JP2013237615A - Foam aerosol composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a foam aerosol composition having foamability creating fine creamy foams, giving an easy condition for massaging by maintaining a foamed state during massaging practice, excellent in cleansing capacity, and capable of giving moist feeling and softness without stretch in skin after wiping or washing away.SOLUTION: A foam aerosol composition comprises: a sulfonate type surfactant; a polyoxyethylene glycerol fatty acid ester, a liquid at 25 °C; carbon dioxide; and a 3-5 hydrocarbon having a vapor pressure of 0.1-0.3 MPa at 25 °C.

Description

The present invention relates to a foamy aerosol composition, and in particular, it has excellent foaming properties and foam stability, is easy to massage, has excellent cleaning power, and gives a moist feel after washing without any firmness. It relates to a foamy aerosol composition that can be produced.

Aerosol compositions containing carbon dioxide (hereinafter also referred to as carbon dioxide) are widely used, such as a spray type for spraying lotion, and a foam type for discharging facial cleansing foam. In particular, the foam type has the effect of applying cosmetics discharged in the form of foam to the skin to block the skin and the outside air, and carbon dioxide promotes blood circulation and promotes metabolism. In addition, since carbon dioxide has an effect of promoting the penetration of various active ingredients contained in the composition, it has been developed as a facial cleanser or a massage material.

However, the foam-type foam type that uses carbon dioxide as a propellant, unlike conventional LPG gas or dimethyl ether used as a propellant, has a weak foaming power, and when applied for facial cleansing after application There is a problem that foam is difficult to stabilize, such as soft foam and easy defoaming. If the foam is not stable enough, the foam cannot be cushioned between the skin such as the face and the palm of the hand, causing irritation due to skin friction and impairing the barrier against outside air. Has a weak effect on the skin and cannot sufficiently increase metabolism. In addition, when combined with a surfactant such as fatty acid soap, ionicity is lost due to carbon dioxide and fatty acid aggregation occurs, so there are restrictions on the surfactant to be blended, there is no feeling of tension after washing, and it is moist It was difficult to give a feeling of use.

In view of these problems, various aerosol compositions have been studied. For example, aerosol type cosmetics (for example, refer to Patent Document 1) containing polyglycerin monofatty acid ester, saccharide, silicone oil and carbon dioxide, polyglycerin alkyl ether, polyhydric alcohol, water-soluble polymer and carbon dioxide. Examples thereof include aerosol type skin cosmetics (see, for example, Patent Document 2). In addition, a specific anionic surfactant such as ether sulfuric acid, ether carboxylic acid, N-acylamino acid or a salt thereof, (meth) acrylic acid polymer, polysaccharide polymer, carbon dioxide and hydrocarbon mixture An aerosol-type pack comprising a stock solution and a propellant containing a foamy skin coating agent (see, for example, Patent Document 3 or 4), an acylamino acid type surfactant, a polyhydric alcohol, a water-soluble polymer and silicone oil. Cosmetics (for example, refer patent document 5) etc. are mentioned.

JP 2011-093877 A JP 2011-093878 A JP 2011-084490 A JP 2010-248098 A JP 2008-037773 A

However, in the aerosol-type cosmetics described in Patent Document 1, although the improvement in foam quality is recognized by adding saccharides, the stickiness of saccharides is strong, especially after the cosmetics are wiped off or washed away. The sticky feeling may remain, and the comfort after use was impaired. Moreover, in the aerosol type skin cosmetic described in Patent Document 2, the stability of foam is improved by blending a water-soluble polymer, but the foaming property is insufficient, and the skin cleaning effect Since it is weak, it has not yet been fully satisfactory after use. In the foamy skin coating composition described in Patent Documents 3 and 4, the carbon dioxide gas and hydrocarbon mixture is used as a propellant to reduce irritation associated with gas bursting, but after wiping or washing away. After a long time, the feeling of tension was strong. In addition, in the aerosol type pack cosmetic described in Patent Document 5, by using an acylamino acid type surfactant and blending silicone oil, although the skin moist feeling after washing has been improved, Silicone oil has an effect on foaming properties and foam stability, and foams disappear during massage during washing.

Therefore, the subject of the present invention is excellent foaming property to form a fine creamy foam, easy to massage while maintaining the foam state even during massage treatment, excellent cleaning power, even after wiping or washing away, It is an object of the present invention to provide a foamy aerosol composition capable of giving a moist feel without having the skin sticky.

As a result of intensive studies to solve the above problems, the present inventor has obtained carbon dioxide and carbon dioxide having a specific vapor pressure in a stock solution containing a sulfonic acid type surfactant and a specific polyoxyethylene glycerin fatty acid ester. By adding hydrogen as a propellant, it is a foamy aerosol that has excellent foaming and foam stability, is easy to massage, has good cleaning power, and has a moist feel after washing. The inventors have found that a composition can be obtained and have completed the present invention.

That is, this invention is a foamy aerosol composition characterized by containing the following component (A)-(D).
(A) a sulfonic acid type surfactant,
(B) Polyoxyethylene glycerin fatty acid ester which is liquid at 25 ° C. (C) Carbon dioxide (D) Hydrocarbon having 3 to 5 carbon atoms having a vapor pressure of 0.1 to 0.3 MPa at 25 ° C.

