JP2011093878A - Aerosol type skin cosmetic - Google Patents
Aerosol type skin cosmetic Download PDFInfo
- Publication number
- JP2011093878A JP2011093878A JP2010002054A JP2010002054A JP2011093878A JP 2011093878 A JP2011093878 A JP 2011093878A JP 2010002054 A JP2010002054 A JP 2010002054A JP 2010002054 A JP2010002054 A JP 2010002054A JP 2011093878 A JP2011093878 A JP 2011093878A
- Authority
- JP
- Japan
- Prior art keywords
- aerosol
- skin cosmetic
- type skin
- foam
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 44
- 239000000443 aerosol Substances 0.000 title claims abstract description 17
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 19
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 17
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract description 11
- 150000005215 alkyl ethers Chemical class 0.000 claims abstract description 9
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 9
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 9
- 229920001577 copolymer Polymers 0.000 claims description 10
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 8
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 8
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 8
- 229920002545 silicone oil Polymers 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 125000003342 alkenyl group Chemical group 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 150000002772 monosaccharides Chemical class 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 150000002016 disaccharides Chemical class 0.000 claims description 3
- 239000006260 foam Substances 0.000 abstract description 39
- 229920000223 polyglycerol Polymers 0.000 abstract 1
- -1 etc. Chemical compound 0.000 description 13
- 229920001296 polysiloxane Polymers 0.000 description 13
- 238000005406 washing Methods 0.000 description 12
- 150000001720 carbohydrates Chemical class 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 150000004676 glycans Chemical class 0.000 description 8
- 229920001282 polysaccharide Polymers 0.000 description 8
- 239000005017 polysaccharide Substances 0.000 description 8
- 239000003380 propellant Substances 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- HANWHVWXFQSQGJ-UHFFFAOYSA-N 1-tetradecoxytetradecane Chemical compound CCCCCCCCCCCCCCOCCCCCCCCCCCCCC HANWHVWXFQSQGJ-UHFFFAOYSA-N 0.000 description 5
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 5
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 4
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 description 4
- LTSWUFKUZPPYEG-UHFFFAOYSA-N 1-decoxydecane Chemical compound CCCCCCCCCCOCCCCCCCCCC LTSWUFKUZPPYEG-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000284 extract Substances 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 239000003915 liquefied petroleum gas Substances 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- 230000001815 facial effect Effects 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 230000007794 irritation Effects 0.000 description 3
- 235000010449 maltitol Nutrition 0.000 description 3
- 239000000845 maltitol Substances 0.000 description 3
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 3
- 229940035436 maltitol Drugs 0.000 description 3
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 239000005720 sucrose Substances 0.000 description 3
- JYKSTGLAIMQDRA-UHFFFAOYSA-N tetraglycerol Chemical compound OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO JYKSTGLAIMQDRA-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- WQZGKKKJIJFFOK-SVZMEOIVSA-N (+)-Galactose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-SVZMEOIVSA-N 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 2
- HQLVRJJDJGNYQW-UHFFFAOYSA-O 3-prop-1-enyl-1H-imidazol-3-ium Chemical compound CC=C[NH+]1C=NC=C1 HQLVRJJDJGNYQW-UHFFFAOYSA-O 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- ZAQJHHRNXZUBTE-UHFFFAOYSA-N D-threo-2-Pentulose Natural products OCC(O)C(O)C(=O)CO ZAQJHHRNXZUBTE-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- ZAQJHHRNXZUBTE-UCORVYFPSA-N L-ribulose Chemical compound OC[C@H](O)[C@H](O)C(=O)CO ZAQJHHRNXZUBTE-UCORVYFPSA-N 0.000 description 2
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- OVVGHDNPYGTYIT-VHBGUFLRSA-N Robinobiose Natural products O(C[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)O1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](C)O1 OVVGHDNPYGTYIT-VHBGUFLRSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- PYMYPHUHKUWMLA-LMVFSUKVSA-N aldehydo-D-ribose Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](O)C=O PYMYPHUHKUWMLA-LMVFSUKVSA-N 0.000 description 2
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 description 2
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 2
- 230000009172 bursting Effects 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- DENRZWYUOJLTMF-UHFFFAOYSA-N diethyl sulfate Chemical compound CCOS(=O)(=O)OCC DENRZWYUOJLTMF-UHFFFAOYSA-N 0.000 description 2
- 229940008406 diethyl sulfate Drugs 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 235000010355 mannitol Nutrition 0.000 description 2
- 230000004060 metabolic process Effects 0.000 description 2
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 2
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 235000010356 sorbitol Nutrition 0.000 description 2
- 229960002920 sorbitol Drugs 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- 150000008163 sugars Chemical class 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 1
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- LGQKSQQRKHFMLI-SJYYZXOBSA-N (2s,3r,4s,5r)-2-[(3r,4r,5r,6r)-4,5,6-trihydroxyoxan-3-yl]oxyoxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@H](O)CO[C@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)OC1 LGQKSQQRKHFMLI-SJYYZXOBSA-N 0.000 description 1
- NNOKXWHHOOMPPR-UHFFFAOYSA-N 1-ethenyl-1h-imidazol-1-ium;trichloride Chemical compound [Cl-].[Cl-].[Cl-].C=C[NH+]1C=CN=C1.C=C[NH+]1C=CN=C1.C=C[NH+]1C=CN=C1 NNOKXWHHOOMPPR-UHFFFAOYSA-N 0.000 description 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- MPJSWQKTHQXGQA-UHFFFAOYSA-M 3,3-dimethyl-3-azoniabicyclo[3.1.1]heptane;chloride Chemical compound [Cl-].C1[N+](C)(C)CC2CC1C2 MPJSWQKTHQXGQA-UHFFFAOYSA-M 0.000 description 1
- QIGJYVCQYDKYDW-UHFFFAOYSA-N 3-O-alpha-D-mannopyranosyl-D-mannopyranose Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(CO)OC(O)C1O QIGJYVCQYDKYDW-UHFFFAOYSA-N 0.000 description 1
- XPFCZYUVICHKDS-UHFFFAOYSA-N 3-methylbutane-1,3-diol Chemical compound CC(C)(O)CCO XPFCZYUVICHKDS-UHFFFAOYSA-N 0.000 description 1
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- LGQKSQQRKHFMLI-UHFFFAOYSA-N 4-O-beta-D-xylopyranosyl-beta-D-xylopyranose Natural products OC1C(O)C(O)COC1OC1C(O)C(O)C(O)OC1 LGQKSQQRKHFMLI-UHFFFAOYSA-N 0.000 description 1
- KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical compound C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 description 1
- BQBYBPAPSIWHCE-UHFFFAOYSA-N 5-(dimethylamino)-2-methylpent-2-enoic acid Chemical compound CN(C)CCC=C(C)C(O)=O BQBYBPAPSIWHCE-UHFFFAOYSA-N 0.000 description 1
- SQDAZGGFXASXDW-UHFFFAOYSA-N 5-bromo-2-(trifluoromethoxy)pyridine Chemical compound FC(F)(F)OC1=CC=C(Br)C=N1 SQDAZGGFXASXDW-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- JPLATTLXZFUKRQ-UHFFFAOYSA-N Agarobiose Natural products OCC1OC(OC2C(O)COC2C(O)C=O)C(O)C(O)C1O JPLATTLXZFUKRQ-UHFFFAOYSA-N 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 102000011632 Caseins Human genes 0.000 description 1
