JP2005538228A - ナノ複合材料、その製造方法およびその用途 - Google Patents
ナノ複合材料、その製造方法およびその用途 Download PDFInfo
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- JP2005538228A JP2005538228A JP2004535003A JP2004535003A JP2005538228A JP 2005538228 A JP2005538228 A JP 2005538228A JP 2004535003 A JP2004535003 A JP 2004535003A JP 2004535003 A JP2004535003 A JP 2004535003A JP 2005538228 A JP2005538228 A JP 2005538228A
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/005—Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/28—Compounds of silicon
- C09C1/30—Silicic acid
- C09C1/3081—Treatment with organo-silicon compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3684—Treatment with organo-silicon compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
- C09J167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/54—Inorganic substances
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Nanotechnology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Silicon Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10241510A DE10241510A1 (de) | 2002-09-07 | 2002-09-07 | Nanokomposite, Verfahren zu ihrer Herstellung und ihre Verwendung |
| PCT/DE2003/002933 WO2004024811A2 (de) | 2002-09-07 | 2003-09-04 | Nanokomposite, verfahren zu ihrer herstellung und ihre verwendung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2005538228A true JP2005538228A (ja) | 2005-12-15 |
| JP2005538228A5 JP2005538228A5 (https=) | 2006-07-20 |
Family
ID=31724496
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004535003A Withdrawn JP2005538228A (ja) | 2002-09-07 | 2003-09-04 | ナノ複合材料、その製造方法およびその用途 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20060084723A1 (https=) |
| EP (1) | EP1525227A2 (https=) |
| JP (1) | JP2005538228A (https=) |
| AU (1) | AU2003266194A1 (https=) |
| DE (2) | DE10241510A1 (https=) |
| WO (1) | WO2004024811A2 (https=) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008502817A (ja) * | 2004-06-14 | 2008-01-31 | カダント ウェブ システムズ インコーポレイテッド | 抄紙機に使用する平面エレメント |
| JP2010538107A (ja) * | 2007-08-31 | 2010-12-09 | キャボット コーポレイション | 変性された金属酸化物のナノ粒子分散液の調製方法 |
| JP2011514306A (ja) * | 2008-02-29 | 2011-05-06 | ピルキントン グループ リミテッド | 耐火性窓ガラス |
| JP2012530041A (ja) * | 2009-06-16 | 2012-11-29 | ピルキントン グループ リミテッド | 積層構造体 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| DE10326538A1 (de) | 2003-06-12 | 2005-01-05 | Institut für Neue Materialien Gemeinnützige GmbH | Abriebfeste optische Schichten und Formkörper |
| DE102004008202A1 (de) * | 2004-02-18 | 2005-09-01 | Basf Ag | Komposites aus Thermoplasten mit monodispers verteilten Füllstoffen |
| DE102004010504B4 (de) * | 2004-03-04 | 2006-05-04 | Degussa Ag | Hochtransparente lasermarkierbare und laserschweißbare Kunststoffmaterialien, deren Verwendung und Herstellung sowie Verwendung von Metallmischoxiden und Verfahren zur Kennzeichnung von Produktionsgütern |
| EP1751796A1 (en) * | 2004-05-20 | 2007-02-14 | General Electric Company, (a New York Corporation) | Organic matrices containing nanomaterials to enhance bulk thermal conductivity |
| EP1805260B1 (en) * | 2004-10-27 | 2009-10-14 | E.I. Du Pont De Nemours And Company | Self-bonding coating composition |
| US7704586B2 (en) * | 2005-03-09 | 2010-04-27 | Degussa Ag | Plastic molded bodies having two-dimensional and three-dimensional image structures produced through laser subsurface engraving |
| WO2006111492A2 (en) * | 2005-04-19 | 2006-10-26 | Ciba Specialty Chemicals Holding Inc. | Polyether polyols, polyester polyols and polyurethanes of low residual aldehyde content |
| DE102005022782A1 (de) * | 2005-05-12 | 2006-11-16 | Tesa Ag | Haftklebemassen und Verfahren zu deren Herstellung |
