JP2006324247A - 高分子電解液組成物、高分子電解液及びそれを含む染料感応太陽電池とその製造方法 - Google Patents
高分子電解液組成物、高分子電解液及びそれを含む染料感応太陽電池とその製造方法 Download PDFInfo
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- JP2006324247A JP2006324247A JP2006136844A JP2006136844A JP2006324247A JP 2006324247 A JP2006324247 A JP 2006324247A JP 2006136844 A JP2006136844 A JP 2006136844A JP 2006136844 A JP2006136844 A JP 2006136844A JP 2006324247 A JP2006324247 A JP 2006324247A
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- dye
- polymer electrolyte
- solar cell
- sensitized solar
- electrode
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/20—Light-sensitive devices
- H01G9/2004—Light-sensitive devices characterised by the electrolyte, e.g. comprising an organic electrolyte
- H01G9/2009—Solid electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M14/00—Electrochemical current or voltage generators not provided for in groups H01M6/00 - H01M12/00; Manufacture thereof
- H01M14/005—Photoelectrochemical storage cells
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Abstract
【解決手段】本発明によれば、側鎖に一つ以上のエチレングリコールを有する単官能性または多官能性の単量体、重合開始剤、リチウム塩、及び有機溶媒を含む染料感応太陽電池用の高分子電解液組成物が提供される。本発明の高分子電解液組成物は、高分子電解液を構成する酸化−還元電解質の揮発可能性を最小化して太陽電池の外部温度の上昇のような外部環境の変化に対して安定した光電気化学的特性を提供できる。
【選択図】図2B
Description
第1電極としては、ガラス基板上にフッ素含有酸化スズ(FTO)がコーティングされたものを準備した後、ドクターブレード法を利用して、約18μmほどのTiO2膜を蒸着した。蒸着されたTiO2膜を450℃で30分間熱処理した後、エタノールに0.3mMRu(4,4’−dicarboxy−2,2’−bipyridine)2(NCS)2染料が溶解された染料色素液内に浸漬させて、染料吸着処理を24時間以上行った。
第1電極としては、ガラス基板上にフッ素含有酸化スズ(FTO)がコーティングされたものを準備した後、ドクターブレード法を利用して約18μmほどのTiO2膜を蒸着した。蒸着されたTiO2膜を450℃で30分間熱処理した後、エタノールに0.3mMRu(4,4’−dicarboxy−2,2’−bipyridine)2(NCS)2染料が溶解された染料色素液内に浸漬させて、染料吸着処理を24時間以上行った。
24 高分子層
25 第1電極
26 第2電極
Claims (18)
- 側鎖に一つ以上のエチレングリコールを有する単官能性または多官能性の単量体と、重合開始剤と、リチウム塩と、有機溶媒と、を含むことを特徴とする、染料感応太陽電池用の高分子電解液組成物。
- 前記単官能性または多官能性の単量体は、メチル(メタ)アクリレート、エチル(メタ)アクリレート、メタキシエチル(メタ)アクリレート、エトキシエチル(メタ)アクリレート、ビニルアセテート、ビニルピバレート、ビニルプロピオネート、ビニルピリジン、ビニルピロリドン、ポリエチレングリコールジアクリレート、ポリエチレングリコールジメタクリレート、ジエチレングリコール−2−エチルへキシルエーテルアクリレート、ビニルアクリレート、トリメチロールプロパントリ(メタ)アクリレート及びその誘導体、ペンタエリスリトールテトラ(メタ)アクリレート及びその誘導体、並びに、ジペンタエリスリトールヘキサ(メタ)アクリレートからなる群から選択されることを特徴とする、請求項1に記載の染料感応太陽電池用の高分子電解液組成物。
- 前記単官能性または多官能性の単量体の添加量は、高分子電解液100質量部を基準として1〜10質量部であることを特徴とする、請求項1に記載の染料感応太陽電池用の高分子電解液組成物。