- 108010076119 Caseins Proteins 0.000 description 1
- 229920001287 Chondroitin sulfate Polymers 0.000 description 1
- 241000951471 Citrus junos Species 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 239000001879 Curdlan Substances 0.000 description 1
- 229920002558 Curdlan Polymers 0.000 description 1
- AVGPOAXYRRIZMM-UHFFFAOYSA-N D-Apiose Natural products OCC(O)(CO)C(O)C=O AVGPOAXYRRIZMM-UHFFFAOYSA-N 0.000 description 1
- HEBKCHPVOIAQTA-NGQZWQHPSA-N D-Arabitol Natural products OC[C@H](O)C(O)[C@H](O)CO HEBKCHPVOIAQTA-NGQZWQHPSA-N 0.000 description 1
- GUBGYTABKSRVRQ-CUHNMECISA-N D-Cellobiose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-CUHNMECISA-N 0.000 description 1
- YTBSYETUWUMLBZ-UHFFFAOYSA-N D-Erythrose Natural products OCC(O)C(O)C=O YTBSYETUWUMLBZ-UHFFFAOYSA-N 0.000 description 1
- RFSUNEUAIZKAJO-VRPWFDPXSA-N D-Fructose Natural products OC[C@H]1OC(O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-VRPWFDPXSA-N 0.000 description 1
- ASNHGEVAWNWCRQ-LJJLCWGRSA-N D-apiofuranose Chemical compound OC[C@@]1(O)COC(O)[C@@H]1O ASNHGEVAWNWCRQ-LJJLCWGRSA-N 0.000 description 1
- ASNHGEVAWNWCRQ-UHFFFAOYSA-N D-apiofuranose Natural products OCC1(O)COC(O)C1O ASNHGEVAWNWCRQ-UHFFFAOYSA-N 0.000 description 1
- HEBKCHPVOIAQTA-QWWZWVQMSA-N D-arabinitol Chemical compound OC[C@@H](O)C(O)[C@H](O)CO HEBKCHPVOIAQTA-QWWZWVQMSA-N 0.000 description 1
- YTBSYETUWUMLBZ-IUYQGCFVSA-N D-erythrose Chemical compound OC[C@@H](O)[C@@H](O)C=O YTBSYETUWUMLBZ-IUYQGCFVSA-N 0.000 description 1
- UQPHVQVXLPRNCX-GSVOUGTGSA-N D-erythrulose Chemical compound OC[C@@H](O)C(=O)CO UQPHVQVXLPRNCX-GSVOUGTGSA-N 0.000 description 1
- ZGVNGXVNRCEBDS-HSUXUTPPSA-N D-hamamelose Chemical compound OC[C@@H](O)[C@@H](O)[C@](O)(CO)C=O ZGVNGXVNRCEBDS-HSUXUTPPSA-N 0.000 description 1
- ZGVNGXVNRCEBDS-UHFFFAOYSA-N D-hamamelose Natural products OCC(O)C(O)C(O)(CO)C=O ZGVNGXVNRCEBDS-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- BJHIKXHVCXFQLS-PUFIMZNGSA-N D-psicose Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](O)C(=O)CO BJHIKXHVCXFQLS-PUFIMZNGSA-N 0.000 description 1
- SRBFZHDQGSBBOR-SOOFDHNKSA-N D-ribopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@@H]1O SRBFZHDQGSBBOR-SOOFDHNKSA-N 0.000 description 1
- LKDRXBCSQODPBY-OEXCPVAWSA-N D-tagatose Chemical compound OCC1(O)OC[C@@H](O)[C@H](O)[C@@H]1O LKDRXBCSQODPBY-OEXCPVAWSA-N 0.000 description 1
- YTBSYETUWUMLBZ-QWWZWVQMSA-N D-threose Chemical compound OC[C@@H](O)[C@H](O)C=O YTBSYETUWUMLBZ-QWWZWVQMSA-N 0.000 description 1
- SQNRKWHRVIAKLP-UHFFFAOYSA-N D-xylobiose Natural products O=CC(O)C(O)C(CO)OC1OCC(O)C(O)C1O SQNRKWHRVIAKLP-UHFFFAOYSA-N 0.000 description 1
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 1
- ZAQJHHRNXZUBTE-WUJLRWPWSA-N D-xylulose Chemical compound OC[C@@H](O)[C@H](O)C(=O)CO ZAQJHHRNXZUBTE-WUJLRWPWSA-N 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 239000004386 Erythritol Substances 0.000 description 1
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- BIVBRWYINDPWKA-VLQRKCJKSA-L Glycyrrhizinate dipotassium Chemical compound [K+].[K+].O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@H]1CC[C@]2(C)[C@H]3C(=O)C=C4[C@@H]5C[C@](C)(CC[C@@]5(CC[C@@]4(C)[C@]3(C)CC[C@H]2C1(C)C)C)C(O)=O)C([O-])=O)[C@@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@H]1O BIVBRWYINDPWKA-VLQRKCJKSA-L 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- AYRXSINWFIIFAE-SCLMCMATSA-N Isomaltose Natural products OC[C@H]1O[C@H](OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O)[C@@H](O)[C@@H](O)[C@@H]1O AYRXSINWFIIFAE-SCLMCMATSA-N 0.000 description 1
- LKDRXBCSQODPBY-AMVSKUEXSA-N L-(-)-Sorbose Chemical compound OCC1(O)OC[C@H](O)[C@@H](O)[C@@H]1O LKDRXBCSQODPBY-AMVSKUEXSA-N 0.000 description 1
- WQZGKKKJIJFFOK-DHVFOXMCSA-N L-galactose Chemical compound OC[C@@H]1OC(O)[C@@H](O)[C@H](O)[C@@H]1O WQZGKKKJIJFFOK-DHVFOXMCSA-N 0.000 description 1
- SRBFZHDQGSBBOR-OWMBCFKOSA-N L-ribopyranose Chemical compound O[C@H]1COC(O)[C@@H](O)[C@H]1O SRBFZHDQGSBBOR-OWMBCFKOSA-N 0.000 description 1
- ZAQJHHRNXZUBTE-WVZVXSGGSA-N L-xylulose Chemical compound OC[C@H](O)[C@@H](O)C(=O)CO ZAQJHHRNXZUBTE-WVZVXSGGSA-N 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- NBGXQZRRLOGAJF-UHFFFAOYSA-N Maltulose Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)(CO)OCC1O NBGXQZRRLOGAJF-UHFFFAOYSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- KSHFWAZCFMBCKS-UHFFFAOYSA-N N-[3-(dimethylamino)pentadecyl]-2-methylprop-2-enamide Chemical compound C(C(=C)C)(=O)NCCC(N(C)C)CCCCCCCCCCCC KSHFWAZCFMBCKS-UHFFFAOYSA-N 0.000 description 1
- 241000183666 Nepsera aquatica Species 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 108010020346 Polyglutamic Acid Proteins 0.000 description 1
- 108010039918 Polylysine Proteins 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- HDSBZMRLPLPFLQ-UHFFFAOYSA-N Propylene glycol alginate Chemical compound OC1C(O)C(OC)OC(C(O)=O)C1OC1C(O)C(O)C(C)C(C(=O)OCC(C)O)O1 HDSBZMRLPLPFLQ-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- BUEBVQCTEJTADB-UHFFFAOYSA-N Sambubiose Natural products OC1C(O)C(CO)OC(O)C1OC1C(O)C(O)C(O)CO1 BUEBVQCTEJTADB-UHFFFAOYSA-N 0.000 description 1
- HIWPGCMGAMJNRG-ACCAVRKYSA-N Sophorose Natural products O([C@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HIWPGCMGAMJNRG-ACCAVRKYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- DRQXUCVJDCRJDB-UHFFFAOYSA-N Turanose Natural products OC1C(CO)OC(O)(CO)C1OC1C(O)C(O)C(O)C(CO)O1 DRQXUCVJDCRJDB-UHFFFAOYSA-N 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 125000004442 acylamino group Chemical group 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- GZCGUPFRVQAUEE-KAZBKCHUSA-N aldehydo-D-talose Chemical compound OC[C@@H](O)[C@H](O)[C@H](O)[C@H](O)C=O GZCGUPFRVQAUEE-KAZBKCHUSA-N 0.000 description 1
- PYMYPHUHKUWMLA-YUPRTTJUSA-N aldehydo-L-lyxose Chemical compound OC[C@H](O)[C@@H](O)[C@@H](O)C=O PYMYPHUHKUWMLA-YUPRTTJUSA-N 0.000 description 1
- 150000001312 aldohexoses Chemical class 0.000 description 1
- 150000001323 aldoses Chemical class 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- HDTRYLNUVZCQOY-BTLHAWITSA-N alpha,beta-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-BTLHAWITSA-N 0.000 description 1
- HMFHBZSHGGEWLO-UHFFFAOYSA-N alpha-D-Furanose-Ribose Natural products OCC1OC(O)C(O)C1O HMFHBZSHGGEWLO-UHFFFAOYSA-N 0.000 description 1
- SRBFZHDQGSBBOR-STGXQOJASA-N alpha-D-lyxopyranose Chemical compound O[C@@H]1CO[C@H](O)[C@@H](O)[C@H]1O SRBFZHDQGSBBOR-STGXQOJASA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- QIGJYVCQYDKYDW-KQBIKJCISA-N beta-D-Glcp-(1->3)-D-Galp Chemical compound OC[C@H]1O[C@@H](O[C@@H]2[C@@H](O)C(O)O[C@H](CO)[C@@H]2O)[C@H](O)[C@@H](O)[C@@H]1O QIGJYVCQYDKYDW-KQBIKJCISA-N 0.000 description 1
- WOHYVFWWTVNXTP-TWOHWVPZSA-N beta-D-fructofuranosyl-(2,1)-beta-D-fructofuranose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@]1(O)CO[C@@]1(CO)[C@@H](O)[C@H](O)[C@@H](CO)O1 WOHYVFWWTVNXTP-TWOHWVPZSA-N 0.000 description 1
- DLRVVLDZNNYCBX-ZZFZYMBESA-N beta-melibiose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)O1 DLRVVLDZNNYCBX-ZZFZYMBESA-N 0.000 description 1
- HIWPGCMGAMJNRG-UHFFFAOYSA-N beta-sophorose Natural products OC1C(O)C(CO)OC(O)C1OC1C(O)C(O)C(O)C(CO)O1 HIWPGCMGAMJNRG-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229940059329 chondroitin sulfate Drugs 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 235000019316 curdlan Nutrition 0.000 description 1
