JP2007009202A - マイケル付加反応を促進するための方法 - Google Patents
マイケル付加反応を促進するための方法 Download PDFInfo
- Publication number
- JP2007009202A JP2007009202A JP2006172293A JP2006172293A JP2007009202A JP 2007009202 A JP2007009202 A JP 2007009202A JP 2006172293 A JP2006172293 A JP 2006172293A JP 2006172293 A JP2006172293 A JP 2006172293A JP 2007009202 A JP2007009202 A JP 2007009202A
- Authority
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- Japan
- Prior art keywords
- mixture
- functional
- functional mixture
- michael
- alkali metal
- Prior art date
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- Granted
Links
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- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000004715 ethylene vinyl alcohol Substances 0.000 description 1
- 229920006226 ethylene-acrylic acid Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011151 fibre-reinforced plastic Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000007775 flexo coating Methods 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- HZXMRANICFIONG-UHFFFAOYSA-N gallium phosphide Chemical compound [Ga]#P HZXMRANICFIONG-UHFFFAOYSA-N 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000011086 glassine Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- 238000007757 hot melt coating Methods 0.000 description 1
- JPWGVWGUTMQFFK-UHFFFAOYSA-N hydroxymethyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCO.CC(=O)CC(=O)OCO.CC(=O)CC(=O)OCO JPWGVWGUTMQFFK-UHFFFAOYSA-N 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229960002479 isosorbide Drugs 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- WRIRWRKPLXCTFD-UHFFFAOYSA-N malonamide Chemical class NC(=O)CC(N)=O WRIRWRKPLXCTFD-UHFFFAOYSA-N 0.000 description 1
- 150000002690 malonic acid derivatives Chemical class 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 238000009828 non-uniform distribution Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000003444 phase transfer catalyst Substances 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052572 stoneware Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- HLLICFJUWSZHRJ-UHFFFAOYSA-N tioxidazole Chemical compound CCCOC1=CC=C2N=C(NC(=O)OC)SC2=C1 HLLICFJUWSZHRJ-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/02—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by the reacting monomers or modifying agents during the preparation or modification of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31935—Ester, halide or nitrile of addition polymer
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Abstract
【解決手段】0.01μm〜500μmの平均粒子サイズを有する、均一に分散された固体反応プロモーターが、少なくとも1つの多官能性マイケル供与体および少なくとも1つの多官能性マイケル受容体の硬化性混合物を調製するために開示される。得られた硬化性混合物は、コーティング、接着剤、シーラントおよびエラストマーとして有用である。
【選択図】なし
Description
本発明は、エネルギー省により授与された契約No.FG36−04GO14317の下で政府援助においてなされた。政府は、本発明において特定の権利を有する。
0.01μm〜500μmの平均粒子サイズを有する1つ以上の均一に分散された固体反応プロモーターを、少なくとも1つの多官能性マイケル供与体および少なくとも1つの多官能性マイケル受容体をさらに含む硬化性官能性混合物の一部、最高ではその全部に添加する工程。
Morecure(商標)2000=ビスフェノールAジグリシジルエーテルのジアクリレート(Rohm and Haas社製)。
SR−306HP(商標)=トリプロピレングリコールジアクリレート(Sartomer社製)。
Miramer(商標)M3160 =エトキシル化(6)トリメチロールプロパントリアクリレート、分子量560(Miwon Commercial社製造、Rahn USA社販売)。
SS−200=ケイ酸ナトリウム粉末、200メッシュサイズ(PQ社製)。
Cab−o−sil(商標)M−5=ヒュームドシリカ(Cabot社製)。
Jeffamine(商標)D−230 =ポリエーテルジアミン(Huntsman社製)。
GTAA=グリセロールトリスアセトアセテート。
FRP=繊維強化プラスチック。
モノマー混合物の調製
Morcure(商標)2000(1650g)およびSR−306HP(商標)(1350g)を4リットルのステンレス鋼ビーカーの中に計量した。混合物を機械的に攪拌し、そして50℃にまで暖め、透明な溶液を作った。
モノマー混合中の均一に分散した固体触媒の調製
1.4リットルの水平ビーズミル(Dynomill KDL−Pilot、CB Mill製)を1mmケイ酸ジルコニウムビーズ(2644g)で満たした。実施例1(2275g)からのモノマー混合物および炭酸ナトリウム(1225g)を4リットルのステンレス鋼ビーカーの中に計量した。混合物を機械的に混ぜ、そして水平ビーズミルにより145分間回転をかけた。得られた混合物は、35%の炭酸ナトリウム、36%のMorcure(商標)2000、29%のトリプロピレングリコールジアクリレートという組成を有した。粉末化触媒の体積平均粒子サイズは、Coulter LS−120レーザー光分散装置により決定され、0.84μmであった。
不均一固体触媒粉末の調製
炭酸ナトリウムを35メッシュふるいおよび60メッシュふるいを使って分画した。35メッシュふるいを通って、そして60メッシュふるいの上に残った物質を使用した。ふるいの目の大きさに基づいて、得られた粉末は、粒子サイズ範囲250〜500μm、平均粒子サイズ380μmを有すると推測された。
可溶性触媒/モノマー溶液の調製
Morcure(商標)2000(64.4g)、SR−306HP(商標)(27.6g)および酢酸カリウム(4.5g)を70℃に加熱し、そして1時間攪拌した。熱いままの混合物を濾過し、溶けない固体を取り除き、次いで室温にまで冷やした。少量のサンプルを0.1N塩酸で滴定し、溶けている酢酸カリウム触媒の量を決定した。濾過された溶液は、1.9%の酢酸カリウム、68.7%のMorcure(商標)2000および29.4%のトリプロピレングリコールジアクリレートという組成を有していた。
均一に分散された固体触媒を含む接着剤混合物の調製
Morcure(商標)2000(11.95g)、SR−306HP(商標)(4.77g)および実施例2からの微粉砕触媒/モノマー混合物(2.57g)を50℃に加熱し、そして攪拌して、66.7%のMorcure(商標)2000、28.6%のトリプロピレングリコールジアクリレートおよび4.7%の微粉砕炭酸ナトリウム固体触媒という組成を有する混合物を生成させた。この混合物は、室温において24時間後も沈殿の兆候を示さない均一な懸濁物であった。
不均一固体触媒を含む接着剤混合物の調製
Morcure(商標)2000(12.88g)、SR−306HP(5.52g)および実施例3からのふるいにかけられた触媒粉末を50℃に加熱し、そして攪拌して、66.7%のMorcure(商標)2000、28.6%のSR−306HPおよび4.7%の粗い炭酸ナトリウム固体触媒という組成を有する混合物を生成させた。この懸濁物は、室温において24時間後に容器の底に沈殿する目に見える触媒粒子を有していた。この混合物を使用直前に攪拌し、触媒が混合物の中で懸濁するのを確実にした。
溶解している触媒を含む接着剤混合物の調製
Morcure(商標)2000(1.79g)、SR−306HP(商標)(0.77g)および実施例4からの溶解性触媒溶液を50℃に加熱し、そして攪拌して、68.9%のMorcure(商標)2000、29.5%のSR−306HP(商標)および1.6%の酢酸カリウム溶解性触媒という組成を有する混合物を生成させた。
接着剤混合物のポットライフ
実施例5、6および7の接着剤混合物ならびにトリメチロールプロパントリス−アセトアセテートのサンプルを35℃において平衡状態にした。それぞれの接着サンプルに、11.61gのトリメチロールトリス−アセトアセテートを加えた。得られた混合物を短時間混合し、次いでBrookfield LVDT粘度計を使って、100rpmにおいてスピンドル25を用いて粘度を測定した。最初の粘度を記録した。ポットライフを最初の粘度の2倍の粘度となった時間として記録した。結果を表1にまとめる。
ラミネートの調製
トリメチロールプロパントリス−アセトアセテート(11.61g)を実施例5、6および7の接着剤混合物の作製したばかりのサンプルに加えた。そのサンプルを短時間混合し、PolyType実験用コーターを使って印刷されたペットフィルム(Dupont 48LBT)の上にロールコーティングし、次いで1ミル厚の線形低密度ポリエチレンフィルム(Pliant GF−10)を接着剤コーティングと接触させた。ペットフィルム上の印刷は、Color Converting Industries社製のSealtech青インクおよび白インクからなっていた。両方のインクは、残留酸官能性を含むと考えられている。インクコート重量を1.9g/m2として重量測定法で測定した。
ラミネートの外観
実施例9からのラミネートのサンプルを、25倍立体顕微鏡を使って目視により評価した。実施例5および7からの接着剤を使って調製したラミネートは、滑らかで均一に見えた。実施例6からの接着剤を使って調製したラミネートは、その外観を損なう目に見える砂模様を有していた。
ラミネートの接着
実施例8からのラミネートのサンプルを、Tピール接着について以下のように試験した。各ラミネートの1”の広さの細片を切り出し、そしてその細片を10in/分の速度において引張試験機で引き離した。2つのフィルムを分離するのに必要な最大の力として、Tピール接着を記録した。4つの細片を各ラミネートについてテストし、結果が平均された。結果は、以下の表3のようになった。
アクリル系塩基
アクリル系塩基を以下の成分を混合することにより作製した。SS−200およびCab−o−sil(商標)M5を、高速ミキサーを使って残りの成分の中に分散させた。
接着剤
実施例12のアクリル系塩基をGTAAと混ぜた。GTAAに対するアクリル系塩基の重量比は、80.34〜19.66であった。
接着剤の評価
実施例13の接着剤をラップ剪断試験によって評価した。
基体の長方形片を、目的の組成物を使って同じタイプの基体の別の長方形片に接着させ、複合構造物を形成させた。その複合構造物の一端には、基体の長方形片のフリー部分があった。また、他端には、基体の長方形片の一部があった。基体の「フリー」部分とは、別の基体片のいずれの部分にも隣接していない部分である。
注(2):FRP基体が裂けたときにサンプルが破損した。
Claims (11)
- 少なくとも1つの多官能性マイケル供与体および少なくとも1つの多官能性マイケル受容体をさらに含む硬化性官能性混合物の一部、最高ではその全部に、0.01μm〜500μmの平均粒子サイズを有する1つ以上の均一に分散された固体反応プロモーターを添加する工程;
を含む、官能性混合物を硬化する方法。 - 1つ以上の均一に分散された固体反応プロモーターが:
アルカリフェノキシド塩、アルカリ金属酸化物、アルカリ金属水酸化物、アルカリ土類金属酸化物、アルカリ土類金属水酸化物、アルカリ金属以外の金属の酸化物、およびアルカリ金属以外の金属の水酸化物、アルカリ金属ケイ酸塩、アルカリ金属以外の金属のケイ酸塩、アルカリ土類金属ケイ酸塩、アミン、アミン−官能性ポリマー、アミン−官能性樹脂、塩基性金属塩、アルカリ金属炭酸塩、アルカリ土類金属炭酸塩、アルカリ金属リン酸塩、アルカリ土類金属リン酸塩、リン酸水素アルカリ金属塩、リン酸水素アルカリ土類金属塩、アルカリ金属リン酸エステル、アルカリ土類金属リン酸エステル、アルカリ金属パイロリン酸塩、アルカリ土類金属パイロリン酸塩、1〜22個の炭素原子を有するアルカリ金属カルボキシレート、1〜22個の炭素原子を有するアルカリ土類金属カルボキシレート、および1〜22個の炭素原子を有する金属カルボキシレート:からなる群から選択される、請求項1に記載の方法。 - 硬化性官能性混合物が、0〜5重量%の:(a)水、または(b)1つ以上の酸、または(c)1つ以上の酸無水物、またはそれらの組合せ:をさらに含む、請求項1に記載の方法。
- 均一に分散された固体反応プロモーターが、0.1μm〜20μmの平均粒子サイズを有する、請求項1に記載の方法。
- 硬化した官能性混合物と接触する少なくとも1つの基体を含む、被覆された物品であって;
該硬化した官能性混合物が(a)0.01μm〜500μmの平均粒子サイズを有する1つ以上の均一に分散された固体反応プロモーター;(b)少なくとも1つの多官能性マイケル供与体;および(c)少なくとも1つの多官能性マイケル受容体;をさらに含む:
被覆された物品。 - 硬化した官能性混合物と接触する少なくとも2つの基体を含む接着された物品であって;
該硬化した官能性混合物が(a)0.01μm〜500μmの平均粒子サイズを有する1つ以上の均一に分散された固体反応プロモーター;(b)少なくとも1つの多官能性マイケル供与体;および(c)少なくとも1つの多官能性マイケル受容体;をさらに含む:
接着された物品。 - (a)0.01μm〜500μmの平均粒子サイズを有する1つ以上の均一に分散された固体反応プロモーター;(b)少なくとも1つの多官能性マイケル供与体;および(c)少なくとも1つの多官能性マイケル受容体:
を含む硬化性官能性混合物。 - 請求項7の硬化性官能性混合物から製造されたラミネート接着剤。
- 請求項7の硬化性官能性混合物から製造されたシーラント。
- 請求項7の硬化性官能性混合物から製造されたエラストマー。
- 請求項7の硬化性官能性混合物から製造された発泡体。
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US11/444,778 US7799943B2 (en) | 2005-06-24 | 2006-05-30 | Method for promoting Michael addition reactions |
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Cited By (4)
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JP2008279760A (ja) * | 2007-05-14 | 2008-11-20 | Rohm & Haas Co | 硬化性および硬化した木材粒子複合体ならびにその製造法 |
JP2008290446A (ja) * | 2007-05-14 | 2008-12-04 | Rohm & Haas Co | 硬化性および硬化した木材粒子複合体ならびにその製造法 |
WO2009119588A1 (ja) * | 2008-03-24 | 2009-10-01 | アイカ工業株式会社 | 樹脂組成物、ハードコート剤、フィルム、及び成型体の製造方法 |
JP2018535853A (ja) * | 2015-12-02 | 2018-12-06 | ダウ グローバル テクノロジーズ エルエルシー | 付加製造炭素マイケル付加物品及びそれらを作製する方法 |
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EP2170923B1 (en) * | 2007-06-25 | 2015-10-14 | Sun Chemical Corporation | Process for preparation of oligomeric or polymeric compounds using selective michael addition |
MX2014009992A (es) * | 2012-03-09 | 2014-11-25 | Ccp Composites Llc | Resina termoendurecible de acetoacetilo para recubrimiento en gel sin compustos orgánicos volátiles. |
US9598549B2 (en) | 2012-09-28 | 2017-03-21 | Dow Global Technologies Llc | Functionalized oligomers |
US9023976B2 (en) | 2013-05-01 | 2015-05-05 | Robert Bernard Login | Amide-imide compounds and their corresponding polymers |
KR101881215B1 (ko) | 2016-09-13 | 2018-08-16 | 성균관대학교산학협력단 | 화합물, 이를 이용하는 비대칭 마이클 첨가 반응을 이용한 화합물의 제조 방법, 및 페니버트 화합물의 제조 방법 |
BR112019022571B1 (pt) | 2017-05-11 | 2024-02-06 | Ecolab Usa Inc | Composição de tratamento de piso, e, método para limpar ou restaurar um piso |
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DE602005008661D1 (de) * | 2004-05-03 | 2008-09-18 | Rohm & Haas | Michael-addierungs Zusammensetzungen |
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Cited By (4)
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JP2008279760A (ja) * | 2007-05-14 | 2008-11-20 | Rohm & Haas Co | 硬化性および硬化した木材粒子複合体ならびにその製造法 |
JP2008290446A (ja) * | 2007-05-14 | 2008-12-04 | Rohm & Haas Co | 硬化性および硬化した木材粒子複合体ならびにその製造法 |
WO2009119588A1 (ja) * | 2008-03-24 | 2009-10-01 | アイカ工業株式会社 | 樹脂組成物、ハードコート剤、フィルム、及び成型体の製造方法 |
JP2018535853A (ja) * | 2015-12-02 | 2018-12-06 | ダウ グローバル テクノロジーズ エルエルシー | 付加製造炭素マイケル付加物品及びそれらを作製する方法 |
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US20090275713A1 (en) | 2009-11-05 |
DE602006012585D1 (de) | 2010-04-15 |
KR20060135523A (ko) | 2006-12-29 |
JP4404877B2 (ja) | 2010-01-27 |
US7799943B2 (en) | 2010-09-21 |
EP1741741B1 (en) | 2010-03-03 |
KR100849400B1 (ko) | 2008-07-31 |
EP1741741A3 (en) | 2007-03-14 |
EP1741741A2 (en) | 2007-01-10 |
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