JP4637229B2 - Hairdressing cosmetics - Google Patents

Description

  The present invention relates to a hair styling cosmetic. More specifically, the present invention relates to a hair styling cosmetic that has a high setting power but also has a sufficient arranging power.

Conventionally, hair gels, hair foams, hair sprays and the like have been commonly used as hairdressing cosmetics. However, these hair styling cosmetics maintain and maintain the hairstyle with a film-forming polymer. Therefore, the hair style setting power and the hair style keeping power, which is a function for maintaining the setting power, are excellent, but there is a drawback that a feeling of inconvenience caused by the stiffness occurs. In addition, because it is excellent in setting power and its keeping power, once set, it is difficult to reset to a different hairstyle again, and further, it is difficult to arrange the hairstyle during setting, that is, it is difficult to arrange it Was a drawback.
Although technology for reducing the wrinkle by compounding sugar alcohol derivatives, etc. has been developed, it is difficult to reset, and the ability to arrange is poor, and the film is brittle and flaking occurs. There was also a problem that it was easy (Patent Document 1, Patent Document 2).

On the other hand, hair wax, which has been supported mainly by young people in recent years, can move and arrange hair by the stickiness of solid fats and oils, but has weakness in setting power and hairstyle keeping power. (Patent Document 3).
And in order to improve the fixing force and sustainability, the technique which mix | blended film-forming polymer and semi-solid wax has also been developed (patent document 4).
However, the reality is that it has a poor ability to arrange and is still unsatisfactory as a hair styling cosmetic that consumers really want.

JP2002-167317 JP2006-69903 JP 10-45546 JP2005-239555

  As a result of diligent research in view of the above-mentioned viewpoints, the present inventor has identified (A) a film-forming polymer, (B) a sugar and / or sugar alcohol, (C) a wax containing an ester bond, and (D) a liquid oil component. It has been found that adjusting the content of each component and the content of each component to a specific mass ratio can solve the disadvantages of the prior art and provide a hairdressing cosmetic product truly desired by consumers. It came to be completed.

It is an object of the present invention to provide a hair styling cosmetic that is excellent in set power and hair style keeping power, solves poor touch during use, has excellent arranging power, and does not cause flaking problems. To do.

That is, the present invention is a hair styling cosmetic containing a film-forming polymer and a sugar alcohol .
(A) 1-15% by mass of film-forming polymer
(B) 0.5-30 mass% sugar alcohol
(C) 0.2-15% by mass of wax containing an ester bond
(D) It contains liquid oil, and the mass ratio of (E) (A) component and (B) component content is (B) / (A) = 1 / 2-3
(F) Mass ratio of content of (A) component and (C) component is (C) / (A) = 1 / 5-1
(G) Mass ratio of content of (C) component and (D) component is (D) / (C) = 1 / 2-3 / 2
A hair styling cosmetic composition, characterized in that it is,
The film-forming polymer (A) is methacryloyloxyethylcarboxybetaine / alkyl methacrylate copolymer, vinylpyrrolidone / methacrylamide / vinylimidazole copolymer, N-dimethylaminoethyl / alkyl acrylate / tripropylene glycol diacrylate. Copolymer, vinyl pyrrolidone / dimethylaminoethyl methacrylate copolymer diethyl sulfate, alkyl acrylate / diacetone acrylamide copolymer, polyurethane-10, vinyl pyrrolidone / vinyl acetate copolymer, octyl amide / acrylic acid It is either a hydroxypropylpropyl / butylaminoethyl methacrylate copolymer,
The (B) sugar alcohol is any one of mannitol, xylitol, erythritol, sorbitol, maltitol, and inositol .

In the present invention, the wax containing (C) the ester bond is candelilla wax, and the liquid oil (D) is pentaerythrityl tetraethylhexanoate having an ester bond. Hair styling cosmetics.

  Moreover, this invention provides said hair-styling cosmetics characterized by further containing (H) volatile oil.

  The hair styling cosmetic composition of the present invention is excellent in setting power and hair style keeping power, solves poor touch, is excellent in arranging power, and has no problem of flaking.

The present invention is described in detail below.
<(A) film-forming polymer>
Examples of the film-forming polymer include acrylic, vinyl-based, urethane-based, and polysaccharide-based film-forming polymers.