- 229940078035 curdlan Drugs 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 229940101029 dipotassium glycyrrhizinate Drugs 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- FBPFZTCFMRRESA-GUCUJZIJSA-N galactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-GUCUJZIJSA-N 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- DLRVVLDZNNYCBX-RTPHMHGBSA-N isomaltose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)C(O)O1 DLRVVLDZNNYCBX-RTPHMHGBSA-N 0.000 description 1
- 150000002574 ketohexoses Chemical class 0.000 description 1
- 150000002581 ketopentoses Chemical class 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- JCQLYHFGKNRPGE-FCVZTGTOSA-N lactulose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 JCQLYHFGKNRPGE-FCVZTGTOSA-N 0.000 description 1
- 229960000511 lactulose Drugs 0.000 description 1
- PFCRQPBOOFTZGQ-UHFFFAOYSA-N lactulose keto form Natural products OCC(=O)C(O)C(C(O)CO)OC1OC(CO)C(O)C(O)C1O PFCRQPBOOFTZGQ-UHFFFAOYSA-N 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- JCQLYHFGKNRPGE-HFZVAGMNSA-N maltulose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 JCQLYHFGKNRPGE-HFZVAGMNSA-N 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-N methyl sulfate Chemical compound COS(O)(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229940088644 n,n-dimethylacrylamide Drugs 0.000 description 1
- YLGYACDQVQQZSW-UHFFFAOYSA-N n,n-dimethylprop-2-enamide Chemical compound CN(C)C(=O)C=C YLGYACDQVQQZSW-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 229960000292 pectin Drugs 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 150000002972 pentoses Chemical class 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000724 poly(L-arginine) polymer Polymers 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 108010011110 polyarginine Proteins 0.000 description 1
- 229920002643 polyglutamic acid Polymers 0.000 description 1
- 229920000656 polylysine Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 235000010409 propane-1,2-diol alginate Nutrition 0.000 description 1
- 239000000770 propane-1,2-diol alginate Substances 0.000 description 1
- 239000001651 pyrus cydonia seed extract Substances 0.000 description 1
- HEBKCHPVOIAQTA-ZXFHETKHSA-N ribitol Chemical compound OC[C@H](O)[C@H](O)[C@H](O)CO HEBKCHPVOIAQTA-ZXFHETKHSA-N 0.000 description 1
- OVVGHDNPYGTYIT-PEPLWKDOSA-N robinose Chemical compound O[C@@H]1[C@H](O)[C@@H](O)[C@H](C)O[C@H]1OC[C@@H]1[C@H](O)[C@H](O)[C@@H](O)[C@H](O)O1 OVVGHDNPYGTYIT-PEPLWKDOSA-N 0.000 description 1
- OVVGHDNPYGTYIT-BNXXONSGSA-N rutinose Chemical compound O[C@@H]1[C@H](O)[C@@H](O)[C@H](C)O[C@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)O1 OVVGHDNPYGTYIT-BNXXONSGSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- BUEBVQCTEJTADB-IGQSMMPPSA-N sambubiose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)CO1 BUEBVQCTEJTADB-IGQSMMPPSA-N 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 235000019615 sensations Nutrition 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- HIWPGCMGAMJNRG-RTPHMHGBSA-N sophorose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)OC(O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HIWPGCMGAMJNRG-RTPHMHGBSA-N 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 235000010487 tragacanth Nutrition 0.000 description 1
- 239000000196 tragacanth Substances 0.000 description 1
- 229940116362 tragacanth Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- RULSWEULPANCDV-PIXUTMIVSA-N turanose Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](C(=O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O RULSWEULPANCDV-PIXUTMIVSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- DFKDOZMCHOGOBR-UHFFFAOYSA-N zaragozic acid A Natural products O1C(C(O)(C(O2)C(O)=O)C(O)=O)(C(O)=O)C(OC(=O)C=CC(C)CC(C)CC)C(O)C21CCC(=C)C(OC(C)=O)C(C)CC1=CC=CC=C1 DFKDOZMCHOGOBR-UHFFFAOYSA-N 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、マッサージしやすく、洗い流した後も、肌にしっとりとした感触を与えるエアゾール型皮膚化粧料に関するものである。 The present invention relates to an aerosol type skin cosmetic that is easy to massage and gives a moist feel to the skin even after washing.
エアゾール型皮膚化粧料は、化粧水を噴霧するスプレータイプや、洗顔料やパックなどを泡状にして吐出するフォームタイプなど幅広く利用されている。特に、フォームタイプでは泡状に吐出された化粧料が肌に塗布されることにより、肌と外気とを遮断し、皮膚温を上昇させることで皮膚の新陳代謝を促進させ、組成物中に含まれる有効成分の浸透を促進する効果を持つため、マッサージ料として検討が進められている。
しかし、フォームタイプにおいては、皮膚上で泡状の化粧料をある程度の時間、マッサージを行うと、体温で泡状の化粧料が暖められることで泡が柔らかく(粗く)なってしまい、泡が安定化しにくいという問題がある。泡が粗く、泡の安定性が不十分であると、顔などの皮膚と手のひらの間に泡のクッションができず、摩擦による刺激が大きくなってしまう。また、外気との遮断性が損なわれるため、新陳代謝を十分に高めることできない。
また、LPG等のガスで発泡させるエアゾール型皮膚化粧料では、マッサージ施術中に皮膚上で泡の破裂に伴う、プチプチ弾ける感触が刺激と感じられることがあり、デリケートな肌質の人では、ひりひり感を感じ、炎症を起こしてしまうという問題があった。
Aerosol-type skin cosmetics are widely used, such as a spray type for spraying lotion and a foam type for discharging facial cleansers or packs in the form of foam. In particular, in foam type, cosmetics discharged in the form of foam are applied to the skin to block the skin and the outside air, and the skin temperature is raised to promote skin metabolism and are included in the composition. Since it has the effect of promoting the penetration of active ingredients, it has been studied as a massage fee.
However, in the foam type, if foamed cosmetics are massaged for a certain amount of time on the skin, the foams are softened (coarsed) by warming the foamed cosmetics at body temperature, and the foam is stable. There is a problem that it is difficult to convert. If the foam is rough and the stability of the foam is insufficient, the foam cannot be cushioned between the skin such as the face and the palm of the hand, resulting in increased irritation due to friction. In addition, the ability to block the outside air is impaired, so that the metabolism cannot be sufficiently increased.
In addition, in aerosol-type skin cosmetics that are foamed with a gas such as LPG, the feeling of bubble wrapping that is associated with the bursting of bubbles on the skin may be felt as a stimulus during massage treatment. There was a problem of feeling sensation and causing inflammation.
このような問題に鑑み様々な検討が行われている。例えば、アシルアミノ酸塩と糖アルコールと水溶性多糖類を組み合わせるエアゾール型泡状パック化粧料(特許文献1参照)、キサンタンガムとマルメロ種子抽出物を含有する泡沫形成化粧料(特許文献2参照)、炭酸ガスと、ポリグリセリンモノ脂肪酸エステルと、グリセリンとを組み合わせるエアゾール型水性洗顔化粧料(特許文献3参照)などが挙げられる。 Various studies have been conducted in view of such problems. For example, an aerosol-type foam pack cosmetic combining an acyl amino acid salt, a sugar alcohol, and a water-soluble polysaccharide (see Patent Document 1), a foam-forming cosmetic containing xanthan gum and quince seed extract (see Patent Document 2), carbonic acid Examples thereof include an aerosol-type aqueous facial cleansing cosmetic (see Patent Document 3) that combines gas, polyglycerin monofatty acid ester, and glycerin.
しかしながら、特許文献1、2に記載のエアゾール型皮膚化粧料では、多糖類を配合したことで、泡質の向上が認められるものの、多糖類のべたつき感が強く、特に皮膚化粧料の拭き取りや、洗い流した後にもべたつき感が残る場合があり、使用後の快適さが損なわれていた。
特許文献3に記載のエアゾール型皮膚化粧料では、炭酸ガスを噴射剤として利用することで、ガスの破裂に伴う刺激を低減させてはいるが、泡の安定性が低く、マッサージ施術中に泡が消失されてしまうものであった。
従って、本発明の課題は、キメ細かい泡で、コシがあり、適度な粘性を与えるクリーミーな泡で、マッサージ施術中においても泡状態が維持されてマッサージしやすく、拭き取り又は洗い流した後も、べたつき感がなく、肌にしっとりとした感触を与えるエアゾール型皮膚化粧料を提供することにある。
However, in the aerosol-type skin cosmetics described in Patent Documents 1 and 2, although the improvement in foam quality is recognized by blending polysaccharides, the stickiness of the polysaccharides is strong, especially wiping off the skin cosmetics, In some cases, a sticky feeling remained after washing, and the comfort after use was impaired.
