JP2010024202A - Cosmetic composition and oily foamy aerosol cosmetic - Google Patents
Cosmetic composition and oily foamy aerosol cosmetic Download PDFInfo
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- JP2010024202A JP2010024202A JP2008189917A JP2008189917A JP2010024202A JP 2010024202 A JP2010024202 A JP 2010024202A JP 2008189917 A JP2008189917 A JP 2008189917A JP 2008189917 A JP2008189917 A JP 2008189917A JP 2010024202 A JP2010024202 A JP 2010024202A
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- cosmetic
- cosmetic composition
- fatty acid
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 139
- 239000000203 mixture Substances 0.000 title claims abstract description 96
- 239000000443 aerosol Substances 0.000 title claims abstract description 63
- 239000006260 foam Substances 0.000 claims abstract description 51
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 37
- 229930195729 fatty acid Natural products 0.000 claims abstract description 37
- 239000000194 fatty acid Substances 0.000 claims abstract description 37
- 239000003921 oil Substances 0.000 claims abstract description 35
- -1 diglycerol fatty acid ester Chemical class 0.000 claims abstract description 29
- 239000003380 propellant Substances 0.000 claims abstract description 21
- 239000007788 liquid Substances 0.000 claims abstract description 19
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 14
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 11
- 239000010696 ester oil Substances 0.000 claims abstract description 7
- 229940105990 diglycerin Drugs 0.000 claims description 23
- 150000004671 saturated fatty acids Chemical class 0.000 claims description 9
- 239000003925 fat Substances 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 2
- 238000005187 foaming Methods 0.000 abstract description 9
- 229920006395 saturated elastomer Polymers 0.000 abstract 2
- 235000019198 oils Nutrition 0.000 description 32
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 15
- 238000011156 evaluation Methods 0.000 description 12
- 239000003915 liquefied petroleum gas Substances 0.000 description 11
- OQILCOQZDHPEAZ-UHFFFAOYSA-N octyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 description 10
- 239000004006 olive oil Substances 0.000 description 9
- 235000008390 olive oil Nutrition 0.000 description 9
- ZQEOGELFLULIGO-UHFFFAOYSA-N CCCCCCCC(=O)OCC(O)COCC(O)CO Chemical compound CCCCCCCC(=O)OCC(O)COCC(O)CO ZQEOGELFLULIGO-UHFFFAOYSA-N 0.000 description 8
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 229940070765 laurate Drugs 0.000 description 8
- 230000002688 persistence Effects 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 6
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 5
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- OGELJRHPEZALCC-UHFFFAOYSA-N [3-(2,3-dihydroxypropoxy)-2-hydroxypropyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(O)COCC(O)CO OGELJRHPEZALCC-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 3
- 239000005639 Lauric acid Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- UIVPNOBLHXUKDX-UHFFFAOYSA-N 3,5,5-trimethylhexyl 3,5,5-trimethylhexanoate Chemical compound CC(C)(C)CC(C)CCOC(=O)CC(C)CC(C)(C)C UIVPNOBLHXUKDX-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 2
- 229940100554 isononyl isononanoate Drugs 0.000 description 2
- 229940119170 jojoba wax Drugs 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 229960002446 octanoic acid Drugs 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- WAYINTBTZWQNSN-UHFFFAOYSA-N 11-methyldodecyl 3,5,5-trimethylhexanoate Chemical compound CC(C)CCCCCCCCCCOC(=O)CC(C)CC(C)(C)C WAYINTBTZWQNSN-UHFFFAOYSA-N 0.000 description 1
- NFIHXTUNNGIYRF-UHFFFAOYSA-N 2-decanoyloxypropyl decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)OC(=O)CCCCCCCCC NFIHXTUNNGIYRF-UHFFFAOYSA-N 0.000 description 1
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 1
- 240000000912 Macadamia tetraphylla Species 0.000 description 1
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 235000019774 Rice Bran oil Nutrition 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 239000008194 pharmaceutical composition Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229940116422 propylene glycol dicaprate Drugs 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 239000010668 rosemary oil Substances 0.000 description 1
- 229940058206 rosemary oil Drugs 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は噴射剤とともにエアゾール化して油状の泡沫を噴出する油状泡沫性エアゾール化粧料に充填される化粧料組成物及び該組成物と噴射剤を含有する前記油状泡沫性エアゾール化粧料に関する。 The present invention relates to a cosmetic composition filled in an oily foam aerosol cosmetic that aerosolizes with a propellant to eject oily foam, and the oily foam aerosol cosmetic containing the composition and a propellant.
油分を噴射剤によってエアゾール化して泡とするエアゾール化粧料はクレンジング化粧料等として活用されている。油分そのものには起泡性がないため、一般的には油分に界面活性剤を添加した組成物のエアゾール化によって油状泡沫性エアゾール化粧料を調製している。現在までに、界面活性剤としてポリグリセリン脂肪酸エステル用いて油分とともに含有する発泡性のエアゾール化粧料の技術が多く開示されている（例えば、特許文献１〜７参照。）。 Aerosol cosmetics in which oil is aerosolized with a propellant to make bubbles are used as cleansing cosmetics and the like. Since the oil itself has no foaming property, an oily foam aerosol cosmetic is generally prepared by aerosolizing a composition obtained by adding a surfactant to the oil. To date, many technologies for foamable aerosol cosmetics containing polyglycerin fatty acid esters as surfactants together with oil have been disclosed (for example, see Patent Documents 1 to 7).