  Examples of the acrylic and vinyl film-forming polymers that are anionic include alkyl acrylate / diacetone acrylamide copolymers (plus size L-53P, plus size L-9909B, plus size L-9948B, etc. Also made by alkyl acrylate / octyl acrylamide copolymer (Dermacryl 79 (made by NSC Japan)), polyethylene glycol / polypropylene glycol-25 / dimethicone / acrylates copolymer (rubyflex SILK) (Made by BASF)), acrylic acid / acrylic acid amide / ethyl acrylate copolymer (Ultrahold 8, Ultrahold Strong (made by BASF)), alkyl acrylate copolymer (aniset NF-1000, aniset HS-) 3000 etc. For example, an octylamide acrylate / hydroxypropylpropyl acrylate / butylaminoethyl methacrylate copolymer (AMPHOMER SH30, AMPHOMER LV-71 (Nippon NSC Corporation) Methacryloyloxyethylcarboxybetaine / alkyl methacrylate copolymer (Yukaformer R205, Yukaformer 301, Yukaformer SM, Yukaformer 104D etc. (Mitsubishi Chemical Corporation), RAM Resin-1000, RAM Resin-2000, RAM Resin) -3000, RAM resin-4000 (manufactured by Osaka Organic Chemical Co., Ltd.)), dimethyldiallylammonium chloride / acrylic acid copolymer (Mercoat 280, Mercoat 295 (manufactured by Nalco)), dimethyl diallyl chloride For example, vinyl pyrrolidone / dimethylaminoethyl methacrylate copolymer diethyl sulfate (HC polymer) may be used as long as it is cationic, such as a monium / acrylamide / acrylic acid copolymer (Mercoat Plus 3330, Marquat Plus 3331 (manufactured by Nalco)). 1S (M), HC polymer 2 (manufactured by Osaka Organic Chemical Co., Ltd.), Guff Coat 755N (manufactured by ISP)), vinylpyrrolidone, dimethylaminopropyl methacrylamide, lauryl dimethylaminopropyl methacrylamide copolymer (Stylee W-20) (Manufactured by ISP)) vinylpyrrolidone / N, N-dimethylaminoethyl methacrylate / alkyl acrylate / tripropylene glycol diacrylate copolymer (Coscut GA467, Koscut GA468 (manufactured by Osaka Organic Chemical Industry Co., Ltd.)), Dimethylmethylenepiperidinium trichloride (Mercoat 100 (manufactured by Nalco)), dimethyldiallylammonium chloride / acrylamide copolymer (Mercoat 550 (manufactured by Nalco)), trimethylaminopropylacrylamide / dimethylacrylamide copolymer, etc. If it is nonionic, for example, polyvinylpyrrolidone (rubiscol K17, rubiscol K30, rubiscol K90 (manufactured by BASF), PVP K (manufactured by ISP)), vinylpyrrolidone / vinyl acetate copolymer (PVP / VA S-) 630, PVP / VA E-735, PVP / VA E-335 (above ISP), Rubiscor VA73W, Rubiscor 37E (above BASF), PVA-6450 (Osaka Organic Chemical Co., Ltd.)), Vinyl methyl ether Alkyl maleate copolymer (Gantrez A-425, Gantrez ES-225, Gantrez ES-335, etc. (manufactured by ISP)), vinylpyrrolidone / methacrylamide / vinylimidazole copolymer (ruby set clear (manufactured by BASF)) Etc. can be illustrated.

  In the case of urethane, Yodosol PUD (manufactured by Nippon SC Co., Ltd.), Ruby Set P.I. U. If the polymer of R. (made by BASF) and Unexamined-Japanese-Patent No. 2006-213706 is an acryl-urethane type, the polymer of DynamX (made by NSC Japan) and Japanese Patent Application No. 2006-183144 can be illustrated.

  Polysaccharides include gum arabic, glucan, succinoglycan, carrageenan, caraya gum, tragacanth gum, guar gum, locust bean gum, galactomannan gum, xanthan gum, starch, carob gum, quince seed (malmello), casein, dextrin, gelatin, pectin Acid sodium, sodium alginate, methylcellulose, ethylcellulose, carboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, crystalline cellulose, chlorinated O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose, chlorinated O- [2- Hydroxy-3- (trimethylammonio) propyl] guar gum, O- [2-hydroxy-3- (trimethylammonio) propyl] locust chloride Ngamu can be exemplified chloride Hidorokishipuropirutorimoniumu starch.

