JP2015151342A - foaming aerosol products - Google Patents
foaming aerosol products Download PDFInfo
- Publication number
- JP2015151342A JP2015151342A JP2014024043A JP2014024043A JP2015151342A JP 2015151342 A JP2015151342 A JP 2015151342A JP 2014024043 A JP2014024043 A JP 2014024043A JP 2014024043 A JP2014024043 A JP 2014024043A JP 2015151342 A JP2015151342 A JP 2015151342A
- Authority
- JP
- Japan
- Prior art keywords
- container
- mass
- carbon dioxide
- liquefied gas
- stock solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000443 aerosol Substances 0.000 title claims abstract description 36
- 238000005187 foaming Methods 0.000 title abstract description 10
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 134
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 66
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 66
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims abstract description 60
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 15
- 239000011550 stock solution Substances 0.000 claims description 49
- 239000007791 liquid phase Substances 0.000 claims description 19
- 239000002453 shampoo Substances 0.000 claims description 6
- 239000000945 filler Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 42
- 239000006260 foam Substances 0.000 description 14
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 12
- -1 alkyl ether carboxylates Chemical class 0.000 description 10
- 239000003915 liquefied petroleum gas Substances 0.000 description 9
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 8
- 238000002156 mixing Methods 0.000 description 6
- 239000001294 propane Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 230000002688 persistence Effects 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 229940024606 amino acid Drugs 0.000 description 4
- 235000001014 amino acid Nutrition 0.000 description 4
- 239000002280 amphoteric surfactant Substances 0.000 description 4
- 229920006317 cationic polymer Polymers 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- RESQVPCTJIALIE-UHFFFAOYSA-N 2-methylprop-2-enoic acid;sulfuric acid Chemical compound OS(O)(=O)=O.CC(=C)C(O)=O RESQVPCTJIALIE-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000017531 blood circulation Effects 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229940088644 n,n-dimethylacrylamide Drugs 0.000 description 2
- YLGYACDQVQQZSW-UHFFFAOYSA-N n,n-dimethylprop-2-enamide Chemical compound CN(C)C(=O)C=C YLGYACDQVQQZSW-UHFFFAOYSA-N 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 210000004761 scalp Anatomy 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- BQBYBPAPSIWHCE-UHFFFAOYSA-N 5-(dimethylamino)-2-methylpent-2-enoic acid Chemical compound CN(C)CCC=C(C)C(O)=O BQBYBPAPSIWHCE-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Natural products NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N N-methylaminoacetic acid Natural products C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 108010077895 Sarcosine Proteins 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229940009098 aspartate Drugs 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- DENRZWYUOJLTMF-UHFFFAOYSA-N diethyl sulfate Chemical compound CCOS(=O)(=O)OCC DENRZWYUOJLTMF-UHFFFAOYSA-N 0.000 description 1
- 229940008406 diethyl sulfate Drugs 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 239000008266 hair spray Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 229940049256 laureth-4 carboxylic acid Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229940097941 polyglyceryl-10 laurate Drugs 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229940043230 sarcosine Drugs 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229940104261 taurate Drugs 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- 239000005028 tinplate Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/30—Materials not provided for elsewhere for aerosols
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Description
本発明は、発泡性エアゾール製品に関する。 The present invention relates to foamable aerosol products.
ヘアスプレー、洗顔フォーム、整髪料等の化粧料にあっては、使い勝手の良さから原液を噴射剤と共に容器に充填し、容器からの噴射後に形成した泡を塗布する発泡性エアゾール製品が普及している。近年、二酸化炭素(炭酸ガス)による皮膚の血行促進効果が注目されており、上述のような発泡性エアゾール製品における噴射剤の一成分として二酸化炭素を容器に充填し、この容器からの噴射により発泡形成した泡を皮膚に作用させる技術が知られている(特開2013−213062号公報、特開2009−269914号公報、特開2010−248098号公報参照)。 For cosmetics such as hair sprays, facial cleansing foams, and hair styling products, foamable aerosol products that fill the container with the stock solution together with the propellant and apply foam formed after spraying from the container have become popular. Yes. In recent years, the effect of carbon dioxide (carbon dioxide gas) on promoting blood circulation in the skin has attracted attention, and carbon dioxide is filled in a container as a propellant in the foamable aerosol product as described above, and foaming is achieved by jetting from this container. Techniques for causing the formed foam to act on the skin are known (see JP 2013-213062 A, JP 2009-269914 A, and JP 2010-248098 A).
ところで、発泡性エアゾール製品のゲージ圧力(容器の内圧と大気圧との圧力差)は、安全性などの観点から、一般的に上限が設定される。
その圧力上限を一定にする場合、二酸化炭素に基づく皮膚への作用を高めたいとき、容器に充填する二酸化炭素の増量が望まれる。この増量は、二酸化炭素のみを充填ガスとすれば、達成されやすい。しかし、二酸化炭素のみであると発泡性が不十分となるため、充填するガスとして液化ガスを併用する必要がある。この併用の一方で、二酸化炭素の充填量の減少が予想される。
By the way, the gauge pressure of the foamable aerosol product (pressure difference between the internal pressure of the container and the atmospheric pressure) is generally set to an upper limit from the viewpoint of safety and the like.
When the pressure upper limit is made constant, when the action on the skin based on carbon dioxide is desired to be increased, it is desired to increase the amount of carbon dioxide filled in the container. This increase is easily achieved if only carbon dioxide is used as the filling gas. However, if only carbon dioxide is used, the foaming property becomes insufficient, so it is necessary to use a liquefied gas in combination as the gas to be filled. On the other hand, a decrease in the filling amount of carbon dioxide is expected.
本発明は、上記事情に鑑み、安全性などの観点からゲージ圧力の上限を設けた上で、液化ガスと二酸化炭素を充填ガスとして併用する際に、容器内の二酸化炭素濃度を一定以上とした発泡性エアゾール製品の提供を目的とする。 In view of the above circumstances, the present invention sets the upper limit of the gauge pressure from the viewpoint of safety and the like, and when using liquefied gas and carbon dioxide as a filling gas, the carbon dioxide concentration in the container is set to a certain level or more. The purpose is to provide foamable aerosol products.