しかしながら、従来の前記タイプの油状泡沫性エアゾール化粧料は、エアゾールに充填される組成物の油分と界面活性剤が均一に溶解しないために均一性が悪かったり、組成物が低温に保存されることにより析出物が見られるようになる等低温安定性が悪かったりで、エアゾール化粧料の安定性が充分でなかった。さらに油状泡沫性エアゾール化粧料が噴出する泡沫の泡状態において、起泡性が充分でなかったり、起泡した泡が充分に持続しない等多くの問題があった。 However, the conventional oily foam aerosol cosmetics of the above-mentioned type have poor uniformity because the oil and surfactant of the composition filled in the aerosol are not uniformly dissolved, and the composition is stored at a low temperature. As a result, the low-temperature stability was poor, such as the appearance of precipitates, and the stability of aerosol cosmetics was not sufficient. Furthermore, in the foam state of the foam from which the oily foam aerosol cosmetic composition is ejected, there are many problems such as insufficient foaming properties and insufficient foam persistence.
本発明は上記事情に鑑みてなされたもので、その目的は、前記エアゾール化粧料に充填される組成物の均一性、低温安定性が優れ、起泡性、泡の持続性において優れた泡が得られる油状泡沫性エアゾール化粧料を提供することにある。 The present invention has been made in view of the above circumstances, and its purpose is that the composition filled in the aerosol cosmetics has excellent uniformity and low-temperature stability, and has excellent foaming properties and foam sustainability. The object is to provide an oily foam aerosol cosmetic composition to be obtained.
本発明者らは上記課題を解決するために、エアゾール化粧料に充填される組成物の構成成分である油分及び界面活性剤について鋭意研究を行った結果、特定の組成からなる水酸基を有するジグリセリン脂肪酸エステルを、特定の液状油分とともに配合した組成物（化粧料）を調製し、該組成物を配合して油状泡沫性エアゾール化粧料を調製することにより上記課題が解決されることを見出し、本発明を完成するに至った。 In order to solve the above-mentioned problems, the present inventors conducted diligent research on oils and surfactants that are constituents of a composition filled in aerosol cosmetics, and as a result, diglycerin having a hydroxyl group having a specific composition. A composition (cosmetics) in which a fatty acid ester is blended with a specific liquid oil is prepared, and the above problem is solved by blending the composition to prepare an oily foam aerosol cosmetic. The invention has been completed.
すなわち、第一発明は、油脂類及び／又はエステル油からなる液状油分と水酸基を有するジグリセリン脂肪酸エステルを含有する油状泡沫性エアゾール化粧料用化粧料組成物であって、前記水酸基を有するジグリセリン脂肪酸エステルが、下記（Ａ）〜（Ｃ）の脂肪酸のエステルの混合物からなることを特徴とする油状泡沫性エアゾール化粧料用化粧料組成物である。
（Ａ）炭素数８の直鎖飽和脂肪酸
（Ｂ）炭素数１２の直鎖飽和脂肪酸
（Ｃ）炭素数１８の分岐飽和脂肪酸
That is, the first invention is an oily foam aerosol cosmetic cosmetic composition containing a liquid oil component comprising fats and / or ester oils and a diglycerin fatty acid ester having a hydroxyl group, the diglycerin having the hydroxyl group. A fatty acid ester is a cosmetic composition for oily foam aerosol cosmetics, characterized in that it comprises a mixture of esters of the following fatty acids (A) to (C).
(A) C8 linear saturated fatty acid (B) C12 linear saturated fatty acid (C) C18 branched saturated fatty acid
また、第二発明は、前記油状泡沫性エアゾール化粧料用化粧料組成物と噴射剤とを含有する油状泡沫性エアゾール化粧料である。 Moreover, 2nd invention is an oily foam aerosol cosmetics containing the said cosmetic composition for oily foam aerosol cosmetics, and a propellant.
また、第三発明は、油状泡沫性エアゾール化粧料がクレンジング化粧料であることを特徴とする前記油状泡沫性エアゾール化粧料であり、該油状泡沫性エアゾール化粧料は、例えば油性化粧料に対する洗浄力に優れており、クレンジング化粧料として用いることが好適である。 The third invention is the oily foam aerosol cosmetic characterized in that the oily foam aerosol cosmetic is a cleansing cosmetic, and the oily foam aerosol cosmetic is, for example, a detergency for oily cosmetics. It is suitable for use as a cleansing cosmetic.
本発明によれば、油脂類及び／又はエステル油からなる液状油分と特定組成の水酸基を有するジグリセリン脂肪酸エステルを配合して化粧料組成物を調製したので、均一溶解性、低温安定性に優れた化粧料組成物が得られる。該化粧料組成物と噴射剤を配合した油状泡沫性エアゾール化粧料は安定であり、さらに該油状泡沫性エアゾール化粧料の噴射によって得られる泡沫は、優れた起泡性、優れた泡の持続性を有する。前記油状泡沫性エアゾール化粧料は優れたクレンジング機能を有するクレンジング化粧料として有用である。 According to the present invention, since a cosmetic composition was prepared by blending a liquid oil component consisting of fats and oils and / or ester oils and a diglycerin fatty acid ester having a hydroxyl group of a specific composition, it was excellent in uniform solubility and low-temperature stability. A cosmetic composition is obtained. The oily foam aerosol cosmetic comprising the cosmetic composition and the propellant is stable, and the foam obtained by spraying the oily foam aerosol cosmetic has excellent foamability and excellent foam persistence. Have The oily foam aerosol cosmetic is useful as a cleansing cosmetic having an excellent cleansing function.
以下、本発明を実施するための最良の形態について詳述する。 Hereinafter, the best mode for carrying out the present invention will be described in detail.