  The type of the film-forming polymer is not limited, but acrylic, vinyl and urethane film agents are particularly preferable.

  The content of the film-forming polymer is 1 to 15% by mass with respect to the total amount of the hairdressing cosmetic.

<(B) Sugar and / or sugar alcohol>
Examples of the sugar include monosaccharides and oligosaccharides.

  Monosaccharides include tricarbon sugars (eg, D-glyceryl aldehyde, dihydroxyacetone, etc.); tetracarbon sugars (eg, D-erythrose, D-erythrulose, D-threose, etc.); pentose sugars (eg, L-arabinose) , D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, etc .; hexose (eg, D-glucose, D-talose, D-bucose, D -Galactose, D-fructose, L-galactose, L-mannose, D-tagatose, etc .; heptosaccharide (eg, aldheptose, heproose, etc.); octose sugar (eg, octulose, etc.); deoxy sugar (eg, 2- Deoxy-D-ribose, 6-deoxy-L-galactose, 6-deoxy-L-mannose, etc .; amino sugars (eg, D-glucosamine, D-galactosamine, sialic acid, aminouronic acid, Etc. neuraminic acid); uronic acid (e.g., D- glucuronic acid, D- mannuronic acid, L- guluronic acid, D- galacturonic acid, L- iduronic acid) and the like. These derivatives (POE / POP addition, alkyl group addition, cationization, anionization, silylation) are also included.

  Examples of oligosaccharides include sucrose, maltose, cellobiose, gunthianos, umbelliferose, lactose, planteose, isolicnose, trehalose, raffinose, lycnose, umbilicin, stachyose verbus course and the like. These derivatives (POE / POP addition, alkyl group addition, cationization, anionization, silylation) are also included.

  Examples of the sugar alcohol include mannitol, xylitol, erythritol, sorbitol, maltitol, inositol and the like. These derivatives (POE / POP addition, alkyl group addition, cationization, anionization, silylation) are also included.

  The type of sugar and / or sugar alcohol is not limited, but sugar alcohol, especially maltitol and sorbitol are most suitable.

Content of sugar and / or sugar alcohol is 0.5-30 mass% with respect to the total amount of hairdressing cosmetics. Then, the mass ratio of the contents of the component (A) and the component (B) specified in the requirement (E) is determined to be (B) / (A) = 1/2 to 3).

<(C) wax containing ester bond>
Examples of waxes that contain ester linkages include owl, beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ibota wax, snow wax, whale wax, montan wax, rice bran wax, rice wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugarcane. A wax etc. are mentioned. Lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, and other plants and fruits Extraction wax or the like.

  The type of wax containing an ester bond is not limited, but among these, candelilla wax and carnauba wax are optimal.

  The content of the wax containing an ester bond is 0.2 to 15% by mass with respect to the total amount of the hairdressing cosmetic. Then, the mass ratio of the contents of the component (A) and the component (C) specified in the requirement (F) is determined to be (C) / (A) = 1 / 5-1.

<(D) Liquid oil>
In the present invention, the liquid oil component is an oil component that exhibits a liquid state at 25 ° C. Examples of the liquid oil include hydrocarbon oil and ester oil having an ester bond.

  Examples of the hydrocarbon oil include liquid paraffin, isoparaffin, squalane, squalene, and polybutene.