本発明者が、二酸化炭素及び液化ガスの併用とゲージ圧力0.80MPa以下の条件において鋭意検討を行った結果、原液に対する液化ガス及びイソペンタンの質量比率を高めれば上記二酸化炭素濃度が高まる傾向があり、容器内に充填された二酸化炭素濃度を1.20質量%以上にできることを見出し、本発明を完成するに至った。 As a result of intensive studies by the inventor on the combined use of carbon dioxide and liquefied gas and a gauge pressure of 0.80 MPa or less, the concentration of carbon dioxide tends to increase if the mass ratio of liquefied gas and isopentane to the stock solution is increased. The inventors have found that the concentration of carbon dioxide charged in the container can be 1.20% by mass or more, and have completed the present invention.
すなわち、本発明に係る発泡性エアゾール製品は、下記[A]、[B]及び[C]が容器に充填された発泡性エアゾール製品であって、前記容器の25℃におけるゲージ圧力が0.80MPa以下、前記[A]に対する前記[B]の質量比[B]/[A]が3.0/97.0以上、前記容器内に充填された前記[C]の濃度が1.20質量%以上であることを特徴とする。
[A]アニオン界面活性剤を含む原液
[B]液化ガス、又は、液化ガス及びイソペンタン
[C]二酸化炭素
That is, the foamable aerosol product according to the present invention is a foamable aerosol product in which the following [A], [B] and [C] are filled in a container, and the gauge pressure of the container at 25 ° C. is 0.80 MPa. Hereinafter, the mass ratio [B] / [A] of the [B] to the [A] is 3.0 / 97.0 or more, and the concentration of the [C] filled in the container is 1.20% by mass. It is the above.
[A] Stock solution containing an anionic surfactant [B] Liquefied gas, or liquefied gas and isopentane [C] Carbon dioxide
本発明に係る発泡性エアゾール製品は、例えば、シャンプーとして使用される。水が媒体である[A]原液を構成とする泡の毛髪上での持続性は、酸化染毛処理などで受けた損傷を原因とする毛髪の親水性の高まりに伴って低下するが、本発明に係る発泡性エアゾール製品では上記の通り質量比[B]/[A]が3.0/97.0以上なので、その持続性の低下が抑えられる。 The foamable aerosol product according to the present invention is used, for example, as a shampoo. The persistence on the hair of the foam comprising the [A] stock solution in which water is the medium decreases as the hydrophilicity of the hair increases due to damage caused by oxidative hair dyeing treatment, etc. In the foamable aerosol product according to the invention, since the mass ratio [B] / [A] is 3.0 / 97.0 or more as described above, a decrease in the sustainability is suppressed.
本発明に係る発泡性エアゾール製品の25℃における前記ゲージ圧力は、例えば0.45MPa以上である。 The said gauge pressure in 25 degreeC of the foamable aerosol product which concerns on this invention is 0.45 Mpa or more, for example.
本発明に係る発泡性エアゾール製品の前記質量比[B]/[A]は、例えば30.0/70.0以下である。 The mass ratio [B] / [A] of the foamable aerosol product according to the present invention is, for example, 30.0 / 70.0 or less.
本発明に係る発泡性エアゾール製品の20℃での前記[B]における液化ガスの圧力は、0.10MPa以上0.45MPa以下が良い。0.10MPa以上であると、発泡性に好ましく、0.45MPa以下であると、形成した泡の持続性に好ましい。 The pressure of the liquefied gas in [B] at 20 ° C. of the foamable aerosol product according to the present invention is preferably 0.10 MPa or more and 0.45 MPa or less. When it is 0.10 MPa or more, it is preferable for foaming properties, and when it is 0.45 MPa or less, it is preferable for sustainability of the formed bubbles.
本発明に係る発泡性エアゾール製品の前記容器内における前記[C]の濃度は、例えば0.45質量%以上3.00質量%以下である。 The concentration of [C] in the container of the foamable aerosol product according to the present invention is, for example, 0.45 mass% or more and 3.00 mass% or less.
本発明によれば、原液に対する液化ガス及びイソペンタンの質量比を高めることで、容器内の二酸化炭素濃度も高くできるので、二酸化炭素及び液化ガスの併用とゲージ圧力0.80MPa以下とを条件としても、二酸化炭素濃度を1.20質量%以上にできる。 According to the present invention, since the concentration of carbon dioxide in the container can be increased by increasing the mass ratio of the liquefied gas and isopentane to the stock solution, the combined use of carbon dioxide and liquefied gas and the gauge pressure of 0.80 MPa or less are also required. The carbon dioxide concentration can be made 1.20% by mass or more.
本実施形態の発泡性エアゾール製品に基づき、本発明を以下に説明する。本実施形態の発泡性エアゾール製品は、毛髪を洗浄するためのシャンプー用途に適するものであり、[A]原液、[B]液化ガス、又は、液化ガス及びイソペンタン、並びに、[C]二酸化炭素が容器に充填され、ゲージ圧力を所定値以下に設定したものである。 The present invention will be described below based on the foamable aerosol product of the present embodiment. The foamable aerosol product of this embodiment is suitable for shampoo use for washing hair, and [A] undiluted solution, [B] liquefied gas, or liquefied gas and isopentane, and [C] carbon dioxide The container is filled and the gauge pressure is set to a predetermined value or less.
([A]原液)
[A]原液は、アニオン界面活性剤が水に配合されたものである([A]原液における水の配合量は、例えば70質量%以上である。)。また、[A]原液には、本発明の効果を損なわない範囲で、シャンプー原料として公知のものを任意に配合しても良い。
([A] undiluted solution)
[A] The stock solution is a mixture of an anionic surfactant and water (the amount of water in the [A] stock solution is, for example, 70% by mass or more). Moreover, you may mix | blend what is well-known as a shampoo raw material with [A] stock solution in the range which does not impair the effect of this invention.
