JP2007123935A - Substrate treatment equipment and method - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To enable a final processing of development steps with new clean developer, and changing a surface of a substrate into a cleaned state when the development is finished, by supplying the new developer to the surface of the substrate terminating the development. <P>SOLUTION: This substrate treatment equipment 1 is provided with a liquid layer forming chamber 2 which supplies the developer to the surface of the substrate S carried in a horizontal attitude to form a liquid layer of the developer on the surface of the substrate S due to the surface tension of the developer, a treatment progressing chamber 3 which holds the substrate S formed with the liquid layer of the developer and advances treatment with the developer of the liquid layer, and an attitude converting chamber 4 which converts the attitude of the substrate S after the treatment with the liquid layer of the developer into a slant attitude, wherein the attitude converting chamber 4 supplies the developer to the surface of the substrate S turned into the slant attitude. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

  The present invention relates to a developer, an etching solution, and an etching solution for various substrates to be processed such as a semiconductor wafer, a glass substrate for LCD (liquid crystal display device) and a glass substrate for PDP (plasma display panel), a glass substrate for photomask, and a printed substrate. The present invention relates to a substrate processing apparatus and a substrate processing method for supplying and processing a processing liquid such as a rinsing liquid.

  An example of a substrate processing apparatus that performs processing by supplying a processing liquid to various substrates to be processed is disclosed in Japanese Patent Application Laid-Open No. 1-250958. The apparatus disclosed in this publication transports a substrate in a horizontal position in a processing tank, supplies a developing solution as a processing liquid to the surface of the substrate in a shower shape, and then transfers the substrate to a buffer tank. Then, the substrate is tilted once, the developer on the substrate is poured off to return the substrate to a horizontal posture, and then the substrate is transported to a water rinsing tank to be washed.

  In the above-described conventional apparatus, since the developer is continuously supplied in a shower shape during the processing time, the amount of the developer used is increased and the running cost is high. In addition, since the washing process is performed on the developed substrate in a horizontal posture, the washing water stays near the center of the substrate. For this reason, the efficiency of the water washing is poor, the water washing becomes insufficient, or it takes a long time for the water washing, and the board is bent so as to protrude downward due to the weight of the washing water retained in the center of the board. There is a risk of breakage, and the retention of washing water at the center of the substrate is promoted.

  Such a problem is not a specific problem that occurs when the washing process is performed after the development process, but a problem that also occurs when the other washing process is performed, for example, when an etching solution is supplied as a processing solution to the substrate and then the washing process is performed. This is a problem that occurs in common in the substrate processing apparatus and the substrate processing method for performing the water washing process after supplying the processing liquid to the substrate and processing it.

  Accordingly, an object of the present invention is to solve the above technical problems, reduce the consumption of processing liquid, reduce the running cost, perform efficient water washing, and prevent the substrate from being damaged. An apparatus and a substrate processing method are provided.

The invention described in claim 1 for achieving the above object is a substrate processing apparatus for supplying a processing liquid to a surface of a substrate for processing.
A transport unit configured to transport the substrate in a horizontal position; a liquid layer forming unit configured to supply a processing liquid to the surface of the substrate transported in a horizontal position and form a liquid layer on the substrate surface by surface tension of the processing liquid; and the liquid layer A process advancing means for holding the substrate on which the liquid layer is formed and processing the liquid layer with the processing liquid; an attitude converting means for converting the attitude of the substrate after the liquid layer processing to an inclined attitude; and an inclination by the attitude converting means And a processing liquid supply means for supplying the processing liquid to the surface of the substrate in a posture.

  The invention according to claim 2 includes a step of supplying the processing liquid to the surface of the substrate transported in a horizontal posture and forming a liquid layer of the processing liquid on the substrate surface by the surface tension of the processing liquid, and the supply of the processing liquid is stopped. Holding the substrate on which the liquid layer of the processing liquid is formed and proceeding with the processing of the liquid layer with the processing liquid; converting the posture of the substrate into an inclined posture after the processing with the liquid layer of the processing liquid; And a step of supplying the processing liquid to the surface of the substrate converted into a posture.

  According to the first and second aspects of the present invention, a new processing liquid can be supplied to the surface of the substrate after the processing of the liquid layer with the processing liquid, and the last processing step can be processed with the new clean processing liquid. The substrate surface at the end can be cleaned.

  Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.

  FIG. 1 is a side view schematically showing the overall configuration of the substrate processing apparatus according to the first embodiment of the present invention. The substrate processing apparatus 1 supplies a developing solution, which is a processing solution, to a surface of a rectangular LCD glass substrate (hereinafter simply referred to as a substrate) S to perform a developing process, and then supplies a cleaning solution to perform a cleaning process. is there.

  The substrate processing apparatus 1 includes a liquid layer forming chamber 2 for supplying a developer to the surface of a substrate S transported in a horizontal posture and forming a developer liquid layer on the surface of the substrate S by the surface tension of the developer, The processing progress chamber 3 for holding the substrate S on which the liquid layer of the liquid is formed and proceeding the processing of the liquid layer with the developing solution, and the posture of the substrate S after the processing with the liquid layer of the developing solution is inclined from the horizontal posture. A posture changing chamber 4 for converting to a substrate, a cleaning chamber 5 for supplying and cleaning the surface of the substrate S in an inclined posture, a drying chamber 6 for drying the substrate S after cleaning, and a substrate after drying in a horizontal posture. And a posture conversion chamber 7 to be returned.

  In the liquid layer forming chamber 2, a transport roller 21 that transports the substrate S in a horizontal posture, and a developer is supplied to the surface of the substrate S that is transported in a horizontal posture by the transport roller 21, and the developer liquid is supplied to the upper surface thereof. A developer supply nozzle 22 for forming a layer is provided. As shown in FIG. 2, the transport roller 21 supports only a part of the rear edge of the substrate S and a part of the center of the rear surface without touching the central portion of the rear surface of the substrate S, and prevents the substrate S from meandering. A so-called flanged edge support roller having a flange 21a is used. Further, the developer stored in the developer tank 11 is supplied to the developer supply nozzle 22 by the pump 12.

  The processing progress chamber 3 is provided with a transport roller 31 that receives and holds the substrate S transported by the transport roller 21 in a state where the developer layer is formed on the upper surface from the liquid layer forming chamber 2. . The transport roller 31 is configured by providing support disks 31b that are in contact with the lower surface of the substrate at a plurality of locations on one rotating shaft 31a.

  FIG. 3 is a plan view of the posture conversion chamber 4. The posture conversion chamber 4 is provided with a transport roller 41 that receives and holds the substrate S transported by the transport roller 31 in a state where a developer liquid layer is formed from the processing progress chamber 3. The transport roller 41 has the same configuration as the transport roller 31. In addition, since the transfer rollers 31 and 41 may cause some meandering during the transfer to the substrate S and cause a positional shift from side to side as indicated by a broken line in FIG. On the downstream side in the direction, there is provided a position correcting means for correcting the position shift when the position shift occurs in the substrate S and positioning the substrate S at a correct position (shown by a solid line in FIG. 3). Such position correcting means is composed of a roller 47 that contacts the edge of the substrate S that has been moved forward and backward by the cylinder 46 to cause a positional shift and guides it to the correct position. Further, the posture conversion chamber 4 includes an inclination mechanism that can switch the posture of the transport roller 41 between a state in which the substrate S is held in a horizontal posture and a state in which the substrate S is held in a right-down slanted posture in the substrate transport direction. 42 is provided. The tilt mechanism 42 includes a roller frame 43 that rotatably supports the left and right sides of the transport roller 41, and a substrate transport direction in which the roller frame 43 is rotatably supported on the right side in the substrate transport direction (substrate transport direction). And a cylinder 45 which is coupled to the roller frame 43 and lifts the left side of the roller frame 43 on the left side in the substrate transport direction.

  With the tilt mechanism 42, the posture conversion chamber 4 receives the substrate S transported in the horizontal posture from the processing progress chamber 3 by the transport roller 31 with the transport roller 41 in the horizontal posture as shown in FIG. As shown in FIG. 5, the cylinder 45 is extended to incline the transport roller 41, so that the substrate S can be transported in a state where the substrate S is tilted downward to the right in the substrate transport direction.

