JP2006500339A5 - - Google Patents
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- Publication number
- JP2006500339A5 JP2006500339A5 JP2004525400A JP2004525400A JP2006500339A5 JP 2006500339 A5 JP2006500339 A5 JP 2006500339A5 JP 2004525400 A JP2004525400 A JP 2004525400A JP 2004525400 A JP2004525400 A JP 2004525400A JP 2006500339 A5 JP2006500339 A5 JP 2006500339A5
- Authority
- JP
- Japan
- Prior art keywords
- component
- catalyst
- oxirane
- lactone
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 claims 3
- 238000005810 carbonylation reaction Methods 0.000 claims 2
- 230000003197 catalytic Effects 0.000 claims 2
- 150000002596 lactones Chemical class 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N oxane Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 2
- 125000003358 C2-C20 alkenyl group Chemical group 0.000 claims 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims 1
- 150000004703 alkoxides Chemical class 0.000 claims 1
- 125000002877 alkyl aryl group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 125000004432 carbon atoms Chemical group C* 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 150000001869 cobalt compounds Chemical class 0.000 claims 1
- FJDJVBXSSLDNJB-LNTINUHCSA-N cobalt;(Z)-4-hydroxypent-3-en-2-one Chemical compound [Co].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O FJDJVBXSSLDNJB-LNTINUHCSA-N 0.000 claims 1
- WHWBTOCNUBAGRL-UHFFFAOYSA-N cobalt;formaldehyde Chemical group [Co].O=C WHWBTOCNUBAGRL-UHFFFAOYSA-N 0.000 claims 1
- 230000000875 corresponding Effects 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 150000002736 metal compounds Chemical class 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
Claims (4)
- オキシランの接触カルボニル化によるラクトンの製造方法において、触媒として、
ａ） 成分Ａとして少なくとも１種のコバルト化合物及び
ｂ） 成分Ｂとして一般式（Ｉ）
ＭＸｘＲｎ−ｘ （Ｉ）
［式中、
Ｍは、Ａｌ、Ｍｇ又はＺｎを表し、
Ｒは、水素又はＣ１〜Ｃ３２−アルキル、Ｃ２〜Ｃ２０−アルケニル、Ｃ３〜Ｃ２０−シクロアルキル、Ｃ６〜Ｃ１８−アリール、Ｃ７〜Ｃ２０−アラルキル又はＣ７〜Ｃ２０−アルカリールを表し、その際、Ｍと結合した炭素原子以外の炭素原子に置換基が存在することができ、
Ｘは、Ｃｌ、Ｂｒ、Ｉ、スルホナート、酸化物、Ｃ１〜Ｃ３２−アルコキシド又はアミドを表し、
ｎは、Ｍの原子価に相当する数を表し、
ｘは、０〜ｎの範囲内の数を表し、
その際、ｎ及びｘは、電荷中性が生じるように選択される］の少なくとも１種の金属化合物
からなる触媒系を使用することを特徴とする、オキシランの接触カルボニル化によるラクトンの製造方法。 - 反応条件下で、コバルトカルボニル化合物が存在するように成分Ａを選択することを特徴とする、請求項１記載の方法。
- 成分ＢはＡｌＣｌｘＲ３−ｘであり、ｘは０〜３の数であり、ＲはＣ１〜Ｃ６−アルキルであることを特徴とする、請求項１又は２記載の方法。
- Ａｌ（Ｃ２Ｈ５）３／Ｃｏ（ａｃａｃ）３の組み合わせを除く、請求項１から３までのいずれか１項記載の触媒。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10235317A DE10235317A1 (de) | 2002-08-01 | 2002-08-01 | Katalysator und Verfahren zur Carbonylierung von Oxiranen |
| PCT/EP2003/008479 WO2004012860A1 (de) | 2002-08-01 | 2003-07-31 | Katalysator und verfahren zur carbonylierung von oxiranen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2006500339A JP2006500339A (ja) | 2006-01-05 |
| JP2006500339A5 true JP2006500339A5 (ja) | 2006-09-14 |
| JP4546826B2 JP4546826B2 (ja) | 2010-09-22 |
Family
ID=30128647
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004525400A Expired - Fee Related JP4546826B2 (ja) | 2002-08-01 | 2003-07-31 | オキシランをカルボニル化するための触媒及び方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7420064B2 (ja) |
| EP (1) | EP1545773B1 (ja) |
| JP (1) | JP4546826B2 (ja) |
| AT (1) | ATE389452T1 (ja) |
| DE (2) | DE10235317A1 (ja) |
| ES (1) | ES2299731T3 (ja) |
| WO (1) | WO2004012860A1 (ja) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10235316A1 (de) | 2002-08-01 | 2004-02-12 | Basf Ag | Katalysator und Verfahren zur Carbonylierung von Oxiranen |
| EP1615901A1 (en) * | 2003-04-09 | 2006-01-18 | Shell Internationale Researchmaatschappij B.V. | Carbonylation of epoxides |
| DE102004002875A1 (de) * | 2004-01-20 | 2005-10-06 | Basf Ag | Katalysator zur Carbonylierung von Oxiranen |
| CN102421821B (zh) | 2009-04-08 | 2014-12-10 | 诺沃梅尔公司 | β-内酯的制造方法 |
| EP2771307B1 (en) * | 2011-10-26 | 2018-05-30 | Novomer, Inc. | Process for production of acrylates from epoxides |
| JP5843658B2 (ja) * | 2012-02-24 | 2016-01-13 | 株式会社日本触媒 | エポキシドのラクトン化方法 |
| JP5843659B2 (ja) * | 2012-02-24 | 2016-01-13 | 株式会社日本触媒 | エポキシドのラクトン化用触媒及びそれを用いたラクトン化方法 |
| DK2667638T3 (en) | 2012-05-24 | 2016-05-09 | Oticon As | Hearing aid with external electrode |
| WO2015085295A2 (en) | 2013-12-07 | 2015-06-11 | Novomer, Inc. | Nanofiltration membranes and methods of use |