The foamed aerosol composition of the present invention is excellent in foaming properties and foam stability, is easy to massage, has excellent cleaning power, and can give a moist feel without having the skin stretch after cleaning.

Hereinafter, the present invention will be described in detail.

The component (A) sulfonic acid type surfactant used in the present invention is not affected by the foaming property and the stability of the foam even when the pH is lowered by adding carbon dioxide. For the purpose of. Examples of such sulfonic acid type surfactants include alkyl sulfosuccinate, polyoxyethylene alkyl sulfosuccinate, α-olefin sulfonate, α-sulfo fatty acid methyl ester salt, and acyl isethionate.

The alkylsulfosuccinate and polyoxyethylene alkylsulfosuccinate are exemplified by the following general formula (1), and are obtained by esterifying maleic anhydride and alcohol and reacting sodium nitrite. Specific examples of fatty acids that are alkyl groups are coconut oil fatty acids, palm kernel fatty acids, lauric acid, myristic acid, palmitic acid, oleic acid, stearic acid, and mixtures thereof, which are fatty acids having 8 to 22 carbon atoms. Further, the number of moles of ethylene oxide added is 0 to 10 moles, preferably 2 to 5 moles per mole of surfactant. Specific examples of the salt serving as a counter ion are alkali metals such as sodium and potassium, magnesium Alkaline earth metals such as triethanolamine, diethanolamine, monoethanolamine, aminomethylpropanol, ammonia, and other organic alkalis, basic amino acids such as arginine, lysine, and histidine, and mixtures thereof. Specific examples of these polyoxyethylene alkyl ether carboxylates include disodium lauryl sulfosuccinate, disodium dodecene sulfosuccinate, disodium undecylenate monoethanolamide sulfosuccinate, polyoxyethylene alkyl (12-14) sulfosuccinate Sodium (1E.O.), polyoxyethylene alkyl (12-14) sulfosuccinate disodium (2E.O.), polyoxyethylene coconut oil fatty acid sulfosuccinate disodium (2E.O.), polyoxyethylene sulfosuccinic acid Examples include disodium lauryl (1E.O.), disodium lauryl polyoxyethylene sulfosuccinate (2E.O.), and disodium polyoxyethylene lauroyl ethanolamide (5E.O.) sulfosuccinate. Among these, polyoxyethylene sulfosuccinate disodium lauryl (1EO), polyoxyethylene alkyl (12-14) disodium sulfosuccinate (2E. O.) is preferred.

（Ｒ¹は炭素数８〜２２のアルキル基、ｎは０〜１０の整数、Ｍ¹はアルカリ金属、アルカリ土類金属、有機アルカリ、塩基性アミノ酸を示す。）

(R ¹ is an alkyl group having 8 to 22 carbon atoms, n is an integer of 0 to 10, M ¹ is an alkali metal, an alkaline earth metal, an organic alkali, or a basic amino acid.)

The α-olefin sulfonate is exemplified by the following general formulas (2) and (3), and is obtained by thermal decomposition of paraffin wax, polymerization of ethylene, and sulfonation. Generally, the α-olefin sulfonate is commercially available as a mixture of 70 to 80% of the composition of the general formula (2) and 20 to 30% of the composition of the general formula (3). Specific examples of the salt serving as a counter ion include alkali metals such as sodium and potassium, alkaline earth metals such as magnesium, organic alkalis such as triethanolamine, diethanolamine, monoethanolamine, aminomethylpropanol, and ammonia, arginine, lysine, Basic amino acids such as histidine and mixtures thereof. Among these α-olefin sulfonates, sodium tetradecenesulfonate is preferable.

（ｐは８〜１４の整数、Ｍ²はアルカリ金属、アルカリ土類金属、有機アルカリ、塩基性アミノ酸を示す。）

(P represents an integer of 8 to 14, M ² represents an alkali metal, an alkaline earth metal, an organic alkali, or a basic amino acid.)

（ｑは８〜１４の整数、Ｍ³はアルカリ金属、アルカリ土類金属、有機アルカリ、塩基性アミノ酸を示す。）

(Q represents an integer of 8 to 14, M ³ represents an alkali metal, an alkaline earth metal, an organic alkali, or a basic amino acid.)

The α-sulfo fatty acid methyl ester salt is exemplified by the following general formula (4), and is obtained by sulfonated fatty acid methyl ester. Specific examples of the salt serving as a counter ion are sodium,
Alkaline metals such as potassium, alkaline earth metals such as magnesium, organic alkalis such as triethanolamine, diethanolamine, monoethanolamine, aminomethylpropanol and ammonia, basic amino acids such as arginine, lysine and histidine, and mixtures thereof . Among these α-sulfo fatty acid methyl ester salts, coconut oil fatty acid methyl-α-sulfonate sodium and palm kernel oil fatty acid methyl-α-sulfonate sodium are preferable.

(R represents an integer of 8 to 14, M ⁴ represents an alkali metal, alkaline earth metal, organic alkali, or basic amino acid.)

