JP2006502199A5 - - Google Patents
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- Publication number
- JP2006502199A5 JP2006502199A5 JP2004540944A JP2004540944A JP2006502199A5 JP 2006502199 A5 JP2006502199 A5 JP 2006502199A5 JP 2004540944 A JP2004540944 A JP 2004540944A JP 2004540944 A JP2004540944 A JP 2004540944A JP 2006502199 A5 JP2006502199 A5 JP 2006502199A5
- Authority
- JP
- Japan
- Prior art keywords
- alkene
- catalyst
- carboxylic acid
- reaction zone
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims 39
- 150000001336 alkenes Chemical class 0.000 claims 22
- 239000003054 catalyst Substances 0.000 claims 17
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 12
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 9
- -1 alkenyl carboxylate Chemical class 0.000 claims 9
- 229910001882 dioxygen Inorganic materials 0.000 claims 9
- 239000007789 gas Substances 0.000 claims 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 6
- 239000005977 Ethylene Substances 0.000 claims 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 6
- 239000000203 mixture Substances 0.000 claims 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 3
- 238000004519 manufacturing process Methods 0.000 claims 3
- 239000001301 oxygen Substances 0.000 claims 3
- 229910052760 oxygen Inorganic materials 0.000 claims 3
- 239000000377 silicon dioxide Substances 0.000 claims 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 230000003197 catalytic effect Effects 0.000 claims 2
- 239000011261 inert gas Substances 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- 239000012071 phase Substances 0.000 claims 2
- 238000010926 purge Methods 0.000 claims 2
- 229910052684 Cerium Inorganic materials 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- 241000255925 Diptera Species 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 125000003342 alkenyl group Chemical group 0.000 claims 1
- 229910052787 antimony Inorganic materials 0.000 claims 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims 1
- 229910052788 barium Inorganic materials 0.000 claims 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 229910052793 cadmium Inorganic materials 0.000 claims 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 230000007423 decrease Effects 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 230000005764 inhibitory process Effects 0.000 claims 1
- 229910052746 lanthanum Inorganic materials 0.000 claims 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims 1
- 239000007791 liquid phase Substances 0.000 claims 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 239000000376 reactant Substances 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0223215.5 | 2002-10-07 | ||
| GBGB0223215.5A GB0223215D0 (en) | 2002-10-07 | 2002-10-07 | Processs |
| PCT/GB2003/004220 WO2004031120A1 (en) | 2002-10-07 | 2003-09-29 | Process for the production of alkenyl carboxylates |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2006502199A JP2006502199A (ja) | 2006-01-19 |
| JP2006502199A5 true JP2006502199A5 (enExample) | 2006-11-09 |
| JP4933047B2 JP4933047B2 (ja) | 2012-05-16 |
Family
ID=9945419
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004540944A Expired - Fee Related JP4933047B2 (ja) | 2002-10-07 | 2003-09-29 | カルボン酸アルケニルの製造方法 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7534910B2 (enExample) |
| EP (1) | EP1549605B1 (enExample) |
| JP (1) | JP4933047B2 (enExample) |
| KR (1) | KR101131028B1 (enExample) |
| CN (1) | CN100577627C (enExample) |
| AU (1) | AU2003271871A1 (enExample) |
| BR (1) | BR0315131A (enExample) |
| CA (1) | CA2497802A1 (enExample) |
| ES (1) | ES2388663T3 (enExample) |
| GB (1) | GB0223215D0 (enExample) |
| MX (1) | MXPA05003676A (enExample) |
| TW (1) | TWI314926B (enExample) |
| WO (1) | WO2004031120A1 (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2934264B1 (fr) * | 2008-07-22 | 2012-07-20 | Arkema France | Fabrication d'esters de vinyle a partir de matieres renouvelables, esters de vinyle obtenus et utilisations |
| DE102010001097A1 (de) * | 2010-01-21 | 2011-07-28 | Wacker Chemie AG, 81737 | Verfahren zur Herstellung von Vinylacetat |
| JP7291141B2 (ja) * | 2018-07-27 | 2023-06-14 | 株式会社クラレ | 1,3-ビスアシルオキシ-2-メチレンプロパンの製造方法 |
| CN110746296A (zh) * | 2019-11-12 | 2020-02-04 | 云南正邦科技有限公司 | 一种用微通道反应器制备乙酸乙烯酯的方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0685449B1 (en) * | 1994-06-02 | 1999-08-18 | The Standard Oil Company | Fluid bed process for the acetoxylation of ethylene in the production of vinyl acetate |
| GB9826754D0 (en) * | 1998-12-04 | 1999-01-27 | Bp Chem Int Ltd | Process for the production of vinyl acetate |
-
2002
- 2002-10-07 GB GBGB0223215.5A patent/GB0223215D0/en not_active Ceased
-
2003
- 2003-09-26 TW TW092126702A patent/TWI314926B/zh not_active IP Right Cessation
- 2003-09-29 ES ES03753709T patent/ES2388663T3/es not_active Expired - Lifetime
- 2003-09-29 CN CN03823267A patent/CN100577627C/zh not_active Expired - Fee Related
- 2003-09-29 CA CA002497802A patent/CA2497802A1/en not_active Abandoned
- 2003-09-29 JP JP2004540944A patent/JP4933047B2/ja not_active Expired - Fee Related
- 2003-09-29 BR BR0315131-0A patent/BR0315131A/pt not_active IP Right Cessation
- 2003-09-29 US US10/529,723 patent/US7534910B2/en not_active Expired - Fee Related
- 2003-09-29 MX MXPA05003676A patent/MXPA05003676A/es active IP Right Grant
- 2003-09-29 KR KR1020057005925A patent/KR101131028B1/ko not_active Expired - Fee Related
- 2003-09-29 WO PCT/GB2003/004220 patent/WO2004031120A1/en not_active Ceased
- 2003-09-29 AU AU2003271871A patent/AU2003271871A1/en not_active Abandoned
- 2003-09-29 EP EP03753709A patent/EP1549605B1/en not_active Expired - Lifetime
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