In the aerosol type skin cosmetic described in Patent Document 3, carbon dioxide gas is used as a propellant to reduce irritation associated with gas bursting, but the stability of the foam is low, and foam is reduced during massage treatment. Disappeared.
Therefore, the object of the present invention is a fine foam, a firm, creamy foam that gives an appropriate viscosity, maintains a foam state even during massage treatment, is easy to massage, and feels sticky after wiping or washing away. The object is to provide an aerosol type skin cosmetic that gives a moist feel to the skin.
本発明者は上記課題を解決するために鋭意研究を行なった結果、ポリグリセリンアルキルエーテルと多価アルコールと水溶性高分子と炭酸ガスを組み合せてエアゾール型皮膚化粧料とすることにより、泡がキメ細かく、コシがあり、かつクリーミーでマッサージしやすく、拭き取り又は洗い流した後にべたつき感がなく、肌にしっとり感を付与できることを見出し、本発明を完成するに至った。 As a result of diligent research to solve the above-mentioned problems, the present inventor made an aerosol-type skin cosmetic by combining polyglycerin alkyl ether, polyhydric alcohol, water-soluble polymer, and carbon dioxide gas, so that the foam is fine. The present invention was completed by finding that it is firm, easy to massage with cream, has no stickiness after being wiped off or washed away, and can give a moist feeling to the skin.
即ち、本発明は、(A)ポリグリセリンアルキルエーテル、(B)多価アルコール、(C)水溶性高分子、及び(D)炭酸ガスを含有することを特徴とするエアゾール型マッサージ剤化粧料である。 That is, the present invention is an aerosol-type massage agent cosmetic comprising (A) polyglycerin alkyl ether, (B) polyhydric alcohol, (C) a water-soluble polymer, and (D) carbon dioxide. is there.
本発明のエアゾール型皮膚化粧料は、キメ細かく、シコがあり、適度な粘性を与えるクリーミーな泡を生じ、マッサージ施術中においても皮膚上で泡状態が維持できるためマッサージしやすく、拭き取り又は洗い流した後も、べたつき感がなく、肌にしっとりとした感触を付与できる。 The aerosol-type skin cosmetic of the present invention is fine and has a crisp, creamy foam that gives an appropriate viscosity, and can maintain a foam state on the skin even during massage treatment, so it is easy to massage and after wiping or washing away However, there is no stickiness, and the skin can be moistened.
以下、本発明の構成を詳述する。 Hereinafter, the configuration of the present invention will be described in detail.
本発明における(A)ポリグリセリンアルキルエーテルは、ポリグリセリンモノアルキルエーテルであり、下記一般式(1)で表されるものが好適に用いられる。
R−(OCH2−CH(OH)−CH2)n−OH (1)
〔式中、Rは炭素数8〜18の直鎖又は分岐鎖のアルキル又はアルケニル基を示し、nは2以上の整数を示す。〕
The (A) polyglycerin alkyl ether in the present invention is a polyglycerin monoalkyl ether, and those represented by the following general formula (1) are preferably used.
R— (OCH 2 —CH (OH) —CH 2 ) n —OH (1)
[Wherein, R represents a linear or branched alkyl or alkenyl group having 8 to 18 carbon atoms, and n represents an integer of 2 or more. ]
一般式(1)におけるRは炭素数8〜18の直鎖又は分岐鎖のアルキル又はアルケニル基であり、好ましくは炭素数9〜16の直鎖又は分岐鎖のアルキル又はアルケニル基であり、さらに好ましくは10〜14の直鎖又は分岐鎖のアルキル又はアルケニル基である。また、一般式(1)におけるnは2以上の整数であり、好ましくは2〜50であり、より好ましくは2〜10である。 R in the general formula (1) is a linear or branched alkyl or alkenyl group having 8 to 18 carbon atoms, preferably a linear or branched alkyl or alkenyl group having 9 to 16 carbon atoms, and more preferably. Is a 10-14 linear or branched alkyl or alkenyl group. Moreover, n in General formula (1) is an integer greater than or equal to 2, Preferably it is 2-50, More preferably, it is 2-10.
また、(A)成分の具体例としては、例えば、デカグリセリンモノオクチルエーテル、デカグリセリンモノデシルエーテル、デカグリセリンモノラウリルエーテル、デカグリセリンモノミリスチルエーテル、オクタグリセリンモノオクチルエーテル、オクタグリセリンモノデシルエーテル、オクタグリセリンモノラウリルエーテル、オクタグリセリンモノミリスチルエーテル、ヘキサグリセリンモノオクチルエーテル、ヘキサグリセリンモノデシルエーテル、ヘキサグリセリンモノラウリルエーテル、ヘキサグリセリンモノミリスチルエーテル、テトラグリセリンモノオクチルエーテル、テトラグリセリンモノデシルエーテル、テトラグリセリンモノラウリルエーテル、テトラグリセリンモノミリスチルエーテル等を例示することができる。上記(A)成分は、単独で又は2種以上を適宜組み合わせて用いることができる。
好適な(A)成分としては、テトラグリセリンラウリルエーテル、ヘキサグリセリンモノミリスチルエーテル、デカグリセリンモノラウリルエーテルが挙げられる。
Specific examples of the component (A) include, for example, decaglycerin monooctyl ether, decaglycerin monodecyl ether, decaglycerin monolauryl ether, decaglycerin monomyristyl ether, octaglycerin monooctyl ether, octaglycerin monodecyl ether, Octaglycerol monolauryl ether, Octaglycerol monomyristyl ether, Hexaglycerol monooctyl ether, Hexaglycerol monodecyl ether, Hexaglycerol monolauryl ether, Hexaglycerol monomyristyl ether, Tetraglycerol monooctyl ether, Tetraglycerol monodecyl ether, Tetraglycerol Examples thereof include monolauryl ether and tetraglycerin monomyristyl ether. The said (A) component can be used individually or in combination of 2 or more types as appropriate.
Suitable examples of the component (A) include tetraglycerin lauryl ether, hexaglycerin monomyristyl ether, and decaglycerin monolauryl ether.
本発明における(A)ポリグリセリンアルキルエーテルの好ましい含有量としては、本発明皮膚化粧料全量中に0.1〜5質量%(以下、単に%と略す。)が好ましく、さらに好ましくは0.5〜2%である。ポリグリセリンアルキルエーテルの含有量が当該範囲内であると泡のクリーミーさ、泡安定性が良好となる。 The preferable content of the (A) polyglycerin alkyl ether in the present invention is preferably 0.1 to 5% by mass (hereinafter simply referred to as “%”) in the total amount of the skin cosmetic of the present invention, and more preferably 0.5. ~ 2%. When the content of the polyglycerin alkyl ether is within the above range, the creaminess and foam stability of the foam are good.
本発明における(B)多価アルコールは、アルコール性水酸基を分子構造内に2個以上有する化合物であり、通常化粧料に用いるものであれば特に限定されないが、当該多価アルコールには、加水分解によって10分子以上の単糖類を生じる多糖類(Cl(H2O)mで表される炭水化物;l、mは整数。)は含まない。多価アルコールとしては、2価又は3価アルコール及び糖類が挙げられる。ここで糖類には単糖類、二糖類及び糖アルコールが含まれる。 The (B) polyhydric alcohol in the present invention is a compound having two or more alcoholic hydroxyl groups in the molecular structure and is not particularly limited as long as it is usually used for cosmetics. Does not contain polysaccharides (carbohydrates represented by C 1 (H 2 O) m ; l and m are integers) that yield 10 or more monosaccharides. Examples of the polyhydric alcohol include divalent or trivalent alcohol and saccharide. Here, saccharides include monosaccharides, disaccharides and sugar alcohols.
2価又は3価アルコールの具体例としては、エチレングリコール、ジエチレングリコール、ポリエチレングリコール(数平均分子量1000未満)、プロピレングリコール、ジプロピレングリコール、ポリプロピレングリコール(数平均分子量1000未満)、グリセリン、ジグリセリン、ポリグリセリン、イソプレングリコール、1,3−ブチレングリコールなどが挙げられる。
好ましい2価又は3価アルコールとしては、グリセリン、ポリグリセリン、プロピレングリコール、ポリプロピレングリコール(数平均分子量1000未満)、ポリエチレングリコール(分子量1000未満)、1,3−ブチレングリコールを用いることができる。
Specific examples of the dihydric or trihydric alcohol include ethylene glycol, diethylene glycol, polyethylene glycol (number average molecular weight less than 1000), propylene glycol, dipropylene glycol, polypropylene glycol (number average molecular weight less than 1000), glycerin, diglycerin, poly Examples include glycerin, isoprene glycol, and 1,3-butylene glycol.