The acyl isethionate is exemplified by the following general formula (5), and is obtained by condensation and esterification of a fatty acid and an isethionate. Specific examples of the fatty acid include coconut oil fatty acid, palm kernel fatty acid, lauric acid, myristic acid, palmitic acid, oleic acid, stearic acid, and mixtures thereof, which are fatty acids having 8 to 22 carbon atoms. Specific examples of the salt serving as a counter ion include alkali metals such as sodium and potassium, alkaline earth metals such as magnesium, organic alkalis such as triethanolamine, diethanolamine, monoethanolamine, aminomethylpropanol, and ammonia, arginine, lysine, Basic amino acids such as histidine and mixtures thereof. Among these α-sulfo fatty acid methyl ester salts, coconut oil fatty acid ethyl ester sodium sulfonate and palm kernel oil fatty acid ethyl ester sodium sulfonate are preferable.

（Ｒ²は炭素数８〜２２のアルキル基、Ｍ⁵はアルカリ金属、アルカリ土類金属、有機アルカリ、塩基性アミノ酸を示す。）

(R ² represents an alkyl group having 8 to 22 carbon atoms, and M ⁵ represents an alkali metal, an alkaline earth metal, an organic alkali, or a basic amino acid.)

The N-acylmethyl taurine salt is exemplified by the following general formula (6), and is obtained by condensing and esterifying a fatty acid and an N-methyl taurine salt. Specific examples of the fatty acid include coconut oil fatty acid, palm kernel fatty acid, lauric acid, myristic acid, palmitic acid, oleic acid, stearic acid, and mixtures thereof, which are fatty acids having 8 to 22 carbon atoms. Specific examples of the salt serving as a counter ion include alkali metals such as sodium and potassium, alkaline earth metals such as magnesium, organic alkalis such as triethanolamine, diethanolamine, monoethanolamine, aminomethylpropanol, and ammonia, arginine, lysine, Basic amino acids such as histidine, and mixtures thereof. Specific examples of these N-acylmethyl taurine salts include N-coconut oil fatty acid methyl taurine sodium, N-lauroyl methyl taurine sodium, N-palm nuclear fatty acid methyl taurine sodium, N-myristoyl methyl taurine sodium, N-palmitoyl methyl. Examples include taurine sodium, N-stearoylmethyl taurine sodium, N-caproylmethyl taurine sodium, N-coconut oil fatty acid methyl taurine magnesium and the like. Among these, N-coconut oil fatty acid methyl taurine sodium and N-lauric acid methyl taurine sodium are preferable from the viewpoint of foamability.

（Ｒ³は炭素数８〜２２のアルキル基、Ｍ⁶はアルカリ金属、アルカリ土類金属、有機アルカリ、塩基性アミノ酸を示す。）

(R ³ represents an alkyl group having 8 to 22 carbon atoms, and M ⁶ represents an alkali metal, alkaline earth metal, organic alkali, or basic amino acid.)

These component (A) sulfonic acid type surfactants in the present invention are alkyl sulfosuccinate, polyoxyethylene alkyl sulfosuccinate, α-olefin sulfonate, α-sulfo fatty acid methyl ester salt, acyl isethionate, N -It can mix | blend 1 type individually or in combination of 2 or more types among acylmethyl taurine salts. Among these sulfonic acid type surfactants, polyoxyethylene alkylsulfosuccinate and N-acylmethyl taurate are preferable in terms of touch because they are less creamy and less foamy after washing. Furthermore, N-acylmethyl taurate is particularly preferable in that it is less susceptible to foaming and foam stability due to pH reduction by carbon dioxide.

A preferable blending amount of the sulfonic acid type surfactant in the present invention is 0.5 to 10% by mass (hereinafter simply referred to as “%”) in the entire composition in the pressure vessel, and particularly preferably 2 to 7%. It is. When the blending amount of the surfactant is less than 0.5%, foaming properties may not be obtained, and when the blending amount exceeds 10%, the foam becomes too hard to be applied to the skin, and the massage property is improved. It may be missing.

The component (B) used in the present invention is a polyoxyethylene glycerin fatty acid ester which is liquid at 25 ° C., which is a known substance known as a nonionic surfactant, and has liquid properties at 25 ° C. The added mole number of polyoxyethylene is preferably 5 to 10, and the fatty acid preferably has 12 to 20 carbon atoms. From the viewpoint of hydrophilic / lipophilic balance, those having an HLB value in the range of 8 to 13 are preferred, and those having the range of 9 to 12 are particularly preferred. Examples of such polyoxyethylene glycerin fatty acid esters include polyoxyethylene coconut oil fatty acid glycerin (5E.O.), polyoxyethylene coconut oil fatty acid glycerin (7E.O.), polyoxyethylene coconut oil fatty acid glycerin (10E). O.), polyoxyethylene palm kernel fatty acid glycerin (5E.O.), polyoxyethylene palm kernel fatty acid glycerin (7E.O.), polyoxyethylene palm kernel fatty acid glycerin (10E.O.), polyoxy Glycerin ethylene oleate (5E.O.), glycerin polyoxyethylene oleate (7E.O.), glycerin polyoxyethylene oleate (10E.O.), glycerin polyoxyethylene isostearate (5E.O.), Polyoxyethylene isostear Glyceryl acid (7E.O.), glyceryl polyoxyethylene isostearate (10E.O.), polyoxyethylene (capryl / capric acid) glyceryl (5E.O.), polyoxyethylene (capryl / capric acid) glyceryl (7E.O.), polyoxyethylene (capryl / capric acid) glyceryl (10E.O.) and the like can be mentioned, and one of these can be used alone or two or more can be combined.

