JP5775671B2 - Aerosol-type cosmetics - Google Patents
Aerosol-type cosmetics Download PDFInfo
- Publication number
- JP5775671B2 JP5775671B2 JP2010002053A JP2010002053A JP5775671B2 JP 5775671 B2 JP5775671 B2 JP 5775671B2 JP 2010002053 A JP2010002053 A JP 2010002053A JP 2010002053 A JP2010002053 A JP 2010002053A JP 5775671 B2 JP5775671 B2 JP 5775671B2
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- JP
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- Prior art keywords
- aerosol
- foam
- acid
- mass
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- OVVGHDNPYGTYIT-BNXXONSGSA-N rutinose Chemical compound O[C@@H]1[C@H](O)[C@@H](O)[C@H](C)O[C@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)O1 OVVGHDNPYGTYIT-BNXXONSGSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- BUEBVQCTEJTADB-IGQSMMPPSA-N sambubiose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)CO1 BUEBVQCTEJTADB-IGQSMMPPSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229940010747 sodium hyaluronate Drugs 0.000 description 1
- 229940045944 sodium lauroyl glutamate Drugs 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
- HIWPGCMGAMJNRG-RTPHMHGBSA-N sophorose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)OC(O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HIWPGCMGAMJNRG-RTPHMHGBSA-N 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 235000010487 tragacanth Nutrition 0.000 description 1
- 239000000196 tragacanth Substances 0.000 description 1
- 229940116362 tragacanth Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- RULSWEULPANCDV-PIXUTMIVSA-N turanose Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](C(=O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O RULSWEULPANCDV-PIXUTMIVSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- DFKDOZMCHOGOBR-UHFFFAOYSA-N zaragozic acid A Natural products O1C(C(O)(C(O2)C(O)=O)C(O)=O)(C(O)=O)C(OC(=O)C=CC(C)CC(C)CC)C(O)C21CCC(=C)C(OC(C)=O)C(C)CC1=CC=CC=C1 DFKDOZMCHOGOBR-UHFFFAOYSA-N 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
本発明は、マッサージしやすく、洗い流した後も、肌にしっとりとした感触を与え、べたつき感のないエアゾール型化粧料に関するものである。 The present invention relates to an aerosol-type cosmetic that is easy to massage, gives a moist feel to the skin even after washing, and has no stickiness.
エアゾール型化粧料は、化粧水を噴霧するスプレータイプや、洗顔料やパックなどを泡状にして吐出するフォームタイプなど幅広く利用されている。特に、フォームタイプでは泡状に吐出された化粧料が肌に塗布されることにより、肌と外気とを遮断し、皮膚温を上昇させることで皮膚の新陳代謝を促進させ、組成物中に含まれる有効成分の浸透を促進する効果を持つため、マッサージ料として検討が進められている。
しかし、フォームタイプにおいては、皮膚上で泡状の化粧料をある程度の時間、マッサージを行うと、体温で泡状の化粧料が暖められることで泡が柔らかく(粗く)なってしまい、泡が安定化しにくいという問題がある。泡が粗く、泡の安定性が不十分であると、顔などの皮膚と手のひらの間に泡のクッションができず、摩擦による刺激が大きくなってしまう。また、外気との遮断性が損なわれるため、新陳代謝を十分に高めることできない。
また、LPG等のガスで発泡させるエアゾール型化粧料では、マッサージ施術中に皮膚上で泡の破裂に伴う、プチプチ弾ける感触が刺激と感じられることがあり、デリケートな肌質の人では、ひりひり感を感じ、炎症を起こしてしまうという問題があった。
Aerosol-type cosmetics are widely used, such as a spray type for spraying lotion and a foam type for discharging facial cleansers or packs in the form of foam. In particular, in foam type, cosmetics discharged in the form of foam are applied to the skin to block the skin and the outside air, and the skin temperature is raised to promote skin metabolism and are included in the composition. Since it has the effect of promoting the penetration of active ingredients, it has been studied as a massage fee.
However, in the foam type, if foamed cosmetics are massaged for a certain amount of time on the skin, the foams are softened (coarsed) by warming the foamed cosmetics at body temperature, and the foam is stable. There is a problem that it is difficult to convert. If the foam is rough and the stability of the foam is insufficient, the foam cannot be cushioned between the skin such as the face and the palm of the hand, resulting in increased irritation due to friction. In addition, the ability to block the outside air is impaired, so that the metabolism cannot be sufficiently increased.
In addition, in aerosol-type cosmetics that are foamed with a gas such as LPG, the feeling of bubble wrapping that is associated with the bursting of bubbles on the skin may be felt as a stimulus during massage treatment. There was a problem of feeling irritated and causing inflammation.
このような問題に鑑み様々な検討が行われている。例えば、アシルアミノ酸塩と糖アルコールと水溶性多糖類を組み合わせるエアゾール型泡状パック化粧料(特許文献1参照)、キサンタンガムとマルメロ種子抽出物を含有する泡沫形成化粧料(特許文献2参照)、炭酸ガス、ポリグリセリンモノ脂肪酸エステル、グリセリンとを組み合わせるエアゾール型水性洗顔化粧料(特許文献3参照)などが挙げられる。 Various studies have been conducted in view of such problems. For example, an aerosol-type foam pack cosmetic that combines an acyl amino acid salt, a sugar alcohol, and a water-soluble polysaccharide (see Patent Document 1), a foam-forming cosmetic containing xanthan gum and quince seed extract (see Patent Document 2), carbonic acid Examples thereof include aerosol type aqueous facial cleansing cosmetics (see Patent Document 3) that combine gas, polyglycerin monofatty acid ester, and glycerin.