  As ester oils having ester bonds, synthetic ester oils such as isopropyl myristate, isocetyl myristate, diheptyl undecyl adipate, dihexyl decyl adipate, (hydrogenated rosin / diisostearate) glyceryl, decyl oleate, octanoic acid Cetyl, octyldodecyl myristate, isopropyl palmitate, isostearyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate, myristyl lactate, lanolin acetate, isocetyl stearate , Isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol fatty acid ester, N-alkyl glycol noisostearate, neopentyl glycol dicaprate, diisostearyl malate, glycerin di-2-heptylundecanoate, trimethylolpropane tri-2-ethylhexanoate, trimethylolpropane triisostearate, tetra-2 -Pentaerythritol ethylhexanoate, glyceryl tri-2-ethylhexanoate, glyceryl trioctanoate, glyceryl triisopalmitate, trimethylolpropane triisostearate, polyglyceryl triisostearate, glyceryl triisostearate, glyceryl diisostearate, hydroxystearic acid Cholesteryl, neopentyl glycol dicaprate, polyglyceryl diisostearate, dipentaerythrityl hexahydroxystearate, La (hydroxystearic acid / isostearic acid) dipentaerythrityl, cetyl 2-ethylhexanoate, 2-ethylhexyl palmitate, glycerin trimyristate, glyceride tri-2-heptyl undecanoate, castor oil fatty acid methyl ester, macadamia nut fatty acid phytosterol, macadamia nut Fatty acid cholesteryl, lauroyl glutamate di (cholesteryl / octyldodecyl), lauroyl glutamate di (phytosteryl / octyldodecyl), isononyl isononanoate, tetra (ethylhexanoic acid / benzoic acid) pentaerythrityl, oleyl oleate, acetoglyceride, palmitic acid 2 -Heptylundecyl, diisobutyl adipate, N-lauroyl-L-glutamic acid-2-octyldodecyl ester, adipic acid 2-heptylundecyl, ethyl laurate, di-2-ethylhexyl sebacate, 2-hexyldecyl myristate, octyl palmitate, 2-hexyldecyl palmitate, diisobutyl adipate, 2-hexyldecyl adipate, sebacic acid Examples include diisopropyl, 2-ethylhexyl succinate, lanolin fatty acid octyldodecyl, and triethyl citrate.

  Natural ester oils include cavocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanca oil, castor oil, flaxseed oil, Examples include safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, eucalyptus oil, and hydrogenated products thereof.

  The type of liquid oil is not limited, but ester oil having an ester bond is preferable, among which glyceryl tri-2-ethylhexanoate, diisostearyl malate, cetyl 2-ethylhexanoate, and pentaerythrityl tetraethylhexanoate are particularly preferable. Is preferably pentaerythrityl tetraethylhexanoate.

The content of the liquid oil is preferably 0.1 to 22.5% by mass with respect to the total amount of the cosmetic. Then, the mass ratio of the contents of the component (C) and the component (D) specified in the requirement (G) is determined so as to be (D) / (C) = 1/2 to 3/2.

<(H) Volatile oil>
In the present invention, it is preferable to further contain (H) a volatile oil.
The volatile oil includes volatile hydrocarbon oils such as lower paraffin and isoparaffin having 10 to 16 carbon atoms, linear and cyclic silicones such as decamethylpentasiloxane, octamethyltetrasiloxane, dodecamethylhexasiloxane, methyl par Fluorine-modified oils such as fluorobutyl ether and ethyl perfluorobutyl ether are listed.

  The content of (H) volatile oil (D) liquid oil is appropriately determined, but is preferably 1 to 10% by mass with respect to the total amount of the cosmetic.

The hairdressing cosmetic composition of the present invention is produced by a conventional method by mixing the above essential components. The dosage form is not limited, but gel, wax, and cream are preferable.
The hair styling cosmetic composition of the present invention is preferably used as an emulsified composition by a conventional method with an appropriate emulsifier. Particularly preferred products for the present invention are hair gels, hair creams, hair milks, hair waxes.

  Hereinafter, the present invention will be described in more detail with reference to examples. The present invention is not limited to these examples. About a compounding quantity, mass% is shown unless there is particular notice. Prior to the examples, the evaluation method and evaluation criteria used in the present invention will be described.

