JP2006117676A5 - - Google Patents
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- Publication number
- JP2006117676A5 JP2006117676A5 JP2005305219A JP2005305219A JP2006117676A5 JP 2006117676 A5 JP2006117676 A5 JP 2006117676A5 JP 2005305219 A JP2005305219 A JP 2005305219A JP 2005305219 A JP2005305219 A JP 2005305219A JP 2006117676 A5 JP2006117676 A5 JP 2006117676A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- nickel
- mixture
- weight
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000007868 Raney catalyst Substances 0.000 description 2
- 229910000564 Raney nickel Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- -1 Raney copper) Chemical compound 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Description
適当な触媒は、好ましくは、ニッケル触媒単独、並びにニッケル（ラネーニッケルも含む）と他の金属との混合物である。前記の他の金属としては、例えば、パラジウム、白金、コバルト、ロジウム、イリジウム、鉄、ルテニウム、オスミウム、マンガン、レニウム、クロム、モリブデン、銅（ラネー銅も含む）またはビスマスなどが挙げられる。前記混合物は、不均一系でもよいし、または触媒表面へのドーパントでもよい。担体材料は特に制限はない。適当な担体材料は、例えば、アルミナ及び他の金属酸化物、炭素、ケイ藻土、二酸化ケイ素、炭化ケイ素、ゼオライト及びこれらの類似物などである。好ましくは、ラネーニッケルと、活性炭に担持させたパラジウムとの混合物が使用される。触媒の使用量は広い範囲で変えることができる。通常は、式（Ｉ）の化合物の使用量を基準にして０．２〜１５重量％、好ましくは０．５〜１０重量％の触媒が存在するように、十分な触媒が使用される。
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004051267A DE102004051267B3 (de) | 2004-10-21 | 2004-10-21 | Verfahren zur kontinuierlichen Herstellung von Alkylenglykoldiethern |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2006117676A JP2006117676A (ja) | 2006-05-11 |
| JP2006117676A5 true JP2006117676A5 (ja) | 2008-12-04 |
Family
ID=35447947
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2005305219A Ceased JP2006117676A (ja) | 2004-10-21 | 2005-10-20 | アルキレングリコールジエーテルの連続的製造方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20060089515A1 (ja) |
| EP (1) | EP1650181A1 (ja) |
| JP (1) | JP2006117676A (ja) |
| CN (1) | CN100595179C (ja) |
| DE (1) | DE102004051267B3 (ja) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103641695A (zh) * | 2013-12-18 | 2014-03-19 | 河南能源化工集团研究院有限公司 | 乙二醇为原料联产乙二醇乙醚及乙二醇二乙醚的方法 |
| CN106554258B (zh) | 2015-09-30 | 2019-07-26 | 中国科学院大连化学物理研究所 | 由乙二醇单甲醚直接制备乙二醇二甲醚并联产乙二醇的方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3428692A (en) * | 1966-02-28 | 1969-02-18 | Continental Oil Co | Preparation of nonionic detergents |
| DE2434057C2 (de) * | 1974-07-16 | 1982-08-19 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von Glykoldimethyläthern |
| DE2640505C2 (de) * | 1976-09-09 | 1978-08-31 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von Aethern |
| DE2900279A1 (de) * | 1979-01-05 | 1980-07-24 | Hoechst Ag | Verfahren zur herstellung von methylethern |
| DE3025434C2 (de) * | 1979-07-04 | 1982-09-16 | Nisso Petrochemical Industry Co., Ltd., Tokyo | Verfahren zur Herstellung von Alkylenglykoldiäthern |
| JPS568338A (en) * | 1979-07-04 | 1981-01-28 | Nisso Yuka Kogyo Kk | Preparation of ether |
| US4308402A (en) * | 1979-11-20 | 1981-12-29 | Shell Oil Company | Process for methyl-capped alkoxylates |
| DE3025190C1 (de) * | 1980-07-03 | 1987-01-02 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von methylblockierten Ethoxylaten |
| DE3128962A1 (de) * | 1981-07-22 | 1983-02-10 | Hoechst Ag, 6000 Frankfurt | "verfahren zur herstellung von alkylenglykoldiethern |
| CA1219285A (en) * | 1981-09-30 | 1987-03-17 | Union Carbide Corporation | Hydrogenolysis process for the production of monoethylene glycol monomethyl ether, monoethylene glycol and ethanol |
| JPS6028429A (ja) * | 1983-07-26 | 1985-02-13 | Nippon Shokubai Kagaku Kogyo Co Ltd | ポリエチレングリコ−ルジアルキルエ−テル製造用触媒 |
| DE3802783A1 (de) * | 1988-01-30 | 1989-08-10 | Hoechst Ag | Verfahren zur herstellung von alkylenglykoldialkylethern |
| JPH03197435A (ja) * | 1989-12-27 | 1991-08-28 | Mitsui Toatsu Chem Inc | エーテル化合物の製造法 |
| DE102006010940A1 (de) * | 2006-03-09 | 2007-09-13 | Clariant International Limited | Verfahren zur Herstellung von längerkettigen Polyalkylenglykoldiethern |
-
2004
- 2004-10-21 DE DE102004051267A patent/DE102004051267B3/de not_active Expired - Fee Related
-
2005
- 2005-09-15 CN CN200510104065.1A patent/CN100595179C/zh not_active Expired - Fee Related
- 2005-10-11 EP EP05022109A patent/EP1650181A1/de not_active Withdrawn
- 2005-10-20 JP JP2005305219A patent/JP2006117676A/ja not_active Ceased
- 2005-10-21 US US11/256,126 patent/US20060089515A1/en not_active Abandoned
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