JP2006347896A - Composition for oily foaming aerosol - Google Patents
Composition for oily foaming aerosol Download PDFInfo
- Publication number
- JP2006347896A JP2006347896A JP2005172474A JP2005172474A JP2006347896A JP 2006347896 A JP2006347896 A JP 2006347896A JP 2005172474 A JP2005172474 A JP 2005172474A JP 2005172474 A JP2005172474 A JP 2005172474A JP 2006347896 A JP2006347896 A JP 2006347896A
- Authority
- JP
- Japan
- Prior art keywords
- oily
- composition
- oil
- aerosol
- foam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000443 aerosol Substances 0.000 title claims abstract description 64
- 239000000203 mixture Substances 0.000 title claims abstract description 56
- 238000005187 foaming Methods 0.000 title abstract description 6
- 239000006260 foam Substances 0.000 claims abstract description 65
- 239000002537 cosmetic Substances 0.000 claims abstract description 13
- 150000005215 alkyl ethers Chemical class 0.000 claims abstract description 12
- 229920000223 polyglycerol Polymers 0.000 abstract description 4
- 238000004140 cleaning Methods 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 35
- 235000019198 oils Nutrition 0.000 description 35
- -1 alkyl phosphate derivative Chemical class 0.000 description 27
- 239000002994 raw material Substances 0.000 description 23
- 238000000034 method Methods 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 9
- 239000003380 propellant Substances 0.000 description 9
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- 229940105990 diglycerin Drugs 0.000 description 7
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 6
- 239000003925 fat Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 5
- 239000003599 detergent Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 230000005923 long-lasting effect Effects 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- HANWHVWXFQSQGJ-UHFFFAOYSA-N 1-tetradecoxytetradecane Chemical compound CCCCCCCCCCCCCCOCCCCCCCCCCCCCC HANWHVWXFQSQGJ-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- JYKSTGLAIMQDRA-UHFFFAOYSA-N tetraglycerol Chemical compound OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO JYKSTGLAIMQDRA-UHFFFAOYSA-N 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 description 3
- LTSWUFKUZPPYEG-UHFFFAOYSA-N 1-decoxydecane Chemical compound CCCCCCCCCCOCCCCCCCCCC LTSWUFKUZPPYEG-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 3
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 3
- 239000003915 liquefied petroleum gas Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- AGNTUZCMJBTHOG-UHFFFAOYSA-N 3-[3-(2,3-dihydroxypropoxy)-2-hydroxypropoxy]propane-1,2-diol Chemical compound OCC(O)COCC(O)COCC(O)CO AGNTUZCMJBTHOG-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 2
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- 125000003342 alkenyl group Chemical group 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000010495 camellia oil Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 2
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- UUWJHAWPCRFDHZ-UHFFFAOYSA-N 1-dodecoxydodecane;phosphoric acid Chemical compound OP(O)(O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC UUWJHAWPCRFDHZ-UHFFFAOYSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 1
- 240000000912 Macadamia tetraphylla Species 0.000 description 1
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 240000002834 Paulownia tomentosa Species 0.000 description 1
- 235000010678 Paulownia tomentosa Nutrition 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 235000019774 Rice Bran oil Nutrition 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- 241000270666 Testudines Species 0.000 description 1
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 235000006732 Torreya nucifera Nutrition 0.000 description 1
- 244000111306 Torreya nucifera Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SASYSVUEVMOWPL-NXVVXOECSA-N decyl oleate Chemical compound CCCCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC SASYSVUEVMOWPL-NXVVXOECSA-N 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 229940042935 dichlorodifluoromethane Drugs 0.000 description 1
- UMNKXPULIDJLSU-UHFFFAOYSA-N dichlorofluoromethane Chemical compound FC(Cl)Cl UMNKXPULIDJLSU-UHFFFAOYSA-N 0.000 description 1
- 229940099364 dichlorofluoromethane Drugs 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013345 egg yolk Nutrition 0.000 description 1
- 210000002969 egg yolk Anatomy 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- GQXQIRNPJBUEGY-UHFFFAOYSA-N hexadecan-7-yl 2,2-dimethyloctanoate Chemical compound CCCCCCCCCC(CCCCCC)OC(=O)C(C)(C)CCCCCC GQXQIRNPJBUEGY-UHFFFAOYSA-N 0.000 description 1
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- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
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- 229940057995 liquid paraffin Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
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- 239000002736 nonionic surfactant Substances 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
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- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 1
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- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
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- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
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- Cosmetics (AREA)
Abstract
Description
本発明は、油性化粧料のクレンジング剤等として有用な油状泡沫性エアゾール用組成物に関し、更に詳しくは、ポリグリセリンアルキルエーテルと油脂とを含有することを特徴とする洗浄力、使用性に優れ、洗いあがりが良好で、且つ、きめの細かい泡沫、泡沫の安定性も良好な油状泡沫性エアゾール用組成物に関する。 The present invention relates to an oily foam aerosol composition useful as a cleansing agent for oily cosmetics, and more specifically, it has excellent detergency and usability characterized by containing polyglycerin alkyl ether and oil and fat, The present invention relates to an oily foam aerosol composition having good washing-off, fine foam, and good foam stability.