As preferable divalent or trivalent alcohols, glycerin, polyglycerin, propylene glycol, polypropylene glycol (number average molecular weight less than 1000), polyethylene glycol (molecular weight less than 1000), and 1,3-butylene glycol can be used.
単糖類の具体例としては、D−エリツルロース,D−エリトロース,D−トレオース等のテトロース類、D−アラビノース,L−アラビノース,D−キシロース,D−リキソース,L−リキソース,D−リボース等のアルドペントース類、D−キシルロース,L−キシルロース,D−リブロース,L−リブロース等のケトペントース類、D−ガラクトース,L−ガラクトース,D−グルコース,D−タロース,D−マンノース等のアルドヘキソース類、L−ソルボース,D−タガトース,D−プシコース,D−フルクトース等のケトヘキソース類、D−アピオース,D−ハマメロース等の分枝糖類などが挙げられる。二糖類の具体例としては、キシロビオース,アガロビオース,カラビオース,マルトース,イソマルトース,ソホロース,セロビオース,トレハロース,ネオトレハロース,イソトレハロース,イヌロビオース,ビシアノース,イソプリメベロース,サンブビオース,プリメベロース,ソラビオース,メリビオース,ラクトース,リコビオース,エピセロビオース,スクロース,ツラノース,マルツロース,ラクツロース,エピゲンチビオース,ロビノビオース,シラノビオース,ルチノース等が挙げられる。糖アルコールとしては、エリスリトール,D−アラビトール,キシリトール,D−リビトール,ガラクチトール,D−グルシトール,D−マンニトール,マルチトール等が挙げられる。
好ましい糖類としては、グルコース、マルトース、マルチトール、スクロース、マンニトール、ソルビトール、トレハロースを用いることができる。
Specific examples of monosaccharides include aldoses such as D-erythrulose, D-erythrose, D-threose, etc., D-arabinose, L-arabinose, D-xylose, D-lyxose, L-lyxose, D-ribose, etc. Pentoses, ketopentoses such as D-xylulose, L-xylulose, D-ribulose, L-ribulose, aldohexoses such as D-galactose, L-galactose, D-glucose, D-talose, D-mannose, L- Examples thereof include ketohexoses such as sorbose, D-tagatose, D-psicose and D-fructose, and branched sugars such as D-apiose and D-hamamelose. Specific examples of disaccharides include xylobiose, agarobiose, carabiose, maltose, isomaltose, sophorose, cellobiose, trehalose, neotrehalose, isotrehalose, inulobiose, vicyanose, isoprimebellose, sambubiose, primebellose, solabiose, melibiose, Examples include lycobiose, epicellobiose, sucrose, turanose, maltulose, lactulose, epigentibose, robinobiose, silanobiose, and rutinose. Examples of the sugar alcohol include erythritol, D-arabitol, xylitol, D-ribitol, galactitol, D-glucitol, D-mannitol, maltitol and the like.
As preferred saccharides, glucose, maltose, maltitol, sucrose, mannitol, sorbitol, and trehalose can be used.
多価アルコールは、一種又は二種以上を組み合わせて用いることができる。これらの多価アルコールのうち、糖類を用いると、洗い流した後のしっとりした感触の面で優れ、好ましい。多価アルコールと糖類を併用する場合、糖類以外の多価アルコールは、糖類の含有量に対して、好ましくは質量比で10:1〜1:2、さらに好ましくは5:1〜1:1の割合で含有することが、洗い流した後のしっとり感に優れるとともに、泡のクリーミー感、泡安定性にも優れ、特に好ましい。 A polyhydric alcohol can be used 1 type or in combination of 2 or more types. Of these polyhydric alcohols, use of saccharides is preferable because it is excellent in moist feeling after washing away. When the polyhydric alcohol and the saccharide are used in combination, the polyhydric alcohol other than the saccharide is preferably 10: 1 to 1: 2 by mass ratio, more preferably 5: 1 to 1: 1 with respect to the saccharide content. Containing in a proportion is particularly preferable because it is excellent in moist feeling after washing off, and excellent in creamy feeling and foam stability.
本発明における(B)多価アルコールの好ましい含有量としては、本発明皮膚化粧料全量中に5〜50%が好ましく、さらに好ましくは10〜30%である。多価アルコールの含有量が当該範囲であれば、クリーミーな泡で、泡安定性が高く、洗い流した後でもべたつかずにしっとりとした感触が得られる。 As preferable content of (B) polyhydric alcohol in this invention, 5 to 50% is preferable in this invention skin cosmetics whole quantity, More preferably, it is 10 to 30%. If the content of the polyhydric alcohol is within the above range, creamy foam, high foam stability, and a moist feel can be obtained without being sticky after washing.
本発明における(C)水溶性高分子としては、多糖類(加水分解によって10分子以上の単糖類を生じる糖類)、タンパク・ポリアミノ酸系高分子、ビニル系高分子、ポリエーテル系高分子、ポリアミド系高分子、ポリエステル系高分子、ポリウレタン又はこれらの誘導体等が用いられる。
多糖類又はその誘導体の具体例としては、グアーガム、ローカストビーンガム、クイーンスシード、カラギーナン、ガラクタン、アラビアゴム、トラガント、ペクチン、キサンタンガム、デキストリン、サクシノグルカン、カードラン、ヒアルロン酸、コンドロイチン硫酸等の天然多糖類、メチルセルロース、エチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、カルボキシメチルセルロース、メチルヒドロキシプロピルセルロース、カチオン化セルロース、アルギン酸塩、アルギン酸プロピレングリコール、可溶性デンプン、カルボキシメチルデンプン、メチルデンプン等の合成あるいは半合成多糖類が挙げられる。
タンパク・ポリアミノ系高分子又はその誘導体の具体例としては、ゼラチン、カゼイン、アルブミン、コラーゲン、ポリグルタミン酸、ポリリジン、ポリアルギニンが挙げられる。
ビニル系高分子又はその誘導体の具体例としては、ポリビニルアルコール、ポリビニルメチルエーテル、ポリビニルエチルエーテル等のポリビニルエーテル類、ポリアクリル酸、ポリアクリル酸ナトリウム、ポリアクリル酸ヒドロキシエチル、ポリメタクリル酸ジメチルアミノエチル、カルボキシビニルポリマー等のアクリル酸系あるいはメタクリル酸系ポリマー、ポリメタクリルアミド、ポリN,N−ジメチルアクリルアミド等のポリアクリルあるいはポリメタクリルアミド酸、ポリビニルピロリドン、ビニルピロリドン共重合体、ポリN−ビニルイミダゾール、ポリ4−ビニルピリジンあるいはこれらの誘導体、マレイン酸等のカルボキシビニル基含有ポリマー、ポリ(N,N−ジメチル−3,5−メチレンピペリジウムクロライド)、N,N−ジメチル−3,5−メチレンピペリジニウムクロライド)−アクリルアミド共重合体、又はこれらの誘導体、更には上記ポリマーの単量体を含有する共重合体等が挙げられる。
その他の水溶性高分子又はその誘導体としてはポリエチレングリコール(数平均分子量1000以上)等のポリエーテル系高分子、水溶性ナイロン等のポリアミド系高分子、酸化エチレン・酸化プロピレンブロック共重合体等のポリエステル系高分子、水溶性ポリウレタン又はこれらの誘導体等が挙げられる。
Examples of the water-soluble polymer (C) in the present invention include polysaccharides (saccharides that produce 10 or more monosaccharides by hydrolysis), protein / polyamino acid polymers, vinyl polymers, polyether polymers, polyamides. Polymer, polyester polymer, polyurethane, or derivatives thereof are used.
Specific examples of polysaccharides or derivatives thereof include guar gum, locust bean gum, queen seed, carrageenan, galactan, gum arabic, tragacanth, pectin, xanthan gum, dextrin, succinoglucan, curdlan, hyaluronic acid, chondroitin sulfate, etc. Synthetic or semi-synthetic polysaccharides such as natural polysaccharides, methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose, methylhydroxypropylcellulose, cationized cellulose, alginate, propylene glycol alginate, soluble starch, carboxymethyl starch, methyl starch Examples include sugars.
Specific examples of the protein / polyamino polymer or derivative thereof include gelatin, casein, albumin, collagen, polyglutamic acid, polylysine, and polyarginine.