A development processing chamber is constituted by the liquid layer forming chamber 2, the processing progress chamber 3, and the attitude changing chamber 4, and receiving trays T2, T3, and T4 for collecting the developer are provided below these chambers.
The developer collected by these trays T2, T3, T4 is collected in the developer tank 11 and reused.

  The cleaning chamber 5 receives the substrate S transferred from the posture conversion chamber 4 by the transfer roller 41 in an inclined posture and transfers the substrate S in the same inclined posture, and the substrate S transferred in an inclined posture by the transfer roller 51. The cleaning liquid supply nozzle 52 supplies the cleaning liquid to the upper surface, the cleaning liquid supply nozzle 53 supplies the cleaning liquid to the lower surface of the substrate S, and the roll brush 54 that contacts and cleans the lower surface of the substrate S. Yes. The cleaning liquid supply nozzles 52 and 53 are connected to an ultrapure water supply source 55 as a cleaning liquid. The transport roller 51 is formed of a flanged edge support roller similar to the transport roller 21.

  The drying chamber 6 receives the substrate S transported from the cleaning chamber 5 by the transport roller 51 in an inclined posture and transports the substrate S in the same tilted posture, and the upper surface of the substrate S transported in the tilted posture by the transport roller 61. The air knife 62 blows air and blows away the cleaning liquid to dry, and the air knife 63 blows air against the lower surface of the substrate S and blows the cleaning liquid to dry. The conveyance roller 61 is formed of a flanged edge support roller similar to the conveyance roller 21.

  The posture conversion chamber 7 is provided with a transport roller 71 that receives and holds the substrate S transported by the transport roller 61 from the drying chamber 6. The conveyance roller 71 is formed of a flanged edge support roller similar to the conveyance roller 21. Further, the posture conversion chamber 7 has an inclination mechanism capable of switching the posture of the transport roller 71 between a state in which the substrate S is held in a horizontal posture and a state in which the substrate S is held in a right-down inclined posture in the substrate transport direction. 72 is provided. The configuration of the tilting mechanism 72 is substantially the same as that of the tilting mechanism 42, and thus detailed illustration and description thereof will be omitted.

  Although not shown in FIG. 1, each chamber is partitioned by a partition that partitions the mists of the processing liquid so as not to enter each other. Each of the transport rollers 21, 31, 41, 51, 61, 71 is rotationally driven by a drive source (not shown), and the entire operation of the substrate processing apparatus 1 including on / off of each drive and the drive speed is not shown. It is controlled by a control unit comprising a microcomputer.

  Next, the operation of the substrate processing apparatus 1 based on the control of the control unit and the processing method based on the operation will be described in detail.

  A substrate S supplied from a substrate supply device (not shown) is transported in a horizontal posture by a transport roller 21 and passes through the liquid layer forming chamber 2 at a constant speed, while developing from the developer supply nozzle 22 on the surface of the substrate S. The liquid is supplied, and the supplied developer forms a liquid layer of the developer on the surface of the substrate S by surface tension.

  The substrate S on which the liquid layer of the developer is formed in the liquid layer forming chamber 2 is transferred from the transport roller 21 to the transport roller 31 and is transported to the processing progress chamber 3. When the transport roller 31 receives the substrate S and carries it into the processing progress chamber 3, the transport roller 31 temporarily stops transporting the substrate S by driving for a predetermined time to stop the substrate S or slows the transport speed. Then, processing of the liquid layer formed on the upper surface with a developing solution is advanced to perform so-called paddle development. During this time, the transport roller 31 is stopped or decelerated, so that the subsequent substrate S is transported in consideration of a distance that avoids collision between the substrates.

  In this processing progress chamber 3, a new developing solution is not supplied to the upper surface of the substrate S, and the developing process is performed only with the developing solution supplied in the liquid layer forming chamber 2, thereby reducing the consumption of the developing solution. it can. In the processing progress chamber 3, when a flanged edge support roller such as the transport roller 21 is used, the edge of the substrate S comes into contact with the flange and is held on the upper surface of the substrate S by surface tension. Since the liquid may come into contact with the collar portion and the developer may flow out, here, the transport roller 31 that is in contact with and supports only the lower surface of the substrate S is used. If there is no problem in terms of the amount of the developer flowing out, the use of the edge support roller with a hook is preferable in terms of the stability of the substrate conveyance. Further, while the substrate S is being transported on the transport roller 31, the substrate S may be displaced from side to side as indicated by a two-dot chain line in FIG. Corrected by 4.

  When the development processing is performed for a predetermined time in the processing progress chamber 3, the substrate S is transferred from the transport roller 31 to the transport roller 41 with the developer layer formed on the upper surface and transported to the attitude conversion chamber 4. Is done. When the substrate S is transported onto the transport roller 41 of the posture conversion chamber 4, the cylinder 46 first drives the roller 47 to correct the position of the substrate S to the correct transport position. Next, the cylinder 45 of the tilt mechanism 42 is extended to tilt the transport roller 41 so that the substrate S is tilted to the right side in the substrate transport direction. Note that this posture conversion operation may be performed while the transport roller 41 is driven, or may be performed after the transport roller 41 is temporarily stopped. Due to the inclination of the substrate S, almost all of the developer in the liquid layer on the upper surface of the substrate S flows down, so that the amount of the developer taken out to the subsequent process is very small. In addition, the developer that has flowed down is collected in the lower tray T4.

  In this posture changing chamber 4, a developer nozzle 49 indicated by a broken line in FIG. 1 is provided to place the substrate S in an inclined posture, and then a new developer is supplied to the surface of the substrate S from a developer supply source (not shown). May be. With this configuration, a new developer can be supplied to the surface of the substrate S that has completed paddle development, and the last of the development process can be processed with the new clean developer, so that the surface of the substrate S at the end of development is in a clean state. it can.

  The substrate S which has been inclined in the posture conversion chamber 4 and is transferred by the transfer roller 41 is transferred to the transfer roller 51 and transferred to the cleaning chamber 5 with the same inclination posture. The conveyance from the posture conversion chamber 4 to the cleaning chamber 5 is performed by driving the conveyance rollers 41 and 51 at a higher speed than other conveyance operations. Thus, the cleaning liquid can be supplied to the entire surface of the substrate S with as little time difference as possible to wash away the developer that is in contact with the substrate S, and the development processing can be completed quickly without unevenness.

  In the cleaning chamber 5, the cleaning liquid is supplied from the cleaning liquid supply nozzles 52 and 53 to the upper surface and the lower surface of the substrate S conveyed in an inclined posture by the conveying roller 51 for cleaning. At this time, since the substrate S remains in an inclined posture, the cleaning liquid flows down quickly, the cleaning liquid does not stay near the center of the substrate S, and the water cleaning efficiency is high, and the cleaning liquid is sufficient in a short time. The substrate S can be washed with water, and there is no possibility that the substrate S is bent or damaged by the weight of the cleaning liquid staying in the center of the substrate S. Here, a roll brush 54 is provided on the lower surface side of the substrate S where the development process is not performed so that a sufficient cleaning effect can be obtained. Here, some developer flows around the back surface of the substrate S when supplying the developer in the liquid layer forming chamber 2, and some developer remains attached even when the substrate S is inclined. If an alkali developer is used as the developer, the alkali component also acts as a detergent. Therefore, sufficient cleaning is performed in combination with the action of the roll brush 54 provided on the lower surface side of the substrate S. The effect is obtained. The cleaning liquid (ultra pure water) is supplied from the cleaning liquid supply nozzle 53 to the lower surface after cleaning by the roll brush 54, and the developer component is sufficiently removed.

  The substrate S transferred from the cleaning chamber 5 by the transfer roller 51 in an inclined posture is transferred to the transfer roller 61 and transferred to the drying chamber 6 while maintaining the same inclined posture. In the transfer chamber 6, air is blown from the air knives 62 and 63 onto the upper and lower surfaces of the substrate S transferred in an inclined posture by the transfer roller 61, and the cleaning liquid is blown off and dried. Since the substrate S is in an inclined posture, most of the cleaning liquid has already flowed down, but the substrate S dries more quickly and uniformly by the action of the air knives 62 and 63.

  The substrate S transferred from the drying chamber 6 by the transfer roller 61 in an inclined posture is transferred to the transfer roller 71 and transferred to the posture changing chamber 7 with the same inclined posture. When the substrate S is carried onto the transport roller 71 in the posture conversion chamber 7, the cylinder (not shown) of the tilt mechanism 72 contracts to bring the transport roller 71 into a horizontal state and bring the substrate S into a horizontal posture. Then, after the posture changing operation, the transport roller 71 is driven to carry the substrate S to a substrate receiving device (not shown).