- 前記ジエチレングリコール−2−エチルへキシルエーテルアクリレートの添加量は、高分子電解液100質量部を基準として1〜10質量部であることを特徴とする、請求項2に記載の染料感応太陽電池用の高分子電解液組成物。
- 前記単官能性または多官能性の単量体の質量平均分子量は、100〜1,000であることを特徴とする、請求項1に記載の染料感応太陽電池用の高分子電解液組成物。
- 前記重合開始剤は、ベンゾイルパーオキサイド、アゾビスイソブチロニトリル、ベンゾフェノン、アセトフェノン、ベンゾインメチルエーテル、及びベンゾインエチルエーテルからなる群から選択された一つ以上であることを特徴とする、請求項1に記載の染料感応太陽電池用の高分子電解液組成物。
- 前記重合開始剤の添加量は、高分子電解液100質量部を基準として0.05〜0.2質量部であることを特徴とする、請求項1に記載の染料感応太陽電池用の高分子電解液組成物。
- 前記リチウム塩は、LiPF6、LiBF4、LiClO4、Li(CF3SO2)2、LiCF3SO3、LiSbF6及びLiAsF6からなる群から選択される何れか一つであることを特徴とする、請求項1に記載の染料感応太陽電池用の高分子電解液組成物。
- 前記リチウム塩の濃度は、0.4〜1.5Mであることを特徴とする、請求項1に記載の染料感応太陽電池用の高分子電解液組成物。
- 前記有機溶媒は、アセトニトリル、エチレングリコール、ブタノール、イソブチルアルコール、イソペンチルアルコール、イソプロピルアルコール、エチルエーテル、ジオキサン、テトラヒドロフラン、n−ブチルエーテル、プロピルエーテル、イソプロピルエーテル、アセトン、メチルエチルケトン、メチルブチルケトン、イソブチルケトン、エチレンカーボネート(EC)、ジエチルカーボネート(DEC)、プロピレンカーボネート(PC)、ジメチルカーボネート(DMC)、エチルメチルカーボネート(EMC)、γ−ブチロラクトン(GBL)、N−メチル−2−ピロリドン及び3−メタキシプロピオニトリル(MP)からなる群から選択された一つ以上であることを特徴とする、請求項1に記載の染料感応太陽電池用の高分子電解液組成物。
- 前記有機溶媒の含量は、電解液組成物全体の含量を基準として10〜90質量部であることを特徴とする、請求項1に記載の染料感応太陽電池用の高分子電解液組成物。
- 可塑剤として、エチレンカーボネートまたはプロピレンカーボネートをさらに含むことを特徴とする、請求項1に記載の染料感応太陽電池用の高分子電解液組成物。
- ジエチレングリコール−2−エチルへキシルエーテルアクリレート、安息香酸エチルエーテル、LiClO4、及びエチレンカーボネートを含むことを特徴とする、請求項1に記載の染料感応太陽電池用の高分子電解液組成物。
- 請求項1〜13の何れか1項に記載の高分子電解液組成物を重合して得られる太陽電池用の高分子電解液。
- 前記重合された高分子電解液は、液体電解液をさらに含むことを特徴とする、請求項14に記載の太陽電池用の高分子電解液。
- 前記液体電解液は、リチウム塩または有機溶媒であることを特徴とする、請求項15に記載の太陽電池用の高分子電解液。
- 第1電極を設け、前記第1電極の上部に多孔質膜を形成するステップと、
前記多孔質膜を一定の間隔をおいて、ガラスを覆ってセルを形成するステップと、
前記多孔質膜と前記ガラスとの間に、側鎖に一つ以上のエチレングリコールを有する単官能性または多官能性の単量体、重合開始剤、リチウム塩、及び有機溶媒を含む高分子電解液組成物を注入し、重合するステップと、
前記セルを分解し、前記多孔質膜及び重合された高分子電解液組成物と一定の間隔をおいて第2電極を形成するステップと、
前記第2電極に微細孔を形成し、前記微細孔を通じて液体電解液を注入するステップと、
を含むことを特徴とする、染料感応太陽電池の製造方法。 - 相互対向した第1電極及び第2電極と、
前記第1電極と前記第2電極との間に介在され、染料が吸着されている多孔質膜と、
前記第1電極と前記第2電極との間に介在された請求項13に記載の高分子電解液と、
を含むことを特徴とする、染料感応太陽電池。
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KR101034618B1 (ko) * | 2007-12-13 | 2011-05-12 | 한국에너지기술연구원 | 자외선 경화형 우레탄아크릴레이트를 포함하는 염료감응태양전지용 겔형 고분자 전해질, 이를 포함하는 염료감응태양전지 및 염료감응 태양전지의 제조방법 |
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JP5785030B2 (ja) * | 2011-08-18 | 2015-09-24 | 株式会社Screenホールディングス | 全固体電池の製造方法 |
CN103489645B (zh) * | 2013-09-02 | 2016-08-17 | 常州大学 | 一种染料敏化太阳能电池用凝胶电解质及其制备方法 |
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