エアゾール用組成物には、原液、噴射剤の組み合わせにより安定型泡沫、速崩壊型泡沫、噴射型泡沫等がある。従来、安定型泡沫は、噴射剤が溶解している油相からなる内相と噴射剤との溶解性の悪い水相との２相からなるＯ／Ｗ型エマルジョンで形成されていた。Ｏ／Ｗ型エマルジョンの泡沫エアゾール組成物には、クレンジング用化粧料があるが、洗浄力が低く油性のメーキャップの洗浄には不適当であった。特許文献１及び特許文献２には、油性化粧料のクレンジング剤等としてポリオキシエチレン付加型非イオン界面活性剤とアルキルリン酸誘導体、ポリグリセリン脂肪酸エステルを用いた油状泡沫性エアゾール用組成物が開示されている。この油状泡沫性エアゾール用組成物は、洗浄力、洗いあがりは良好であるが、泡質のきめ細かさ、泡沫安定性において、更に改良が望まれていた。 Aerosol compositions include stable foams, fast disintegrating foams, and jetting foams depending on the combination of the stock solution and the propellant. Conventionally, a stable foam has been formed by an O / W type emulsion composed of two phases of an internal phase composed of an oil phase in which a propellant is dissolved and an aqueous phase having poor solubility of the propellant. The foam aerosol composition of the O / W type emulsion has a cleansing cosmetic, but has a low detergency and is unsuitable for cleaning oily makeup. Patent Document 1 and Patent Document 2 disclose an oily foam aerosol composition using a polyoxyethylene-added nonionic surfactant, an alkyl phosphate derivative, and a polyglycerin fatty acid ester as a cleansing agent for oily cosmetics. Has been. This oily foam aerosol composition has good detergency and washability, but further improvements in foam fineness and foam stability have been desired.
本発明の目的は、洗浄力、使用性に優れ、洗いあがりが良好で、且つ、きめの細かい泡沫、泡沫の安定性も良好な油状泡沫性エアゾール用組成物を提供することにある。 It is an object of the present invention to provide an oily foam aerosol composition having excellent detergency and usability, good wash-off and fine foam and good foam stability.
本発明者らは、上記課題を解決すべく創意研究を重ねた結果、ポリグリセリンアルキルエーテルを含有することを特徴とする油状泡沫性エアゾール組成物が洗浄力、使用性に優れ、洗いあがり良好で、且つ、きめの細かい泡沫、泡沫安定性も良好であることを見出し、本発明を完成するに至った。 As a result of repeated creative research to solve the above-mentioned problems, the present inventors have found that an oily foam aerosol composition characterized by containing a polyglycerin alkyl ether has excellent detergency, usability, and good wash-out. And it discovered that fine foam and foam stability were also favorable, and came to complete this invention.
以下、本発明について詳細に説明する。 Hereinafter, the present invention will be described in detail.
本発明の油状泡沫性エアゾール用組成物には、ポリグリセリンアルキルエーテル以外の成分として安定な泡沫の形成の点より、油脂が含まれることが好ましい。 The oily foam aerosol composition of the present invention preferably contains fats and oils from the viewpoint of forming a stable foam as a component other than the polyglycerin alkyl ether.