| CN101184803B (zh) * | 2005-05-27 | 2013-11-06 | 西巴特殊化学品控股有限公司 | 官能化的纳米颗粒 |
| CA2616231C (en) | 2005-08-25 | 2013-02-05 | E. I. Dupont De Nemours And Company | Process for the production of a scratch resistant vehicle coating |
| JP5541864B2 (ja) | 2005-08-25 | 2014-07-09 | コーティングス フォーリン アイピー カンパニー, エルエルシー | 変性ナノ粒子 |
| KR100824545B1 (ko) | 2006-04-21 | 2008-04-23 | 요업기술원 | 에스테르계 알칼리 가용성 화합물이 결합된 세라믹 나노입자를 포함하는 심색성이 우수한 폴리에스테르 수지조성물 |
| US7846492B2 (en) * | 2006-04-27 | 2010-12-07 | Guardian Industries Corp. | Photocatalytic window and method of making same |
| EP2027224A2 (en) * | 2006-06-14 | 2009-02-25 | E.I. Du Pont De Nemours And Company | Coated substrate having enhanced scratch and mar resistance |
| DE102007021199B4 (de) * | 2006-07-17 | 2016-02-11 | Evonik Degussa Gmbh | Zusammensetzungen aus organischem Polymer als Matrix und anorganischen Partikeln als Füllstoff, Verfahren zu deren Herstellung sowie deren Verwendung und damit hergestellte Formkörper |
| EP1884532A1 (en) * | 2006-07-31 | 2008-02-06 | Italdry S.r.L. | Process to produce a nanocomposite material and nanocomposite material produced with said process |
| DE102006039638B3 (de) * | 2006-08-24 | 2007-11-15 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Nanofüllstoffe, Nanokomposite aus einem organischen Bindemittel und oberflächenmodifizierten Nanofüllstoffen, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE102006061057A1 (de) * | 2006-12-22 | 2008-06-26 | Wacker Chemie Ag | Organofunktionelle Silikonharzschichten auf Metalloxiden |
| WO2008107304A2 (en) * | 2007-03-05 | 2008-09-12 | Basf Se | Surface-modified nanoparticles comprising a cationic colorant for use in color filters |
| WO2008145585A1 (de) * | 2007-05-25 | 2008-12-04 | Basf Se | Verfahren zur verteilung von silikaten in beschichtungsmassen |
| DE102007044302A1 (de) | 2007-09-17 | 2009-03-19 | Bühler PARTEC GmbH | Verfahren zur Dispergierung von feinteiligen anorganischen Pulvern in flüssigen Medien unter Verwendung von reaktiven Siloxanen |
| DE102010044563B4 (de) | 2010-09-07 | 2015-04-09 | Fachhochschule Lübeck | Stabile Dispersionen |
| DK2638090T3 (da) * | 2010-11-11 | 2015-05-04 | Dow Global Technologies Llc | Polyurethanbaseret tætningsmiddel til isoleret glas |
| US9963595B2 (en) | 2011-05-18 | 2018-05-08 | Axalta Coating Systems Ip Co., Llc | Coating composition and method for producing powder coating |
| ITMI20111273A1 (it) * | 2011-07-08 | 2013-01-09 | Fond Cariplo | Polimeri ramificati di acido lattico ad alta viscosita' nel fuso e alta shear sensitivity e loro nano compositi |
| WO2015055280A1 (en) * | 2013-10-15 | 2015-04-23 | Merck Patent Gmbh | Coated silica particles for ink-jet printing of organic electronic devices, a method for their production and devices produced therewith |
| CN114657546B (zh) * | 2022-04-07 | 2022-11-15 | 武汉铁路职业技术学院 | 一种用于铁路轨道预埋件的防腐蚀处理工艺 |
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| US5081164A (en) * | 1990-04-17 | 1992-01-14 | Lai Laboratories, Inc. | Organosilicon dental composite restorative materials |
| WO1993011190A1 (en) * | 1991-11-26 | 1993-06-10 | Allied-Signal Inc. | Polymer nanocomposites formed by melt processing of a polymer and an exfoliated layered material derivatized with reactive organo silanes |
| ATE196919T1 (de) * | 1994-02-02 | 2000-10-15 | Mitsubishi Rayon Co | Beschichtungszusammensetzung und daraus hergestellte oberflächenbeschichtete form |
| EP0753549A3 (de) * | 1995-06-28 | 1999-04-28 | Bayer Ag | Oberflächenmodifizierte, oxidische oder silikatische Füllstoffe und ihre Verwendung |
| US6852252B2 (en) * | 1997-03-12 | 2005-02-08 | William Marsh Rice University | Use of metalnanoshells to impede the photo-oxidation of conjugated polymer |
| US7144627B2 (en) * | 1997-03-12 | 2006-12-05 | William Marsh Rice University | Multi-layer nanoshells comprising a metallic or conducting shell |
| US6344272B1 (en) * | 1997-03-12 | 2002-02-05 | Wm. Marsh Rice University | Metal nanoshells |
| JP3972347B2 (ja) * | 1997-03-28 | 2007-09-05 | Jsr株式会社 | 液状硬化性樹脂組成物 |
| US6699724B1 (en) * | 1998-03-11 | 2004-03-02 | Wm. Marsh Rice University | Metal nanoshells for biosensing applications |
| US6428811B1 (en) * | 1998-03-11 | 2002-08-06 | Wm. Marsh Rice University | Temperature-sensitive polymer/nanoshell composites for photothermally modulated drug delivery |
| DE19846660A1 (de) * | 1998-10-09 | 2000-04-13 | Inst Oberflaechenmodifizierung | Hochtemperaturbeständige polymerisierbare Metalloxidpartikel |
| BR0113999A (pt) * | 2000-09-21 | 2003-08-12 | Rohm & Haas | Processo para preparar uma dispersão polimérica aquosa nanocompósita de argila, dispersão nanocompósita aquosa, espessador, dispersante, aglutinante, composição de tinta flexográfica, verniz de sobre impressão, modificador de pó de cimento seco, semente polimérica nanocompósita de argila, composição polimérica nanocompósita de argila, e, método para preparar uma pluralidade de partìculas poliméricas nanocompósitas de argila ocas |
| US6914095B2 (en) * | 2000-09-21 | 2005-07-05 | Rohm And Haas Company | Nanocomposite compositions and methods for making and using same |
| EP1322675A2 (en) * | 2000-09-21 | 2003-07-02 | Rohm And Haas Company | Hydrophobically modified clay polymer nanocomposites |
| DE60227518D1 (de) * | 2001-05-31 | 2008-08-21 | Gordon L Nelson | Organisch/anorganische nanoverbundgegenstände erhältlich durch extrusion |
| KR100628841B1 (ko) * | 2001-11-13 | 2006-09-29 | 데구사 아게 | 분해가능한 경화성 결합조립체 |
| US20030148042A1 (en) * | 2001-12-28 | 2003-08-07 | Zhikai Wang | Ultrasonic method for the production of inorganic/organic hybrid nanocomposite |
| US6833186B2 (en) * | 2002-04-10 | 2004-12-21 | Ppg Industries Ohio, Inc. | Mineral-filled coatings having enhanced abrasion resistance and wear clarity and methods for using the same |
| US6790904B2 (en) * | 2002-06-03 | 2004-09-14 | Ppg Industries Ohio, Inc. | Liquid coating of film-forming resin and particles chemically modified to lower surface tension |
-
2002
- 2002-09-07 DE DE10241510A patent/DE10241510A1/de not_active Withdrawn
-
2003
- 2003-09-04 DE DE10393704T patent/DE10393704D2/de not_active Expired - Lifetime
- 2003-09-04 AU AU2003266194A patent/AU2003266194A1/en not_active Abandoned
- 2003-09-04 EP EP03794812A patent/EP1525227A2/de not_active Withdrawn
- 2003-09-04 WO PCT/DE2003/002933 patent/WO2004024811A2/de not_active Ceased
- 2003-09-04 JP JP2004535003A patent/JP2005538228A/ja not_active Withdrawn
-
2005
- 2005-03-04 US US11/071,258 patent/US20060084723A1/en not_active Abandoned
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008502817A (ja) * | 2004-06-14 | 2008-01-31 | カダント ウェブ システムズ インコーポレイテッド | 抄紙機に使用する平面エレメント |
| JP4860607B2 (ja) * | 2004-06-14 | 2012-01-25 | カダント インコーポレイテッド | 抄紙機に使用する平面エレメント |
| JP2010538107A (ja) * | 2007-08-31 | 2010-12-09 | キャボット コーポレイション | 変性された金属酸化物のナノ粒子分散液の調製方法 |
| JP2011514306A (ja) * | 2008-02-29 | 2011-05-06 | ピルキントン グループ リミテッド | 耐火性窓ガラス |
| JP2012530041A (ja) * | 2009-06-16 | 2012-11-29 | ピルキントン グループ リミテッド | 積層構造体 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2004024811A3 (de) | 2004-09-16 |
| EP1525227A2 (de) | 2005-04-27 |
| DE10393704D2 (de) | 2005-07-21 |
| AU2003266194A8 (en) | 2004-04-30 |
| WO2004024811A2 (de) | 2004-03-25 |
| US20060084723A1 (en) | 2006-04-20 |
| DE10241510A1 (de) | 2004-03-18 |
| AU2003266194A1 (en) | 2004-04-30 |
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