アニオン界面活性剤は、頭皮等の汚れを除去する成分であり、発泡性にも寄与する。一種又は二種以上のアニオン界面活性剤を、[A]原液に配合する。 An anionic surfactant is a component that removes dirt such as the scalp and contributes to foaming properties. One or more types of anionic surfactants are blended in the [A] stock solution.
上記アニオン界面活性剤としては、例えば、N−アシルアミノ酸塩、アルキルエーテルカルボン酸塩などのカルボン酸系アニオン界面活性剤;N−アシルメチルタウリン塩などのスルホン酸系アニオン界面活性剤;アルキル硫酸塩、ポリオキシエチレンアルキルエーテル硫酸塩などの硫酸系アニオン界面活性剤;ポリオキシエチレンスルホコハク酸アルキルなどのスルホサクシネート系アニオン界面活性剤;が挙げられる(アニオン界面活性剤の塩の形態としては、ナトリウム塩、カリウム塩、トリエタノール塩、モノエタノール塩などが挙げられる。)。N−アシルアミノ酸塩は、頭皮への刺激が低いアニオン界面活性剤といわれている。このN−アシルアミノ酸塩としては、例えば、N−アシルグルタミン酸塩、N−アシルアラニン塩、N−アシルサルコシン酸塩、N−アシルグリシン塩、N−アシルアスパラギン酸塩が挙げられる。 Examples of the anionic surfactant include carboxylic acid anionic surfactants such as N-acyl amino acid salts and alkyl ether carboxylates; sulfonic acid anionic surfactants such as N-acylmethyl taurate; alkyl sulfates , Sulfate anionic surfactants such as polyoxyethylene alkyl ether sulfates; sulfosuccinate anionic surfactants such as polyoxyethylene sulfosuccinic acid alkyls, etc. Salt, potassium salt, triethanol salt, monoethanol salt, etc.). N-acyl amino acid salts are said to be anionic surfactants with low irritation to the scalp. Examples of the N-acyl amino acid salt include N-acyl glutamate, N-acyl alanine, N-acyl sarcosine, N-acyl glycine, and N-acyl aspartate.
[A]原液におけるアニオン界面活性剤の配合量は、汚れ除去及び発泡性を効果的とする観点から、3質量%以上30質量%以下が好ましく、5質量%以上25質量%以下がより好ましく、10質量%以上20質量%以下がさらに好ましい。 [A] The amount of the anionic surfactant in the stock solution is preferably 3% by mass or more and 30% by mass or less, more preferably 5% by mass or more and 25% by mass or less from the viewpoint of effective soil removal and foaming properties. 10 mass% or more and 20 mass% or less are more preferable.
[A]原液には、上記の通り、公知のシャンプー原料が任意に配合される。この任意原料としては、例えば、両性界面活性剤、ノニオン界面活性剤、カチオン性高分子、低級アルコール、多価アルコール、糖類、アミノ酸、動植物抽出物、無機化合物、香料、防腐剤が挙げられる。 [A] A known shampoo raw material is arbitrarily blended in the stock solution as described above. Examples of the optional raw material include amphoteric surfactants, nonionic surfactants, cationic polymers, lower alcohols, polyhydric alcohols, saccharides, amino acids, animal and plant extracts, inorganic compounds, fragrances, and preservatives.
ポリグリセリン脂肪酸エステルなどのノニオン界面活性剤の配合は、発泡性や泡の持続性に好適である。[A]原液におけるノニオン界面活性剤の配合量は、例えば0.1質量%以上である。この配合量の上限は、発泡性に影響する[A]原液の粘度を低くするために、5質量%が良く、4質量%が好ましく、3質量%がより好ましく、1質量%が更に好ましい。 Mixing nonionic surfactants such as polyglycerin fatty acid esters is suitable for foaming properties and foam persistence. [A] The blending amount of the nonionic surfactant in the stock solution is, for example, 0.1% by mass or more. The upper limit of the blending amount is preferably 5% by mass, preferably 4% by mass, more preferably 3% by mass, and still more preferably 1% by mass in order to lower the viscosity of the stock solution [A] that affects foamability.
酢酸ベタイン型両性界面活性剤などの両性界面活性剤の配合は、発泡性や泡の持続性に好適である。[A]原液における配合量は、両性界面活性剤が例えば0.1質量%以上である。この配合量の上限は、発泡性に影響する[A]原液の粘度を低くするために、8質量%が良く、6質量%が好ましく、4質量%がより好ましく、2質量%が更に好ましい。 Formulation of amphoteric surfactants such as betaine acetate type amphoteric surfactants is suitable for foamability and foam sustainability. [A] The compounding amount in the stock solution is 0.1% by mass or more for the amphoteric surfactant, for example. The upper limit of the blending amount is preferably 8% by mass, preferably 6% by mass, more preferably 4% by mass, and still more preferably 2% by mass in order to lower the viscosity of the stock solution [A] that affects foamability.
また、カチオン性高分子の配合は、[A]原液を髪から洗い流すときの指通り性を向上させる。このカチオン性高分子としては、カチオン化セルロース、カチオン化グアーガム、ビニルピロリドン・N,N−ジメチルアミノエチルメタクリル酸共重合体ジエチル硫酸塩、アクリルアミド・アクリル酸・塩化ジメチルジアリルアンモニウム共重合体、N,N−ジメチルアミノエチルメタクリル酸ジエチル硫酸塩・N,N−ジメチルアクリルアミド・ジメタクリル酸ポリエチレングリコール共重合体などが挙げられる。[A]原液におけるカチオン性高分子の配合量は、例えば0.1質量%以上1質量%以下である。 In addition, the addition of the cationic polymer improves the fingering property when the [A] stock solution is washed away from the hair. Examples of the cationic polymer include cationized cellulose, cationized guar gum, vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate, acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer, N, N-dimethylaminoethyl diethyl methacrylate sulfate / N, N-dimethylacrylamide / polyethylene glycol dimethacrylate copolymer and the like. [A] The blending amount of the cationic polymer in the stock solution is, for example, 0.1% by mass or more and 1% by mass or less.