しかしながら、特許文献1、2に記載のエアゾール型化粧料では、多糖類を配合したことで、泡質の向上が認められるものの、多糖類のべたつき感が強く、特に化粧料の拭き取りや、洗い流した後にもべたつき感が残る場合があり、使用後の快適さが損なわれていた。
特許文献3に記載のエアゾール型化粧料では、炭酸ガスを噴射剤として利用することで、ガスの破裂に伴う刺激を低減させてはいるが、泡の安定性が低く、マッサージ施術中に泡が消失されてしまうものであった。
従って、本発明の課題は、キメ細かい泡で、コシがあり、適度な粘性を与えるクリーミーな泡で、マッサージ施術中においても泡状態が維持されてマッサージしやすく、拭き取り又は洗い流した後も、べたつき感がなく、肌にしっとりとした感触を与えるエアゾール型化粧料を提供することにある。
However, in the aerosol type cosmetics described in Patent Documents 1 and 2, the improvement in foam quality is recognized by blending polysaccharides, but the polysaccharides are strongly sticky, and especially the cosmetics are wiped off or washed away. The sticky feeling may remain afterwards, and the comfort after use was impaired.
In the aerosol-type cosmetics described in Patent Document 3, the stimulation associated with the gas burst is reduced by using carbon dioxide gas as a propellant, but the stability of the foam is low, and foam is generated during massage treatment. It would be lost.
Therefore, the object of the present invention is a fine foam, a firm, creamy foam that gives an appropriate viscosity, maintains a foam state even during massage treatment, is easy to massage, and feels sticky after wiping or washing away. The object is to provide an aerosol type cosmetic that gives a moist feel to the skin.
本発明者は上記課題を解決するために鋭意研究を行なった結果、ポリグリセリン脂肪酸エステルと糖類と水溶性高分子と炭酸ガスを組み合せてエアゾール型化粧料とすることにより、泡がキメ細かく、コシがあり、かつクリーミーでマッサージしやすく、拭き取り又は洗い流した後にべたつき感がなく、肌にしっとり感を付与できることを見出し、本発明を完成するに至った。 As a result of diligent research to solve the above-mentioned problems, the present inventor made an aerosol-type cosmetic by combining polyglycerin fatty acid ester, saccharide, water-soluble polymer and carbon dioxide gas. It has been found that it is creamy and easy to massage, has no stickiness after wiping or washing off, and can give a moist feeling to the skin, and the present invention has been completed.
即ち、本発明の請求項1は、(A)ポリグリセリンモノ脂肪酸エスエルと(B)糖類と(C)シリコーン油と(D)炭酸ガスを含有することを特徴とするエアゾール型化粧料である。 That is, claim 1 of the present invention is an aerosol type cosmetic comprising (A) polyglycerin monofatty acid S, (B) saccharide, (C) silicone oil, and (D) carbon dioxide.
本発明のエアゾール型化粧料は、キメ細かく、コシがあり、適度な粘性を与えるクリーミーな泡を生じ、マッサージ施術中においても皮膚上で泡状態が維持できるためマッサージしやすく、拭き取り又は洗い流した後もべたつき感がなく、肌にしっとりとした感触を付与できる。 The aerosol type cosmetics of the present invention are fine and firm, produce creamy foam that gives moderate viscosity, and can maintain a foam state on the skin even during massage treatment, so it is easy to massage, even after wiping or washing away There is no stickiness, and a moist feel can be imparted to the skin.
以下、本発明の構成を詳述する。 Hereinafter, the configuration of the present invention will be described in detail.
本発明における(A)ポリグリセリンモノ脂肪酸エスエルは、グリセリンの縮合体であるポリグリセリンのOH基に脂肪酸が一個エステル結合したものであり、下記一般式(1)で表されるものが好適に用いられる。 The (A) polyglycerin monofatty acid ester in the present invention is one in which one fatty acid is ester-bonded to the OH group of polyglycerin, which is a condensate of glycerin, and those represented by the following general formula (1) are preferably used. It is done.
(式中、Rはいずれか一つが炭素数8〜20の脂肪酸残基であり、他は水素原子であり、nは2〜18の整数であり重合モル数を示す。) (In the formula, any one of R is a fatty acid residue having 8 to 20 carbon atoms, the other is a hydrogen atom, and n is an integer of 2 to 18 and indicates the number of moles of polymerization.)
本発明に用いられる(A)ポリグリセリンモノ脂肪酸エステルは、グリセリンの平均重合度が2〜18、さらに6〜14、特に8〜12であることが好ましい。なかでもデカグリセリンが特に好ましい。
ポリグリセリンモノ脂肪酸エステルを構成する脂肪酸は、いずれか1つが炭素数8〜20の脂肪酸が好ましく、より好ましくは炭素数10〜18の脂肪酸であり、さらに好ましくは炭素数12〜16の脂肪酸である。また、脂肪酸は飽和、不飽和、直鎖、分岐鎖いずれであってもよいが、特に直鎖状飽和脂肪酸が好ましい。脂肪酸の具体例としてはラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、イソステアリン酸、オレイン酸、ヤシ油脂肪酸等が挙げられる。好ましくは、ラウリン酸、ミリスチン酸、パルミチン酸であるが、特にラウリン酸が好ましい。
本発明に用いられるポリグリセリン脂肪酸エステルの具体例としては、ラウリン酸デカグリセリル、ミリスチン酸デカグリセリル、パルミチン酸デカグリセリル、ラウリン酸ドデカグリセリル、ミリスチン酸ドデカグリセリル、パルミチン酸ドデカグリセリル等であり、これらを一種又は二種以上を組み合わせて添加することが出来る。これらの中でも特にラウリン酸デカグリセリル、ミリスチン酸デカグリセリルを用いることが好適である。
The (A) polyglycerol mono fatty acid ester used in the present invention preferably has an average polymerization degree of glycerol of 2 to 18, more preferably 6 to 14, and particularly preferably 8 to 12. Of these, decaglycerin is particularly preferable.
