JP5367193B1 - Effervescent aerosol products - Google Patents

Abstract

An object of the present invention is to provide a foamable aerosol product containing a propellant containing carbon dioxide and having excellent foamability and good foam quality.
The present invention relates to a foamable aerosol product in which [A] a stock solution containing an anionic surfactant and [B] a propellant is filled in a pressure-resistant container, and [B] the propellant is isopentane, liquefied petroleum It is a foamable aerosol product used as a shampoo, containing a gas and carbon dioxide, and having a total mass ratio of isopentane and liquefied petroleum gas to the stock solution [A] of 4/96 to 10/90. It is preferable that the foamable aerosol product excludes those in which a hydrocarbon mixture satisfying the following conditions (1) and (2) is filled in a pressure resistant container in an amount of 0.1% by mass to 3% by mass. (1) A hydrocarbon mixture selected from hydrocarbons having 3 to 5 carbon atoms. (2) A hydrocarbon mixture containing 70% by mass or more and 100% by mass or less of saturated hydrocarbons having a vapor pressure at 35 ° C. of 0.1 MPa or more and less than 0.5 MPa.
[Selection figure] None

Description

  The present invention relates to foamable aerosol products.

  For cosmetics such as hair sprays, facial cleansing foams, hair styling products, etc., foam that fills the concentrate with a propellant in a pressure-resistant container and sprays the concentrate with foam to apply the foam that is formed. Aerosol products are widespread.

  In recent years, attention has been paid to the effect of promoting blood circulation of skin by carbon dioxide. Carbon dioxide is contained as a component of a propellant in the foamable aerosol product as described above, and carbon dioxide is contained in the foam formed by the injection of the propellant. Techniques for embedding carbon and causing it to act on the skin have been developed (see Japanese Patent Application Laid-Open Nos. 2009-269914 and 2010-248098).

  However, when carbon dioxide is used as a propellant, foaming is low and foamed foam tends to break, so foam formation and foam persistence are not always sufficient. In the above-described prior art, addition of hydrocarbons and components of the stock solution are devised as a propellant, but foamability is not sufficient, and there is room for improvement.

JP 2009-269914 A JP 2010-248098 A

  The present invention has been made based on the above circumstances, and its object is to provide a foamable aerosol product containing a propellant containing carbon dioxide and having excellent foamability and good foam quality. It is to be.

The invention made to solve the above problems is
[A] a stock solution containing an anionic surfactant (hereinafter also referred to as “[A] stock solution”), and [B] a foamable aerosol product in which a pressure-resistant container is filled,
The [B] propellant contains isopentane, liquefied petroleum gas (hereinafter also referred to as “LPG”) and carbon dioxide,
The foamable aerosol product is characterized in that the total mass ratio of the isopentane and the liquefied petroleum gas to the stock solution [A] is from 4/96 to 10/90.

  The foamable aerosol product [A] contains an anionic surfactant in the stock solution, and [B] propellant contains isopentane, liquefied petroleum gas, and carbon dioxide, and the total [A] of the above isopentane and liquefied petroleum gas. By making the mass ratio with respect to the undiluted | stock solution into the said specific range, while being excellent in foamability, favorable foam quality can be expressed. It is presumed that the above effect is achieved by the combination of the fine foaming property of carbon dioxide, the high foaming property of liquefied petroleum gas, and the sustainability of foam of isopentane.

  The foamable aerosol product is preferably used as a shampoo. Thereby, it is excellent in the feeling at the time of a rinse, and the finishing feeling after hair drying, In addition, the above-mentioned blood circulation promotion effect can be made to act on a scalp effectively.

  The filling amount of the liquefied petroleum gas is preferably larger than the filling amount of the isopentane. Thereby, the feeling at the time of a rinse is more excellent.

  The anionic surfactant preferably contains polyoxyethylene lauryl ether acetate and polyoxyethylene sulfosuccinate lauryl salt. Thereby, the foamability is more excellent and the foam quality is better.

  The mass ratio of the polyoxyethylene sulfosuccinic acid lauryl salt to the polyoxyethylene lauryl ether acetate is preferably 0.5 or more and 3.0 or less. By setting the mass ratio within the specific range, the fineness and lightness of the foam can be imparted, and when used as a shampoo, the hair is imparted with a sense of volume and softness after drying the hair. be able to.

  The liquefied petroleum gas is a mixture of propane and butane, and a mixed gas in which these ratios are adjusted according to the purpose.

  The foamable aerosol product of the present invention has excellent foamability and good foam quality, and can effectively exert the blood circulation promoting effect of carbon dioxide on the scalp and the like.

<Foaming aerosol products>
The foamable aerosol product of the present invention includes [A] stock solution, [B] propellant, and a pressure vessel. Hereinafter, the foamable aerosol product will be described in detail.

[[A] Stock solution]
[A] The stock solution contains an anionic surfactant, and water such as purified water is blended therein (the amount of water in the [A] stock solution is, for example, 70% by mass or more). Moreover, [A] undiluted | stock solution may contain arbitrary components in the range which does not impair the effect of this invention.

(Anionic surfactant)
An anionic surfactant is a component that removes dirt such as the scalp and contributes to foaming properties. In addition, you may use this anionic surfactant individually or in combination of 2 or more types.

  Examples of the anionic surfactant include acyl amino acids or salts thereof (sodium salt, potassium salt, triethanolamine salt, etc.); coconut oil fatty acid sodium, coconut oil fatty acid potassium, cocoyl isethionic acid or a salt thereof (sodium salt). Polyoxyethylene lauryl ether sulfuric acid or a salt thereof (sodium salt, potassium salt, etc.); polyoxyethylene lauryl ether acetic acid or a salt thereof (sodium salt, potassium salt, etc.); disodium alkylsulfosuccinate; polyoxy Ethylenesulfosuccinic acid or salts thereof (sodium salt, potassium salt, etc.); lauroyl hydrolyzed silk sodium; isostearic acid hydrolyzed silk AMP (2-amino-2-methyl-1-propanol, a condensate of isostearic acid and hydrolyzed silk) Salt); Illy hydrolyzed soybean protein potassium; cocoyl hydrolyzed collagen salt (sodium salt, potassium salt, etc.); sodium tetradecene sulfonate; polyoxyethylene lauryl ether phosphate or its salt (sodium salt, potassium salt, etc.) .

  Among these, as the anionic surfactant, from the viewpoint of foamability and foam quality, polyoxyethylene lauryl ether acetate (the average added mole number of polyoxyethylene in polyoxyethylene lauryl ether acetate is 2 or more) 12 or less, preferably 2 or more and 6 or less) and polyoxyethylene sulfosuccinic acid lauryl salt (the average added mole number of polyoxyethylene in polyoxyethylene sulfosuccinic acid lauryl salt is preferably 2 or more and 12 or less, and 2 or more 6 or less is more preferable.) It is more preferable that both of these are included. For the same reason, the polyoxyethylene lauryl ether acetate is more preferably sodium polyoxyethylene lauryl ether acetate, and the polyoxyethylene sulfosuccinate lauryl salt is more preferably disodium polyoxyethylene sulfosuccinate lauryl.

  [A] The content of the anionic surfactant in the stock solution is preferably 3% by mass or more and 30% by mass or less, more preferably 5% by mass or more and 25% by mass or less, from the viewpoint of effectively achieving soil removal and foaming properties. Preferably, 10 mass% or more and 20 mass% or less are more preferable.

  When the anionic surfactant contains polyoxyethylene lauryl ether acetate and polyoxyethylene sulfosuccinate lauryl salt, the mass ratio of polyoxyethylene sulfosuccinate lauryl salt to polyoxyethylene lauryl ether acetate is 0. It is preferably 5 or more and 3.0 or less, more preferably 0.7 or more and 2.5 or less, and further preferably 1.0 or more and 2.0 or less. By setting the mass ratio in the above range, fineness and lightness of the foam can be imparted, and when used as a shampoo, it can impart a sense of volume and softness to the hair after drying the hair. it can.

(Optional component)
[A] In addition to the anionic surfactant and water, the stock solution is a known shampoo component such as an amphoteric surfactant, a nonionic surfactant, a lower alcohol, a polyhydric alcohol, a saccharide, a polymer compound, and an amino acid. It may contain components such as animal and plant extracts, inorganic compounds, fragrances, and preservatives. Among these, it is preferable to contain a polymer compound, particularly a cationic polymer. In addition, you may use each arbitrary component individually or in combination of 2 or more types, respectively.

  The cationic polymer is a component that improves the fingering property during washing. Examples of the cationic polymer include cationized cellulose, cationized guar gum, vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate, acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer, N, N-dimethylaminoethyl diethyl methacrylate methacrylate / N, N-dimethylacrylamide / polyethylene glycol dimethacrylate copolymer and the like. [A] The content of the cationic polymer in the stock solution is preferably 0.1% by mass or more and 1% by mass or less.

(Form)
[A] The stock solution may be liquid. When the viscosity of the liquid [A] stock solution is measured using a B-type viscometer (temperature: 25 ° C., rotor: appropriately set according to viscosity, rotor rotational speed: 60 rpm), 60 seconds from the start of viscosity measurement The value after the lapse is preferably 10 mPa · s or more and 1,000 mPa · s or less, more preferably 20 mPa · s or more and 500 mPa · s or less, and further preferably 30 mPa · s or more and 400 mPa · s or less. In addition, when an amphoteric surfactant is included as an optional component, [A] the viscosity of the stock solution and the foam foaming property may be affected. [A] in the case of containing an amphoteric surfactant The content of the amphoteric surfactant in the stock solution is preferably 3% by mass or less, more preferably 2% by mass or less, and further preferably 1% by mass or less.

(PH)
[A] The pH of the stock solution should be weakly acidic. By keeping the pH weakly acidic, it is possible to suppress the carbon dioxide from becoming carbonate and enhance the blood circulation promoting effect, and the foaming property and the discharge property are deteriorated due to the increase in viscosity accompanying the decrease in pH. Can be suppressed. [A] The pH of the stock solution is preferably 4.0 or more and 6.8 or less, and more preferably 5.0 or more and 6.5 or less.

[[B] propellant]
[B] The propellant contains isopentane, liquefied petroleum gas, and carbon dioxide. [B] The propellant may contain components other than isopentane, liquefied petroleum gas, and carbon dioxide as long as the effects of the present invention are not impaired.

(carbon dioxide)
Carbon dioxide is an active ingredient that imparts a blood circulation promoting effect, and also functions as a propellant. This carbon dioxide is filled in the pressure vessel as a gas. Part of it is dissolved in the liquid in the pressure-resistant container, and foams on the skin by the injection of the propellant. Gaseous carbon dioxide present in the foamed foam and carbon dioxide dissolved in the liquid have a blood circulation promoting action on the skin.

  Therefore, the carbon dioxide is preferably dissolved in a high concentration in the liquid in the pressure vessel. As a density | concentration in the liquid in the pressure vessel of the said carbon dioxide, 100 mass ppm or more and 8,000 mass ppm or less are preferable, 1,000 mass ppm or more and 7,000 mass ppm or less are more preferable, 2,000 mass ppm More preferably, it is 6,000 ppm by mass or less.

(Isopentane and liquefied petroleum gas)
The said isopentane and liquefied petroleum gas are components which are injected with a carbon dioxide and form a bubble with a carbon dioxide. This isopentane is presumed to contribute to the persistence of the foam. On the other hand, it is speculated that liquefied petroleum gas contributes to initial foamability due to its high volatility.

  The liquefied petroleum gas contains propane and n-butane and / or i-butane. It is preferable that n-butane and i-butane coexist in terms of excellent foam formation at low temperatures.

  [B] The filling amount of the propellant is preferably 0.5 parts by mass or more and 30 parts by mass or less, more preferably 1 part by mass or more and 20 parts by mass or less, with respect to 100 parts by mass of the stock solution [A]. More preferred is 15 parts by mass or less. [B] By making the filling amount of the propellant within the above range, [A] the stock solution can be efficiently injected.

  [B] The mass ratio of the total of isopentane and liquefied petroleum gas in the propellant to the [A] stock solution is 4/96 or more and 10/90 or less. By setting the total mass ratio of the isopentane and liquefied petroleum gas to the stock solution [A] in the above range, it is possible to exhibit excellent foam quality and excellent foam quality. The mass ratio is preferably 5/95 or more and 10/90 or less, and more preferably 6/94 or more and 8/92 or less from the viewpoint of foamability and the like.

  [B] In the propellant, the filling amount of the liquefied petroleum gas is preferably larger than the filling amount of isopentane. Thereby, the feeling at the time of a rinse is more excellent.

[Pressure vessel]
The pressure vessel is a pressure-resistant vessel filled with [A] stock solution and [B] propellant. The pressure vessel may be a known pressure vessel used for foamable aerosol products, and is formed of a metal such as aluminum, aluminum alloy, tinplate, or steel. In addition, this pressure vessel may have a resin layer laminated on the inner surface or an inner bag inside.

<Method for producing foamable aerosol product>
The foamable aerosol product can be produced by filling the pressure-resistant container with [A] stock solution and [B] propellant.

  EXAMPLES Hereinafter, although this invention is demonstrated concretely based on an Example, this invention is not limited to these Examples.

<[A] Preparation of stock solution>
[A] Each component used for blending with water for preparation of the stock solution and the blending amount in the [A] stock solution are shown below. In Tables 2, 3 and 5, “-” indicates that the corresponding component was not blended.

(Anionic surfactant)
Polyoxyethylene lauryl ether sodium acetate Polyoxyethylene sulfosuccinate lauryl disodium cocoyl glutamate Na
Lauroyl aspartate Na
(Other ingredients)
Isostearamidpropyl betaine Lauramide propyl betaine Polyoxyethylene dioleic acid methyl glucoside Monolauric acid polyglyceryl Polyoxypropylene (1) Palm oil fatty acid monoisopropanolamide N, N-dimethylaminoethyl methacrylate diethyl sulfate / N, N-dimethyl Acrylamide-dimethacrylic acid polyethylene glycol copolymer Polyethylene glycol 1540
O- [2-Hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose l-menthol 1,3-butylene glycol anhydrous ethanol citric acid fragrance

<Production of foamable aerosol products (1)>
[Example 1]
Based on the blending amounts shown in Table 1, each component was mixed with water to prepare [A] (A-1) as a stock solution. Then, 94 parts by mass of the stock solution (A-1) and 1.2 parts by mass of isopentane as a propellant [B], 4.8 parts by mass of LPG, and 1.2 parts by mass of carbon dioxide were filled in an aluminum pressure-resistant container. A foamable aerosol product was obtained.

[Examples 2-6 and Comparative Examples 1-3]
Each foamable aerosol product was obtained in the same manner as in Example 1 except that the components having the types and blending amounts shown in Table 2 below were used.

<Evaluation (1)>
Using the foamable aerosol products of Examples and Comparative Examples, sensory evaluation was performed according to the following criteria for foamability, foam quality, touchability and finish feeling by three specialized panelists. The evaluation results are shown in Table 2. In addition, the evaluation result in Table 2 is a relative evaluation result in the evaluation (1).

[Foaming]
Using each foamable aerosol product, the size of bubbles immediately after being discharged from the pressure vessel and the bubble retention when discharged from the pressure vessel and left on a vinyl wrap for 1 hour were evaluated according to the following criteria.
◎: 3 out of 3 are good ○: 2 out of 3 are good △: 2 out of 3 are bad ×: 3 out of 3 are bad

[Foam quality]
Using each foamable aerosol product, the elasticity of the foam immediately after being discharged from the pressure vessel was evaluated according to the following criteria.
◎: 3 out of 3 are good ○: 2 out of 3 are good △: 2 out of 3 are bad ×: 3 out of 3 are bad

[Fingering]
Using each foamable aerosol product, the foam discharged from the pressure vessel was applied to the hair wet with water and shampooed, and the goodness of the hair after finger rinsing with running water was evaluated according to the following criteria.
◎: 3 out of 3 are good ○: 2 out of 3 are good △: 2 out of 3 are bad ×: 3 out of 3 are bad

[Finished feeling]
Shampoo with each foamable aerosol product, apply a treatment containing a cationic surfactant after rinsing, rinse off, dry hair and evaluate the volume feeling and softness of the hair according to the following criteria did.
◎: 3 out of 3 are good ○: 2 out of 3 are good △: 2 out of 3 are bad ×: 3 out of 3 are bad

  As is clear from the evaluation results in Table 2, both foamability and foam quality were good in the examples. On the other hand, in the comparative example, at least one of foamability and foam quality was bad.

<Production of foamable aerosol products (2)>
[Reference Examples 1a and 1b]
Based on the blending amounts shown in Table 3, each component was mixed with water to prepare stock solutions (1a) and (1b). And each obtained undiluted | stock solution and the propellant which consists of LPG and a carbon dioxide were filled in the pressure-resistant container made from aluminum with the compounding quantity shown in Table 4, respectively, and the foamable aerosol product of each reference example was obtained.

<Evaluation (2)>
Using the foamable aerosol products of Reference Examples 1a and 1b, sensory evaluation of foamability and foam quality was conducted by three specialized panelists in the same manner as in the above evaluation (1). The evaluation results are shown in Table 4. The evaluation results in Table 4 indicate relative evaluations with respect to Reference Example 1b (displayed as “reference” in Table 4).

  As is apparent from the evaluation results in Table 4, an effervescent aerosol product (Reference Example 1a) containing sodium polyoxyethylene lauryl ether acetate and disodium polyoxyethylene sulfosuccinate as anionic surfactants was obtained by using sodium cocoyl glutamate. In addition, both foamability and foam quality are good as compared with the one containing Naurolaurylaspartate (Reference Example 1b).

<Production of foamable aerosol product (3)>
[Reference Examples 2a to 2c]
Based on the blending amounts shown in Table 5, each component was mixed with water to prepare stock solutions (2a) to (2c). And each obtained undiluted | stock solution and the propellant which consists of LPG and a carbon dioxide were filled in the pressure-resistant container made from aluminum with the compounding quantity shown in Table 6, respectively, and the foamable aerosol product of each reference example was obtained.

<Evaluation (3)>
Using the foamable aerosol products of Reference Examples 2a to 2c, sensory evaluation was performed on the texture and lightness of the foam, the sense of volume and the softness of the hair by three specialized panelists according to the following criteria. The evaluation results are shown in Table 6. The evaluation results in Table 6 are relative evaluation results in the evaluation (3).

[Foam texture and lightness]
Using each foamable aerosol product, the fineness and lightness of the foam when it was grasped after being discharged from the pressure vessel was evaluated by touch according to the following criteria.
◎: 3 out of 3 are good ○: 2 out of 3 are good △: 2 out of 3 are bad ×: 3 out of 3 are bad

[Volume]
Each foamable aerosol product is sprayed onto the hair, treated with a treatment containing a cationic surfactant, dried, and then light and slippery as you pass your hand from the root toward the tip of the hair The feeling was evaluated by touch according to the following criteria.
◎: 3 out of 3 are good ○: 2 out of 3 are good △: 2 out of 3 are bad ×: 3 out of 3 are bad

[Hair softness]
Each foamable aerosol product is sprayed onto the hair, treated with a treatment containing a cationic surfactant, dried, and then the middle of the hair to the fingertips of the hair tip and the softness of the hair when grasped This was evaluated by touch according to the following criteria.
◎: 3 out of 3 are good ○: 2 out of 3 are good △: 2 out of 3 are bad ×: 3 out of 3 are bad

  As is clear from the evaluation results in Table 6, as the anionic surfactant, the foam texture is higher when the content of disodium polyoxyethylene sulfosuccinate is higher than the content of sodium polyoxyethylene lauryl ether acetate. Fineness, lightness, volume and softness of hair are good.

  The present invention can provide a foamable aerosol product containing a propellant containing carbon dioxide and having excellent foamability and good foam quality.

Claims (8)

[A] a stock solution containing an anionic surfactant, and [B] a foamable aerosol product filled with a propellant in a pressure-resistant container,
The [B] propellant contains isopentane, liquefied petroleum gas and carbon dioxide,
The total mass ratio of the isopentane and liquefied petroleum gas to the [A] stock solution is 4/96 or more and 10/90 or less,
The viscosity of the above [A] stock solution is 10 mPa · s or more and 1,000 mPa · s or less,
A foamable aerosol product used as a shampoo. 2. The foamable aerosol product according to claim 1, wherein a hydrocarbon mixture satisfying the following conditions (1) and (2) is excluded except that the pressure vessel is filled in an amount of 0.1 mass% to 3 mass%.
(1) A hydrocarbon mixture selected from hydrocarbons having 3 to 5 carbon atoms (2) Carbonization containing 70% by mass or more and 100% by mass or less of saturated hydrocarbons having a vapor pressure of 0.1 MPa or more and less than 0.5 MPa at 35 ° C. Hydrogen mixture   The foamable aerosol product according to claim 1 or 2, wherein the total mass ratio of the isopentane and liquefied petroleum gas to the stock solution [A] is 5/95 or more and 10/90 or less.   The foamable aerosol product according to claim 1, 2 or 3, wherein a filling amount of the liquefied petroleum gas is larger than a filling amount of the isopentane.   The foamable aerosol product according to any one of claims 1 to 4, wherein cationized cellulose is blended. 6. The anionic surfactant according to claim 1, wherein one or more selected from acylamino acid salts, polyoxyethylene lauryl ether acetates and polyoxyethylene sulfosuccinates are included. The foamable aerosol product according to item.   The foamable aerosol product according to any one of claims 1 to 5, wherein the anionic surfactant comprises polyoxyethylene lauryl ether acetate and polyoxyethylene sulfosuccinate lauryl salt. The foamable aerosol product according to claim 7 , wherein a mass ratio of the polyoxyethylene sulfosuccinic acid lauryl salt to the polyoxyethylene lauryl ether acetate is 0.5 or more and 3.0 or less.