[A]原液の剤型は、液状であると良い。液状である[A]原液の粘度は、B型粘度計を使用して測定(温度:25℃、ロータ:粘度に応じて適宜設定、ロータの回転速度:粘度に応じて適宜設定)した場合、粘度計測開始から60秒後の値が10mPa・s以上1,000mPa・s以下が好ましく、20mPa・s以上500mPa・s以下がより好ましく、30mPa・s以上400mPa・s以下がさらに好ましい。 [A] The dosage form of the stock solution may be liquid. When the viscosity of the liquid [A] stock solution is measured using a B-type viscometer (temperature: 25 ° C., rotor: appropriately set according to the viscosity, rotor rotational speed: appropriately set according to the viscosity) The value 60 seconds after the start of viscosity measurement is preferably 10 mPa · s or more and 1,000 mPa · s or less, more preferably 20 mPa · s or more and 500 mPa · s or less, and further preferably 30 mPa · s or more and 400 mPa · s or less.
[A]原液のpHは、中性乃至弱酸性であるとよい。pHを弱酸性に保つことで、二酸化炭素が炭酸塩になるのを抑制して血行促進効果を高めることができると共に、pH低下に伴う[A]原液の粘度上昇による発泡性及び吐出性の悪化が抑えられる。[A]原液のpHとしては、4.0以上7.5以下が良く、5.0以上7.0以下が好ましく、5.0以上6.8以下がより好ましく、5.0以上6.5以下が更に好ましい。 [A] The pH of the stock solution may be neutral to weakly acidic. By keeping the pH weakly acidic, the effect of promoting blood circulation can be enhanced by suppressing carbon dioxide from becoming carbonate, and [A] deterioration of foamability and dischargeability due to an increase in viscosity of the stock solution accompanying a decrease in pH. Is suppressed. [A] The pH of the stock solution is preferably from 4.0 to 7.5, preferably from 5.0 to 7.0, more preferably from 5.0 to 6.8, and from 5.0 to 6.5. The following is more preferable.
本実施形態の発泡性エアゾール製品において、容器内での[A]原液の充填量は、適宜設定される。その充填量は、例えば、容器の容積100mlあたり、40g以上65g以下が良く、45g以上60g以下が好ましい。40g以上にすることで、製品の使用期間が長くなり、65g以下にすることで、容器に充填する[C]二酸化炭素の増量に好ましい。 In the foamable aerosol product of the present embodiment, the filling amount of the stock solution [A] in the container is appropriately set. The filling amount is, for example, preferably 40 g or more and 65 g or less, and preferably 45 g or more and 60 g or less per 100 ml volume of the container. By making it 40 g or more, the use period of the product becomes longer, and by making it 65 g or less, it is preferable for increasing the amount of [C] carbon dioxide filled in the container.
([B]液化ガス、又は、液化ガス及びイソペンタン)
本実施形態の発泡性エアゾール製品における容器には、[B]液化ガス、又は、液化ガス及びイソペンタンが充填される。充填された液化ガス、イソペンタンは、共に、[C]二酸化炭素の充填によって、気液平衡状態となる。また、液化ガス、イソペンタンは、共に、容器から噴出された[A]原液を発泡させるものであり、イソペンタンの充填は、泡の持続性に適する。
([B] Liquefied gas or liquefied gas and isopentane)
The container in the foamable aerosol product of this embodiment is filled with [B] liquefied gas, or liquefied gas and isopentane. Both the filled liquefied gas and isopentane are in a vapor-liquid equilibrium state by filling with [C] carbon dioxide. The liquefied gas and isopentane both foam the [A] stock solution ejected from the container, and filling with isopentane is suitable for the sustainability of the foam.
上記液化ガスの圧力は、適宜設定すべきであるが、20℃において0.10MPa以上0.45MPa以下が良く、0.15MPa以上0.35MPa以下が好ましく、0.15MPa以上0.30MPa以下がより好ましく、0.15MPa以上0.25MPa以下がさらに好ましい。その圧力を0.15MPa以上にすることで、発泡性が良好となり、0.45MPa以下にすることで、形成した泡の持続性が良好となると共に、容器に充填できる二酸化炭素を増量できる。 The pressure of the liquefied gas should be set as appropriate, but it is preferably 0.10 MPa or more and 0.45 MPa or less at 20 ° C., preferably 0.15 MPa or more and 0.35 MPa or less, and more preferably 0.15 MPa or more and 0.30 MPa or less. Preferably, it is 0.15 MPa or more and 0.25 MPa or less. By setting the pressure to 0.15 MPa or more, the foamability is improved, and by setting the pressure to 0.45 MPa or less, the sustainability of the formed foam is improved and the amount of carbon dioxide that can be filled in the container can be increased.
本実施形態における液化ガスは、液化石油ガス(LPG)であり、プロパンとn−ブタン、プロパンとi−ブタン、又は、プロパンとn−ブタンとi−ブタンであると良い。また、液化ガス及びイソペンタンを容器に充填する場合には、プロパンとn−ブタンとイソペンタン、プロパンとi−ブタンとイソペンタン、又は、プロパンとn−ブタンとi−ブタンとイソペンタンであると良い。 The liquefied gas in this embodiment is liquefied petroleum gas (LPG), and may be propane and n-butane, propane and i-butane, or propane, n-butane and i-butane. Further, when the container is filled with liquefied gas and isopentane, propane and n-butane and isopentane, propane and i-butane and isopentane, or propane, n-butane, i-butane and isopentane are preferable.
容器に充填するときの[A]([A]原液)に対する[B]([B]液化ガス、又は、液化ガス及びイソペンタン)の質量比[B]/[A]は、3.0/97.0以上であり、5.0/95.0以上が良く、10.0/90.0以上が好ましく、15.0/85.0以上がより好ましい。また、その質量比[B]/[A]は、30.0/70.0以下が良く、25.0/75.0以下が好ましい。質量比[B]/[A]が3.0/97.0以上であると、容器内に充填する[C]二酸化炭素を増量でき、質量比[B]/[A]が30.0/70.0以下であると、形成した泡におけるアニオン界面活性剤を増量できる。なお、上記質量比[B]/[A]において、[B]が液化ガスの場合には、液化ガスの量で算出される質量比であり、[B]が液化ガス及びイソペンタンの場合には、液化ガス及びイソペンタンの総量で算出される質量比である。 The mass ratio [B] / [A] of [B] ([B] liquefied gas or liquefied gas and isopentane) to [A] ([A] stock solution) when filling the container is 3.0 / 97. 0.0 or more, preferably 5.0 / 95.0 or more, preferably 10.0 / 90.0 or more, and more preferably 15.0 / 85.0 or more. Further, the mass ratio [B] / [A] is preferably 30.0 / 70.0 or less, and preferably 25.0 / 75.0 or less. When the mass ratio [B] / [A] is 3.0 / 97.0 or more, the amount of [C] carbon dioxide charged in the container can be increased, and the mass ratio [B] / [A] is 30.0 / If it is 70.0 or less, the amount of anionic surfactant in the formed foam can be increased. In the above mass ratio [B] / [A], when [B] is a liquefied gas, the mass ratio is calculated by the amount of liquefied gas, and when [B] is a liquefied gas and isopentane. , Mass ratio calculated by the total amount of liquefied gas and isopentane.
また、液化ガスと共にイソペンタンを充填する場合には、液化ガスの量がイソペンタンよりも多いと良い。これにより、発泡性が良好となる。 Moreover, when filling isopentane with liquefied gas, the quantity of liquefied gas is good to be larger than isopentane. Thereby, foamability becomes favorable.
([C]二酸化炭素)
本実施形態の発泡性エアゾール製品において、容器内に充填された[C]二酸化炭素の濃度は、1.20質量%以上であり、1.30質量%以上が良く、1.40質量%以上が好ましく、1.50質量%以上がより好ましく、1.60質量%以上が更に好ましく、1.70質量%以上がより更に好ましい。一方で、容器内に充填された[C]二酸化炭素の濃度上限は、例えば3.00質量%であり、上記の質量比[B]/[A]と容器のゲージ圧力を共に高めることで設定できる濃度である。ここで、容器内に充填された[C]二酸化炭素の濃度は、「(容器に充填された[C]二酸化炭素)/(容器に充填された[A]原液、[B]液化ガス、イソペンタン、及び[C]二酸化炭素)×100」により算出される。
([C] carbon dioxide)
In the foamable aerosol product of the present embodiment, the concentration of [C] carbon dioxide filled in the container is 1.20% by mass or more, preferably 1.30% by mass or more, and 1.40% by mass or more. Preferably, 1.50 mass% or more is more preferable, 1.60 mass% or more is further preferable, and 1.70 mass% or more is further more preferable. On the other hand, the upper limit of the concentration of [C] carbon dioxide filled in the container is, for example, 3.00% by mass, and is set by increasing both the mass ratio [B] / [A] and the gauge pressure of the container. This is a possible concentration. Here, the concentration of [C] carbon dioxide charged in the container is “([C] carbon dioxide charged in the container) / ([A] stock solution, [B] liquefied gas, isopentane charged in the container). , And [C] carbon dioxide) × 100 ”.
容器内に充填された[C]二酸化炭素の一部は、充填された[A]原液、[B]液化ガス、イソペンタンを構成とする液相部に含まれる。このときに液相部に含まれた[C]二酸化炭素の濃度は、0.45質量%以上が良く、0.60質量%以上が好ましく、0.75質量%以上がより好ましく、0.90質量%以上が更に好ましく、1.00質量%以上がより更に好ましい。一方で、液相部に含まれた[C]二酸化炭素の濃度上限は、容器のゲージ圧力を高めることで設定できる濃度であり、例えば2.50質量%である。 A part of [C] carbon dioxide filled in the container is contained in a liquid phase part composed of the filled [A] stock solution, [B] liquefied gas, and isopentane. At this time, the concentration of [C] carbon dioxide contained in the liquid phase part is preferably 0.45% by mass or more, preferably 0.60% by mass or more, more preferably 0.75% by mass or more, and 0.90. % By mass or more is more preferable, and 1.00% by mass or more is more preferable. On the other hand, the upper limit of the concentration of [C] carbon dioxide contained in the liquid phase part is a concentration that can be set by increasing the gauge pressure of the container, for example, 2.50% by mass.
上記の液相部に含まれた[C]二酸化炭素の濃度は、以下の通り、気体の状態方程式等から算出される値を採用する。
PV=w/M・RT
液相部に含まれた[C]の濃度=([C]の充填量−w)/([A]及び[B]の充填量+[C]の充填量−w)×100
w(g):容器内の気相部の炭酸ガス量
P(atm):25℃での容器のゲージ圧力(MPa)×9.87+1atm
V(L):容器内気相部の体積算出値(容器の容量−充填質量/比重)
M:44(二酸化炭素の分子量)
R(atm・L/K・mol):0.082
T(K):273+25℃
[A](g):原液
[B](g):液化ガス及びイソペンタン
[C](g):二酸化炭素
As the concentration of [C] carbon dioxide contained in the liquid phase part, a value calculated from a gas state equation or the like is adopted as follows.
PV = w / M · RT
Concentration of [C] contained in the liquid phase portion = (filling amount of [C] −w) / (filling amount of [A] and [B] + filling amount of [C] −w) × 100
w (g): Carbon dioxide gas amount in the gas phase in the container P (atm): Gauge pressure (MPa) of the container at 25 ° C. × 9.87 + 1 atm
V (L): Calculated volume of the gas phase part in the container (capacity of the container−filling mass / specific gravity)
M: 44 (molecular weight of carbon dioxide)
R (atm · L / K · mol): 0.082
T (K): 273 + 25 ° C
[A] (g): Stock solution [B] (g): Liquefied gas and isopentane [C] (g): Carbon dioxide
[C]二酸化炭素の一部が液相部に含まれるのは上記の通りであり、この液相部に含まれる[C]二酸化炭素の全部が[A]原液に含まれているとした場合、[A]原液に含まれた[C]二酸化炭素の濃度は、「([C]の充填量−w)/([A]の充填量+[C]の充填量−w)×100」により算出される。[A]原液に含まれた[C]二酸化炭素の濃度は、0.50質量%以上が良く、0.70質量%以上が好ましく、0.85質量%以上がより好ましく、1.00質量%以上が更に好ましく、1.10質量%以上がより更に好ましい。一方で、[A]原液に含まれた[C]二酸化炭素の濃度上限は、例えば2.80質量%である。 [C] The case where a part of carbon dioxide is contained in the liquid phase part is as described above, and [C] all the carbon dioxide contained in the liquid phase part is assumed to be contained in the [A] stock solution. The concentration of [C] carbon dioxide contained in the stock solution [A] is “([C] filling amount−w) / ([A] filling amount + [C] filling amount−w) × 100”. Is calculated by [A] The concentration of [C] carbon dioxide contained in the stock solution is preferably 0.50% by mass or more, preferably 0.70% by mass or more, more preferably 0.85% by mass or more, and 1.00% by mass. The above is more preferable, and 1.10% by mass or more is even more preferable. On the other hand, the upper limit of the concentration of [C] carbon dioxide contained in the [A] stock solution is, for example, 2.80% by mass.
(容器)
本実施形態の発泡性エアゾール製品における容器は、公知の耐圧性容器であると良く、その材質は、例えばアルミニウム、アルミニウム合金、ブリキ、鋼などの金属製のものである。この容器は、内面に樹脂層が積層されているもの、内部に内袋を有するものであってもよい。
(container)
The container in the foamable aerosol product of the present embodiment may be a known pressure-resistant container, and the material thereof is made of metal such as aluminum, aluminum alloy, tinplate, and steel. This container may have a resin layer laminated on the inner surface or an inner bag inside.
(ゲージ圧力)
本実施形態の発泡性エアゾール製品における容器のゲージ圧力は、安全性の観点から、25℃の温度条件で0.80MPa以下であり、0.65MPa以下が良い。一方、25℃でのゲージ圧力の下限は、容器内への[C]二酸化炭素の充填量を増加させるためには、0.45MPaが良く、0.50MPaが好ましく、0.55MPaがより好ましく、0.60MPaが更に好ましい。
(Gauge pressure)
The gauge pressure of the container in the foamable aerosol product of the present embodiment is 0.80 MPa or less and preferably 0.65 MPa or less at a temperature condition of 25 ° C. from the viewpoint of safety. On the other hand, the lower limit of the gauge pressure at 25 ° C. is preferably 0.45 MPa, preferably 0.50 MPa, more preferably 0.55 MPa in order to increase the filling amount of [C] carbon dioxide into the container. 0.60 MPa is more preferable.
(用途)
本実施形態の発泡性エアゾール製品は、[A]原液にアニオン界面活性剤が配合されているから、毛髪などを洗浄するためのシャンプーとして使用できるものである。洗浄対象となる毛髪が損傷に伴って親水性が高まったものであったとしても、上記質量比[B]/[A]を3.0/97.0以上にすることで、泡の持続性が向上する。これは、質量比[B]/[A]を高めた泡においては、親水性である[A]原液の濃度が低くなっているから、泡の毛髪への吸収性が抑えられるからと考えられる。
(Use)
The foamable aerosol product of this embodiment can be used as a shampoo for washing hair and the like because [A] an anionic surfactant is blended in the stock solution. Even if the hair to be cleaned has increased hydrophilicity due to damage, by maintaining the mass ratio [B] / [A] to 3.0 / 97.0 or more, the persistence of the foam Will improve. This is thought to be because, in the foam with an increased mass ratio [B] / [A], the concentration of the hydrophilic [A] stock solution is low, so that the absorbability of the foam into the hair is suppressed. .
以下、本発明を実施例に基づいて具体的に説明するが、本発明は、これらの実施例に限定されるものではない。 EXAMPLES Hereinafter, although this invention is demonstrated concretely based on an Example, this invention is not limited to these Examples.
実施例、比較例及び参考例の発泡性エアゾール製品を製造した。その詳細は、以下の通りである。
([A]原液)
水と他の原料を配合し、クエン酸でpH5.60に調整したものを、実施例、比較例及び参考例で使用した[A]原液とした。その原料と配合濃度は、次の通りとした。ポリオキシエチレンラウリルエーテル酢酸ナトリウム(表示名称:ラウレス−4カルボン酸Na)9質量%、ポリオキシエチレンスルホコハク酸ラウリル二ナトリウム7質量%、モノラウリン酸ポリグリセリル(表示名称:ラウリン酸ポリグリセリル−10)0.5質量%、ポリオキシプロピレン(1)ヤシ油脂肪酸モノイソプロパノールアミド(表示名称:PPG−2コカミド)3質量%、N,N−ジメチルアミノエチルメタクリル酸ジエチル硫酸塩・N,N−ジメチルアクリルアミド・ジメタクリル酸ポリエチレングリコール共重合体(表示名称:ポリクオタニウム−52)0.2質量%、ポリエチレングリコール1540(表示名称:PEG−32)0.4質量%、カチオン化セルロース(表示名称:ポリクオタニウム−10)0.2質量%、l−メントール0.6質量%、PCAメンチル0.1質量%、エタノール0.1質量%、1,3−ブチレングリコール0.2質量%、香料0.5質量%
The foamable aerosol products of Examples, Comparative Examples and Reference Examples were produced. The details are as follows.
([A] Stock solution)
A mixture of water and other raw materials, and adjusted to pH 5.60 with citric acid was used as [A] stock solution used in Examples, Comparative Examples and Reference Examples. The raw materials and blending concentrations were as follows. Sodium polyoxyethylene lauryl ether acetate (display name: laureth-4 carboxylic acid Na) 9% by mass, disodium polyoxyethylene sulfosuccinate 7% by mass, polyglyceryl monolaurate (display name: polyglyceryl-10 laurate) 0.5 % By mass, polyoxypropylene (1) coconut oil fatty acid monoisopropanolamide (designated name: PPG-2 cocamide) 3% by mass, N, N-dimethylaminoethyl diethyl methacrylate sulfate, N, N-dimethylacrylamide, dimethacryl Acid polyethylene glycol copolymer (display name: polyquaternium-52) 0.2 mass%, polyethylene glycol 1540 (display name: PEG-32) 0.4 mass%, cationized cellulose (display name: polyquaternium-10) 2 The amount% l-menthol 0.6% by weight, PCA menthyl 0.1 wt%, ethanol 0.1 weight%, 1,3-butylene glycol 0.2 wt%, perfume 0.5%
(発泡性エアゾール製品)
容器に、[A]原液、[B]液化ガスであるLPG、イソペンタンを充填し、最後に[C]二酸化炭素を充填することで、実施例、比較例及び参考例の発泡性エアゾール製品を製造した。下記表1には、容器に充填した[A]、[B]、[C]の充填量等の製品の詳細を示す。
(Foaming aerosol products)
The container is filled with [A] stock solution, [B] liquefied gas LPG and isopentane, and finally [C] carbon dioxide is filled to produce foamable aerosol products of Examples, Comparative Examples and Reference Examples. did. Table 1 below shows details of products such as the filling amounts of [A], [B], and [C] filled in the container.
なお、表1において、「[A]原液の体積(ml)」は、「[A]原液(g)」/「[A]原液の比重」により算出される値であり、「[B]LPG及びイソペンタンの総体積(ml)」は、「[B]LPG及びイソペンタンの総量(g)」/「[B]LPG及びイソペンタンの混合比重」により算出される値であり、「液相部の体積(ml)」は、「[A]原液の体積(ml)」+「[B]LPG及びイソペンタンの総体積(ml)」により算出される値であり、「気相部の体積(ml)」は、「容器の容量(ml)」−「液相部の体積(ml)」により算出される値である。 In Table 1, “[A] Stock solution volume (ml)” is a value calculated by “[A] Stock solution (g)” / “[A] Stock solution specific gravity”, and “[B] LPG And “total volume (ml) of isopentane” is a value calculated by “total amount of [B] LPG and isopentane (g)” / “mixed specific gravity of [B] LPG and isopentane”, and “volume of liquid phase part” “(Ml)” is a value calculated by “[A] volume of stock solution (ml)” + “total volume of [B] LPG and isopentane (ml)”, and “volume of gas phase part (ml)”. Is a value calculated by “volume of container (ml)” − “volume of liquid phase part (ml)”.
下記表2〜5には、実施例、比較例、参考例の質量比[B]/[A]等を示す。これら表中において、「容器内に充填された[C]二酸化炭素濃度(%)」は、表1における値により算出される値であって、「[C]炭酸ガス(g)」/「[A]原液、[B]LPG、イソペンタン及び[C]二酸化炭素の総量(g)」×100により算出される。「容器内気相部における[C]二酸化炭素質量(g)」は、上記の状態方程式に基づいて算出される「w」である。「容器内液相部に含まれた[C]二酸化炭素質量(g)」は、表1の「[C]二酸化炭素」−「w」により算出される。「[A]原液に含まれた[C]二酸化炭素濃度(%)」は、液相部に含まれる[C]二酸化炭素が全て[A]原液に含まれるとしたものであって、「容器内液相部に含まれた[C]二酸化炭素質量(g)」/「『[A]原液(g)』+『容器内液相部に含まれた[C]二酸化炭素質量(g)』」×100により算出される。「容器内液相部に含まれた[C]二酸化炭素濃度(%)」は、「容器内液相部に含まれた[C]二酸化炭素質量(g)」/「『[A]原液、[B]LPG及びイソペンタンの総量(g)』+『容器内液相部に含まれた[C]二酸化炭素質量(g)』」×100により算出される。 Tables 2 to 5 below show mass ratios [B] / [A] and the like of Examples, Comparative Examples, and Reference Examples. In these tables, “[C] carbon dioxide concentration (%) charged in the container” is a value calculated from the values in Table 1, and “[C] carbon dioxide (g)” / “[[ A] Stock solution, [B] LPG, isopentane and [C] total amount of carbon dioxide (g) ”× 100. The “[C] carbon dioxide mass (g) in the gas phase portion in the container” is “w” calculated based on the above equation of state. The “[C] carbon dioxide mass (g) contained in the liquid phase part in the container” is calculated by “[C] carbon dioxide” − “w” in Table 1. “[A] Concentration of carbon dioxide contained in [A] stock solution (%)” means that all of [C] carbon dioxide contained in the liquid phase part is contained in [A] stock solution. [C] Carbon dioxide mass (g) contained in the inner liquid phase portion] / “[A] Stock solution (g)” + “[C] Carbon dioxide mass (g) contained in the liquid phase portion in the container” ”× 100. “[C] carbon dioxide concentration (%) contained in the liquid phase part in the container” is “[C] carbon dioxide mass (g) contained in the liquid phase part in the container” ”/“ “[A] Stock solution, [B] Total amount of LPG and isopentane (g) ”+“ [C] carbon dioxide mass (g) contained in liquid phase part in container ”” × 100
下記表2において、「質量比[B]/[A]」の値が大きいほど、「容器内に充填された[C]二酸化炭素濃度(%)」、「[A]原液に含まれた[C]二酸化炭素濃度(%)」及び「容器内液相部に含まれた[C]二酸化炭素濃度(%)」の値が大きくなったことを確認できる。また、酸化染毛処理の履歴がある毛髪に塗布したところ、「質量比[B]/[A]」の値が大きいほど、泡の持続性が高い傾向があった。
下記表3において、質量比[B]/[A]が相対的に低くても、ゲージ圧力を高めれば、「容器内に充填された[C]二酸化炭素濃度(%)」、「[A]原液に含まれた[C]二酸化炭素濃度(%)」及び「容器内液相部に含まれた[C]二酸化炭素濃度(%)」が高まったことを確認できる。
下記表4において、表2と同じ傾向を確認できる。また、泡の持続性傾向も同様であった。
Claims (8)
前記容器の25℃におけるゲージ圧力が0.80MPa以下、
前記[A]に対する前記[B]の質量比[B]/[A]が3.0/97.0以上、
前記容器内に充填された前記[C]の濃度が1.20質量%以上であることを特徴とする発泡性エアゾール製品。
[A]アニオン界面活性剤を含む原液
[B]液化ガス、又は、液化ガス及びイソペンタン
[C]二酸化炭素 The following [A], [B] and [C] are foamable aerosol products filled in a container,
The gauge pressure at 25 ° C. of the container is 0.80 MPa or less,
The mass ratio [B] / [A] of [B] to [A] is 3.0 / 97.0 or more,
A foamable aerosol product, wherein the concentration of the [C] filled in the container is 1.20% by mass or more.
[A] Stock solution containing an anionic surfactant [B] Liquefied gas, or liquefied gas and isopentane [C] Carbon dioxide
The foamable aerosol product according to any one of claims 1 to 7, wherein a concentration of the [C] in the container is 3.00% by mass or less.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014024043A JP6505365B2 (en) | 2014-02-12 | 2014-02-12 | Effervescent aerosol product |
PCT/JP2014/075831 WO2015122044A1 (en) | 2014-02-12 | 2014-09-29 | Foamable aerosol product |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014024043A JP6505365B2 (en) | 2014-02-12 | 2014-02-12 | Effervescent aerosol product |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2015151342A true JP2015151342A (en) | 2015-08-24 |
JP6505365B2 JP6505365B2 (en) | 2019-04-24 |
Family
ID=53799800
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014024043A Active JP6505365B2 (en) | 2014-02-12 | 2014-02-12 | Effervescent aerosol product |
Country Status (2)
Country | Link |
---|---|
JP (1) | JP6505365B2 (en) |
WO (1) | WO2015122044A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6738141B2 (en) * | 2015-11-24 | 2020-08-12 | 株式会社マンダム | Aerosol cosmetics |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003252725A (en) * | 2002-02-28 | 2003-09-10 | Daizo:Kk | Foamable aerosol composition |
JP2005002046A (en) * | 2003-06-12 | 2005-01-06 | Kao Corp | Foamable skin liniment |
JP2009269914A (en) * | 2008-04-11 | 2009-11-19 | Kao Corp | Foamed skin liniment |
JP2012121813A (en) * | 2010-12-06 | 2012-06-28 | Kao Corp | Skin liniment |
JP2013091642A (en) * | 2012-11-07 | 2013-05-16 | Milbon Co Ltd | Foaming aerosol product |
JP2013224275A (en) * | 2012-04-20 | 2013-10-31 | Kracie Home Products Ltd | Foam-like aerosol composition |
JP2013227232A (en) * | 2012-04-24 | 2013-11-07 | Kracie Home Products Ltd | Foamy aerosol composition |
JP2013237615A (en) * | 2012-04-20 | 2013-11-28 | Kracie Home Products Ltd | Foam aerosol composition |
JP2013241359A (en) * | 2012-05-18 | 2013-12-05 | Daizo:Kk | Foamable aerosol composition |
-
2014
- 2014-02-12 JP JP2014024043A patent/JP6505365B2/en active Active
- 2014-09-29 WO PCT/JP2014/075831 patent/WO2015122044A1/en active Application Filing
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003252725A (en) * | 2002-02-28 | 2003-09-10 | Daizo:Kk | Foamable aerosol composition |
JP2005002046A (en) * | 2003-06-12 | 2005-01-06 | Kao Corp | Foamable skin liniment |
JP2009269914A (en) * | 2008-04-11 | 2009-11-19 | Kao Corp | Foamed skin liniment |
JP2012121813A (en) * | 2010-12-06 | 2012-06-28 | Kao Corp | Skin liniment |
JP2013224275A (en) * | 2012-04-20 | 2013-10-31 | Kracie Home Products Ltd | Foam-like aerosol composition |
JP2013237615A (en) * | 2012-04-20 | 2013-11-28 | Kracie Home Products Ltd | Foam aerosol composition |
JP2013227232A (en) * | 2012-04-24 | 2013-11-07 | Kracie Home Products Ltd | Foamy aerosol composition |
JP2013241359A (en) * | 2012-05-18 | 2013-12-05 | Daizo:Kk | Foamable aerosol composition |
JP2013091642A (en) * | 2012-11-07 | 2013-05-16 | Milbon Co Ltd | Foaming aerosol product |
Also Published As
Publication number | Publication date |
---|---|
JP6505365B2 (en) | 2019-04-24 |
WO2015122044A1 (en) | 2015-08-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5367193B1 (en) | Effervescent aerosol products | |
KR101923743B1 (en) | Foamable aerosol composition | |
JP2018012673A (en) | Aerosol composition for cosmetics | |
JP5554007B2 (en) | Foam skin application | |
JP5554005B2 (en) | Foam skin application | |
JP2017095393A (en) | Foamy skin cleanser | |
CN103800214A (en) | Detergent composition | |
JP5801525B2 (en) | Liquid detergent composition | |
JP6505365B2 (en) | Effervescent aerosol product | |
JP5959932B2 (en) | Foamable aerosol composition | |
JP2013213062A (en) | Foaming aerosol product | |
JP6155024B2 (en) | Aerosol cosmetics | |
KR101906857B1 (en) | Foamy cosmetic material | |
JP7280045B2 (en) | Effervescent aerosol product and hair washing method | |
JP7257154B2 (en) | Foaming aerosol product and hair washing method | |
JP2021107335A (en) | Aerosol product and hair processing method | |
JP2017141417A (en) | Liquid cleanser composition | |
JP5707226B2 (en) | Aerosol skin cleanser | |
JP6739181B2 (en) | Effervescent aerosol product and hair treatment method | |
JP3711576B2 (en) | Non-gas former composition | |
JP7280040B2 (en) | Hair cleansing composition and aerosol product | |
JP5465911B2 (en) | Skin cleanser | |
JP5996936B2 (en) | Effervescent aerosol products | |
JP5920777B2 (en) | Foamable aerosol composition | |
JP6045197B2 (en) | Effervescent aerosol products |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20161213 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180130 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180329 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180904 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20181030 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20190312 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20190327 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6505365 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |