4
- 239000012300 argon atmosphere Substances 0.000 description 4
- 238000003754 machining Methods 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 229910002710 Au-Pd Inorganic materials 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 230000033001 locomotion Effects 0.000 description 3
- 229910052758 niobium Inorganic materials 0.000 description 3
- 239000010955 niobium Substances 0.000 description 3
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- 208000014451 palmoplantar keratoderma and congenital alopecia 2 Diseases 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
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- Physical Vapour Deposition (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006087940A JP2007262472A (ja) | 2006-03-28 | 2006-03-28 | 金色装飾品およびその製造方法 |
| CN200680010467.8A CN101160418B (zh) | 2005-03-31 | 2006-03-31 | 金色装饰品及其制造方法 |
| PCT/JP2006/306955 WO2006106981A1 (ja) | 2005-03-31 | 2006-03-31 | 金色装飾品およびその製造方法 |
| KR1020077024682A KR100962104B1 (ko) | 2005-03-31 | 2006-03-31 | 금색 장식품 및 그 제조 방법 |
| CN201210454466XA CN102994949A (zh) | 2005-03-31 | 2006-03-31 | 金色装饰品及其制造方法 |
| US11/910,163 US7771836B2 (en) | 2005-03-31 | 2006-03-31 | Golden ornament and process for producing the same |
| EP06730903A EP1870486A4 (en) | 2005-03-31 | 2006-03-31 | GOLDEN ORNAMENT AND METHOD OF MANUFACTURING THE SAME |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006087940A JP2007262472A (ja) | 2006-03-28 | 2006-03-28 | 金色装飾品およびその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2007262472A true JP2007262472A (ja) | 2007-10-11 |
| JP2007262472A5 JP2007262472A5 (https=) | 2009-05-07 |
Family
ID=38635734
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006087940A Withdrawn JP2007262472A (ja) | 2005-03-31 | 2006-03-28 | 金色装飾品およびその製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2007262472A (https=) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009299142A (ja) * | 2008-06-13 | 2009-12-24 | Ntn Corp | 耐摩耗性ＴｉＮ膜およびその形成体 |
| JP2011256424A (ja) * | 2010-06-08 | 2011-12-22 | Citizen Holdings Co Ltd | 硬質装飾部材 |
| WO2012039501A1 (ja) | 2010-09-21 | 2012-03-29 | シチズンホールディングス株式会社 | 白色硬質装飾部材 |
| WO2013141081A1 (ja) | 2012-03-19 | 2013-09-26 | シチズンホールディングス株式会社 | 白色硬質被膜層を有する硬質装飾部材およびその製造方法 |
| WO2013140986A1 (ja) | 2012-03-19 | 2013-09-26 | シチズンホールディングス株式会社 | 有色硬質装飾部材 |
| WO2013140989A1 (ja) | 2012-03-19 | 2013-09-26 | シチズンホールディングス株式会社 | 硬質装飾部材 |
| WO2014156897A1 (ja) | 2013-03-29 | 2014-10-02 | シチズンホールディングス株式会社 | グレー色調層を有する硬質装飾部材 |
-
2006
- 2006-03-28 JP JP2006087940A patent/JP2007262472A/ja not_active Withdrawn
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009299142A (ja) * | 2008-06-13 | 2009-12-24 | Ntn Corp | 耐摩耗性ＴｉＮ膜およびその形成体 |
| JP2011256424A (ja) * | 2010-06-08 | 2011-12-22 | Citizen Holdings Co Ltd | 硬質装飾部材 |
| WO2012039501A1 (ja) | 2010-09-21 | 2012-03-29 | シチズンホールディングス株式会社 | 白色硬質装飾部材 |
| US9120933B2 (en) | 2010-09-21 | 2015-09-01 | Citizen Holdings Co., Ltd. | White hard decorative member |
| WO2013141081A1 (ja) | 2012-03-19 | 2013-09-26 | シチズンホールディングス株式会社 | 白色硬質被膜層を有する硬質装飾部材およびその製造方法 |
| WO2013140986A1 (ja) | 2012-03-19 | 2013-09-26 | シチズンホールディングス株式会社 | 有色硬質装飾部材 |
| WO2013140989A1 (ja) | 2012-03-19 | 2013-09-26 | シチズンホールディングス株式会社 | 硬質装飾部材 |
| US9448535B2 (en) | 2012-03-19 | 2016-09-20 | Citizen Holdings Co., Ltd. | Rigid decorative member having white rigid coating layer, and method for producing the same |
| US9464355B2 (en) | 2012-03-19 | 2016-10-11 | Citizen Holdings Co., Ltd. | Colored rigid decorative member |
| US9471040B2 (en) | 2012-03-19 | 2016-10-18 | Citizen Holdings Co., Ltd. | Rigid decorative member |
| WO2014156897A1 (ja) | 2013-03-29 | 2014-10-02 | シチズンホールディングス株式会社 | グレー色調層を有する硬質装飾部材 |
| US9869011B2 (en) | 2013-03-29 | 2018-01-16 | Citizen Watch Co., Ltd. | Hard decorative member having gray-tone layer |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20090325 |
|
| A621 | Written request for application examination |
Effective date: 20090325 Free format text: JAPANESE INTERMEDIATE CODE: A621 |
|
| A761 | Written withdrawal of application |
Effective date: 20111116 Free format text: JAPANESE INTERMEDIATE CODE: A761 |