本発明に係る油状泡沫性エアゾール化粧料は、油状泡沫性エアゾール化粧料用化粧料組成物と噴射剤とを含有する。以下、油状泡沫性エアゾール化粧料を単に「エアゾール化粧料」ともいい、油状泡沫性エアゾール化粧料用化粧料組成物を単に「化粧料組成物」ともいう。 The oily foam aerosol cosmetic composition according to the present invention contains an oily foam aerosol cosmetic composition and a propellant. Hereinafter, the oily foam aerosol cosmetic is also simply referred to as “aerosol cosmetic”, and the oily foam aerosol cosmetic composition is also simply referred to as “cosmetic composition”.
本発明に係る化粧料組成物には、水酸基を有するジグリセリン脂肪酸エステル（以下、単に「ジグリセリン脂肪酸エステル」または「脂肪酸ジグリセリル」という。さらに、カプリル酸、ラウリン酸、イソステアリン酸等の具体的な脂肪酸の水酸基を有するジグリセリンエステルについても同様に「水酸基を有する」を省略して表記する。）が配合される。前記ジグリセリン脂肪酸エステルは、下記（Ａ）〜（Ｃ）の脂肪酸のエステルの混合物からなる（以下、この本発明のジグリセリン脂肪酸エステルの混合物を「特定のジグリセリン脂肪酸エステル混合物」という。）。
（Ａ）炭素数８の直鎖飽和脂肪酸
（Ｂ）炭素数１２の直鎖飽和脂肪酸
（Ｃ）炭素数１８の分岐飽和脂肪酸
なお、（Ａ）の脂肪酸はカプリル酸であり、（Ｂ）の脂肪酸はラウリン酸である。また、（Ｃ）の脂肪酸としてはイソステアリン酸であることが好ましい。
The cosmetic composition according to the present invention includes a diglycerin fatty acid ester having a hydroxyl group (hereinafter simply referred to as “diglycerin fatty acid ester” or “fatty acid diglyceryl”. Furthermore, specific examples of caprylic acid, lauric acid, isostearic acid, etc.) Similarly, a diglycerin ester having a hydroxyl group of a fatty acid is represented by omitting “having a hydroxyl group”. The diglycerin fatty acid ester is composed of a mixture of the following fatty acid esters (A) to (C) (hereinafter, the diglycerin fatty acid ester mixture of the present invention is referred to as “specific diglycerin fatty acid ester mixture”).
(A) C8 linear saturated fatty acid (B) C12 linear saturated fatty acid (C) C18 branched saturated fatty acid The fatty acid (A) is caprylic acid, and the fatty acid (B) Is lauric acid. The fatty acid (C) is preferably isostearic acid.
ジグリセリン脂肪酸エステルは、例えば、公知の方法に従ってジグリセリンと脂肪酸とを窒素ガス等の不活性ガス存在下に加熱エステル化反応させ、所望によりさらに蒸留精製することによって得られるが、この方法に限定されるものではない。 The diglycerin fatty acid ester can be obtained, for example, by subjecting diglycerin and a fatty acid to a heat esterification reaction in the presence of an inert gas such as nitrogen gas according to a known method, and further purifying by distillation if desired. Is not to be done.
本発明に係る前記ジグリセリン脂肪酸エステルは、市販品を用いることが可能であり、市販品の例としては、例えばサンソフトＱ−８１Ｂ（ジグリセリンカプリル酸エステル）、サンソフトＱ−１２Ｄ（ジグリセリンラウリン酸エステル）（以上、太陽化学株式会社製）、コスモール４１Ｖ（ジグリセリンイソステアリン酸エステル）（日清オイリオグループ株式会社製）等が挙げられる。 Commercially available products can be used as the diglycerin fatty acid ester according to the present invention. Examples of commercially available products include Sunsoft Q-81B (diglycerin caprylate) and Sunsoft Q-12D (diglycerin). Lauric acid ester) (above, manufactured by Taiyo Kagaku Co., Ltd.), Cosmol 41V (diglycerin isostearic acid ester) (manufactured by Nisshin Oilio Group, Inc.) and the like.
本発明に係る前記ジグリセリン脂肪酸エステルの含有量は、特定のジグリセリン脂肪酸エステル混合物量として、化粧料組成物全量中１２〜８０質量％であることが好ましい。含有量がこの範囲であると、均一性、低温安定性に優れた化粧料組成物が得られ、この化粧料組成物を含有したエアゾール化粧料は安定で、泡状態が優れたものになる。さらに好ましい特定のジグリセリン脂肪酸エステル混合物の含有量は化粧料組成物全量中１６〜６０質量％である。 The content of the diglycerin fatty acid ester according to the present invention is preferably 12 to 80% by mass in the total amount of the cosmetic composition as the amount of the specific diglycerin fatty acid ester mixture. When the content is within this range, a cosmetic composition excellent in uniformity and low-temperature stability can be obtained, and the aerosol cosmetic containing the cosmetic composition is stable and has an excellent foam state. Furthermore, content of the preferable specific diglycerin fatty acid ester mixture is 16 to 60% by mass in the total amount of the cosmetic composition.
本発明に係る化粧料組成物には、さらに油脂類及び／又はエステル油からなる液状油分（以下、「特定の液状油分」という。）が配合される。なお、前記エステル油には油脂類が除かれる。本発明において液状油分は常温（２０℃）で液状であるものであり、特定の液状油分は前記ジグリセリン脂肪酸エステルと組み合わせて配合することにより、エアゾール化粧料に発泡性を付与させることができる。特定の液状油分は、一種又は二種以上が適宜選択されて配合される。特定の液状油分の具体例としては、例えば、油脂類として、オリーブ油、ホホバ油、米胚芽油、小麦胚芽油、サフラワー油、マカデミアナッツ油、ヒマシ油、ローズマリー油、コメヌカ油、アボカド油、ブドウ種子油等、エステル油として、パルミチン酸オクチル、トリ−２−エチルヘキサン酸グリセリル、トリ（カプリル・カプリン酸）グリセリン、ミリスチン酸イソプロピル、ジカプリン酸プロピレングリコール、２−エチルヘキサン酸セチル、イソノナン酸イソノニル、イソノナン酸イソトリデシル等が挙げられる。 The cosmetic composition according to the present invention is further mixed with a liquid oil component (hereinafter referred to as “specific liquid oil component”) composed of fats and oils and / or ester oils. In addition, fats and oils are excluded from the ester oil. In the present invention, the liquid oil is liquid at ordinary temperature (20 ° C.), and the specific liquid oil can be blended with the diglycerin fatty acid ester to impart foaming properties to the aerosol cosmetic. One or two or more specific liquid oil components are appropriately selected and blended. Specific examples of the specific liquid oil include, for example, oils and fats such as olive oil, jojoba oil, rice germ oil, wheat germ oil, safflower oil, macadamia nut oil, castor oil, rosemary oil, rice bran oil, avocado oil, grape As seed oils, ester oils such as octyl palmitate, glyceryl tri-2-ethylhexanoate, glyceryl tri (capryl / capric acid), isopropyl myristate, propylene glycol dicaprate, cetyl 2-ethylhexanoate, isononyl isononanoate, And isotridecyl isononanoate.
特定の液状油分として、特にオリーブ油を配合することが好ましい。オリーブ油は好ましくは特定の液状油分全量中５０質量％以上配合されると安定で、優れた泡状態のエアゾール化粧料が得られる。このものはクレンジング化粧料としての効果にも優れたものになる。 In particular, olive oil is preferably blended as the specific liquid oil. The olive oil is preferably stable when it is blended in an amount of 50% by mass or more based on the total amount of the specific liquid oil, and an excellent foam cosmetic aerosol can be obtained. This product also has an excellent effect as a cleansing cosmetic.
特定の液状油分の含有量は、化粧料組成物全量中２０〜８８質量％であることが好ましい。含有量がこの範囲であると、均一性、低温安定性に優れた化粧料組成物が得られ、この化粧料組成物を含有したエアゾール化粧料は安定で、泡状態が優れたものになる。さらに好ましい特定の液状油分の含有量は化粧料組成物全量中４０〜８４質量％である。 The specific liquid oil content is preferably 20 to 88% by mass in the total amount of the cosmetic composition. When the content is within this range, a cosmetic composition excellent in uniformity and low-temperature stability can be obtained, and the aerosol cosmetic containing the cosmetic composition is stable and has an excellent foam state. A more preferable specific liquid oil content is 40 to 84% by mass in the total amount of the cosmetic composition.
本発明に係る化粧料組成物には、前記成分の他に、化粧料、医薬部外品、医薬組成物等に通常用いられる他の成分を本発明の効果を損なわない範囲で適宜配合することができる。前記任意配合成分としては、例えば、前記本発明の必須成分以外の油分（例えば、炭化水素油（流動パラフィン、軽質流動イソパラフィン、スクワラン等）、シリコーン油（メチルポリシロキサン、メチルフェニルポリシロキサン、メチルハイドロジェンポリシロキサン、デカメチルシクロペンタシロキサン等）、高級アルコール（オレイルアルコール、イソステアリルアルコール等）、高級脂肪酸（オレイン酸、イソステアリン酸等）等の特定の液状油分以外の液状油分、固形油分、半固形油分）、本発明の必須成分以外の界面活性剤（水酸基を有するグリセリン脂肪酸エステル、ジグリセリン脂肪酸エステル以外の水酸基を有するポリグリセリン脂肪酸エステルを含む。）、保湿剤、油溶性高分子、油ゲル化剤、粉末、顔料、香料、水等を挙げることができる。 In the cosmetic composition according to the present invention, in addition to the above-mentioned components, other components usually used in cosmetics, quasi-drugs, pharmaceutical compositions and the like are appropriately blended within a range not impairing the effects of the present invention. Can do. Examples of the optional component include oils other than the essential components of the present invention (for example, hydrocarbon oil (liquid paraffin, light liquid isoparaffin, squalane, etc.), silicone oil (methylpolysiloxane, methylphenylpolysiloxane, methylhydro Genpolysiloxane, decamethylcyclopentasiloxane, etc.), higher alcohols (oleyl alcohol, isostearyl alcohol, etc.), higher fatty acids (oleic acid, isostearic acid, etc.) and other liquid oils other than specific liquid oils, solid oils, semi-solids Oil), surfactants other than essential components of the present invention (including glycerin fatty acid ester having a hydroxyl group, polyglycerin fatty acid ester having a hydroxyl group other than diglycerin fatty acid ester), moisturizer, oil-soluble polymer, oil gelation Agent, powder, pigment, fragrance, water, etc. It can be mentioned.
本発明に係る化粧料組成物は公知の方法に従って製造することができる。例えば、前記成分を適宜加熱して撹拌混合し、製造される。 The cosmetic composition according to the present invention can be produced according to a known method. For example, the components are appropriately heated and mixed by stirring.
本発明に係る噴射剤としては、液化石油ガス（以下、ＬＰＧという。）を使用することが望ましい。ＬＰＧとしては、例えば、プロパン、ブタンの混合物等化粧品用として一般に用いられるものであれば特に制限はない。 As the propellant according to the present invention, it is desirable to use liquefied petroleum gas (hereinafter referred to as LPG). LPG is not particularly limited as long as it is generally used for cosmetics such as a mixture of propane and butane.
本発明に係るエアゾール化粧料は、化粧料組成物と噴射剤とを配合して、公知の方法に従って製造することができる。例えば、エアゾール缶等のエアゾール用容器に化粧料組成物を入れ、前記容器に噴射剤を充填することにより製造することができる。 The aerosol cosmetic according to the present invention can be produced according to a known method by blending a cosmetic composition and a propellant. For example, it can be manufactured by putting a cosmetic composition in an aerosol container such as an aerosol can and filling the container with a propellant.
本発明に係るエアゾール化粧料中における、化粧料組成物と噴射剤の混合比は、特に限定されないが、化粧料組成物／噴射剤の混合比（質量比）が７０／３０〜９０／１０が好ましい。この範囲であると、本発明に係る噴射したときの泡状態を充分に発揮することができる。 The mixing ratio of the cosmetic composition and the propellant in the aerosol cosmetic according to the present invention is not particularly limited, but the mixing ratio (mass ratio) of the cosmetic composition / the propellant is 70/30 to 90/10. preferable. Within this range, the foam state when jetting according to the present invention can be sufficiently exhibited.
本発明に係るエアゾール化粧料の用途としては、特に限定するものではないが、例えば、油性化粧料のクレンジング化粧料、泡状マッサージオイル等が挙げられるが、好ましくは、クレンジング化粧料である。 The use of the aerosol cosmetic according to the present invention is not particularly limited, and examples thereof include cleansing cosmetics for oily cosmetics, foamed massage oils, and the like, but preferably cleansing cosmetics.
以下、さらに実施例を挙げて本発明を説明する。なお、配合量で特に単位の記載のないものは質量％である。 Hereinafter, the present invention will be described with further examples. In addition, what has no description of a unit in a compounding quantity is mass%.
実施例の説明に先立ち本発明で用いた効果試験方法について説明する。 Prior to the description of the examples, the effect test method used in the present invention will be described.
１．化粧料組成物の均一性
製造後の化粧料組成物を専門パネルが肉眼で観察し、下記の評価基準によって評価した。
1. Uniformity of the cosmetic composition The cosmetic composition after production was observed by a specialized panel with the naked eye and evaluated according to the following evaluation criteria.
（評価基準）
○：化粧料組成物の均一性がよい。
×：化粧料組成物の均一性が悪い。
(Evaluation criteria)
○: The uniformity of the cosmetic composition is good.
X: The uniformity of the cosmetic composition is poor.
２．化粧料組成物の低温安定性
化粧料組成物の均一性を確認した後、均一性がよいものにつきテストした。化粧料組成物を５℃、−５℃の恒温槽にそれぞれ保存し、１ヶ月後の外観変化を専門パネルにより下記の評価基準によって評価した。
2. Low-temperature stability of the cosmetic composition After confirming the uniformity of the cosmetic composition, the cosmetic composition having good uniformity was tested. The cosmetic composition was stored in a thermostatic bath at 5 ° C. and −5 ° C., respectively, and the appearance change after one month was evaluated by a professional panel according to the following evaluation criteria.
（評価基準）
○：いずれの温度でも、化粧料組成物の均一性に変化がなく、さらに析出物もなく均一で、経時での安定性がよい。
×：いずれかの温度で析出物が見られる等不均一になり、経時での安定性が悪い。
(Evaluation criteria)
○: At any temperature, there is no change in the uniformity of the cosmetic composition, and there is no precipitate, and the stability over time is good.
X: Precipitates are observed at any temperature, resulting in non-uniformity and poor stability over time.
３．エアゾール化粧料の泡状態
化粧料組成物の均一性、化粧料組成物の低温安定性について、前項迄の化粧料組成物の均一性、化粧料組成物の低温安定性のいずれもが評価○の化粧料組成物について試験を行った。専門パネルにより、試料（化粧料組成物）を充填したエアゾール化粧料を手のひらに噴射したときの泡の状態（起泡力、泡の持続性）を肉眼で観察し、下記の評価基準によって評価した。なお、泡の持続性は、噴射後３分以上泡が消滅しなかったものを「持続性が非常によい」とし、３分未満１分以上消滅しなかったものを「持続性がよい」とし、１分未満で消滅したものを「持続性がない」とした。
3. Foam state of aerosol cosmetics Regarding the uniformity of the cosmetic composition and the low temperature stability of the cosmetic composition, both the uniformity of the cosmetic composition up to the previous item and the low temperature stability of the cosmetic composition are evaluated. The cosmetic composition was tested. The state of foam (foaming power, persistence of foam) when an aerosol cosmetic filled with a sample (cosmetic composition) was sprayed on the palm of the body was observed with the naked eye and evaluated according to the following evaluation criteria. . In addition, as for the persistence of the foam, the one in which the foam did not disappear for 3 minutes or more after the injection was regarded as “very sustainable”, and the one in which the foam did not disappear for less than 1 minute for 1 minute or more was regarded as “good sustain” Those that disappeared in less than 1 minute were defined as “not persistent”.
［起泡力］
（評価基準）
○：起泡する。
×：起泡しない。
[Foaming power]
(Evaluation criteria)
○: Foaming occurs.
X: No foaming.
［泡の持続性］
（評価基準）
◎：泡の持続性が非常によい。
○：泡の持続性がよい。
×：泡の持続性がない。
[Foam persistence]
(Evaluation criteria)
A: The foam persistence is very good.
○: The foam persistence is good.
X: No foam persistence.
〔実施例１〜１６〕
表１〜３に示したそれぞれの成分を必要に応じて加熱して撹拌混合し、化粧料組成物を製造した。次いで、前記化粧料組成物を常温にてエアゾール缶に充填し、バルブをセットし、前記化粧料組成物８０質量部に対して、噴射剤としてＬＰＧを２０質量部充填し、エアゾール化粧料を製造した。さらに、上記実施例１〜１６の化粧料組成物及びエアゾール化粧料につき効果試験を行い、その評価結果を同じ表１〜３に示した。
[Examples 1 to 16]
Each component shown in Tables 1 to 3 was heated and mixed as needed to prepare a cosmetic composition. Next, the cosmetic composition is filled into an aerosol can at room temperature, a valve is set, and 80 parts by mass of the cosmetic composition is filled with 20 parts by mass of LPG as a propellant to produce an aerosol cosmetic. did. Furthermore, the effect test was done about the cosmetic composition and aerosol cosmetics of the said Examples 1-16, and the evaluation result was shown to the same Tables 1-3.
表１〜３の（注）は以下のとおりである。
（注１）サンソフトＱ−８１Ｂ（太陽化学株式会社製）
（注２）サンソフトＱ−１２Ｄ（太陽化学株式会社製）
（注３）コスモール４１Ｖ（日清オイリオグループ株式会社製）
Notes in Tables 1 to 3 are as follows.
(Note 1) Sunsoft Q-81B (manufactured by Taiyo Chemical Co., Ltd.)
(Note 2) Sunsoft Q-12D (manufactured by Taiyo Chemical Co., Ltd.)
(Note 3) Cosmall 41V (Nisshin Oilio Group Co., Ltd.)
表１〜３から明らかなように、特定の液状油分、並びにカプリル酸ジグリセリル、ラウリン酸ジグリセリル及びイソステアリン酸ジグリセリルの混合物を配合した化粧料組成物は、均一に溶解し、均一性がよく、低温安定性がよく安定な組成物であった。これらを充填したエアゾール化粧料は、優れた泡が得られた。 As is apparent from Tables 1 to 3, the cosmetic composition containing a specific liquid oil and a mixture of diglyceryl caprylate, diglyceryl laurate and diglyceryl isostearate dissolves uniformly and has good uniformity. The composition was stable and stable at low temperatures. In the aerosol cosmetics filled with these, excellent foams were obtained.
なお、これら実施例１〜１６のエアゾール化粧料は、化粧した化粧料を落とすクレンジング効果及び前記クレンジング後、クレンジング処理物を水で洗い流す洗いあがり効果は、いずれも良好であり、クレンジング化粧料としての優れた機能を有していた。すなわち、２０名の専門パネルに油性のファンデーションを顔に塗布してもらい、それをエアゾール化粧料を用いて洗浄（クレンジング）した後、前記クレンジング処理物を水で洗い流してもらい、前記クレンジング効果及び洗いあがりの状態を評価した結果、ファンデーションを完全に落とすことができ、さらに処理物を完全に洗い流すことができ、洗いあがりが非常に優れていた。 In addition, the aerosol cosmetics of Examples 1 to 16 are both cleansing effects for removing the cosmetics that have been made up, and the washing-up effects of washing the cleansed product with water after the cleansing, as cleansing cosmetics. It had an excellent function. That is, after having an oily foundation applied to the face of 20 professional panels, it was cleaned (cleansing) with aerosol cosmetics, and then the cleansing product was washed away with water, and the cleansing effect and washing As a result of evaluating the state of the finish, the foundation could be completely removed, and the treated product could be completely washed away, and the finish was very excellent.
〔比較例１〜１４〕
表４及び５に示したそれぞれの成分に基づき、実施例１と同様にして化粧料組成物を製造した。さらに、上記化粧料組成物につき効果試験を行い、その評価結果を同じ表４及び５に示した。なお、比較例１〜１４のいずれの化粧料組成物も均一性または低温安定性の評価が悪かったため、エアゾール化粧料の製造及び評価は行わなかった。
[Comparative Examples 1-14]
Based on the respective components shown in Tables 4 and 5, a cosmetic composition was produced in the same manner as in Example 1. Further, an effect test was conducted on the cosmetic composition, and the evaluation results are shown in Tables 4 and 5 below. In addition, since neither the cosmetic composition of Comparative Examples 1-14 was bad in evaluation of uniformity or low-temperature stability, manufacture and evaluation of aerosol cosmetics were not performed.
表４及び表５の（注）は以下のとおりである。
（注１）サンソフトＱ−８１Ｂ（太陽化学株式会社製）
（注２）サンソフトＱ−１２Ｄ（太陽化学株式会社製）
（注３）コスモール４１Ｖ（日清オイリオグループ株式会社製）
The notes in Table 4 and Table 5 are as follows.
(Note 1) Sunsoft Q-81B (manufactured by Taiyo Chemical Co., Ltd.)
(Note 2) Sunsoft Q-12D (manufactured by Taiyo Chemical Co., Ltd.)
(Note 3) Cosmall 41V (Nisshin Oilio Group Co., Ltd.)
また、評価中、「−」は試験をしなかったことを示す。 Moreover, during evaluation, “-” indicates that the test was not performed.
表４、５から明らかなように、配合する水酸基を有するポリグリセリン脂肪酸エステルの構成が本発明の範囲から外れた比較例１〜１４に係る化粧料組成物は、均一性が悪い、あるいは低温安定性において不安定であり、安定なエアゾール化粧料を得ることができない。したがって、これらの化粧料組成物を用いたものは商品価値のないものであり、エアゾール化しての泡状態を評価するには至らなかった。 As is clear from Tables 4 and 5, the cosmetic compositions according to Comparative Examples 1 to 14 in which the composition of the polyglycerin fatty acid ester having a hydroxyl group to be incorporated is out of the scope of the present invention are poor in uniformity or stable at low temperatures. It is unstable in sex and a stable aerosol cosmetic cannot be obtained. Therefore, those using these cosmetic compositions have no commercial value, and have not been able to evaluate the foamed state after being aerosolized.
以下、さらに本発明に係る化粧料組成物の実施例及び前記化粧料組成物を配合したエアゾール化粧料の実施例を示す。実施例１８以降の製造は実施例１７の方法に準じて行った。なお、以下の実施例で配合の、カプリル酸ジグリセリルはサンソフトＱ−８１Ｂ（太陽化学株式会社製）、ラウリン酸ジグリセリルはサンソフトＱ−１２Ｄ（太陽化学株式会社製）、イソステアリン酸ジグリセリルはコスモール４１Ｖ（日清オイリオグループ株式会社製）を用いた。これらいずれのエアゾール化粧料も優れたクレンジング機能を有するものであった。 Hereinafter, examples of the cosmetic composition according to the present invention and examples of aerosol cosmetics containing the cosmetic composition will be described. Production after Example 18 was carried out according to the method of Example 17. In the following examples, diglyceryl caprylate was Sunsoft Q-81B (manufactured by Taiyo Kagaku), diglyceryl laurate was Sunsoft Q-12D (manufactured by Taiyo Kagaku), and diglyceryl isostearate. Used Cosmall 41V (Nisshin Oillio Group Co., Ltd.). Any of these aerosol cosmetics had an excellent cleansing function.
〔実施例１７〕
Ａ；化粧料組成物（８０質量部）
成分 配合量（質量％）
カプリル酸ジグリセリル（注１） ５．０
ラウリン酸ジグリセリル（注２） １０．０
イソステアリン酸ジグリセリル（注３） ５．０
オリーブ油 ４０．０
２−エチルヘキサン酸セチル ４０．０
合計１００．０
Ｂ；噴射剤（２０質量部）
ＬＰＧ
Example 17
A: Cosmetic composition (80 parts by mass)
Ingredient Amount (% by mass)
Diglyceryl caprylate (Note 1) 5.0
Diglyceryl laurate (Note 2) 10.0
Diglyceryl isostearate (Note 3) 5.0
Olive oil 40.0
Cetyl 2-ethylhexanoate 40.0
Total 100.0
B: propellant (20 parts by mass)
LPG
（製造法）
Ａ（化粧料組成物）の成分を８０℃で充分撹拌混合した後、常温まで冷却して化粧料組成物を製造した。次いで、前記化粧料組成物をエアゾール缶に充填し、バルブをセットし、前記化粧料組成物８０質量部に対して、噴射剤（ＬＰＧ）を２０質量部充填し、エアゾール化粧料を製造した。
(Production method)
A component of A (cosmetic composition) was sufficiently stirred and mixed at 80 ° C., and then cooled to room temperature to produce a cosmetic composition. Then, the cosmetic composition was filled in an aerosol can, a valve was set, and 20 parts by mass of a propellant (LPG) was filled into 80 parts by mass of the cosmetic composition to produce an aerosol cosmetic.
〔実施例１８〕
Ａ；化粧料組成物（８０質量部）
成分 配合量（質量％）
カプリル酸ジグリセリル（注１） ５．０
ラウリン酸ジグリセリル（注２） １０．０
イソステアリン酸ジグリセリル（注３） ５．０
オリーブ油 ６０．０
パルミチン酸オクチル １７．０
流動パラフィン ３．０
合計１００．０
Ｂ；噴射剤（２０質量部）
ＬＰＧ
Example 18
A: Cosmetic composition (80 parts by mass)
Ingredient Amount (% by mass)
Diglyceryl caprylate (Note 1) 5.0
Diglyceryl laurate (Note 2) 10.0
Diglyceryl isostearate (Note 3) 5.0
Olive oil 60.0
Octyl palmitate 17.0
Liquid paraffin 3.0
Total 100.0
B: propellant (20 parts by mass)
LPG
〔実施例１９〕
Ａ；化粧料組成物（８０質量部）
成分 配合量（質量％）
カプリル酸ジグリセリル（注１） ３．０
ラウリン酸ジグリセリル（注２） １２．０
イソステアリン酸ジグリセリル（注３） ５．０
オリーブ油 ８０．０
合計１００．０
Ｂ；噴射剤（２０質量部）
ＬＰＧ
Example 19
A: Cosmetic composition (80 parts by mass)
Ingredient Amount (% by mass)
Diglyceryl caprylate (Note 1) 3.0
Diglyceryl laurate (Note 2) 12.0
Diglyceryl isostearate (Note 3) 5.0
Olive oil 80.0
Total 100.0
B: propellant (20 parts by mass)
LPG
〔実施例２０〕
Ａ；化粧料組成物（８０質量部）
成分 配合量（質量％）
カプリル酸ジグリセリル（注１） １５．０
ラウリン酸ジグリセリル（注２） １５．０
イソステアリン酸ジグリセリル（注３） １０．０
オリーブ油 ４０．０
パルミチン酸オクチル １９．９
水 ０．１
合計１００．０
Ｂ；噴射剤（２０質量部）
ＬＰＧ
Example 20
A: Cosmetic composition (80 parts by mass)
Ingredient Amount (% by mass)
Diglyceryl caprylate (Note 1) 15.0
Diglyceryl laurate (Note 2) 15.0
Diglyceryl isostearate (Note 3) 10.0
Olive oil 40.0
Octyl palmitate 19.9
Water 0.1
Total 100.0
B: propellant (20 parts by mass)
LPG
〔実施例２１〕
Ａ；化粧料組成物（８０質量部）
成分 配合量（質量％）
カプリル酸ジグリセリル（注１） ５．０
ラウリン酸ジグリセリル（注２） ８．０
イソステアリン酸ジグリセリル（注３） ３．０
オリーブ油 ６０．０
パルミチン酸オクチル １４．０
イソノナン酸イソノニル １０．０
合計１００．０
Ｂ；噴射剤（２０質量部）
ＬＰＧ
Example 21
A: Cosmetic composition (80 parts by mass)
Ingredient Amount (% by mass)
Diglyceryl caprylate (Note 1) 5.0
Diglyceryl laurate (Note 2) 8.0
Diglyceryl isostearate (Note 3) 3.0
Olive oil 60.0
Octyl palmitate 14.0
Isononyl isononanoate 10.0
Total 100.0
B: propellant (20 parts by mass)
LPG
〔実施例２２〕
Ａ；化粧料組成物（８０質量部）
成分 配合量（質量％）
カプリル酸ジグリセリル（注１） １５．０
ラウリン酸ジグリセリル（注２） ３０．０
イソステアリン酸ジグリセリル（注３） １５．０
オリーブ油 ２５．０
ホホバ油 ５．０
トリ−２−エチルヘキサン酸グリセリル ５．０
パルミチン酸オクチル ５．０
合計１００．０
Ｂ；噴射剤（２０質量部）
ＬＰＧ
[Example 22]
A: Cosmetic composition (80 parts by mass)
Ingredient Amount (% by mass)
Diglyceryl caprylate (Note 1) 15.0
Diglyceryl laurate (Note 2) 30.0
Diglyceryl isostearate (Note 3) 15.0
Olive oil 25.0
Jojoba oil 5.0
Glyceryl tri-2-ethylhexanoate 5.0
Octyl palmitate 5.0
Total 100.0
B: propellant (20 parts by mass)
LPG
Claims (3)
（Ａ）炭素数８の直鎖飽和脂肪酸
（Ｂ）炭素数１２の直鎖飽和脂肪酸
（Ｃ）炭素数１８の分岐飽和脂肪酸 An oily foam aerosol cosmetic cosmetic composition comprising a liquid oil comprising fats and / or ester oils and a diglycerin fatty acid ester having a hydroxyl group, wherein the diglycerin fatty acid ester having a hydroxyl group is the following (A A cosmetic composition for oily foam aerosol cosmetics, comprising a mixture of esters of fatty acids of (A) to (C).
(A) C8 linear saturated fatty acid (B) C12 linear saturated fatty acid (C) C18 branched saturated fatty acid
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011213680A (en) * | 2010-03-31 | 2011-10-27 | Naris Cosmetics Co Ltd | Foaming cleansing cosmetic |
| JP2012250939A (en) * | 2011-06-03 | 2012-12-20 | Kao Corp | Oily liquid cleansing cosmetic |
| JP2019183079A (en) * | 2018-04-17 | 2019-10-24 | 花王株式会社 | Detergent composition |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003035015A1 (en) * | 2001-10-26 | 2003-05-01 | Taiyo Kagaku Co., Ltd. | Composition for oily foamable aerosol |
| JP2004203847A (en) * | 2002-11-01 | 2004-07-22 | Shiseido Co Ltd | Foaming aerosol makeup remover |
| JP2004352646A (en) * | 2003-05-29 | 2004-12-16 | Pola Chem Ind Inc | Foamy cosmetic with warm feeling stable with time |
| JP2005145903A (en) * | 2003-11-17 | 2005-06-09 | Shiseido Co Ltd | Foamy aerosol makeup cleansing agent |
| JP2006176469A (en) * | 2004-12-24 | 2006-07-06 | Kao Corp | Oily cleanser |
-
2008
- 2008-07-23 JP JP2008189917A patent/JP5164709B2/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003035015A1 (en) * | 2001-10-26 | 2003-05-01 | Taiyo Kagaku Co., Ltd. | Composition for oily foamable aerosol |
| JP2004203847A (en) * | 2002-11-01 | 2004-07-22 | Shiseido Co Ltd | Foaming aerosol makeup remover |
| JP2004352646A (en) * | 2003-05-29 | 2004-12-16 | Pola Chem Ind Inc | Foamy cosmetic with warm feeling stable with time |
| JP2005145903A (en) * | 2003-11-17 | 2005-06-09 | Shiseido Co Ltd | Foamy aerosol makeup cleansing agent |
| JP2006176469A (en) * | 2004-12-24 | 2006-07-06 | Kao Corp | Oily cleanser |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011213680A (en) * | 2010-03-31 | 2011-10-27 | Naris Cosmetics Co Ltd | Foaming cleansing cosmetic |
| JP2012250939A (en) * | 2011-06-03 | 2012-12-20 | Kao Corp | Oily liquid cleansing cosmetic |
| JP2019183079A (en) * | 2018-04-17 | 2019-10-24 | 花王株式会社 | Detergent composition |
| JP7017976B2 (en) | 2018-04-17 | 2022-02-09 | 花王株式会社 | Detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5164709B2 (en) | 2013-03-21 |
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