Among these polyoxyethylene glycerin fatty acid esters, polyoxyethylene coconut oil fatty acid glycerin (7EO), polyoxyethylene isostearic acid glycerin (7EO), polyoxyethylene (capryl / capric acid) glyceryl (7E) O.) is preferable in terms of the creaminess of the foam and the feeling of being less bulky after washing, and polyoxyethylene coconut oil fatty acid glycerin (7E.O.) is particularly preferable because it does not adversely affect the foamability and foam quality.

A preferable blending amount of the polyoxyethylene glycerin fatty acid ester in the present invention is 0.5 to 10%, particularly preferably 1 to 5% in the entire composition in the pressure vessel. If the blending amount of the polyoxyethylene glycerin fatty acid ester is less than 0.5%, the skin may remain moist after washing, and a moist feel may not be obtained. If the blending amount exceeds 10%, foaming occurs. May affect the skin and difficult to apply to the skin.

Component (C) carbon dioxide used in the present invention is a component that fills the pressure-resistant container as a gas and functions as a blood circulation promoting action and a propellant. Part of the carbon dioxide is dissolved in the composition in the pressure vessel and foams when applied to the skin. On the skin, gaseous carbon dioxide in the foam and carbon dioxide dissolved in the liquid portion have an action of promoting blood circulation in the skin. Therefore, it is preferable that carbon dioxide is present at a high concentration in the liquid in the container.

As a preferable blending amount of carbon dioxide in the present invention, blending is preferably performed such that the pressure at 25 ° C. is 0.4 to 0.7 MPa, and further blending so as to be 0.6 to 0.7 MPa. Particularly preferred. Moreover, when converting carbon dioxide to mass%, it is preferable to contain 0.5 to 2% in the entire composition in the pressure vessel, and more preferably 0.8 to 1.5%. If the blending amount of carbon dioxide is less than 0.5%, foaming properties may be insufficient, and if the blending amount exceeds 2%, it is not preferable from the viewpoint of irritation to the skin.

Component (D) hydrocarbon used in the present invention is, for example, one kind or a mixture of two or more kinds selected from hydrocarbons having 3 to 5 carbon atoms such as propane, butane, isobutane, normal butane, isopentane, and normal pentane. , Having a vapor pressure of 0.1 to 0.3 MPa at 25 ° C. When the foamy aerosol composition of the present invention is applied to the skin, it has an action of foaming together with carbon dioxide to form a foam containing carbon dioxide at a high concentration. In order to dissolve carbon dioxide in the liquid in the pressure vessel in order to achieve both good foam quality and blood circulation promotion effect when the foamy aerosol composition of the present invention is discharged, the vapor pressure of the hydrocarbon mixture Is effective, and the vapor pressure at 25 ° C. is preferably 0.1 to 0.3 MPa, more preferably 0.15 to 0.25 MPa.

The preferred blending amount of the hydrocarbon in the present invention is preferably 1 to 10%, more preferably 2 to 5%, in the total composition in the pressure vessel.

Propane or the like is a saturated hydrocarbon having a vapor pressure of more than 0.3 MPa alone at 25 ° C., but a mixture with other hydrocarbons having 3 to 5 carbon atoms has a vapor pressure of 0.1 to 0. 25 at 25 ° C. If it is 3 MPa, it can be used. Usually, liquefied petroleum gas (LPG) is a mixture of propane and butane, and is distributed as a mixed gas in which these ratios are adjusted according to the purpose. In the present invention, the content of hydrocarbons having a high vapor pressure at 25 ° C. is low in order to obtain a foam that can be kept on the skin for a long time by containing the carbon dioxide in a high concentration under a low pressure inside the pressure vessel. It is preferable. Therefore, it is preferable that propane is not substantially blended, but considering industrial availability, it is also possible to use LPG having normal butane and isobutane: propane (mass ratio) of 70 to 100: 0 to 30. Furthermore, it is also possible to use LPG which is 90-99.9: 0.1-10, and it is also possible to use LPG which is 97-99.5: 0.5-3 especially.

In addition, the mass ratio (C) :( D) of the components (C) and (D) filled in the pressure resistant container is in the range of 1: 9 to 1: 4 in order to satisfy both good foam and blood circulation promoting effect. It is preferable that the ratio is 1: 6 to 1: 4, particularly from the viewpoint of blood circulation promotion effect.

Moreover, it is preferable to mix | blend a component (E) polyhydric alcohol with the foam-like aerosol composition of this invention, in order to improve the solubility of a carbon dioxide, and to improve foamability and foam stability.
Polyhydric alcohol includes alcohol, monosaccharide, disaccharide and sugar alcohol having two or more alcoholic hydroxyl groups in the molecular structure.

Specific examples of the dihydric or higher alcohol include ethylene glycol, diethylene glycol, polyethylene glycol (number average molecular weight less than 1000), propylene glycol, dipropylene glycol, polypropylene glycol (number average molecular weight less than 1000), glycerin, diglycerin, polyglycerin. , Isoprene glycol, 1,3-butylene glycol and the like. As preferable divalent or higher alcohols, glycerin, polyglycerin, propylene glycol, polypropylene glycol (number average molecular weight less than 1000), polyethylene glycol (molecular weight less than 1000), and 1,3-butylene glycol can be used.