本発明で用いられる油脂としては、起泡時に液状のものであれば、特に限定するものではなく、天産品でも化学合成品でもよい。例えばアボガド油、ツバキ油、タートル油、マカダミアナッツ油、トウモロコシ油、ミンク油、オリーブ油、ナタネ油、卵黄油、ごま油、パーシック油、小麦胚芽油、サザンカ油、ヒマシ油、アマニ油、サフラワー油、綿実油、エノ油、大豆油、落花生油、茶実油、カヤ油、コメヌカ油、シナギリ油、日本キリ油、ホホバ油、胚芽油、トリオクタン酸グリセリン、トリイソパルミチン酸グリセリン等の液状油脂、流動パラフィン、スクワレン、スクワラン、プリスタン等の炭化水素、オレイン酸、トール油、イソステアリン酸等の高級アルコール脂肪酸、ラウリルアルコール、オレイルアルコール、イソステアリルアルコール、オクチルドデカノール等の高級アルコール、メチルポリシロキサン、メチルフェニルポリシロキサン、メチルハイドロジェンポリシロキサン、デカメチルポリシロキサン等のシリコーン、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ラウリン酸ヘキシル、オレイン酸オレイル、オレイン酸デシルミリスチン酸オクチルドデシル、ジメチルオクタン酸ヘキシルデシル、フタル酸ジエチル、フタル酸ジブチル等のエステル類等が挙げられる。また、上記油脂に水素添加、分別等の処理を施して得られるものでもよい。なお、グリセリド成分としての不飽和脂肪酸、側鎖状脂肪酸やジグリセリド、モノグリセリド等は若干量であれば含まれていてもかまわない。 The oil and fat used in the present invention is not particularly limited as long as it is liquid at the time of foaming, and may be a natural product or a chemically synthesized product. For example, avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil, flaxseed oil, safflower oil, Cotton oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, glycerin trioctanoate, glycerin triisopalmitate, liquid paraffin , Hydrocarbons such as squalene, squalane and pristane, higher alcohol fatty acids such as oleic acid, tall oil, isostearic acid, higher alcohols such as lauryl alcohol, oleyl alcohol, isostearyl alcohol, octyldodecanol, methyl polysiloxane, methyl phenyl poly Siloxane, methyl high Silicone such as rhogen polysiloxane, decamethylpolysiloxane, isopropyl myristate, isopropyl palmitate, hexyl laurate, oleyl oleate, decyl oleate octyldodecyl myristate, hexyldecyl dimethyloctanoate, diethyl phthalate, dibutyl phthalate Ester etc. are mentioned. Moreover, what is obtained by processing the said fats and oils, such as hydrogenation and fractionation, may be used. It should be noted that unsaturated fatty acids, side chain fatty acids, diglycerides, monoglycerides and the like as glyceride components may be contained in a slight amount.
本発明で用いられる油脂の配合量は、特に限定するものではないが、好ましくは、油状泡沫性エアゾール用組成物全量中の１０〜９９重量％であり、さらに好ましくは３０〜９５重量％である。 The amount of fats and oils used in the present invention is not particularly limited, but is preferably 10 to 99% by weight, more preferably 30 to 95% by weight, based on the total amount of the oily foam aerosol composition. .
また、本発明で用いられるポリグリセリンアルキルエーテルとしては、例えば次の一般式（１）で表わされるものが挙げられる。
式（１）におけるＲはアルキル基、アルケニル基、ヒドロキシアルキル基で直鎖状あるいは分岐状のものであれば特に限定されるものではないが、炭素数８〜１８の直鎖もしくは分岐状のアルキル基が好ましく、炭素数８〜１４の直鎖のアルキル基が特に好ましい。具体的には、オクチル基、ノニル基、デシル基、ウンデシル基、ドデシル基、トリデシル基、テトラデシル基が挙げられる。また式（１）におけるｎは２以上の整数であれば特に限定されるものではないが好ましくは２〜１０、特に好ましくは２〜５、更に好ましくは２〜３である。ポリグリセリンモノアルキルエーテルの製造方法としては、塩基性触媒の存在下、脂肪族アルコールに該アルコール／グリシドールの存在モル比が特定となるようにグリシドールを添加して反応させる方法、ポリグリセリンにα−オレフィンエポキシドを反応させることによって得られる方法、酸触媒もしくはアルカリ触媒の存在下でアルキルグリシジルエーテルをポリグリセリンを用いて開環させる方法等が挙げられるが特に限定されるものではない。このようなポリグリセリンモノアルキルエーテルの好ましい例としてはテトラグリセリンモノオクチルエーテル、テトラグリセリンモノデシルエーテル、テトラグリセリンモノドデシルエーテル、テトラグリセリンモノテトラデシルエーテル、トリグリセリンモノオクチルエーテル、トリグリセリンモノデシルエーテル、トリグリセリンモノドデシルエーテル、トリグリセリンモノテトラデシルエーテル、ジグリセリンモノオクチルエーテル、ジグリセリンモノデシルエーテル、ジグリセリンモノドデシルエーテル、ジグリセリンモノテトラデシルエーテル等が挙げられ、より好ましくはジグリセリンモノドデシルエーテル、ジグリセリンモノテトラデシルエーテルである。 