  In the embodiment described above, the processing progress chamber 3 is used as the processing progressing means for holding the substrate S on which the liquid layer of the developer is formed and the processing of the liquid layer by the developer is performed. Although the posture conversion chambers 4 are provided as posture conversion means for converting the posture of the substrate S after the processing into a tilted posture, they can be configured integrally. That is, the processing chamber 3 may be omitted from the substrate processing apparatus 1 of the above embodiment, and the posture changing chamber 4 may be provided following the liquid layer forming chamber 2. With this configuration, the posture changing chamber 4 serves as both posture changing means and processing progress means. When the substrate S on which the liquid layer of the developer is formed in the liquid layer forming chamber 2 is transported to the attitude changing chamber 4, the transport of the substrate S by driving the transport roller 41 is temporarily stopped for a predetermined time to thereby stop the substrate S. Is temporarily stopped, or the feeding speed is slowed down, so that the processing of the liquid layer formed on the upper surface with the developing solution is advanced to perform paddle development. When the development process is performed for a predetermined time, the cylinder 45 of the tilt mechanism 42 of the posture conversion chamber 4 is extended to tilt the transport roller 41, and the substrate S is tilted to the right in the substrate transport direction. What is necessary is just to flow down the developing solution of the liquid layer on the upper surface of the substrate S. According to such a configuration, it is not necessary to provide the processing progress chamber 3, so that the apparatus can be further downsized. In this case as well, the cylinder 46 and the roller 47, which are position correction means, may be provided in the posture changing chamber 4. However, in this case, the position correction of the substrate S by these requires the paddle development for a predetermined processing time, and the substrate is corrected. It is good to carry out immediately before the attitude | position conversion which makes S into an inclination attitude | position. This is to prevent the developer from flowing down during the development time, as in the case where the flanged edge support roller is not used in the processing progress chamber 3.

  The developer supply nozzle 22 used in the present invention may be one that supplies the developer in the form of a spray or one that has a slit-like discharge port and supplies the developer in the form of a curtain. A plurality of seeds can be used in combination. Further, as a means for placing the substrate in an inclined posture, in addition to the configuration in which one side of the substrate is lifted as in the above-described embodiment, a configuration in which one side is lowered may be employed. The present invention is not limited to a development processing apparatus, and can be applied when performing various processes such as an etching process, a peeling process, and a preliminary cleaning process.

It is a typical side view showing the whole substrate processing apparatus composition of a 1st embodiment of the present invention. It is a front view which shows a conveyance roller. It is a top view of a posture change room. It is a perspective view which shows an attitude | position conversion chamber. It is a perspective view which shows an attitude | position conversion chamber.

Explanation of symbols

2 Liquid layer formation chamber 3 Processing progress chamber 4 Posture change chamber 5 Cleaning chamber

Claims (2)

In a substrate processing apparatus for supplying a processing liquid to the surface of a substrate for processing,
A transport unit configured to transport the substrate in a horizontal position; a liquid layer forming unit configured to supply a processing liquid to the surface of the substrate transported in a horizontal position and form a liquid layer on the substrate surface by surface tension of the processing liquid; and the liquid layer A process advancing means for holding the substrate on which the liquid layer is formed and processing the liquid layer with the processing liquid; an attitude converting means for converting the attitude of the substrate after the liquid layer processing to an inclined attitude; and an inclination by the attitude converting means A substrate processing apparatus, comprising: a processing liquid supply unit configured to supply the processing liquid to the surface of the substrate in a posture. A process of supplying a processing liquid to the surface of the substrate transported in a horizontal posture and forming a liquid layer of the processing liquid on the substrate surface by the surface tension of the processing liquid, and forming a liquid layer of the processing liquid by stopping the supply of the processing liquid A step of holding the processed substrate and advancing the processing of the liquid layer with the processing liquid, a step of converting the posture of the substrate into an inclined posture after the processing by the liquid layer of the processing liquid is performed, and a flow of the processing liquid And a step of supplying the processing liquid to the surface of the substrate converted into a posture.

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