Specific examples of vinyl polymers or derivatives thereof include polyvinyl ethers such as polyvinyl alcohol, polyvinyl methyl ether, and polyvinyl ethyl ether, polyacrylic acid, sodium polyacrylate, hydroxyethyl polyacrylate, polydimethylaminoethyl methacrylate , Acrylic acid or methacrylic acid polymers such as carboxyvinyl polymer, polyacryl or polymethacrylamide such as polymethacrylamide, poly N, N-dimethylacrylamide, polyvinyl pyrrolidone, vinyl pyrrolidone copolymer, poly N-vinyl imidazole , Poly-4-vinylpyridine or derivatives thereof, carboxyvinyl group-containing polymers such as maleic acid, poly (N, N-dimethyl-3,5-methylenepiperidinium chloride), , N- dimethyl-3,5-methylene piperidinium chloride) - acrylamide copolymer, or derivatives thereof, more copolymers containing monomer of the above polymers.
Other water-soluble polymers or derivatives thereof include polyether polymers such as polyethylene glycol (number average molecular weight 1000 or more), polyamide polymers such as water-soluble nylon, and polyesters such as ethylene oxide / propylene oxide block copolymers. Based polymer, water-soluble polyurethane, or derivatives thereof.
特にこれらの水溶性高分子のうち、ポリビニルピロリドン及びビニルピロリドン系共重合体が泡のクリーミーさ、洗い流した後のしっとりした感触の面で優れており、特に好ましい。 Among these water-soluble polymers, polyvinyl pyrrolidone and vinyl pyrrolidone-based copolymers are particularly preferable because they are excellent in foam creaminess and moist feeling after washing.
ポリビニルピロリドンとしては、重量平均分子量が8000〜1300000のものが好ましく、更に好ましくは60000〜400000のものが使用できる。 As the polyvinyl pyrrolidone, those having a weight average molecular weight of 8000 to 1300000 are preferable, and those having a weight average molecular weight of 60000 to 400,000 are more preferable.
ビニルピロリドン系共重合体としては、ポリビニルピロリドン/アクリレート/(メタ)アクリル酸共重合体、ビニルピロリドン−N・N−ジメチルアミノエチルメタクリル酸共重合体ジエチル硫酸塩、ビニルイミダゾリウムトリクロライド/ビニルピロリドン共重合体、ポリビニルピロリドン/アルキルアミノアクリレート/ビニルカプロラクタム共重合体、塩化メチルビニルイミダゾリウム・ビニルピロリドン共重合体、メチルビニルイミダゾリウム・ビニルピロリドン共重合体メチル硫酸、(ビニルピロリドン/ジメチルアミノプロピルメタクリルアミド/ラウリルジメチルアミノプロピリメタクリルアミド)共重合体が好ましく使用できる。 Examples of the vinyl pyrrolidone copolymer include polyvinyl pyrrolidone / acrylate / (meth) acrylic acid copolymer, vinyl pyrrolidone-N · N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate, vinyl imidazolium trichloride / vinyl pyrrolidone. Copolymer, polyvinylpyrrolidone / alkylaminoacrylate / vinylcaprolactam copolymer, methylvinylimidazolium / vinylpyrrolidone copolymer, methylvinylimidazolium / vinylpyrrolidone copolymer methylsulfuric acid, (vinylpyrrolidone / dimethylaminopropylmethacrylic) An amide / lauryldimethylaminopropyl methacrylamide) copolymer can be preferably used.
本発明における(C)水溶性高分子の好ましい含有量としては、本発明皮膚化粧料全量中、好ましくは0.01〜2%、さらに好ましくは0.05〜1%、特に好ましくは0.1〜0.5%である。水溶性高分子の含有量が当該範囲内であれば、クリーミーな泡で、マッサージ施術中においても泡状態が維持されてマッサージしやすい。 The preferable content of the (C) water-soluble polymer in the present invention is preferably 0.01 to 2%, more preferably 0.05 to 1%, particularly preferably 0.1 in the total amount of the skin cosmetics of the present invention. ~ 0.5%. If the content of the water-soluble polymer is within the above range, it is creamy foam, and the foam state is maintained even during massage treatment, and massage is easy.
本発明における(D)炭酸ガスは常温で気体であり、エアゾールの噴射剤として配合される。また、吐出される泡質を調整するために、液化石油ガス、ジメチルエーテル等の噴射剤を併用することができる。
本発明のエアゾール型皮膚化粧料には、25℃における圧力が0.4〜0.7MPaとなるように噴射剤を配合することが好ましく、特に皮膚への刺激性の点から、炭酸ガスを質量%に換算して、0.5〜2%とするのが好ましく、さらに好ましくは0.8〜1.2%含有させることが好ましい。
In the present invention, (D) carbon dioxide gas is a gas at room temperature and is blended as an aerosol propellant. Moreover, in order to adjust the foam quality discharged, propellants, such as liquefied petroleum gas and dimethyl ether, can be used together.
The aerosol type skin cosmetic of the present invention preferably contains a propellant so that the pressure at 25 ° C. is 0.4 to 0.7 MPa, and in particular, carbon dioxide gas in mass from the viewpoint of irritation to the skin. In terms of%, it is preferably 0.5 to 2%, and more preferably 0.8 to 1.2%.
本発明のエアゾール型皮膚化粧料には、泡のクリーミーさ、泡安定性、洗い流し後のべたつき感の低減の点から(E)シリコーン油を含有させるのが好ましい。(E)シリコーン油としては、例えば、ジメチルポリシロキサン、ジメチコノール、メチルフェニルポリシロキサン、ポリエーテル変性シリコーン、エポキシ変性シリコーン、フッ素変性シリコーン、アルコール変性シリコーン、アルキル変性シリコーン、アルコキシ変性シリコーン、アミノ変性シリコーン、パーフルオロアルキルポリオキシアルキレン変性シリコーン、環状シリコーン等が挙げられ、これらの中から一種又は二種以上を組み合わせて用いることが出来る。 The aerosol type skin cosmetic of the present invention preferably contains (E) silicone oil from the viewpoint of foam creaminess, foam stability, and reduction in stickiness after washing. (E) Examples of the silicone oil include dimethylpolysiloxane, dimethiconol, methylphenylpolysiloxane, polyether-modified silicone, epoxy-modified silicone, fluorine-modified silicone, alcohol-modified silicone, alkyl-modified silicone, alkoxy-modified silicone, amino-modified silicone, Examples include perfluoroalkyl polyoxyalkylene-modified silicones, cyclic silicones, and the like. Among these, one or a combination of two or more can be used.
好ましいシリコーン油としては、ジメチルポリシロキサン、メチルフェニルポリシロキサン、ポリエーテル変性シリコーン、アミノ変性シリコーンを使用することができる。
また、シリコーン油は使用感(しっとり感、べたつき感のなさ)、泡のクリーミーさの点から、粘度(25℃)が1〜1000mm2/sのものが好ましく、さらに好ましく2〜500mm2/s、特に好ましくは5〜100mm2/sであるものが使用できる。
As a preferable silicone oil, dimethylpolysiloxane, methylphenylpolysiloxane, polyether-modified silicone, and amino-modified silicone can be used.
Further, silicone oils feeling (moist feel, lack of stickiness), in terms of creaminess of the foam, the viscosity (25 ° C.) is preferably has 1 to 1000 mm 2 / s, more preferably 2~500mm 2 / s Particularly preferably, one having 5 to 100 mm 2 / s can be used.
本発明におけるシリコーン油の好ましい含有量としては、本発明皮膚化粧料全量中0.01〜3.0%であり、さらに好ましくは0.1〜1.0%、特に好ましくは0.2〜0.7%である。シリコーン油の含有量が当該範囲内であると、泡のクリーミーさ、泡安定性が良好で、洗い流した後のべたつき感がなく、好ましい。 The preferable content of the silicone oil in the present invention is 0.01 to 3.0%, more preferably 0.1 to 1.0%, and particularly preferably 0.2 to 0% in the total amount of the skin cosmetics of the present invention. 0.7%. When the content of the silicone oil is within the above range, the foam creaminess and foam stability are good, and there is no stickiness after washing, which is preferable.
本発明のエアゾール型皮膚化粧料には、発明の効果を損なわない範囲であれば、上記必須成分の他に界面活性剤、油性成分、シリコーン化合物、高級アルコール、低級アルコール、粉体、植物エキス、防腐剤、殺菌剤、キレート剤、酸化防止剤、pH調整剤、紫外線吸収剤、香料等を配合することが出来る。 In the aerosol type skin cosmetic of the present invention, a surfactant, an oily component, a silicone compound, a higher alcohol, a lower alcohol, a powder, a plant extract, Preservatives, bactericides, chelating agents, antioxidants, pH adjusters, ultraviolet absorbers, fragrances and the like can be blended.