R in the formula (1) is not particularly limited as long as it is a linear or branched alkyl group, alkenyl group, or hydroxyalkyl group, but a linear or branched alkyl group having 8 to 18 carbon atoms. Group is preferable, and a linear alkyl group having 8 to 14 carbon atoms is particularly preferable. Specific examples include octyl group, nonyl group, decyl group, undecyl group, dodecyl group, tridecyl group, and tetradecyl group. Further, n in the formula (1) is not particularly limited as long as it is an integer of 2 or more, but is preferably 2 to 10, particularly preferably 2 to 5, and further preferably 2 to 3. As a method for producing polyglycerol monoalkyl ether, in the presence of a basic catalyst, a method in which glycidol is added to and reacted with an aliphatic alcohol so that the molar ratio of the alcohol / glycidol is specified; A method obtained by reacting an olefin epoxide, a method of ring-opening an alkyl glycidyl ether using polyglycerin in the presence of an acid catalyst or an alkali catalyst, and the like can be mentioned, but it is not particularly limited. Preferred examples of such polyglycerol monoalkyl ether include tetraglycerol monooctyl ether, tetraglycerol monodecyl ether, tetraglycerol monododecyl ether, tetraglycerol monotetradecyl ether, triglycerol monooctyl ether, triglycerol monodecyl ether, Examples include triglycerin monododecyl ether, triglycerin monotetradecyl ether, diglycerin monooctyl ether, diglycerin monodecyl ether, diglycerin monododecyl ether, and diglycerin monotetradecyl ether, more preferably diglycerin monododecyl ether. Diglycerin monotetradecyl ether.
本発明の油状泡沫性エアゾール用組成物は、前記一般式（１）で表されるポリグリセリンモノアルキルエーテルを５０％以上、より好ましくは７０％以上含むことが洗浄性、泡沫安定性の面で好ましい。 The oily foam aerosol composition of the present invention contains 50% or more, more preferably 70% or more of the polyglycerol monoalkyl ether represented by the general formula (1) in terms of detergency and foam stability. preferable.
ポリグリセリンアルキルエーテルの配合量は、特に限定するものではないが、好ましくは油状泡沫性エアゾール用組成物の油脂分に対して０．０１〜５０重量％であり、より好ましくは０．１〜３０重量％であり、さらに好ましくは１〜２０重量％である。 The blending amount of the polyglycerin alkyl ether is not particularly limited, but is preferably 0.01 to 50% by weight, more preferably 0.1 to 30% with respect to the fat and oil content of the oily foam aerosol composition. % By weight, more preferably 1 to 20% by weight.
本発明は、上記ポリグリセリンアルキルエーテルを含有する油状泡沫性エアゾール用組成物に関するものである。 The present invention relates to an oily foam aerosol composition containing the polyglycerin alkyl ether.
本発明に用いられる噴射剤は、通常エアゾールの具体例を挙げるとトリクロロフルオロメタン、ジクロロジフルオロメタン、ジクロロフルオロメタン、トリクロロトリフルオロメタン、ジクロロテトラフルオロメタン等のクロロフルオロカーボン、プロパン、イソブタン、イソペンタン、ノルマルブタン及び液化石油ガス（以下ＬＰＧと略す）等の液化ガスである。これらの噴射剤に加えてジメチルエーテル、炭酸ガス、窒素ガスを用いても良い。これらのガスは単独でもまた２種類以上を混合しても用いることができる。配合量は２〜９０重量％が好ましい。２重量％未満では良好な泡沫が得にくい。 The propellant used in the present invention is usually chlorofluorocarbons such as trichlorofluoromethane, dichlorodifluoromethane, dichlorofluoromethane, trichlorotrifluoromethane, dichlorotetrafluoromethane, propane, isobutane, isopentane, and normal butane. And liquefied gas such as liquefied petroleum gas (hereinafter abbreviated as LPG). In addition to these propellants, dimethyl ether, carbon dioxide gas, or nitrogen gas may be used. These gases can be used alone or in combination of two or more. The blending amount is preferably 2 to 90% by weight. If it is less than 2% by weight, it is difficult to obtain good foam.