Any one of the fatty acids constituting the polyglycerin monofatty acid ester is preferably a fatty acid having 8 to 20 carbon atoms, more preferably a fatty acid having 10 to 18 carbon atoms, and still more preferably a fatty acid having 12 to 16 carbon atoms. . The fatty acid may be saturated, unsaturated, linear or branched, but is particularly preferably a linear saturated fatty acid. Specific examples of the fatty acid include lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, oleic acid, coconut oil fatty acid and the like. Preferred are lauric acid, myristic acid and palmitic acid, with lauric acid being particularly preferred.
Specific examples of the polyglyceryl fatty acid ester used in the present invention include decaglyceryl laurate, decaglyceryl myristate, decaglyceryl palmitate, dodecaglyceryl laurate, dodecaglyceryl myristate, dodecaglyceryl palmitate, and the like. One or a combination of two or more can be added. Among these, it is particularly preferable to use decaglyceryl laurate and decaglyceryl myristate.
本発明におけるポリグリセリンモノ脂肪酸エスエルの好ましい含有量としては、本発明化粧料全量中、0.1〜5.0質量%(以下、単に%と略す。)であり、特に好ましくは0.5〜2.0%である。ポリグリセリンモノ脂肪酸エスエルの含有量が当該範囲内であれば、泡のクリーミーさ、泡安定性が良好となる。 The preferred content of the polyglycerin monofatty acid sell in the present invention is 0.1 to 5.0% by mass (hereinafter simply abbreviated as%) in the total amount of the cosmetic of the present invention, and particularly preferably 0.5 to 2.0%. If the content of the polyglycerin monofatty acid ester is within the above range, the foam creaminess and foam stability will be good.
本発明における(B)糖類としては、通常化粧料に用いるものであれば特に限定されないが、ここでいう(B)糖類には、加水分解によって10分子以上の単糖類を生じる糖類は含まない。糖類としては、単糖類、二糖類又は糖アルコールを用いるのが好ましい。 The (B) saccharide in the present invention is not particularly limited as long as it is usually used in cosmetics. However, the (B) saccharide here does not include a saccharide that produces 10 or more monosaccharides by hydrolysis. As the saccharide, it is preferable to use a monosaccharide, a disaccharide or a sugar alcohol.
単糖類の具体例としては、D−エリツルロース,D−エリトロース,D−トレオース等のテトロース類、D−アラビノース,L−アラビノース,D−キシロース,D−リキソース,L−リキソース,D−リボース等のアルドペントース類、D−キシルロース,L−キシルロース,D−リブロース,L−リブロース等のケトペントース類、D−ガラクトース,L−ガラクトース,D−グルコース,D−タロース,D−マンノース等のアルドヘキソース類、L−ソルボース,D−タガトース,D−プシコース,D−フルクトース等のケトヘキソース類、D−アピオース,D−ハマメロース等の分枝糖類などが挙げられる。二糖類の具体例としては、キシロビオース,アガロビオース,カラビオース,マルトース,イソマルトース,ソホロース,セロビオース,トレハロース,ネオトレハロース,イソトレハロース,イヌロビオース,ビシアノース,イソプリメベロース,サンブビオース,プリメベロース,ソラビオース,メリビオース,ラクトース,リコビオース,エピセロビオース,スクロース,ツラノース,マルツロース,ラクツロース,エピゲンチビオース,ロビノビオース,シラノビオース,ルチノース等が挙げられる。糖アルコールとしては、エリスリトール,D−アラビトール,キシリトール,D−リビトール,ガラクチトール,D−グルシトール,D−マンニトール,マルチトール等が挙げられる。
好ましい糖類としては、グルコース、マルトース、マルチトール、スクロース、マンニトール、ソルビトール、トレハロースを利用することができる。
Specific examples of monosaccharides include aldoses such as D-erythrulose, D-erythrose, D-threose, etc., D-arabinose, L-arabinose, D-xylose, D-lyxose, L-lyxose, D-ribose, etc. Pentoses, ketopentoses such as D-xylulose, L-xylulose, D-ribulose, L-ribulose, aldohexoses such as D-galactose, L-galactose, D-glucose, D-talose, D-mannose, L- Examples thereof include ketohexoses such as sorbose, D-tagatose, D-psicose and D-fructose, and branched sugars such as D-apiose and D-hamamelose. Specific examples of disaccharides include xylobiose, agarobiose, carabiose, maltose, isomaltose, sophorose, cellobiose, trehalose, neotrehalose, isotrehalose, inulobiose, vicyanose, isoprimebellose, sambubiose, primebellose, solabiose, melibiose, Examples include lycobiose, epicellobiose, sucrose, turanose, maltulose, lactulose, epigentibose, robinobiose, silanobiose, and rutinose. Examples of the sugar alcohol include erythritol, D-arabitol, xylitol, D-ribitol, galactitol, D-glucitol, D-mannitol, maltitol and the like.
As preferred saccharides, glucose, maltose, maltitol, sucrose, mannitol, sorbitol and trehalose can be used.
糖類は、一種又は二種以上を組み合わせて添加することができる。これらの糖類のうち、単糖類又は二糖類を用いると、洗い流した後のしっとりした感触の面で特に優れ、好ましい。 Saccharides can be added singly or in combination of two or more. Among these saccharides, use of monosaccharides or disaccharides is particularly excellent and preferable in terms of moist feeling after washing.
本発明における(B)糖類の好ましい含有量としては、本発明化粧料全量中、5〜50%が好ましく、さらに好ましくは10〜30%である。糖類の含有量が当該範囲であれば、クリーミーな泡で、泡安定性が高く、洗い流した後でもべたつかずにしっとりとした感触が得られる。 As preferable content of (B) saccharides in this invention, 5-50% is preferable in the present cosmetics whole quantity, More preferably, it is 10-30%. If the saccharide content is within this range, the foam is creamy, has high foam stability, and can be moistened without being sticky even after washing.
本発明における(C)シリコーン油としては、例えば、ジメチルポリシロキサン、ジメチコノール、メチルフェニルポリシロキサン、ポリエーテル変性シリコーン、エポキシ変性シリコーン、フッ素変性シリコーン、アルコール変性シリコーン、アルキル変性シリコーン、アルコキシ変性シリコーン、アミノ変性シリコーン、パーフルオロアルキルポリオキシアルキレン変性シリコーン、環状シリコーン等が挙げられ、これらの中から一種又は二種以上を組み合わせて添加することが出来る。 Examples of the (C) silicone oil in the present invention include dimethylpolysiloxane, dimethiconol, methylphenylpolysiloxane, polyether-modified silicone, epoxy-modified silicone, fluorine-modified silicone, alcohol-modified silicone, alkyl-modified silicone, alkoxy-modified silicone, amino Modified silicones, perfluoroalkyl polyoxyalkylene-modified silicones, cyclic silicones and the like can be mentioned, and one or more of these can be added in combination.
好ましいシリコーン油としては、メチルフェニルポリシロキサン、ジメチルポリシロキサン、ポリエーテル変性シリコーン、アミノ変性シリコーンが挙げられる。
また、使用感(しっとり感、べたつき感のなさ)、泡のクリーミーさの点から、25℃における粘度が1〜1000mm2/sのものが好ましく、さらに好ましくは2〜500mm2/s、特に好ましくは5〜100mm2/sであるものが利用できる。
Preferred silicone oils include methylphenyl polysiloxane, dimethyl polysiloxane, polyether-modified silicone, and amino-modified silicone.
Further, (lack of moist feeling, stickiness) feeling, in terms of creaminess of the foam preferably has a viscosity at 25 ° C. of 1 to 1000 mm 2 / s, more preferably 2~500mm 2 / s, particularly preferably Can be 5-100 mm 2 / s.
本発明におけるシリコーン油の好ましい含有量としては、本発明化粧料全量中、0.01〜3.0%であり、さらに好ましくは0.1〜1.0%、特に好ましくは0.2〜0.7%である。シリコーン油の含有量が当該範囲内であると、泡のクリーミーさ、泡安定性が良好で、洗い流した後のべたつき感がなく、好ましい。 The preferable content of the silicone oil in the present invention is 0.01 to 3.0%, more preferably 0.1 to 1.0%, particularly preferably 0.2 to 0% in the total amount of the cosmetic of the present invention. 0.7%. When the content of the silicone oil is within the above range, the foam creaminess and foam stability are good, and there is no stickiness after washing, which is preferable.
本発明における(D)炭酸ガスは常温で気体であり、エアゾールの噴射剤として配合される。また、吐出される泡質を調整するために、液化石油ガス、ジメチルエーテル等の噴射剤を併用することができる。
本発明のエアゾール型化粧料には、25℃における圧力が0.4〜0.7MPaとなるように噴射剤を配合することが好ましく、特に皮膚への刺激性の点から、炭酸ガスを質量%に換算して、0.5〜2%とするのが好ましく、さらに好ましくは0.8〜1.2%含有させることが好ましい。
In the present invention, (D) carbon dioxide gas is a gas at room temperature and is blended as an aerosol propellant. Moreover, in order to adjust the foam quality discharged, propellants, such as liquefied petroleum gas and dimethyl ether, can be used together.
The aerosol type cosmetic of the present invention preferably contains a propellant so that the pressure at 25 ° C. is 0.4 to 0.7 MPa. In particular, from the viewpoint of irritation to the skin, carbon dioxide gas is contained by mass%. In terms of, it is preferably 0.5 to 2%, more preferably 0.8 to 1.2%.
本発明のエアゾール型化粧料には、さらにマッサージ施術中の泡状態の維持の点から、(E)水溶性高分子を含有させるのが好ましい。(E)水溶性高分子としては、多糖類(加水分解によって10分子以上の単糖類を生じる糖類)、タンパク・ポリアミノ酸系高分子、ビニル系高分子、ポリエーテル系高分子、ポリアミド系高分子、ポリエステル系高分子、ポリウレタン又はこれらの誘導体等が用いられる。
多糖類又はその誘導体の具体例としては、グアーガム、ローカストビーンガム、クイーンスシード、カラギーナン、ガラクタン、アラビアゴム、トラガント、ペクチン、キサンタンガム、デキストリン、サクシノグルカン、カードラン、ヒアルロン酸、コンドロイチン硫酸等の天然多糖類、メチルセルロース、エチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、カルボキシメチルセルロース、メチルヒドロキシプロピルセルロース、カチオン化セルロース、アルギン酸塩、アルギン酸プロピレングリコール、可溶性デンプン、カルボキシメチルデンプン、メチルデンプン等の合成あるいは半合成多糖類が挙げられる。
タンパク・ポリアミノ系高分子又はその誘導体の具体例としては、ゼラチン、カゼイン、アルブミン、コラーゲン、ポリグルタミン酸、ポリリジン、ポリアルギニンが挙げられる。
ビニル系高分子又はその誘導体の具体例としては、ポリビニルアルコール、ポリビニルメチルエーテル、ポリビニルエチルエーテル等のポリビニルエーテル類、ポリアクリル酸、ポリアクリル酸ナトリウム、ポリアクリル酸ヒドロキシエチル、ポリメタクリル酸ジメチルアミノエチル、カルボキシビニルポリマー等のアクリル酸系あるいはメタクリル酸系ポリマー、ポリメタクリルアミド、ポリN,N−ジメチルアクリルアミド等のポリアクリルあるいはポリメタクリルアミド酸、ポリビニルピロリドン、ビニルピロリドン共重合体、ポリN−ビニルイミダゾール、ポリ4−ビニルピリジンあるいはこれらの誘導体、マレイン酸等のカルボキシビニル基含有ポリマー、ポリ(N,N−ジメチル−3,5−メチレンピペリジウムクロライド)、N,N−ジメチル−3,5−メチレンピペリジニウムクロライド)−アクリルアミド共重合体、又はこれらの誘導体、更には上記ポリマーの単量体を含有する共重合体等が挙げられる。
その他の水溶性高分子又はその誘導体としてはポリエチレングリコール(数平均分子量1000以上)等のポリエーテル系高分子、水溶性ナイロン等のポリアミド系高分子、酸化エチレン・酸化プロピレンブロック共重合体等のポリエステル系高分子、水溶性ポリウレタン又はこれらの誘導体等が挙げられる。
The aerosol type cosmetic of the present invention preferably further contains (E) a water-soluble polymer from the viewpoint of maintaining the foam state during the massage treatment. (E) Water-soluble polymers include polysaccharides (saccharides that produce 10 or more monosaccharides by hydrolysis), protein / polyamino acid polymers, vinyl polymers, polyether polymers, polyamide polymers. Polyester polymers, polyurethane, or derivatives thereof are used.
Specific examples of polysaccharides or derivatives thereof include guar gum, locust bean gum, queen seed, carrageenan, galactan, gum arabic, tragacanth, pectin, xanthan gum, dextrin, succinoglucan, curdlan, hyaluronic acid, chondroitin sulfate, etc. Synthetic or semi-synthetic polysaccharides such as natural polysaccharides, methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose, methylhydroxypropylcellulose, cationized cellulose, alginate, propylene glycol alginate, soluble starch, carboxymethyl starch, methyl starch Examples include sugars.
Specific examples of the protein / polyamino polymer or derivative thereof include gelatin, casein, albumin, collagen, polyglutamic acid, polylysine, and polyarginine.
Specific examples of vinyl polymers or derivatives thereof include polyvinyl ethers such as polyvinyl alcohol, polyvinyl methyl ether, and polyvinyl ethyl ether, polyacrylic acid, sodium polyacrylate, hydroxyethyl polyacrylate, polydimethylaminoethyl methacrylate , Acrylic acid or methacrylic acid polymers such as carboxyvinyl polymer, polyacryl or polymethacrylamide such as polymethacrylamide, poly N, N-dimethylacrylamide, polyvinyl pyrrolidone, vinyl pyrrolidone copolymer, poly N-vinyl imidazole , Poly-4-vinylpyridine or derivatives thereof, carboxyvinyl group-containing polymers such as maleic acid, poly (N, N-dimethyl-3,5-methylenepiperidinium chloride), , N- dimethyl-3,5-methylene piperidinium chloride) - acrylamide copolymer, or derivatives thereof, more copolymers containing monomer of the above polymers.
Other water-soluble polymers or derivatives thereof include polyether polymers such as polyethylene glycol (number average molecular weight 1000 or more), polyamide polymers such as water-soluble nylon, and polyesters such as ethylene oxide / propylene oxide block copolymers. Based polymer, water-soluble polyurethane, or derivatives thereof.
特にこれらの水溶性高分子のうち、ポリビニルピロリドン及びビニルピロリドン系共重合体が泡のクリーミーさ、洗い流した後のしっとりした感触の面で優れており、好ましい。 Among these water-soluble polymers, polyvinyl pyrrolidone and vinyl pyrrolidone-based copolymers are particularly preferable because they are excellent in foam creaminess and moist feeling after washing.
ポリビニルピロリドンとしては、重量平均分子量が8000〜1300000のものが好ましく、更に好ましくは60000〜400000のものが利用できる。 The polyvinyl pyrrolidone preferably has a weight average molecular weight of 8000 to 1300000, more preferably 60000 to 400,000.
ビニルピロリドン系共重合体としては、ポリビニルピロリドン/アクリレート/(メタ)アクリル酸共重合体、ビニルピロリドン−N・N−ジメチルアミノエチルメタクリル酸共重合体ジエチル硫酸塩、ビニルイミダゾリウムトリクロライド/ビニルピロリドン共重合体、ポリビニルピロリドン/アルキルアミノアクリレート/ビニルカプロラクタム共重合体、塩化メチルビニルイミダゾリウム・ビニルピロリドン共重合体、メチルビニルイミダゾリウム・ビニルピロリドン共重合体メチル硫酸、(ビニルピロリドン/ジメチルアミノプロピルメタクリルアミド/ラウリルジメチルアミノプロピリメタクリルアミド)共重合体が好ましく使用できる。 Examples of the vinyl pyrrolidone copolymer include polyvinyl pyrrolidone / acrylate / (meth) acrylic acid copolymer, vinyl pyrrolidone-N · N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate, vinyl imidazolium trichloride / vinyl pyrrolidone. Copolymer, polyvinylpyrrolidone / alkylaminoacrylate / vinylcaprolactam copolymer, methylvinylimidazolium / vinylpyrrolidone copolymer, methylvinylimidazolium / vinylpyrrolidone copolymer methylsulfuric acid, (vinylpyrrolidone / dimethylaminopropylmethacrylate) An amide / lauryldimethylaminopropyl methacrylamide) copolymer can be preferably used.
本発明における水溶性高分子の好ましい含有量としては、本発明化粧料全量中に好ましくは0.01〜2%、さらに好ましくは0.05〜1%、特に好ましくは0.1〜0.5%である。水溶性高分子の含有量が当該範囲内であれば、クリーミーな泡で、マッサージ施術中においても泡状態が維持されてマッサージしやすい。 The preferable content of the water-soluble polymer in the present invention is preferably 0.01 to 2%, more preferably 0.05 to 1%, particularly preferably 0.1 to 0.5% in the total amount of the cosmetic of the present invention. %. If the content of the water-soluble polymer is within the above range, it is creamy foam, and the foam state is maintained even during massage treatment, and massage is easy.
本発明のエアゾール型化粧料には泡質、洗いあがりのしっとり感を向上させる目的で、さらに(F)2価又は3価アルコールを含有させることが好ましい。
2価又は3価アルコールの具体例としては、エチレングリコール、ジエチレングリコール、ポリエチレングリコール(数へ金分子量1000未満)、プロピレングリコール、ジプロピレングリコール、ポリプロピレングリコール(数平均分子量1000未満)、グリセリン、ジグリセリン、ポリグリセリン、イソプレングリコール、1,3−ブチレングリコールなどが挙げられる。
The aerosol type cosmetic of the present invention preferably further contains (F) a divalent or trivalent alcohol for the purpose of improving the foam quality and the moist feeling of washing.
Specific examples of the dihydric or trihydric alcohol include ethylene glycol, diethylene glycol, polyethylene glycol (having a molecular weight of less than 1000), propylene glycol, dipropylene glycol, polypropylene glycol (having a number average molecular weight of less than 1000), glycerin, diglycerin, Polyglycerin, isoprene glycol, 1,3-butylene glycol and the like can be mentioned.
好ましい2価又は3価アルコールとしては、グリセリン、ポリグリセリン、プロピレングリコール、ポリプロピレングリコール(数平均分子量1000未満)、ポリエチレングリコール(分子量1000未満)、1,3−ブチレングリコールを挙げることができる。 Preferred divalent or trivalent alcohols include glycerin, polyglycerin, propylene glycol, polypropylene glycol (number average molecular weight less than 1000), polyethylene glycol (molecular weight less than 1000), and 1,3-butylene glycol.
2価又は3価アルコールは、糖類の含有量に対して、質量比で好ましくは10:1〜1:2、さらに好ましくは5:1〜1:1の割合で含有することが好ましい。2価又は3価アルコールの配合量が当該範囲内であれば、泡質、洗いあがりのしっとり感が良好となる。 The divalent or trivalent alcohol is preferably contained in a mass ratio of 10: 1 to 1: 2, more preferably 5: 1 to 1: 1 with respect to the saccharide content. If the blending amount of the dihydric or trihydric alcohol is within the above range, the foam quality and the moist feeling of washing will be good.
本発明のエアゾール型化粧料には、発明の効果を損なわない範囲であれば、上記必須成分の他に界面活性剤、油性成分、シリコーン化合物、高級アルコール、低級アルコール、粉体、植物エキス、防腐剤、殺菌剤、キレート剤、酸化防止剤、pH調整剤、紫外線吸収剤、香料等を配合することが出来る。 In the aerosol type cosmetics of the present invention, a surfactant, an oily component, a silicone compound, a higher alcohol, a lower alcohol, a powder, a plant extract, an antiseptic, in addition to the above essential components, as long as the effects of the invention are not impaired. Agents, bactericides, chelating agents, antioxidants, pH adjusters, ultraviolet absorbers, fragrances and the like can be blended.
本発明のエアゾール型化粧料は、上記成分を耐圧容器に充填することにより製造できるが、その噴射の形態としては泡状にして吐出するフォームタイプとするのが好ましい。 The aerosol-type cosmetic of the present invention can be produced by filling the above-mentioned components into a pressure-resistant container, but it is preferable to use a foam type in which the foam is ejected in the form of a jet.
本発明のエアゾール型化粧料は、化粧料として特に制限なく利用できるが、拭き取り又は洗い流した後でも皮膚に対する保湿性が高いため、シャンプー、リンス、コンディショナーなどの毛髪化粧料、洗顔料、クレンジング化粧料、パック、マッサージ化粧料などの皮膚化粧料として好適に利用できる。 The aerosol-type cosmetic of the present invention can be used as a cosmetic without any particular limitation. However, since it has high moisture retention on the skin even after being wiped off or washed away, hair cosmetics such as shampoos, rinses and conditioners, facial cleansers, and cleansing cosmetics. It can be suitably used as skin cosmetics such as packs and massage cosmetics.
以下に実施例、比較例を挙げて本発明を説明する。本発明は、これらにより限定されるものではない。 Hereinafter, the present invention will be described with reference to examples and comparative examples. The present invention is not limited to these.
実施例、比較例に示した官能試験の試験方法は下記の通りである。尚、以下の表に示す組成物の含有量は、それぞれ%で示す。 The test methods of the sensory test shown in the examples and comparative examples are as follows. In addition, content of the composition shown in the following table | surfaces is each shown by%.
官能試験
10名の被験者によってエアゾール型化粧料の試料を頬の部位に塗布した。塗布後3分間マッサージを続け、ぬるま湯にて洗い流した。その後被験者本人が、マッサージのしやすさ、洗いあがりのしっとり感、べたつき感の無さについて官能評価し、平均評価点を求めた。評価基準は、以下の通りである。
Sensory test Aerosol-type cosmetic samples were applied to the cheek area by 10 subjects. After application, the massage was continued for 3 minutes and rinsed off with warm water. Thereafter, the subject himself / herself performed a sensory evaluation on the ease of massage, the moist feeling of washing, and the absence of stickiness, and the average evaluation score was obtained. The evaluation criteria are as follows.
4:非常に良好
3:良好
2:やや悪い
1:悪い
4: Very good 3: Good 2: Slightly bad 1: Bad
◎:平均評価点が3.4以上
○:平均評価点が2.8以上、3.4未満
△:平均評価点が2.2以上、2.8未満
× :平均評価点が2.2未満
A: Average evaluation score of 3.4 or more ○: Average evaluation score of 2.8 or more and less than 3.4 Δ: Average evaluation score of 2.2 or more and less than 2.8 ×: Average evaluation score of less than 2.2
実施例1〜4、比較例1〜8
表1に示した処方のエアゾール型化粧料を作製し、前記各試験を実施した。製造方法は噴射剤以外の成分を加熱混合し、冷却後、耐圧容器に充填した。その後、噴射剤加圧することにより充填した。処方と試験結果を表1に併せて示す。
Examples 1-4, Comparative Examples 1-8
Aerosol-type cosmetics having the formulations shown in Table 1 were prepared and the above tests were performed. In the production method, components other than the propellant were heated and mixed, and after cooling, the pressure vessel was filled. Then, it filled by pressurizing a propellant. Table 1 shows the formulation and test results.
表1より明らかなように本発明の成分(A)〜(D)を用いた実施例のエアゾール型化粧料はいずれも優れた性能を有していた。一方、成分(A)〜(D)のうちのいずれかを欠いた比較例では、マッサージのしやすさ、しっとり感、べたつき感の無さのいずれかの面で劣っており、本発明の目的を達成できなかった。 As is clear from Table 1, all of the aerosol type cosmetics of Examples using the components (A) to (D) of the present invention had excellent performance. On the other hand, the comparative example lacking any of the components (A) to (D) is inferior in any aspect of ease of massage, moist feeling, and no stickiness, and is an object of the present invention. Could not be achieved.
実施例5
原液
(A)ラウリン酸デカグリセリル 1.0 %
(F)ジプロピレングリコール 10.0
(B)マルチトール 5.0
(C)ジメチルポリシロキサン(6cs) 0.5
(E)ポリビニルピロリドン(重量平均分子量、400,000) 0.2
(E)ヒドロキシエチルセルロース 0.1
ラウロイルグルタミン酸ナトリウム 0.3
ステアリルアルコール 0.5
ポリオキシエチレン硬化ヒマシ油(60E.O.) 0.3
ポリオキシエチレンセチルエーテル(5E.O.) 0.5
エデト酸2ナトリウム 0.02
チンピエキス 0.1
アルテアエキス 0.05
キラヤエキス 0.05
ヒアルロン酸ナトリウム 0.01
フェノキシエタノール 0.2
グリチルリチン酸ジカリウム 0.1
香料 0.2
精製水 残部
噴射剤
液化石油ガス(0.15MPa、25℃) 5.0
(D)炭酸ガス 1.0
Example 5
Stock solution (A) Decaglyceryl laurate 1.0%
(F) Dipropylene glycol 10.0
(B) Maltitol 5.0
(C) Dimethylpolysiloxane (6cs) 0.5
(E) Polyvinylpyrrolidone (weight average molecular weight, 400,000) 0.2
(E) Hydroxyethyl cellulose 0.1
Sodium lauroyl glutamate 0.3
Stearyl alcohol 0.5
Polyoxyethylene hydrogenated castor oil (60 EO) 0.3
Polyoxyethylene cetyl ether (5EO) 0.5
Edetic acid disodium 0.02
Chimp extract 0.1
Altea extract 0.05
Kiraya extract 0.05
Sodium hyaluronate 0.01
Phenoxyethanol 0.2
Dipotassium glycyrrhizinate 0.1
Fragrance 0.2
Purified water Remaining propellant Liquefied petroleum gas (0.15 MPa, 25 ° C.) 5.0
(D) Carbon dioxide 1.0
上記組成のエアゾール型化粧料を作成し評価したところ、マッサージしやすさ、しっとり感、べたつき感の無さについて、優れた性能を有していた。尚、上記エアゾール型化粧料の圧力(25℃)は0.6MPaであった。 When an aerosol type cosmetic material having the above composition was prepared and evaluated, it had excellent performance in terms of ease of massage, moist feeling, and no stickiness. In addition, the pressure (25 degreeC) of the said aerosol type cosmetics was 0.6 MPa.
尚、上記の実施例5において使用した香料の組成は表2に示す。 The composition of the fragrance used in the above Example 5 is shown in Table 2.
実施例6
原液
(A)ラウリン酸デカグリセリル 2.0%
(B)スクロース 10.0%
(C)ポリエーテル変性シリコーン(KF−6011 信越化学工業社製) 0.5%
(E)ポリビニルピロリドン・N,N−ジメチルアミノエチルメタクリル酸共重合体ジエチル硫酸塩(GAFQUAT734、ISP社製、純分換算) 0.2%
(F)ジグリセリン 2.0%
ポリオキシエチレンセチルエーテル(15E.O.) 0.5%
ユズエキス 0.1%
クエン酸 0.05%
クエン酸ナトリウム 0.05%
精製水 残部
噴射剤
液化石油ガス(0.25MPa、25℃) 3.0%
(D)炭酸ガス 1.5%
Example 6
Stock solution (A) Decaglyceryl laurate 2.0%
(B) Sucrose 10.0%
(C) Polyether-modified silicone (KF-6011 manufactured by Shin-Etsu Chemical Co., Ltd.) 0.5%
(E) Polyvinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate (GAFQUAT734, manufactured by ISP, pure conversion) 0.2%
(F) Diglycerin 2.0%
Polyoxyethylene cetyl ether (15E.O.) 0.5%
Yuzu extract 0.1%
Citric acid 0.05%
Sodium citrate 0.05%
Purified water Remaining propellant Liquefied petroleum gas (0.25 MPa, 25 ° C.) 3.0%
(D) Carbon dioxide 1.5%
本発明によれば、クリーミーな泡で、肌をマッサージしやすく、洗い流した後も、肌にしっとりとした感触を与え、べたつき感のないエアゾール型化粧料を提供できる。 ADVANTAGE OF THE INVENTION According to this invention, it is easy to massage skin with creamy foam, and can provide the aerosol-type cosmetics which give a moist touch to the skin and does not have a sticky feeling after washing away.
Claims (5)
(A)ポリグリセリンの平均重合度が8〜12であり、脂肪酸が炭素数12〜16の直鎖状飽和脂肪酸である、ポリグリセリンモノ脂肪酸エステル:0.1〜5.0質量%
(B)単糖類、二糖類及び糖アルコールから選ばれる糖類
(C)シリコーン油:0.01〜3.0質量%
(D)炭酸ガス An aerosol type cosmetic comprising the following (A) to (D).
(A) Polyglycerin monofatty acid ester in which the average degree of polymerization of polyglycerol is 8 to 12 and the fatty acid is a linear saturated fatty acid having 12 to 16 carbon atoms: 0.1 to 5.0% by mass
(B) Saccharide selected from monosaccharides, disaccharides and sugar alcohols (C) Silicone oil: 0.01 to 3.0% by mass
(D) Carbon dioxide
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JP5986394B2 (en) * | 2012-02-22 | 2016-09-06 | 東洋エアゾール工業株式会社 | Foam forming aerosol composition |
JP5995233B2 (en) * | 2012-04-20 | 2016-09-21 | クラシエホームプロダクツ株式会社 | Foam aerosol composition |
JP6013138B2 (en) * | 2012-10-29 | 2016-10-25 | ポーラ化成工業株式会社 | Foam aerosol type skin external composition |
JP6155024B2 (en) * | 2012-12-28 | 2017-06-28 | 花王株式会社 | Aerosol cosmetics |
CN107613947A (en) * | 2015-05-29 | 2018-01-19 | 花王株式会社 | Spraying cosmetics |
JP6691788B2 (en) * | 2016-02-16 | 2020-05-13 | 花王株式会社 | Aerosol type cosmetics for scalp |
CN112203637B (en) | 2018-06-21 | 2023-02-17 | 花王株式会社 | Aerosol cosmetic product |
EP4159221A4 (en) | 2020-06-02 | 2024-07-03 | Kao Corp | Ultraviolet light sensitivity reducing agent |
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JP2005068084A (en) * | 2003-08-26 | 2005-03-17 | Pola Chem Ind Inc | Foam-like cleaning agent |
JP2005082519A (en) * | 2003-09-08 | 2005-03-31 | Kanebo Cosmetics Inc | Foamy aerosol-type cosmetic |
JP4355264B2 (en) * | 2004-06-25 | 2009-10-28 | ポーラ化成工業株式会社 | Warm feeling non-water foam cosmetic |
JP4690863B2 (en) * | 2005-11-11 | 2011-06-01 | ポーラ化成工業株式会社 | Aerosol facial cleansing cosmetic |
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