Specific examples of monosaccharides include aldoses such as D-erythrulose, D-erythrose, D-threose, etc., D-arabinose, L-arabinose, D-xylose, D-lyxose, L-lyxose, D-ribose, etc. Pentoses, ketopentoses such as D-xylulose, L-xylulose, D-ribulose, L-ribulose, aldohexoses such as D-galactose, L-galactose, D-glucose, D-talose, D-mannose, L- Examples thereof include ketohexoses such as sorbose, D-tagatose, D-psicose and D-fructose, and branched sugars such as D-apiose and D-hamamelose.

Specific examples of disaccharides include xylobiose, agarobiose, carabiose, maltose, isomaltose, sophorose, cellobiose, trehalose, neotrehalose, isotrehalose, inulobiose, vicyanose, isoprimebellose, sambubiose, primeverose, solabiose, melibiose, Examples include lycobiose, epicellobiose, sucrose, turanose, maltulose, lactulose, epigentibose, robinobiose, silanobiose, and rutinose.

Examples of the sugar alcohol include erythritol, D-arabitol, xylitol, D-ribitol, galactitol, D-glucitol, D-mannitol, maltitol and the like. As preferred saccharides, glucose, maltose, maltitol, sucrose, mannitol, sorbitol, trehalose, and glucosyl trehalose can be used.

A polyhydric alcohol can be used individually by 1 type or in combination of 2 or more types. Among these polyhydric alcohols, when 1,3-butylene glycol, dipropylene glycol, and glycerin are used, the stability of the foam and a moist feeling after washing off are given. The preferred content of the polyhydric alcohol is preferably 10 to 50%, more preferably 15 to 30% in the entire composition in the pressure vessel. If the content of the polyhydric alcohol is within the above range, creamy foam, high foam stability, and a moist feel can be obtained without being sticky after washing.

The foamed aerosol composition of the present invention can further contain a nonionic surfactant in order to finely adjust foamability and foam stability. Nonionic surfactants include polyoxyethylene (hereinafter abbreviated as POE) sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monolaurate, POE sorbitan tetraoleate, and other POE sorbitan fatty acids. Esters: POE sorbite fatty acid esters such as POE-sorbite monolaurate, POE-sorbite monooleate, POE-sorbite pentaoleate, POE-sorbite monostearate; POE-glycerin monostearate, POE-glycerin monoiso POE glycerin fatty acid esters such as stearate and POE-glycerin triisostearate; POE monooleate, PO
POE fatty acid esters such as E distearate, POE monodiolate, ethylene glycol distearate; POE alkyl ethers such as POE lauryl ether, POE oleyl ether, POE stearyl ether, POE behenyl ether, POE2-octyldodecyl ether, POE cholestanol ether; POE alkyl phenyl ethers such as POE octyl phenyl ether, POE nonyl phenyl ether, and POE dinonyl phenyl ether; pull aronic types such as Pluronic (registered trademark); POE polyoxypropylene (hereinafter abbreviated as POP) cetyl ether; POE / POP2-decyltetradecyl ether, POE / POP monobutyl ether, POE / POP hydrogenated lanolin, POE / POP grease POE / POP alkyl ethers such as phosphorus ether; Tetra POE / tetra POP ethylenediamine condensates such as Tetronic (registered trademark); POE castor oil, POE hydrogenated castor oil, POE hydrogenated castor oil monoisostearate, POE hydrogenated castor Oil triisostearate, POE hydrogenated castor oil monopyroglutamic acid monoisostearic acid diester, POE castor oil hydrogenated castor oil derivatives such as POE hydrogenated castor oil maleic acid; POE beeswax lanolin derivatives such as POE sorbite beeswax; palm oil fatty acid diethanolamide , Alkanolamides such as lauric acid monoethanolamide, fatty acid isopropanolamide, POE propylene glycol fatty acid ester, POE alkylamine, POE fatty acid amide, sucrose fatty acid ester Le, POE nonylphenyl formaldehyde condensate, an alkyl ethoxy dimethylamine oxide, such as trioleyl phosphate. The blending amount of these nonionic surfactants is particularly preferably 0.1 to 10%, more preferably 0.5 to 3% in the total composition in the pressure vessel.

Furthermore, in addition to the above-described components, the foamable aerosol composition of the present invention may optionally contain components that can be generally blended in cosmetics within a range that does not impair the effects of the present invention. Examples of such components include oily components such as fats and oils, waxes, hydrocarbon oils, ester oils, and silicones, alcohols such as higher alcohols and lower alcohols, natural water-soluble polymers, semi-synthetic water-soluble polymers, and synthetic compounds. Polymer compounds such as water-soluble polymers, moisturizers, preservatives, vitamins, anti-inflammatory agents, whitening agents, plant extracts, activators, blood circulation promoters, antiseborrheic agents, inorganic water-soluble polymers, metal ions Various drugs such as a blocking agent are included.