| WO2015171372A1 (en) | 2014-05-05 | 2015-11-12 | Novomer, Inc. | Catalyst recycle methods |
| CA2977969A1 (en) | 2015-02-13 | 2016-08-18 | Novomer, Inc. | Flexible chemical production platform |
| EP3256441B1 (en) * | 2015-02-13 | 2020-04-08 | Novomer, Inc. | Continuous carbonylation processes |
| KR20170134375A (ko) | 2015-02-13 | 2017-12-06 | 노보머, 인코포레이티드 | 폴리프로피오락톤의 제조를 위한 방법 및 시스템 |
| MA41508A (fr) | 2015-02-13 | 2017-12-19 | Novomer Inc | Systèmes et procédés de production d'acide polyacrylique |
| CA2994395A1 (en) | 2015-07-31 | 2017-02-09 | Novomer, Inc. | Production system/production process for acrylic acid and precursors thereof |
| US10144802B2 (en) | 2016-12-05 | 2018-12-04 | Novomer, Inc. | Beta-propiolactone based copolymers containing biogenic carbon, methods for their production and uses thereof |
| US10065914B1 (en) | 2017-04-24 | 2018-09-04 | Novomer, Inc. | Thermolysis of polypropiolactone to produce acrylic acid |
| US10781156B2 (en) | 2017-06-30 | 2020-09-22 | Novomer, Inc. | Compositions for improved production of acrylic acid |
| US10676426B2 (en) | 2017-06-30 | 2020-06-09 | Novomer, Inc. | Acrylonitrile derivatives from epoxide and carbon monoxide reagents |
| US10961209B2 (en) | 2017-08-10 | 2021-03-30 | Novomer, Inc. | Processes for producing beta-lactone and beta-lactone derivatives with heterogenous catalysts |
| US10590099B1 (en) | 2017-08-10 | 2020-03-17 | Novomer, Inc. | Processes for producing beta-lactone with heterogenous catalysts |
| US20190076835A1 (en) | 2017-09-11 | 2019-03-14 | Novomer, Inc. | Processses using multifunctional catalysts |
| EP3691785A4 (en) | 2017-10-05 | 2021-08-04 | Novomer, Inc. | ISOCYANATES, DERIVATIVES AND METHOD FOR THEIR MANUFACTURING |
| US11498894B2 (en) | 2019-03-08 | 2022-11-15 | Novomer, Inc. | Integrated methods and systems for producing amide and nitrile compounds |
| WO2024049975A1 (en) * | 2022-09-02 | 2024-03-07 | Novomer, Inc. | Process for preparing beta-lactones |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1020575A (en) | 1961-07-12 | 1966-02-23 | Ici Ltd | Preparation of polymers of ª‰-lactones |
| US3260738A (en) * | 1965-08-09 | 1966-07-12 | Shell Oil Co | Hydracrylate ester production |
| DE3264875D1 (en) * | 1981-04-21 | 1985-08-29 | Mitsubishi Gas Chemical Co | Process for producing carboxylic acids |
| US5310948A (en) * | 1992-06-29 | 1994-05-10 | Shell Oil Company | Carbonylation of epoxides |
| EP0577206B1 (en) | 1992-06-29 | 1998-08-26 | Shell Internationale Researchmaatschappij B.V. | Carbonylation of epoxides |
| JPH083333A (ja) | 1994-06-22 | 1996-01-09 | Tokuyama Corp | 生分解性脂肪族ポリエステルの溶融押出フィルムおよびそれからなる袋 |
| US5731402A (en) * | 1995-04-25 | 1998-03-24 | Tokuyama Corporation | Biodegradable aliphatic polyester, melt-extrusion film thereof, and process for the production thereof |
| JPH09169753A (ja) | 1995-12-21 | 1997-06-30 | Tokuyama Corp | ２−オキセタノン類化合物の製造方法 |
| WO1999040057A1 (en) * | 1998-02-06 | 1999-08-12 | Shell Internationale Research Maatschappij B.V. | METHOD TO PREPARE α-β UNSATURATED CARBOXYLIC ACIDS |
| AU2001278593A1 (en) * | 2000-08-10 | 2002-02-18 | Davy Process Technology Limited | Process for the carbonylation of oxiranes |
| ES2330930T3 (es) | 2001-12-06 | 2009-12-17 | Cornell Research Foundation, Inc. | Carbonilacion catalitica de heterociclos de tres y cuatro miembros. |
| DE10235316A1 (de) | 2002-08-01 | 2004-02-12 | Basf Ag | Katalysator und Verfahren zur Carbonylierung von Oxiranen |
-
2002
- 2002-08-01 DE DE10235317A patent/DE10235317A1/de not_active Withdrawn
-
2003
- 2003-07-31 ES ES03766380T patent/ES2299731T3/es not_active Expired - Lifetime
- 2003-07-31 DE DE50309427T patent/DE50309427D1/de not_active Expired - Lifetime
- 2003-07-31 EP EP03766380A patent/EP1545773B1/de not_active Expired - Lifetime
- 2003-07-31 AT AT03766380T patent/ATE389452T1/de not_active IP Right Cessation
- 2003-07-31 WO PCT/EP2003/008479 patent/WO2004012860A1/de active IP Right Grant
- 2003-07-31 JP JP2004525400A patent/JP4546826B2/ja not_active Expired - Fee Related
- 2003-07-31 US US10/523,263 patent/US7420064B2/en not_active Expired - Fee Related
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