(1) Setting power Apply 0.2g of the sample to black hair virgin hair (length 10cm, weight 0.5g), use comb to adjust the shape so that it is straight, and dry at room temperature for 2 hours. Five strands were prepared per sample. The maximum stress when this strand was pressed 5 mm was measured using a rheometer (RTC-2002DD (manufactured by Rheotech)). The evaluation criteria are as follows.
<Evaluation criteria>
A: Maximum stress value is 200 g weight or more B: Maximum stress value is less than 150-200 g weight C: Maximum stress value is less than 100-150 g weight D: Maximum stress value is less than 50-100 g weight E: Maximum stress value is 50 g weight Less than

(2) Hair Style Keeping Force Apply 0.4g of sample to black virgin hair (length 15cm, weight 1g), use comb to adjust the shape to straight, 5 strands per sample Was made. This was dried at 50 ° C. for 1 hour, then suspended on a board with a scale, and the length (b) at which the strand was bent was measured with a constant temperature and humidity chamber at a temperature of 30 ° C. and a humidity of 90% RH. Using the length (a) of the bent strand that was measured in advance when the sample was not applied, the keeping force was determined according to the following equation. The closer the value is to 100%, the higher the keeping force and the better the moisture resistance.
Hair style keeping power (%) = {(ab) / a} × 100
<Evaluation criteria>
A: Value is 90% or more B: Value is 70 to less than 90% C: Value is less than 50 to 70% D: Value is less than 50%

(3) Feel (no stiffness)
The hair bundle after applying 0.5 g of a sample to a bundle of black virgin hair (length 20 cm, mass 4.0 g) and drying at room temperature is subjected to a sensory test by 10 female panelists, and the hair The feel (flexibility and smoothness) as cosmetics for cosmetics was evaluated. Each person gave a score according to the following evaluation score criteria, and the scores of 10 people were totaled, and each test product was evaluated according to the following evaluation criteria.
<Evaluation criteria>
5 points: Very good 4 points: Good 3 points: Normal 2 points: Bad 1 point: Very bad <Evaluation criteria>
A: Total score is 40 or more B: Total score is 30 or more and less than 40 C: Total score is 20 or more and less than 30 D: Total score is less than 20

(4) Arrangement force For a bundle of black virgin hair (length: 20 cm, mass: 2 g), 0.5 g of the sample was applied and dried at room temperature. Ease was evaluated by a sensory test by 10 female panelists. The evaluation criteria are as follows.
<Evaluation criteria>
5 points: Easy to arrange 4 points: Slightly easy to arrange 3 points: Normal 2 points: Slightly difficult to arrange 1 point: Cannot arrange <Evaluation criteria>
A: Total score is 40 or more B: Total score is 30 or more and less than 40 C: Total score is 20 or more and less than 30 D: Total score is less than 20

(5) Flaking A hair comb after applying 0.5g of a sample to a bundle of black virgin hair (length 20cm, mass 2g) and drying at room temperature by 10 female panelists. The degree of occurrence of flaking when passed was evaluated. Each person gave a score according to the following evaluation score criteria, and the scores of 10 people were totaled, and each test product was evaluated according to the following evaluation criteria.
<Evaluation criteria>
5 points: Flaking does not occur at all.
4 points: Flakeing hardly occurs.
3 points: Normal (Neither can be said.)
2 points: Some flaking occurs.
1 point: Flaking occurs very much.
<Evaluation criteria>
A: Total score is 40 or more B: Total score is 30 or more and less than 40 C: Total score is 20 or more and less than 30 D: Total score is less than 20

Hair styling cosmetics (hair creams) shown in each table were produced by conventional methods and evaluated according to the above methods. All the examples of the present invention demonstrate excellent effects.

※１：ユカフォーマー３０１（三菱化学株式会社製）
※２：ハイビスワコー１０５（和光純薬工業株式会社製）
＜製法＞
（４）、（８）を（１０）の一部に溶解させた後、（６）を加え均一分散させたものを水相部とする。一方、（２）、（３）、（５）を混合し９０℃にて加温溶解させた油相部を９０℃に加温した残りの（１０）に添加し、ホモミキサーにより乳化しワックス乳化部を得た。ワックス乳化部を水相部に一気に添加し均一混合後、（７）、（９）、（１）を添加、均一溶解させて、ヘアスタイリング用の整髪化粧料（整髪クリーム）を得た。

* 1: Yuka Former 301 (Mitsubishi Chemical Corporation)
* 2: Hibiswako 105 (Wako Pure Chemical Industries, Ltd.)
<Production method>
(4), (8) is dissolved in a part of (10), and then (6) is added and uniformly dispersed to obtain an aqueous phase. On the other hand, the oil phase part obtained by mixing (2), (3) and (5) and heating and dissolving at 90 ° C. is added to the remaining (10) heated to 90 ° C. and emulsified with a homomixer to obtain a wax. An emulsified part was obtained. The wax emulsified part was added to the aqueous phase part at once, and after uniform mixing, (7), (9) and (1) were added and uniformly dissolved to obtain a hair styling cosmetic (hair styling cream) for hair styling.