本発明のエアゾールとは、容器中にエアゾール用組成物と噴射剤を充填して得られるものである。 The aerosol of the present invention is obtained by filling a container with an aerosol composition and a propellant.
本発明の組成物は、上記に挙げた噴射剤を配合しても良いが、噴射剤を配合せずに空気の吹き込み混合による、いわゆるノンガスタイプでも泡沫化が可能である。 The composition of the present invention may be blended with the above-mentioned propellant, but foaming is possible even in a so-called non-gas type by air blowing and mixing without blending the propellant.
本発明の油状泡沫性エアゾール用組成物には、上記の必須成分の他に本発明の目的を達成する範囲で他の成分を適宜配合することができる。例えば、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンアルキルエーテル、ポリオキシプロピレンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル、ポリオキシエチレングリコール脂肪酸エステル、ポリオキシエチレンアルキルエーテル、アルキロールアマイド、ポリオキシエチレン硬化ヒマシ油等の界面活性剤、ポリオキシエチレン・メチルポリシロキサン共重合体、ポリオキシエチレン・ポリオキシプロピレンメチルポリシロキサン共重合体等のポリエーテル変性シリコーンオイル、アルキルリン酸、アルキルエーテルリン酸等のリン酸エステル、酸化チタン、タルク、ベントサイト、カチオン、マイカ等の粉末、防腐剤、色剤、酸化防止剤、水、香料、薬剤、固型油分、半固型油分、アルコール、保湿剤等が挙げられる。 In the oily foam aerosol composition of the present invention, in addition to the above essential components, other components can be appropriately blended within a range that achieves the object of the present invention. For example, glycerin fatty acid ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene alkyl ether, polyoxypropylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene glycol fatty acid ester, polyoxy Surfactant such as ethylene alkyl ether, alkylol amide, polyoxyethylene hydrogenated castor oil, polyether-modified silicone such as polyoxyethylene / methylpolysiloxane copolymer, polyoxyethylene / polyoxypropylenemethylpolysiloxane copolymer Oil, phosphoric acid esters such as alkyl phosphoric acid and alkyl ether phosphoric acid, titanium oxide, talc, ventsite, cation, mica, etc. Powders, preservatives, coloring agent, antioxidant, water, perfume, drug, solid oil component, semisolid oil component, an alcohol, humectants, and the like.
本発明の油状泡沫性エアゾール用組成物の用途としては、特に限定するものではないが、油汚れ等の洗浄剤、油性化粧料のクレンジング剤、日焼け用オイル、ベビーオイル、ヘアーオイル、泡状マッサージオイル等が挙げられ、好ましくは、クレンジング剤としての用途がよい。 The use of the oily foam aerosol composition of the present invention is not particularly limited, but includes cleaning agents such as oil stains, cleansing agents for oily cosmetics, tanning oils, baby oils, hair oils, and foam massages. An oil etc. are mentioned, Preferably, the use as a cleansing agent is good.
次に実施例によって本発明を更に詳細に説明する。なお、本発明はこれらの実施例に限定されるものではない。 Next, the present invention will be described in more detail by way of examples. The present invention is not limited to these examples.
実施例１ 油性洗い流しタイプの油状泡沫性エアゾール
表１に示した原料配合に基づき、以下の方法で、油性洗い流しタイプの油状泡沫性エアゾールを調製した。
Example 1 Oily rinse type oily foam aerosol Based on the raw material formulation shown in Table 1, an oily rinse type oily foam aerosol was prepared by the following method.
表１の原料１から１０までを８０℃にて攪拌溶解し、常温まで冷却することで、油性洗い流しタイプの油状泡沫性エアゾール組成物を得た。その後、１００ｍｌエアゾール缶に組成物１８ｇを充填し、バルブをセットし、噴射剤として液化石油ガス２ｇを充填し、上記油状泡沫性エアゾールを得た。得られた油状泡沫性エアゾールを本発明品Ａ〜Ｆとした。 The raw materials 1 to 10 in Table 1 were stirred and dissolved at 80 ° C. and cooled to room temperature, thereby obtaining an oily flush type oily foam aerosol composition. Thereafter, 18 g of the composition was filled in a 100 ml aerosol can, a valve was set, and 2 g of liquefied petroleum gas was filled as a propellant to obtain the oily foamy aerosol. The obtained oily foamy aerosols were designated as products A to F of the present invention.
