JP2006517244A - セルロース誘導体および吸湿性ポリマーによる洗濯洗剤の洗浄性能の向上 - Google Patents
セルロース誘導体および吸湿性ポリマーによる洗濯洗剤の洗浄性能の向上 Download PDFInfo
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- JP2006517244A JP2006517244A JP2006501675A JP2006501675A JP2006517244A JP 2006517244 A JP2006517244 A JP 2006517244A JP 2006501675 A JP2006501675 A JP 2006501675A JP 2006501675 A JP2006501675 A JP 2006501675A JP 2006517244 A JP2006517244 A JP 2006517244A
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- acid
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- cellulose
- hygroscopic
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/09—Cellulose ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
Abstract
Description
で示される4級化脂肪酸トリエタノールアミンエステル塩である。本発明においての使用できるエステルクォートの典型的な例は、カプロン酸、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、イソステアリン酸、ステアリン酸、オレイン酸、エライジン酸、アラキジン酸、ベヘン酸およびエルカ酸並びに例えば天然油脂の加圧開裂から得られるようなそれらの工業グレードの混合物に基づく生成物である。好ましいものとしては、工業グレードC12/18ココナツ脂肪酸、特に部分水素化C16/18獸脂またはパーム脂肪酸、エライジン酸豊富C16/18脂肪酸カットを使用するものである。4級化エステルを調製するために、脂肪酸およびトリエタノールアミンは、1.1:1〜3:1のモル比で通常使用されうる。エステルクォートの性能比率に関して、1.2:1〜2.2:1、好ましくは1.5:1〜1.9:1の使用比が、特に有利であることが見出されている。好ましく使用されるエステルクォートは、1.5〜1.9のエステル化度を有するモノ−、ジ−およびトリエステルの工業グレード混合物であり、工業グレードC16/18獸脂またはパーム脂肪酸から誘導される(ヨード価0〜40)。式中、R1COが16〜18個の炭素原子を有するアシル基であり、R2がR1COであり、R3が水素原子であり、R4がメチル基であり、m、nおよびpがそれぞれ0であり、Xがメチルスルフェートである式(I)の4級化脂肪酸トリエタノールアミンエステル塩が特に有用であることが見出されている。
で示されるジエタノールアルキルアミンとの4級化エステル塩である。
Claims (15)
- 繊維製品の洗浄における洗濯洗剤の洗浄性能を向上させるための、セルロースのアルキル化およびヒドロキシアルキル化によって得られる汚れ解離性セルロース誘導体と吸湿性ポリマーとの組み合わせの使用。
- 既に洗浄されたおよび/または汚れる前にセルロース誘導体および任意の吸湿性ポリマーの存在下で後処理された繊維製品の洗浄における洗浄性能を向上させるための、セルロースのアルキル化およびヒドロキシアルキル化によって得られる汚れ解離性セルロール誘導体と吸湿性ポリマーとの組み合わせの使用。
- 繊維製品が綿からなるか、または綿を含んでなる請求項1または2に記載の使用。
- 繊維製品の洗浄における洗濯洗剤の洗浄性能を向上させるための、セルロースのアルキル化およびヒドロキシアルキル化によって得られる汚れ解離性セルロース誘導体と、吸湿性ポリマーと、ジカルボン酸および任意のポリマージオールからなるポリエステル活性汚れ解離性ポリマーとの組み合わせの使用。
- セルロース誘導体は、C1−C10基、特にC1−C3基によってアルキル化されており、さらに、C2−C10ヒドロキシアルキル基、特にC2−C3基ヒドロキシアルキル基を有する請求項1〜4のいずれかに記載の使用。
- セルロース誘導体は、アンヒドログリコースモノマー単位につき、平均して、0.5〜2.5個、特に1〜2個のアルキル基および0.02〜0.5個、特に0.05〜0.3個のヒドロキシアルキル基を有する請求項1〜5のいずれかに記載の使用。
- セルロース誘導体の平均分子量は10000D〜150000Dである請求項1〜6のいずれかに記載の使用。
- セルロース誘導体の平均分子量は40000D〜120000D、特に80000D〜110000Dである請求項7に記載の使用。
- 吸湿性ポリマーがポリビニルピロリドン、ポリビニルアルコール、ポリアルキレングリコールおよび/またはアクリル酸、メタアクリル酸およびマレイン酸のホモポリマー並びにそれらのコポリマーから、特にポリアクリル酸から選択されることを特徴とする請求項1〜8のいずれかに記載の使用。
- 吸湿性ポリマーは、500000D〜700000D、特に550000D〜650000Dである請求項9に記載の使用。
- セルロースのアルキル化およびヒドロキシアルキル化によって得られる汚れ解離性セルロース誘導体と吸湿性ポリマーを含有する洗濯洗剤組成物。
- 0.1〜5重量%、特に0.5〜2.5重量%の汚れ解離性セルロース誘導体および/または0.1〜5重量%、特に0.5〜2.5重量%の吸湿性ポリマーを含有する請求項11に記載の組成物。
- 汚れ解離性セルロース誘導体および吸湿性ポリマーを含んでなる粒子を、固体状で存在する追加の洗濯洗剤成分と混合することを特徴とする請求項11または12に記載の固体組成物を製造する方法。
- 汚れ解離性セルロース誘導体と吸湿性ポリマーを含んでなる粒子を、噴霧乾燥工程を用いることによって調製することを特徴とする請求項13に記載の方法。
- 汚れ解離性セルロース誘導体と吸湿性ポリマーを含んでなる粒子を、圧縮成形工程を用いることによって調製することを特徴とする請求項13に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10305306 | 2003-02-10 | ||
DE10351324A DE10351324A1 (de) | 2003-02-10 | 2003-10-31 | Verstärkung der Reinigungsleistung von Waschmitteln durch Cellulosederivat und hygroskopisches Polymer |
PCT/EP2004/000870 WO2004069973A1 (de) | 2003-02-10 | 2004-01-31 | Verstärkung der reinigungsleistung von waschmitteln durch cellulosederivat und hygroskopisches polymer |
Publications (2)
Publication Number | Publication Date |
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JP2006517244A true JP2006517244A (ja) | 2006-07-20 |
JP2006517244A5 JP2006517244A5 (ja) | 2007-03-22 |
Family
ID=32851850
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006501675A Pending JP2006517244A (ja) | 2003-02-10 | 2004-01-31 | セルロース誘導体および吸湿性ポリマーによる洗濯洗剤の洗浄性能の向上 |
Country Status (7)
Country | Link |
---|---|
US (1) | US20060046950A1 (ja) |
EP (1) | EP1592765B1 (ja) |
JP (1) | JP2006517244A (ja) |
AT (1) | ATE363525T1 (ja) |
DE (1) | DE502004003950D1 (ja) |
ES (1) | ES2286602T3 (ja) |
WO (1) | WO2004069973A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010501690A (ja) * | 2006-08-25 | 2010-01-21 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | 綿に作用する汚れ分離性セルロース誘導体含有洗濯洗剤 |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
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EP1592768A2 (de) * | 2003-02-10 | 2005-11-09 | Henkel Kommanditgesellschaft auf Aktien | Verwendung von cellulosederivaten als schaumregulatoren |
DE502004002541D1 (de) * | 2003-02-10 | 2007-02-15 | Henkel Kgaa | Erhöhung der wasseraufnahmefähigkeit von textilien |
EP1592767B1 (de) * | 2003-02-10 | 2007-05-16 | Henkel Kommanditgesellschaft auf Aktien | Bleichmittelhaltige wasch- oder reinigungsmittel mit wasserlöslichem buildersystem und schmutzablösevermögendem cellulosederivat |
DE10351325A1 (de) * | 2003-02-10 | 2004-08-26 | Henkel Kgaa | Wasch- oder Reinigungsmittel mit wasserlöslichem Buildersystem und schmutzablösevermögendem Cellulosederivat |
DE10351321A1 (de) * | 2003-02-10 | 2004-08-26 | Henkel Kgaa | Verstärkung der Reinigungsleistung von Waschmitteln durch eine Kombination von Cellulosderivaten |
DE102005026544A1 (de) * | 2005-06-08 | 2006-12-14 | Henkel Kgaa | Verstärkung der Reinigungsleistung von Waschmitteln durch Polymer |
US9376648B2 (en) | 2008-04-07 | 2016-06-28 | The Procter & Gamble Company | Foam manipulation compositions containing fine particles |
AU2010291393B2 (en) | 2009-09-02 | 2013-07-11 | Unilever Plc | Composition and process for treatment of a fabric |
CN102575197B (zh) | 2009-09-02 | 2013-10-30 | 荷兰联合利华有限公司 | 处理织物的组合物和方法 |
EP2689001B1 (en) * | 2011-05-20 | 2017-09-27 | Dow Global Technologies LLC | Method of promoting soil release from fabrics |
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- 2004-01-31 DE DE502004003950T patent/DE502004003950D1/de not_active Revoked
- 2004-01-31 EP EP04707142A patent/EP1592765B1/de not_active Revoked
- 2004-01-31 ES ES04707142T patent/ES2286602T3/es not_active Expired - Lifetime
- 2004-01-31 AT AT04707142T patent/ATE363525T1/de not_active IP Right Cessation
- 2004-01-31 JP JP2006501675A patent/JP2006517244A/ja active Pending
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2005
- 2005-08-10 US US11/200,750 patent/US20060046950A1/en not_active Abandoned
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Cited By (1)
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JP2010501690A (ja) * | 2006-08-25 | 2010-01-21 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | 綿に作用する汚れ分離性セルロース誘導体含有洗濯洗剤 |
Also Published As
Publication number | Publication date |
---|---|
ES2286602T3 (es) | 2007-12-01 |
EP1592765A1 (de) | 2005-11-09 |
ATE363525T1 (de) | 2007-06-15 |
WO2004069973A1 (de) | 2004-08-19 |
DE502004003950D1 (de) | 2007-07-12 |
EP1592765B1 (de) | 2007-05-30 |
US20060046950A1 (en) | 2006-03-02 |
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