※１：ユカフォーマー３０１（三菱化学株式会社製）
※２：ハイビスワコー１０５（和光純薬工業株式会社製）
＜製法＞
表１の実施例と同様にして製造した。

* 1: Yuka Former 301 (Mitsubishi Chemical Corporation)
* 2: Hibiswako 105 (Wako Pure Chemical Industries, Ltd.)
<Production method>
It manufactured like the Example of Table 1.

※１：ユカフォーマー３０１（三菱化学株式会社製）
※２：ハイビスワコー１０５（和光純薬工業株式会社製）
＜製法＞
表１の実施例と同様にして製造した。

* 1: Yuka Former 301 (Mitsubishi Chemical Corporation)
* 2: Hibiswako 105 (Wako Pure Chemical Industries, Ltd.)
<Production method>
It manufactured like the Example of Table 1.

※１：ユカフォーマー３０１（三菱化学株式会社製）
※２：ハイビスワコー１０５（和光純薬工業株式会社製）
＜製法＞
表１の実施例と同様にして製造した。

* 1: Yuka Former 301 (Mitsubishi Chemical Corporation)
* 2: Hibiswako 105 (Wako Pure Chemical Industries, Ltd.)
<Production method>
It manufactured like the Example of Table 1.

Other examples are shown below.
Example 18
Ingredient (mass%)
(1) Carboxyvinyl polymer 0.5
(Hibiswako 105 (Wako Pure Chemical Industries, Ltd.))
(2) Hydroxypropyl methylcellulose 0.2
(Metroze 65SH-04T (manufactured by Shin-Etsu Chemical Co., Ltd.))
(3) Vinylpyrrolidone / methacrylamide / vinylimidazole copolymer solution (Ruby Set Clear (manufactured by BASF)) 15.0
(4) Patent application 2006-183144 Urethane-modified acrylic polymer aqueous dispersion of Production Example 1 (actual content 40% by mass)
5.0
(5) Polyoxypropylene decaglyceryl ether (70PO) 2.5
(6) Maltitol 10.0
(7) Sodium cocoamphoacetate 1.0
(8) Isostearic acid 0.7
(9) Rice wax 2.0
(10) Glyceryl tri-2-ethylhexanoate 1.5
(11) Polybutene 1.0
(Deodorized Polybutene-P (manufactured by Nikko Rica Corporation))
(12) 2-amino-2-methyl-1-propanol (adjusted to pH 7.0)
Appropriate amount (13) Ethanol 30.0
(14) Fragrance 0.1
(15) edetate trisodium 0.03
(16) Ion exchange water Residue (17) Silicic acid 1.0
<Production method>
After dissolving (6) and (15) in a part of (16), (1) and (2) are added and uniformly dispersed to form an aqueous phase. On the other hand, when (7) was added to the remaining (16) and heated and dissolved at 90 ° C., and (17) was added and dispersed with a homomixer, (8), (9), (10), (11 ), (14) is mixed, and the oil phase part heated and dissolved at 90 ° C. is added and emulsified with a homomixer to obtain a wax emulsified part. After adding the wax emulsified part to the aqueous phase at once, and uniformly mixing, add (12), (13), (5), (3), (4) in this order, and dissolve uniformly to obtain the desired hair styling for hair styling. A material (hair wax) was obtained.

Example 19
Ingredient (mass%)
(1) N-dimethylaminoethyl / alkyl acrylate / tripropylene glycol diacrylate copolymer 1.5
(Coscut GA467, Koscut GA468 (manufactured by Osaka Organic Chemical Industry Co., Ltd.))
(2) O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride 0.5
(Polymer JR-400 (manufactured by Union Carbide Japan))
(3) Vinylpyrrolidone / dimethylaminoethyl methacrylate copolymer diethyl sulfate (20% solution) 20.0
(Guff coat 755N (manufactured by ISP))
(4) Polyoxypropylene diglyceryl (9PO) 5.0
(5) Inositol 15.0
(6) Polyoxyethylene hydrogenated castor oil (40EO) 0.5
(7) Glyceryl stearate 0.2
(8) Carnavalou 5.0
(9) Cetyl 2-ethylhexylate 4.0
(10) Isododecane 2.0
(11) Phosphoric acid (adjusted to pH 5.0) Appropriate amount (12) Ethanol 10.0
(13) Fragrance 0.1
(14) Ion exchange water residue <Production method>
After dissolving (4) and (5) in a part of (14), (1) and (2) are added and uniformly dispersed, and then (11) is added and neutralized as an aqueous phase part. To do. On the other hand, the oil phase part obtained by mixing (6), (7), (8), (9), (10), (13) and heating and dissolving at 90 ° C. was heated to 90 ° C. 14) and emulsified with a homomixer to obtain a wax emulsified part. The wax emulsified part was added to the aqueous phase part at once, and after uniform mixing, (12) and (3) were added and dissolved uniformly to obtain the desired hair styling cosmetic (hair cream).

Example 20
Ingredient (mass%)
(1) Polyoxyethylene decyl tetradecyl ether (20EO) / hexamethylene diisocyanate / polyoxyethylene glycol (240EG) copolymer
1.0
(2) Acrylic acid / alkyl acrylate (C10-30) copolymer 0.3
(PEMULEN TR-2 (BFGoodrich Chemical Company))
(3) Alkyl acrylate diacetone acrylamide copolymer (40% solution)
(Plus size L-9909B (manufactured by Reciprocal Chemical Co., Ltd.)) 15.0
(4) Propylene glycol 2.0
(5) Erythritol 4.0
(6) Polyoxyethylene glyceryl isostearate (20EO) 1.0
(7) Stearic acid 0.5
(8) Beeswaw 4.0
(9) Polyethylene wax 1.0
(10) Diisostearyl malate 2.5
(11) Decamethyltetrasiloxane 5.0
(12) Arginine (adjusted to pH 7.0) Appropriate amount (13) Ethanol 5.0
(14) Fragrance 0.1
(15) edetate trisodium 0.03
(16) Ion-exchanged water Residual (17) Poly (oxyethylene / oxypropylene) / methylpolysiloxane copolymer (FZ-2222 (manufactured by Toray Dow Corning Co., Ltd.) 1.0
<Production method>
(5), (15) is dissolved in a part of (16), and then (2) is added and uniformly dispersed to obtain an aqueous phase. On the other hand, when (4), (1), (12) was added to the remaining (16) and heated and dissolved at 80 degrees, (6), (7), (8), (9), (10), (11), and (14) are mixed and the oil phase part which heated and melt | dissolved at 90 degreeC is added, and it emulsifies with a homomixer, and is set as a wax emulsification part. The wax emulsified part is added to the aqueous phase part at a stretch and mixed uniformly, and then (17) is dissolved in (13) and then added, and then (3) is added and uniformly dissolved to obtain the desired hair styling cosmetic for hair styling (hair Wax).

Example 21
Ingredient (mass%)
(1) Crosslinked N, N-dimethylacrylamide-2-acrylamido-2-methylpropanesulfonic acid sodium copolymer 0.7
(2) Xanthan gum 0.3
(Celtrol (Made by Celtic))
(3) Polyurethane-10 (20% solution) 15.0
(Yodosol PUD (made by NSC Corporation))
(4) Vinylpyrrolidone / vinyl acetate copolymer 8.0
(PVP / VA S-630 (manufactured by General Aniline Film))
(5) Diglycerin 3.0
(6) Hydroxyethylurea 2.0
(7) Sucrose 5.5
(8) Polyoxyethylene hydrogenated castor oil (40EO) 0.5
(9) Isostearic acid 0.2
(10) Carnauba wax 2.5
(11) Microcrystalline wax 0.5
(12) Diethylhexyl succinate 1.5
(13) Polyoxyethylene polyoxypropylene oligosuccinate (3EO, 20PO) 1.0
(Esthe Mall 50 (Nisshin Oillio Co., Ltd.))
(14) Hydrolyzed wheat protein extract 0.5
(Cropeptide W (Croda)
(15) Ethanol 10.0
(16) Fragrance 0.1
(17) Ion exchange water Residual (18) Kaolin 1.0
<Production method>
(5), (6), and (7) are dissolved in a part of (17), and then (1) and (2) are added and uniformly dispersed to form an aqueous phase. On the other hand, when the remaining (17) is heated and dissolved at 90 ° C., (18) is added and uniformly dispersed using a homomixer, and (8), (9), (10), (11) , (12), (13), (16) are mixed, and the oil phase part heated and dissolved at 90 ° C. is added and emulsified with a homomixer to obtain a wax emulsified part. After the wax emulsified part is added to the aqueous phase at once, and uniformly mixed, (14), (15), (3), and (4) are added and uniformly dissolved to obtain the desired hair styling cosmetic (hair wax) Got.

Example 22
Ingredient (mass%)
(1) Octylamide acrylate / hydroxypropyl acrylate / butylaminoethyl methacrylate copolymer 2.0
(AMPHOMER LV-71 (made by NSC Corporation))
(2) Production Example 1 (40% solution) of JP-A-2006-213706 10.0
(3) 1,3-butylene glycol 3.0
(4) Polyethylene glycol (400) 2.0
(5) Mannitol 15.0
(6) Polyoxyethylene polyoxypropylene behenyl ether (15EO, 1PO)
3.0
(7) Sodium cocoamphoacetate 2.0
(8) Carnauba 1.2
(9) Liquid paraffin 0.6
(10) Ion exchange water Residue (11) 2-Amino-2-methyl-1-propanol (adjusted to pH 8.0)
Appropriate amount <Production method>
(3), (4), (5), (11) is dissolved in a part of (10), and then (1) is added and uniformly dissolved in the aqueous phase. On the other hand, part of (10), (6), (7), (8), (9) were heated and uniformly dissolved at 90 degrees, and then part of (10) was added as cold water to 35 ° C. After cooling, a wax dispersion was obtained. This dispersion part (2) was added to the aqueous phase part, and after uniform mixing, a stock solution for hair foam was obtained. 90 parts of this stock solution was packed in an aerosol can, valved, and 10 parts of liquefied petroleum gas (LPG) was filled to obtain a styling foam.

  ADVANTAGE OF THE INVENTION According to this invention, the hairdressing cosmetics which have sufficient arrangement power while having high setting power can be provided. The present invention is a hair styling cosmetic that brilliantly solves the technical problems that conflict with the prior art, and is a hair cosmetic that is extremely useful as a hairstyle product that meets the needs of consumers in recent years.

Claims (3)

In hairdressing cosmetics containing a film-forming polymer and a sugar alcohol ,
(A) 1-15% by mass of film-forming polymer
(B) 0.5-30 mass% sugar alcohol
(C) 0.2-15% by mass of wax containing an ester bond
(D) It contains liquid oil, and the mass ratio of (E) (A) component and (B) component content is (B) / (A) = 1 / 2-3
(F) Mass ratio of content of (A) component and (C) component is (C) / (A) = 1 / 5-1
(G) Mass ratio of content of (C) component and (D) component is (D) / (C) = 1 / 2-3 / 2
A hair styling cosmetic composition, characterized in that it is,
The film-forming polymer (A) is methacryloyloxyethylcarboxybetaine / alkyl methacrylate copolymer, vinylpyrrolidone / methacrylamide / vinylimidazole copolymer, N-dimethylaminoethyl / alkyl acrylate / tripropylene glycol diacrylate. Copolymer, vinyl pyrrolidone / dimethylaminoethyl methacrylate copolymer diethyl sulfate, alkyl acrylate / diacetone acrylamide copolymer, polyurethane-10, vinyl pyrrolidone / vinyl acetate copolymer, octyl amide / acrylic acid It is either a hydroxypropylpropyl / butylaminoethyl methacrylate copolymer,
(B) The hair styling cosmetic characterized in that the sugar alcohol is any one of mannitol, xylitol, erythritol, sorbitol, maltitol, and inositol.   The hair styling according to claim 1, wherein the wax containing (C) an ester bond is candelilla wax, and the liquid oil (D) is pentaerythrityl tetraethylhexanoate having an ester bond. Cosmetics. The hair styling cosmetic composition according to claim 1 or 2, further comprising (H) a volatile oil component.