比較例１ 油性洗い流しタイプの油状泡沫性エアゾール
表２に示した原料配合に基づき、実施例１と同様にして、油性洗い流しタイプの油状泡沫性エアゾールを調製した。
Comparative Example 1 Oily Washing-Type Oily Foam Aerosol Based on the raw material formulation shown in Table 2, an oily washing-type oily foamy aerosol was prepared in the same manner as in Example 1.
すなわち、本発明品Ａ〜Ｆに対し、ポリグリセリンアルキルエーテルを未配合の同油性成分配合組成物を比較品Ａ、ポリオキシエチレン（６）オレイルエーテル配合の同油性成分配合組成物を比較品Ｂ、トリグリセリンモノミリスチン酸エステル配合の同油性成分配合組成物を比較品Ｃ、ジグリセリンモノラウリン酸エステル配合の同油性成分配合組成物を比較品Ｄ、ポリオキシエチレン（４）ラウリルエーテルとポリオキシエチレン（４）ラウリルエーテルリン酸ナトリウム配合の同油性成分配合組成物を比較品Ｅとして、実施例１と同様の方法で上記油状泡沫性エアゾールを得た。 That is, for the products A to F of the present invention, the same oily component blending composition not containing polyglycerin alkyl ether is the comparative product A, and the same oily component blending composition containing polyoxyethylene (6) oleyl ether is the comparison product B. , Triglycerin monomyristic acid ester blended composition of the same oily component Comparative product C, diglycerin monolaurate blended composition of the same oily component blended product, comparative product D, polyoxyethylene (4) lauryl ether and polyoxyethylene (4) The oily foam aerosol was obtained in the same manner as in Example 1, using the same oily component blend composition containing sodium lauryl ether phosphate as Comparative Product E.
※文章中の（ ）内の数字は、酸化エチレンの付加モル数を示す。以下、同じ。 * The numbers in parentheses in the text indicate the number of moles of ethylene oxide added. same as below.
試験例１
本発明品Ａおよび本発明品Ｂおよび本発明品Ｃおよび本発明品Ｄおよび本発明品Ｅおよび本発明品Ｆと、比較品Ａおよび比較品Ｂおよび比較品Ｃおよび比較品Ｄおよび比較品Ｅを比較した。
Test example 1
Invention product A, Invention product B, Invention product C, Invention product D, Invention product E and Invention product F, Comparison product A, Comparison product B, Comparison product C, Comparison product D and Comparison product E Compared.
評価方法および評価基準は以下の通りである。 Evaluation methods and evaluation criteria are as follows.
（泡形成状態）
泡形成状態は肉眼観察にて行なった。評価基準は極めて均一できめ細かい泡を◎、均一できめ細かい泡を〇、きめが粗い泡を△、泡にならず液状を×とした。各エアゾールをアクリル板（縦：１０ｃｍ、横：１０ｃｍ）上に噴射した直後に判定した。
(Bubble formation state)
Foam formation was performed by visual observation. The evaluation criteria were extremely uniform and fine bubbles ◎, uniform and fine bubbles ◯, coarsely textured bubbles Δ, and liquid that did not become bubbles X. Each aerosol was judged immediately after being sprayed onto an acrylic plate (length: 10 cm, width: 10 cm).
（泡安定性）
形成した泡の持続性を評価した。評価基準は持続性が長く１分間以上に渡り泡が持続するものを◎、十分な持続性を有し３０秒間以上に渡り泡が持続するものを〇、１０秒間以上に渡り泡が持続するものを△、全く泡とならず液状であるものを×とした。
(Foam stability)
The persistence of the foam formed was evaluated. The evaluation criteria are long-lasting for long-lasting bubbles for more than 1 minute ◎, long-lasting for long-lasting for more than 30 seconds ○ long-lasting for longer than 10 seconds △, and the thing which is not a bubble at all and is liquid is made into x.
（洗い上がり性）
水洗時の洗い流し性を評価した。評価はパネラー２０名に、油性ファンデーションを塗布してもらい、それを各化粧料を用いて洗浄した後、さらに水で化粧料を洗い流してもらい、洗いあがりの状態を４段階により判定した。４段階による評価基準は、非常に良好を４、良好を３、やや悪いを２、悪いを１とし、各化粧料においてパネラー２０名の平均値を示した。
(Washing ability)
The flushability during washing with water was evaluated. For evaluation, 20 panelists applied an oil-based foundation, washed it with each cosmetic, and then rinsed the cosmetic with water, and the state of washing was judged in four stages. The evaluation criteria based on 4 levels were 4 for very good, 3 for good, 2 for slightly bad, and 1 for bad, and showed the average value of 20 panelists in each cosmetic.
結果を表３に示す。 The results are shown in Table 3.
表３に示すように、本発明品Ａ及び本発明品Ｂ及び本発明品Ｃ及び本発明品Ｄ及び本発明品Ｅ及び本発明品Ｆは、洗浄力、使用性に優れ、洗いあがり良好で、且つ、きめの細かい泡沫、泡沫安定性も良好であるのに対し、比較品Ａ及び比較品Ｂ及び比較品Ｃは全く泡にならず、比較品Ｄ及び比較品Ｅは、泡のきめが粗く、泡沫安定性も低いものであった。 As shown in Table 3, the inventive product A, the inventive product B, the inventive product C, the inventive product D, the inventive product E and the inventive product F are excellent in detergency and usability, and have good wash-up performance. In addition, fine foam and foam stability are good, but Comparative Product A, Comparative Product B, and Comparative Product C are not foamed at all, and Comparative Product D and Comparative Product E are not foamed. It was rough and foam stability was low.
試験例２
表４に示した原料配合に基づき、以下の方法で、Ｏ／Ｗ乳化型の泡沫性エアゾールを作成した。
Test example 2
Based on the raw material composition shown in Table 4, an O / W emulsified foamy aerosol was prepared by the following method.
表４の原料１から３を６０℃で攪拌溶解後、エアゾール缶に充填し、バルブをセットし、原料４及び５を充填し、上記Ｏ／Ｗ乳化型泡沫性エアゾールを得た。 Raw materials 1 to 3 in Table 4 were stirred and dissolved at 60 ° C., and then filled into an aerosol can, a valve was set, and raw materials 4 and 5 were filled to obtain the O / W emulsified foamy aerosol.
表５から明らかなように本発明品Ａ〜Ｆは、従来のＯ／Ｗ乳化型泡沫性エアゾールに比べて、洗浄力が非常に高いものであった。また、本発明品は、従来のポンプ容器式クレンジング化粧料と比べて、手の平に取った時にたれ落ちないことや、顔に塗布し易い等の利点があり、使用性に優れていた。さらに、洗いあがり時にぬるつきが実質的に無く、良好な洗いあがり性を示した。 As is apparent from Table 5, the products A to F of the present invention had a very high detergency compared to conventional O / W emulsified foamy aerosols. In addition, the product of the present invention is superior in usability to the conventional pump container type cleansing cosmetic because it does not sag when it is taken on the palm of the hand and it can be easily applied to the face. Furthermore, there was substantially no stickiness when washed, and good washability was exhibited.
実施例２ サンオイル用油状泡沫性エアゾール
表６に示した原料配合に基づき、以下の方法で、サンオイル用油状泡沫性エアゾールを調製した。
Example 2 Oily Foam Aerosol for Sun Oil Based on the raw material composition shown in Table 6, an oily foam aerosol for sun oil was prepared by the following method.
表６の原料１から９を８０℃で攪拌溶解後、常温まで冷却することで、上記、油状泡沫性エアゾール用組成物を得た。その後、エアゾール缶に充填し、バルブをセットし、原料１０及び１１を充填し、上記油状泡沫性エアゾールを得た。得られた組成物は安定性、使用性に優れていた。 After stirring and dissolving the raw materials 1 to 9 in Table 6 at 80 ° C., the mixture was cooled to room temperature to obtain the oily foam aerosol composition. Then, it filled into the aerosol can, set the valve | bulb, filled with the raw materials 10 and 11, and obtained the said oily foamy aerosol. The obtained composition was excellent in stability and usability.
実施例３ 拭き取りタイプクレンジング化粧料
表７に示した原料配合に基づき、以下の方法で、拭き取りタイプクレンジング化粧料を調製した。
Example 3 Wipe type cleansing cosmetic A wipe type cleansing cosmetic was prepared by the following method based on the raw material composition shown in Table 7.
表７の原料１から５を８０℃で攪拌溶解後、常温まで冷却することで、上記組成物を得た。得られた組成物は安定性、使用性に優れていた。 After stirring and dissolving the raw materials 1 to 5 in Table 7 at 80 ° C., the composition was obtained by cooling to room temperature. The obtained composition was excellent in stability and usability.
実施例４ 洗い流しタイプの油状泡沫性エアゾール
表８に示した原料配合に基づき、以下の方法で、洗い流しタイプの油状泡沫性エアゾールを調製した。
Example 4 Washing-Type Oily Foam Aerosol Based on the raw material formulation shown in Table 8, a washing-type oily foam aerosol was prepared by the following method.
表８の原料１から１０を８０℃で攪拌溶解後、常温まで冷却することで、上記油状泡沫性エアゾールル用組成物を得た。その後、エアゾール缶に充填し、バルブをセットし、原料１１を充填し、上記油状泡沫性エアゾールを得た。得られた組成物は安定性、使用性に優れていた。 The raw materials 1 to 10 in Table 8 were stirred and dissolved at 80 ° C., and then cooled to room temperature, whereby the oily foam aerosol composition was obtained. Then, it filled into the aerosol can, set the valve | bulb, and filled with the raw material 11, and obtained the said oily foamy aerosol. The obtained composition was excellent in stability and usability.
実施例５ ベビーオイル用油状泡沫性エアゾール
表９に示した原料配合に基づき、以下の方法で、ベビーオイル用油状泡沫性エアゾールを調製した。
Example 5 Oily foam aerosol for baby oil An oily foam aerosol for baby oil was prepared by the following method based on the raw material formulation shown in Table 9.
表９の原料１から８を８０℃で攪拌溶解後、常温まで冷却することで、上記油状泡沫性エアゾール用組成物を得た。その後、エアゾール缶に充填し、バルブをセットし、原料９及び１０を充填し、上記油状泡沫性エアゾールを得た。得られた組成物は安定性、使用性に優れていた。 The raw materials 1 to 8 in Table 9 were stirred and dissolved at 80 ° C., and then cooled to room temperature, whereby the oily foam aerosol composition was obtained. Then, it filled into the aerosol can, the valve | bulb was set, and the raw materials 9 and 10 were filled, and the said oily foam aerosol was obtained. The obtained composition was excellent in stability and usability.
実施例６ ヘアーオイル用油状泡沫性エアゾール
表１０に示した原料配合に基づき、以下の方法で、ヘアーオイル用油状泡沫性エアゾールを調製した。
Example 6 Oily Foam Aerosol for Hair Oil Based on the raw material formulation shown in Table 10, an oily foam aerosol for hair oil was prepared by the following method.
表１０の原料１から６を８０℃で攪拌溶解後、常温まで冷却することで、上記油状泡沫性エアゾール用組成物を得た。その後、エアゾール缶に充填し、バルブをセットし、原料７及び８を充填し、上記油状泡沫性エアゾールを得た。得られた組成物は安定性、使用性に優れていた。 After stirring and dissolving the raw materials 1 to 6 in Table 10 at 80 ° C., the mixture was cooled to room temperature to obtain the oily foam aerosol composition. Then, it filled into the aerosol can, set the valve | bulb, filled with the raw materials 7 and 8, and obtained the said oily foamy aerosol. The obtained composition was excellent in stability and usability.
実施例７ マッサージオイル用油状泡沫性エアゾール
表１１に示した原料配合に基づき、以下の方法で、マッサージオイル用油状泡沫性エアゾールを調製した。
Example 7 Oily foam aerosol for massage oil An oily foam aerosol for massage oil was prepared by the following method based on the raw material composition shown in Table 11.
表１１の原料１から８を８０℃で攪拌溶解後、常温まで冷却することで、上記油状泡沫性エアゾール用組成物を得た。その後、エアゾール缶に充填し、バルブをセットし、原料９及び１０を充填し、上記油状泡沫性エアゾールを得た。得られた組成物は安定性、使用性に優れていた。 After stirring and dissolving the raw materials 1 to 8 in Table 11 at 80 ° C., the mixture was cooled to room temperature to obtain the oily foam aerosol composition. Then, it filled into the aerosol can, the valve | bulb was set, and the raw materials 9 and 10 were filled, and the said oily foam aerosol was obtained. The obtained composition was excellent in stability and usability.
本発明の油状泡沫性エアゾール用組成物は、油性化粧料のクレンジング剤等として有用であり、洗浄力、使用性、洗いあがり良好で、且つ、きめの細かい泡沫、泡沫の安定性に優れるものである。 The oily foam aerosol composition of the present invention is useful as a cleansing agent for oily cosmetics, etc., and has excellent detergency, usability, good washing, and excellent fine foam and foam stability. is there.
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