本発明のエアゾール型皮膚化粧料は、上記成分を耐圧容器に充填することにより製造することができ、その噴射の形態としては泡状にして吐出するフォームタイプとするのが好ましい。 The aerosol type skin cosmetic of the present invention can be produced by filling the above components in a pressure-resistant container, and the form of injection is preferably a foam type that is discharged in the form of foam.
本発明のエアゾール型皮膚化粧料は、皮膚化粧料として特に制限なく利用できるが、拭き取り又は洗い流した後でも皮膚に対する保湿性が高いため、洗顔料、クレンジング化粧料、パック、マッサージ化粧料として好適に利用できる。 The aerosol-type skin cosmetic of the present invention can be used as a skin cosmetic without any particular limitation, but has high moisturizing properties on the skin even after being wiped off or washed away, so it is suitable as a facial cleanser, cleansing cosmetic, pack, massage cosmetic. Available.
以下に実施例、比較例を挙げて本発明を説明する。本発明は、これらにより限定されるものではない。 Hereinafter, the present invention will be described with reference to examples and comparative examples. The present invention is not limited to these.
実施例、比較例に示した官能試験の試験方法は下記の通りである。尚、以下の表に示す組成物の含有量は、それぞれ%で示す。 The test methods of the sensory test shown in the examples and comparative examples are as follows. In addition, content of the composition shown in the following table | surfaces is each shown by%.
(官能試験)
10名の被験者によってエアゾール型皮膚化粧料の試料を頬の部位に塗布した。塗布後3分間マッサージを続け、ぬるま湯にて洗い流した。その後、被験者本人が、マッサージのしやすさ、洗いあがりのしっとり感について官能評価し、平均評価点を求めた。評価基準は、以下の通りである。
(Sensory test)
Ten subjects applied aerosol type skin cosmetic samples to the cheek area. After application, the massage was continued for 3 minutes and rinsed off with warm water. Thereafter, the subject himself / herself performed a sensory evaluation on the ease of massage and the moist feeling of washing, and obtained an average evaluation score. The evaluation criteria are as follows.
4:非常に良好
3:良好
2:やや悪い
1:悪い
4: Very good 3: Good 2: Slightly bad 1: Bad
◎:平均評価点が3.4以上
○:平均評価点が2.8以上、3.4未満
△:平均評価点が2.2以上、2.8未満
× :平均評価点が2.2未満
A: Average evaluation score of 3.4 or more ○: Average evaluation score of 2.8 or more and less than 3.4 Δ: Average evaluation score of 2.2 or more and less than 2.8 ×: Average evaluation score of less than 2.2
実施例1〜5、比較例1〜4
表1に示した処方のエアゾール型皮膚化粧料を作製し、前記各試験を実施した。製造方法は噴射剤以外の成分を加熱混合し、冷却後、耐圧容器に充填した。その後、噴射剤を加圧することにより充填した。処方と試験結果を表1に併せて示す。
Examples 1-5, Comparative Examples 1-4
Aerosol-type skin cosmetics having the formulations shown in Table 1 were prepared and the above tests were performed. In the production method, components other than the propellant were heated and mixed, and after cooling, the pressure vessel was filled. Thereafter, the propellant was filled by pressurization. Table 1 shows the formulation and test results.
表1より明らかなように本発明の(A)〜(D)成分を用いた実施例のエアゾール型皮膚化粧料はいずれも優れた性能を有していた。一方、(A)〜(D)の必須成分のいずれかを欠いた比較例では、マッサージのしやすさ、しっとり感のいずれかの面で劣っており、本発明の目的を達成できなかった。 As is clear from Table 1, all of the aerosol type skin cosmetics of the examples using the components (A) to (D) of the present invention had excellent performance. On the other hand, the comparative example lacking any of the essential components (A) to (D) is inferior in any aspect of ease of massage and moist feeling and could not achieve the object of the present invention.
実施例6
原液
(A)テトラグリセリンラウリルエーテル 1.0 %
(B)ジプロピレングリコール 10.0
(B)マルチトール 5.0
(C)ポリビニルピロリドン(重量平均分子量、400,000) 0.2
(C)ヒドロキシエチルセルロース 0.1
(E)ジメチルポリシロキサン(100cs) 0.5
ステアリン酸 0.8
ステアリルアルコール 0.5
ポリオキシエチレン硬化ヒマシ油(60E.O.) 0.3
ポリオキシエチレンセチルエーテル(5E.O.) 0.5
トリエタノールアミン 0.2
エデト酸2ナトリウム 0.02
チンピエキス 0.1
アルテアエキス 0.05
キラヤエキス 0.05
フェノキシエタノール 0.2
グリチルリチン酸ジカリウム 0.1
香料 0.2
精製水 残 部
噴射剤
液化石油ガス(0.15MPa、25℃) 5.0
(D)炭酸ガス 1.0
Example 6
Stock solution (A) Tetraglycerin lauryl ether 1.0%
(B) Dipropylene glycol 10.0
(B) Maltitol 5.0
(C) Polyvinylpyrrolidone (weight average molecular weight, 400,000) 0.2
(C) Hydroxyethyl cellulose 0.1
(E) Dimethylpolysiloxane (100 cs) 0.5
Stearic acid 0.8
Stearyl alcohol 0.5
Polyoxyethylene hydrogenated castor oil (60 EO) 0.3
Polyoxyethylene cetyl ether (5EO) 0.5
Triethanolamine 0.2
Edetic acid disodium 0.02
Chimp extract 0.1
Altea extract 0.05
Kiraya extract 0.05
Phenoxyethanol 0.2
Dipotassium glycyrrhizinate 0.1
Fragrance 0.2
Purified water remainder propellant liquefied petroleum gas (0.15 MPa, 25 ° C.) 5.0
(D) Carbon dioxide 1.0
上記組成のエアゾール型皮膚化粧料を作成し評価したところ、マッサージしやすさ、しっとり感について、優れた性能を有していた。尚、上記エアゾール型皮膚化粧料の圧力(25℃)は、0.6MPaであった。 When an aerosol type skin cosmetic composition having the above composition was prepared and evaluated, it had excellent performance in terms of ease of massage and moist feeling. In addition, the pressure (25 degreeC) of the said aerosol type skin cosmetics was 0.6 MPa.
尚、上記の実施例6において使用した香料の組成は表2に示す。 In addition, the composition of the fragrance | flavor used in said Example 6 is shown in Table 2.
実施例7
原液
(A)デカグリセリンラウリルエーテル 2.0%
(B)スクロース 10.0%
(C)ポリビニルピロリドン・N,N−ジメチルアミノエチルメタクリル酸共重合体ジエチル硫酸塩(GAFQUAT734、ISP社製、純分換算) 0.2%
(E)ポリエーテル変性シリコーン(KF−6011 信越化学工業社製) 0.5%
ポリオキシエチレンセチルエーテル(15E.O.) 0.5%
乳酸 0.02%
乳酸ナトリウム 0.08%
ユズエキス 0.1%
精製水 残部
噴射剤
液化石油ガス(0.25MPa、25℃) 3.0%
(D)炭酸ガス 1.5%
Example 7
Stock solution (A) Decaglycerin lauryl ether 2.0%
(B) Sucrose 10.0%
(C) Polyvinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate (GAFQUAT734, manufactured by ISP, pure conversion) 0.2%
(E) Polyether-modified silicone (KF-6011 manufactured by Shin-Etsu Chemical Co., Ltd.) 0.5%
Polyoxyethylene cetyl ether (15E.O.) 0.5%
Lactic acid 0.02%
Sodium lactate 0.08%
Yuzu extract 0.1%
Purified water Remaining propellant Liquefied petroleum gas (0.25 MPa, 25 ° C.) 3.0%
(D) Carbon dioxide 1.5%
本発明にわれば、クリーミーな泡で、マッサージ施術中においても泡状態が維持されて肌をマッサージしやすく、洗い流した後も、肌にしっとりとした感触を与えるエアゾール型皮膚化粧料を提供できる。 INDUSTRIAL APPLICABILITY According to the present invention, it is possible to provide an aerosol-type skin cosmetic that has creamy foam, maintains a foam state even during a massage treatment, makes it easy to massage the skin, and gives a moist feel to the skin even after washing.
Claims (6)
(A)ポリグリセリンアルキルエーテル
(B)多価アルコール
(C)水溶性高分子
(D)炭酸ガス An aerosol type skin cosmetic comprising the following (A) to (D):
(A) Polyglycerin alkyl ether (B) Polyhydric alcohol (C) Water-soluble polymer (D) Carbon dioxide gas
R−(OCH2−CH(OH)−CH2)n−OH (1)
〔式中、Rは炭素数8〜18の直鎖又は分岐鎖のアルキル又はアルケニル基を示し、nは2以上の整数を示す。〕 (A) The aerosol type skin cosmetic according to claim 1, wherein the polyglycerin alkyl ether is a polyglycerin alkyl ether represented by the following general formula (1).