As fats and oils, avocado oil, camellia oil, evening primrose oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil, linseed oil , Safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin, trioctanoic acid glycerin, triisopalmitic acid Liquid fats such as glycerin; cacao butter, palm oil, horse fat, hydrogenated palm oil, palm oil, beef tallow, sheep fat, hydrogenated beef tallow, palm kernel oil, pork fat, beef bone fat, owl kernel oil, hydrogenated oil, cow leg Examples thereof include solid fats and oils such as fat, mole, and hardened castor oil. The waxes include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ibota wax, whale wax, montan wax, nuka wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, lauryl hexyl, reduced lanolin, jojojo Examples include a wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, and the like. Examples of the hydrocarbon oil include oils such as liquid paraffin, ozokerite, squalane, pristane, paraffin, ceresin, squalene, petrolatum, and microcrystalline wax. Ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate, myristyl lactate, Lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearylate, ethylene glycol di-2-ethylhexylate, dipentaerythritol fatty acid ester, monoisostearic acid N-alkyl glycol, dicaprate neopentyl glycol, malic acid diacid Isostearyl, glycerin di-2-heptylundecanoate, trimethylolpropane tri-2-ethylhexylate, triisostearyl Trimethylolpropane acid, pentane erythritol tetra-2-ethylhexylate, glyceryl triethyl 2-ethylhexylate, trimethylolpropane triisostearate, cetyl 2-ethylhexanoate, 2-ethylhexyl palmitate, glyceryl trimyristate, tri-2 -Heptylundecanoic acid glyceride, castor oil fatty acid methyl ester, oleic acid oil, acetoglyceride, 2-heptylundecyl palmitate, diisobutyl adipate, N-lauroyl-L-glutamic acid-2-octyldecyl ester, adipic acid di-2 -Heptyl undecyl, ethyl laurate, di-2-ethylhexyl sebacate, 2-hexyldecyl myristate, 2-hexyldecyl palmitate, 2-hexyldeadipate Le, sebacic acid diisopropyl, 2-ethylhexyl succinate, ethyl acetate, butyl acetate, amyl acetate, triethyl citrate, crotamiton (C ₁₃ H ₁₇ NO) and the like are exemplified. Examples of silicone include linear polysiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane, and methylhydrogenpolysiloxane; cyclic polysiloxanes such as decamethylpolysiloxane, dodecamethylpolysiloxane, and tetramethyltetrahydrogenpolysiloxane; three-dimensional Examples thereof include silicone resin and silicone rubber forming a network structure.

As higher alcohols, linear alcohols such as lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol; monostearyl glycerin ether (batyl alcohol), 2-decyltetradecinol, lanolin alcohol, Examples thereof include branched chain alcohols such as cholesterol, phytosterol, hexyldodecanol, isostearyl alcohol, and octyldodecanol. Examples of the lower alcohol include ethanol, propanol, isopropanol, isobutyl alcohol, t-butyl alcohol and the like.

Natural water-soluble polymers include arabia gum, tragacanth gum, galactan, guar gum, locust bean gum, tamarint gum, carob gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), alge colloid (gypsum extract), starch (rice, corn, Plant water-soluble polymers such as potato and wheat; microbial water-soluble polymers such as xanthan gum, dextran, succinoglucan, and bullulan; animal water-soluble polymers such as collagen, casein, albumin, and gelatin The Semi-synthetic water-soluble polymers include starch-based water-soluble polymers such as carboxymethyl starch and methylhydroxypropyl starch; methylcellulose, nitrocellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate, hydroxypropylcellulose, carboxy Examples thereof include cellulose water-soluble polymers such as methyl cellulose (CMC), crystalline cellulose, and cellulose powder; and alginic acid water-soluble polymers such as sodium alginate and propylene glycol alginate. Synthetic water-soluble polymers include vinyl water-soluble polymers such as polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, and carboxyvinyl polymer (Carbopol: registered trademark); polyethylene glycol 1,000, 6,000, and 20 Polyoxyethylene water-soluble polymers such as 1,000,000; copolymer water-soluble polymers such as polyoxyethylene polyoxypropylene copolymers; acrylic water-soluble polymers such as sodium polyacrylate, polyethyl acrylate and polyacrylamide In addition to molecules, polyethyleneimine, cationic polymers and the like are exemplified. Examples of the inorganic water-soluble polymer include bentonite, AlMg silicate (Begum: registered trademark), laponite, hectorite, and anhydrous silicic acid.

Moisturizers include polyethylene glycol, propylene glycol, glycerin, 1,3
-Butylene glycol, hexylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12-hydroxystearate, sodium lactate, bile salt, dl-pyrrolidone carboxylate And short chain soluble collagen, diglycerin (EO) PO adduct, Isaiyobara extract, Achillea millefolium extract, Merirot extract and the like. As vitamins, vitamin A such as vitamin oil, retinol and retinol acetate; vitamin B ₂ such as riboflavin, riboflavin butyrate and flavin adenine nucleotides; vitamin B ₆ such as pyridoxine hydrochloride and pyridoxine dioctanoate; L -Ascorbic acid, L-ascorbic acid dipalmitate, L-ascorbic acid-2-sodium sulfate, L-ascorbic acid phosphate DL-α-tocopherol-L-ascorbic acid diester dipotassium, ethylascorbic acid, etc. Vitamin Cs; Pantothenic acids such as calcium pantothenate, D-pantothenyl alcohol, pantothenyl ethyl ether and acetyl pantothenyl ethyl ether; Vitamin Ds such as ergocalciferol and cholecalciferol; Nico Nicotinic acids such as acid, nicotinamide, benzyl nicotinate; vitamin E such as α-tocopherol, tocopherol acetate, DL-α-tocopherol nicotinate, DL-α-tocopherol succinate; vitamin P; exemplified by biotin The Examples of the preservative include methyl paraben, ethyl paraben, butyl paraben, propyl paraben, phenoxyethanol, resorcin, salicylic acid, dehydroacetic acid, hexachlorophene, benzalkonium chloride, isopropylmethylphenol, alkanediol and the like. Examples of the anti-inflammatory agent include glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, and the like. Examples of the whitening agent include ascorbic acid, ascorbic acid derivatives, placenta extract, arbutin, tranexamic acid, kojic acid, sulfur, oil-soluble licorice extract, glaze extract, and yukinoshita extract. Plant extracts include: buckwheat, auren, shikon, peonies, assembly, birch, sage, loquat, carrot, aloe, mallow, iris, grape, yokoinin, loofah, lily, saffron, senkyu, ginger, hypericum, onion, rose Examples of the extract include marie, garlic, pepper, chimpi, toki, seaweed, and tea. Examples of the activator include royal jelly, photosensitizer, cholesterol derivative and the like. Blood circulation promoters include nonyl acid wallenyl amide, nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, gingerone, cantalis tincture, ictamol, caffeine, tannic acid, α-borneol, nicotinic acid tocopherol, inositol hexanicotine. Examples thereof include nate, cyclandrate, cinnarizine, trazoline, acetylcholine, verapamil, cephalanthin, and γ-oryzanol. Examples of antiseborrheic agents include sulfur and thianthol. The sequestering agents include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, edetate dinatium, edetate trisodium, edetate tetrasodium, Examples include sodium acid, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, and edetic acid.

Carbon dioxide blended in the foamed aerosol composition of the present invention does not dissolve as carbon dioxide under alkaline conditions, but becomes carbonate, and does not exhibit foaming properties or blood circulation promoting effects. Therefore, the pH of the stock solution of the foam aerosol composition of the present invention is preferably in the range of pH 3.0 to 8.0 from the viewpoint of obtaining an excellent blood circulation promoting effect by dissolving carbon dioxide at a high concentration. As a pH adjuster for adjusting the pH within these ranges, for example, organic acids such as citric acid, malic acid and tartaric acid, or salts thereof, or phosphoric acid or salts thereof can be used.

The foamy aerosol composition of the present invention is produced by filling a pressure-resistant container with a stock solution containing the components (A) and (B), and further enclosing (C) carbon dioxide and (D) hydrocarbons. At this time, it is also possible to fill with other injection gas as needed.

The pressure vessel only needs to be in a form that allows the content liquid to be discharged in the form of a foam, for example, a normal single-chamber can such as aluminum or tin can be used, and the container material is an acetal resin, A synthetic resin container such as a polycarbonate-based resin, glass, or the like can be used as long as it is within the pressure limit. In particular, when high pressure carbon dioxide is filled industrially once, an impact can having an aluminum container thickness adjusted is preferable. Further, depending on the viscosity of the stock solution, a double container having an inner bag in a pressure resistant container can be used. In the case of a double container, the foamy skin coating agent of the present invention is filled in an inner bag, and a spray gas is filled separately between the pressure-resistant container and the inner bag. This propellant gas can be used as long as it is a gas generally used in aerosol.

The pressure in the pressure vessel is less than 0.7 MPa at 25 ° C., but is preferably 0.4 MPa to 0.7 MPa from the viewpoint of obtaining good foam.

The foam aerosol composition of the present invention is preferably used by applying on the skin and spreading the resulting foam on the skin. Here, as an application means on the skin, it may be directly discharged onto the desired skin to form bubbles on the spot, but it is discharged onto the hand to form bubbles, and the bubbles are formed on the desired skin. You may apply to. The foam formed by the foamy coating composition of the present invention is stable for a long time, and is stable even after performing an operation to spread on the skin, a light massage, etc., so high concentration carbon dioxide acts on the skin for a long time. Excellent blood circulation promoting effect.

Hereinafter, the present invention will be described in more detail with reference to test methods and examples. The present invention is not limited by the following test methods and examples. In addition, in description of an Example including the following test methods, although all the mixture ratios are the mass%, description is abbreviate | omitted.

(1) Foaming aerosol compositions of Examples and Comparative Examples prepared by foaming ordinary methods are stored in a 50 mL glass container after storage at 25 ° C. for 1 week, and the mass of 50 mL of foam is measured. The density per unit volume (1 cm ³ ) was calculated and judged according to the following criteria. In addition, it shows that foamability is so high that a density is small.

(Evaluation criteria)
A: Density is less than 0.15 g / mL. O: Density is 0.15 g / mL or more and less than 0.2 g / mL. Δ: Density is 0.2 g / mL or more and less than 0.3 g / mL. 3g / mL or more

(2) Foam stability After the foam aerosol compositions of Examples and Comparative Examples prepared by a conventional method were stored at 25 ° C. for 1 week, they were injected into a 100 mL graduated cylinder, and the volume after standing for 2 minutes was measured. The stability of the foam was determined according to the following criteria.

(Evaluation criteria)
A: Bubble volume is 90 mL or more. O: Bubble volume is 80 mL or more and less than 90 mL. Δ: Bubble volume is 70 mL or more and less than 80 mL. X: Bubble volume is less than 70 mL.

(3) Sensory test (massage, detergency, lack of tension, moist feeling)
Using the professional panel of 10 persons, the foamy aerosol compositions of Examples and Comparative Examples prepared by a conventional method were applied to the cheek site. After application, massage was performed for 3 minutes and rinsed off with warm water. Thereafter, it was left to dry for 10 minutes. Thereafter, the subject himself / herself performed sensory evaluation on the ease of massage, the cleaning effect, the non-stickiness of washing up, and the moist feeling in 5 stages from 1 to 5, and the average evaluation score was calculated. The evaluation criteria are as follows.

(Evaluation criteria)
◎: Average point is 4.0 or more O: Average point is 3.0 or more and less than 4.0 Δ: Average point is 2.0 or more and less than 3.0 ×: Average point is less than 2.0

Examples 1-26, Comparative Examples 1-10
The foamy aerosol compositions shown in Tables 1 to 3 were prepared and the above tests were performed. The result is combined with Tables 1-3, and is shown.

As is clear from Tables 1 to 3, the foam aerosol compositions of Examples 1 to 26 using the components of the present invention all had excellent performance. On the other hand, Comparative Examples 1 to 10 lacking any of the essential components are inferior in any aspect of foaming properties, foam stability, massage properties, detergency, non-stickiness and moist feeling. The goal could not be achieved.

Hereinafter, other formulation examples of the foamed aerosol composition of the present invention will be given as examples. In addition, as for the foamy aerosol compositions of these examples, each item was examined with respect to the foaming property, foam stability, massage properties, detergency, non-stickiness and moist feeling. Also had excellent properties and was good.

Example 27
(1) N-coconut oil fatty acid methyl taurine sodium 3.0
(2) Polyoxyethylene coconut oil fatty acid (2EO)
Disodium sulfosuccinate 3.0
(3) Polyoxyethylene coconut oil fatty acid glycerin (7EO) 5.0
(4) Carbon dioxide 1.0
(5) Isobutane (0.21 MPa / 20 ° C.) 5.0
(6) Dipropylene glycol 10.0
(7) 1,3-butylene glycol 15.0
(8) Palm oil fatty acid N-methylethanolamide 3.0
(9) Polyoxyethylene hydrogenated castor oil (60 EO) 0.3
(10) Monolauric acid polyoxyethylene sorbitan (20E.O.) 0.2
(11) Methylphenyl polysiloxane 0.5
(SH556, Toray Dow Corning)
(12) Xanthan gum 0.1
(13) Edetate disodium 0.02
(14) L-menthol 0.1
(15) Hamelis water 0.5
(16) Caffeine 0.2
(17) Dipotassium glycyrrhizinate 0.2
(18) Perfume 0.02
(19) Balance of purified water

Production method: After (12) is dispersed in (19), (1) to (3), (6) to (7), (13), and (15) to (17) are sequentially added and mixed uniformly. To do. Next, a base in which (8) to (11), (14) and (18) were uniformly mixed and dissolved was added and mixed uniformly to prepare an aerosol stock solution. A foam aerosol composition was prepared by filling an aluminum aerosol pressure can with the stock solution and (4) and (5).

Example 28
(1) N-lauroylmethyl taurine sodium 2.0
(2) Sodium tetradecene sulfonate 1.0
(3) Palm oil fatty acid methyl-sodium α-sulfonate 0.5
(4) Palm oil fatty acid ethyl ester sodium sulfonate 0.5
(5) Polyoxyethylene coconut oil fatty acid glycerin (7EO) 2.0
(6) Polyoxyethylene oleate glycerin (10E.O.) 2.0
(7) Carbon dioxide 1.0
(8) n-Pentane (0.15 MPa / 20 ° C.) 2.0
(9) Mixed hydrocarbon (0.25 MPa / 20 ° C.) 2.5
(10) Inositol 5.0
(11) Diglycerin 3.0
(12) Sorbitol 5.0
(13) Glucosyl trehalose 5.0
(14) Menthyl glyceryl ether 0.5
(15) Polyvinylpyrrolidone 1.0
(16) Sodium polyacrylate 0.1
(17) Xanthan gum 0.1
(18) Sodium hyaluronate 0.2
(19) Sodium chondroitin sulfate 0.5
(20) Hydrolyzed collagen solution 1.0
(21) Phenoxyethanol 0.2
(22) Fragrance 0.01
(23) Balance of purified water

Production method: After (15) to (19) are dispersed in (23), (1) to (6), (10) to (14), and (20) to (22) are sequentially added and mixed uniformly. Thus, an aerosol stock solution was prepared. A foam aerosol composition was prepared by filling an aluminum aerosol pressure can with the stock solution and (7) to (9).

Claims (4)

A foamy aerosol composition comprising the following components (A) to (D):
(A) Sulfonic acid type surfactant (B) Polyoxyethylene glycerin fatty acid ester which is liquid at 25 ° C (C) Carbon dioxide (D) Carbon number having a vapor pressure of 0.1 to 0.3 MPa at 25 ° C is 3 ~ 5 hydrocarbons 1 type in which sulfonic acid type surfactant is selected from alkylsulfosuccinate, polyoxyethylene alkylsulfosuccinate, α-olefin sulfonate, α-sulfo fatty acid methyl ester salt, acyl isethionate, and N-acyl methyl taurate Or the foamy aerosol composition of Claim 1 which is 2 or more types. Furthermore, component (E) polyhydric alcohol is contained, The foamy aerosol composition of Claim 1 or 2 characterized by the above-mentioned. The foamed aerosol composition according to any one of claims 1 to 3, wherein the mass ratio (C) :( D) of the components (C) and (D) is 1: 9 to 1: 4.