R— (OCH 2 —CH (OH) —CH 2 ) n —OH (1)
[Wherein, R represents a linear or branched alkyl or alkenyl group having 8 to 18 carbon atoms, and n represents an integer of 2 or more. ]
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2010002054A JP5658879B2 (en) | 2009-10-01 | 2010-01-07 | Aerosol skin cosmetics |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009229251 | 2009-10-01 | ||
JP2009229251 | 2009-10-01 | ||
JP2010002054A JP5658879B2 (en) | 2009-10-01 | 2010-01-07 | Aerosol skin cosmetics |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2011093878A true JP2011093878A (en) | 2011-05-12 |
JP5658879B2 JP5658879B2 (en) | 2015-01-28 |
Family
ID=44111218
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010002054A Active JP5658879B2 (en) | 2009-10-01 | 2010-01-07 | Aerosol skin cosmetics |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP5658879B2 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013241359A (en) * | 2012-05-18 | 2013-12-05 | Daizo:Kk | Foamable aerosol composition |
JP2014185125A (en) * | 2013-03-25 | 2014-10-02 | Tadahiro Shimada | Foaming cosmetics |
JP2016030737A (en) * | 2014-07-29 | 2016-03-07 | 株式会社ノエビア | Foamy lotion |
JP2017145245A (en) * | 2016-02-18 | 2017-08-24 | クラシエホームプロダクツ株式会社 | Clogging preventive agent and aerosol foam composition containing the same |
Citations (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6216411A (en) * | 1985-07-16 | 1987-01-24 | Pola Chem Ind Inc | Makeup cosmetic |
JPH05229933A (en) * | 1992-02-21 | 1993-09-07 | Takashi Ishigaki | Foaming powdery cosmetic |
JPH07315463A (en) * | 1994-05-25 | 1995-12-05 | Yoshino Kogyosho Co Ltd | Foam-discharging-pump container |
JP2001072543A (en) * | 1999-09-03 | 2001-03-21 | Daizo:Kk | Aerosol foam composition |
JP2002161022A (en) * | 2000-11-27 | 2002-06-04 | Noevir Co Ltd | Aerosol type foamy pack cosmetic |
JP2003054662A (en) * | 2001-08-10 | 2003-02-26 | Kao Corp | Aerosol cosmetic |
JP2005015405A (en) * | 2003-06-27 | 2005-01-20 | Pola Chem Ind Inc | Foaming cosmetic |
JP2005082518A (en) * | 2003-09-08 | 2005-03-31 | Kanebo Cosmetics Inc | Aerosol-type hair-setting agent |
JP2005082519A (en) * | 2003-09-08 | 2005-03-31 | Kanebo Cosmetics Inc | Foamy aerosol-type cosmetic |
JP2006347896A (en) * | 2005-06-13 | 2006-12-28 | Taiyo Kagaku Co Ltd | Composition for oily foaming aerosol |
JP2007131585A (en) * | 2005-11-11 | 2007-05-31 | Pola Chem Ind Inc | Aerosol preparation-form cleansing cosmetic |
JP2007146030A (en) * | 2005-11-29 | 2007-06-14 | Lion Corp | Detergent composition |
JP2008037773A (en) * | 2006-08-02 | 2008-02-21 | Kao Corp | Aerosol-type pack cosmetic |
JP2009067735A (en) * | 2007-09-14 | 2009-04-02 | Mandom Corp | Cosmetic for hair |
JP2009179583A (en) * | 2008-01-30 | 2009-08-13 | Mandom Corp | Foamy aerosol cosmetic for hair |
-
2010
- 2010-01-07 JP JP2010002054A patent/JP5658879B2/en active Active
Patent Citations (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6216411A (en) * | 1985-07-16 | 1987-01-24 | Pola Chem Ind Inc | Makeup cosmetic |
JPH05229933A (en) * | 1992-02-21 | 1993-09-07 | Takashi Ishigaki | Foaming powdery cosmetic |
JPH07315463A (en) * | 1994-05-25 | 1995-12-05 | Yoshino Kogyosho Co Ltd | Foam-discharging-pump container |
JP2001072543A (en) * | 1999-09-03 | 2001-03-21 | Daizo:Kk | Aerosol foam composition |
JP2002161022A (en) * | 2000-11-27 | 2002-06-04 | Noevir Co Ltd | Aerosol type foamy pack cosmetic |
JP2003054662A (en) * | 2001-08-10 | 2003-02-26 | Kao Corp | Aerosol cosmetic |
JP2005015405A (en) * | 2003-06-27 | 2005-01-20 | Pola Chem Ind Inc | Foaming cosmetic |
JP2005082518A (en) * | 2003-09-08 | 2005-03-31 | Kanebo Cosmetics Inc | Aerosol-type hair-setting agent |
JP2005082519A (en) * | 2003-09-08 | 2005-03-31 | Kanebo Cosmetics Inc | Foamy aerosol-type cosmetic |
JP2006347896A (en) * | 2005-06-13 | 2006-12-28 | Taiyo Kagaku Co Ltd | Composition for oily foaming aerosol |
JP2007131585A (en) * | 2005-11-11 | 2007-05-31 | Pola Chem Ind Inc | Aerosol preparation-form cleansing cosmetic |
JP2007146030A (en) * | 2005-11-29 | 2007-06-14 | Lion Corp | Detergent composition |
JP2008037773A (en) * | 2006-08-02 | 2008-02-21 | Kao Corp | Aerosol-type pack cosmetic |
JP2009067735A (en) * | 2007-09-14 | 2009-04-02 | Mandom Corp | Cosmetic for hair |
JP2009179583A (en) * | 2008-01-30 | 2009-08-13 | Mandom Corp | Foamy aerosol cosmetic for hair |
Non-Patent Citations (1)
Title |
---|
藤本武彦, 全訂版 新・界面活性剤入門, JPN6013063928, October 1981 (1981-10-01), JP, pages 152 - 153, ISSN: 0002714163 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013241359A (en) * | 2012-05-18 | 2013-12-05 | Daizo:Kk | Foamable aerosol composition |
JP2014185125A (en) * | 2013-03-25 | 2014-10-02 | Tadahiro Shimada | Foaming cosmetics |
JP2016030737A (en) * | 2014-07-29 | 2016-03-07 | 株式会社ノエビア | Foamy lotion |
JP2017145245A (en) * | 2016-02-18 | 2017-08-24 | クラシエホームプロダクツ株式会社 | Clogging preventive agent and aerosol foam composition containing the same |
Also Published As
Publication number | Publication date |
---|---|
JP5658879B2 (en) | 2015-01-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5775671B2 (en) | Aerosol-type cosmetics | |
JP5995233B2 (en) | Foam aerosol composition | |
JP5658879B2 (en) | Aerosol skin cosmetics | |
US8298557B2 (en) | Cleansing cosmetic composition | |
JP6282848B2 (en) | Foamable coating composition | |
ES2843905T3 (en) | Oil-in-water emulsion and cosmetic use thereof | |
JP5108817B2 (en) | Hair cosmetics | |
EP2027849A1 (en) | External preparation for skin | |
EP3530722B1 (en) | Detergent composition | |
JP5808709B2 (en) | Foam aerosol composition | |
ES2329600T3 (en) | COSMETIC COMPOSITIONS ABLE TO FOAM. | |
JP6076080B2 (en) | Foam lotion | |
JP4782634B2 (en) | Aerosol pack cosmetic | |
JP6833476B2 (en) | Skin and head cleansing composition | |
ES2399896T3 (en) | Shaving product of non-self-heating spray type | |
JP6693725B2 (en) | Transparent cosmetics | |
KR20110035320A (en) | Cosmetic composition for massage | |
JP3862237B2 (en) | Aerosol-type foam pack cosmetic | |
JP6342366B2 (en) | Transparency cosmetics | |
TW202011936A (en) | Detergent composition | |
JP2013237615A (en) | Foam aerosol composition | |
JP7359637B2 (en) | Cleaning compositions and cleaning products | |
JP7430574B2 (en) | gel skin cosmetics | |
JP7356321B2 (en) | Cleaning compositions and cleaning products | |
WO2019235331A1 (en) | Oil-in-water-type emulsion cosmetic using partially crosslinked or crosslinked dimethylpolysiloxane |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20121211 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20131125 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140107 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140305 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20141125 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20141201 |
|
R151 | Written notification of patent or utility model registration |
Ref document number: 5658879 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R151 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |