JP2005516800A - ポリエステル若しくはコポリエステル/ポリオレフィン積層構造及びその製造方法 - Google Patents
ポリエステル若しくはコポリエステル/ポリオレフィン積層構造及びその製造方法 Download PDFInfo
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
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- B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
- B32B2309/08—Dimensions, e.g. volume
- B32B2309/10—Dimensions, e.g. volume linear, e.g. length, distance, width
- B32B2309/105—Thickness
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Abstract
Description
の組成を有するアルキルアクリレート、アルキルメタクリレート又はそれの組合せから成ることができる。コポリマー中のアクリレート又はメタクリレート成分の量は、コポリマーの約1〜約60重量%、又は約3〜約30重量%、又は約5〜約25重量%であることができる。更にまた、コポリマー成分中のアクリレート又はメタクリレート成分の量は約1から、3、5、7、10、15、20、25、30、35、40、45、50、55又は60重量%であることができ、必要に応じて、いずれの値も上端点又は下端点として使用できる。使用できる具体的なアルキルアクリレートは、アクリル酸又はメタクリル酸のメチル、エチル、プロピル及びブチルエステルであることができる。本明細書中で使用する、コポリマー中のアクリレート又はメタクリレート成分の量は、アルキル基を含むアクリレートの総重量%として測定される。
コポリエステルシート(Spectar(商標),Eastman Chemical Co.,Kingsport,NY)の12”×12”のパネルに、EVAフィルム(Adhesive Films,Inc.)の2.5mil層2層からなるエチレンビニルアセテート(EVA)タイ層と共に、ポリエチレンを基材とする布(Xorel(商標),Carnegie Fabrics,New York,NY)を積層した。このコポリエステルパネルから、幅1”×長さ6”のストリップを切り取り、その先端を金属クランプ1”で水平に支持した。次いで、サンプルの露出端を、ガス圧3psiのブンゼンバーナーからの火炎に20秒間暴露した(布側を下にして)。その間に、パネルの着火が始まった。20秒後に、ブンゼン火炎を除去し、以下の観察を記録した:
・T=9秒:布表面に火炎の伝搬が観察される。火炎がサンプルの表面に沿って移動し始める。コポリエステル層の着火は観察されない。
・T=18秒:コポリエステル層に着火する。火炎はサンプル表面に沿って移動し続けるので、2相の燃焼が観察される。布に着火し、滴り落ちている。
・T=20秒:ブンゼン火炎をサンプルから除去する。
・T=22秒:着火コポリエステルが滴り落ち、次いで露出端で消炎する。火炎は表面に沿って移動し続ける。
・T=50秒:表面火炎がサンプルのクランプ端に達し、試験を終わらせる。
コポリエステルシート(Spectar)の12”×12”のパネルに、EVAフィルム(Adhesive Films,Inc.)の単一の2.5mil層からなるエチレンビニルアセテート(EVA)タイ層と共に、ポリエチレンを基材とする布(Xorel)を積層した。このパネルから、幅1”×長さ6”のストリップを切り取り、その先端を金属クランプ1”で水平に支持した。次いで、サンプルの露出端を、ガス圧3psiのブンゼンバーナーからの火炎に20秒間暴露した(布側を下にして)。その間に、サンプルの着火が始まった。20秒後に、ブンゼン火炎を除去し、以下の観察を記録した:
・T=8秒:布表面に火炎の伝搬が観察される。火炎がサンプルの表面に沿って移動し始める。コポリエステル層の着火は観察されない。
・T=15秒:コポリエステル層の着火はない。火炎は布表面に沿って移動し続ける。布に着火し、滴り落ちている。
・T=19秒:コポリエステル層に着火する。2相燃焼が観察される。火炎がサンプル表面に沿って移動し続ける。布に着火し、滴り落ちている。
・T=20秒:ブンゼン火炎をサンプルから除去する。コポリエステルが滴り落ち、露出端で消炎する。火炎の前方は表面に沿って前進し続ける。
・T=38秒:表面火炎がサンプルのクランプ端に達し、試験を終わらせる。
押出Spectarコポリエステルの基層並びにEVAフィルム(Adhesive Films,Inc.製)の接着層及びXorel布(Carnegie Fabrics製)を有する全厚1/8”の積層体を形成し、ASTM D 635−98:Standard Test Method for Rate of Burning and/or Extent and Time of Burning of Self−supporting Plastics in a Horizontal Positionによる試験のために、SGS U.S. Testing Company(Fairfield,NJ)に送った。以下の結果が得られた。
注:燃焼速度は測定できなかった。
UBC Standard 26−7により、試験した材料はCC2分類に適合する。
コポリエステルシート(Spectar)の12”×12”のパネルに、EMAフィルムの単一の5mil層からなるエチレンメチルアクリレート(EMA;EMAC(商標)(Eastman Chemical Co.製))タイ層と共に、ポリエチレンを基材とする布(Xorel)を積層した。このパネルから、幅1”×長さ6”のストリップを切り取り、その先端を金属クランプ1”で水平に支持した。次いで、サンプルの露出端を、ガス圧3psiのブンゼンバーナーからの火炎に20秒間暴露した(布側を下にして)。その間に、サンプルの着火が始まった。20秒後に、ブンゼン火炎を除去し、以下の観察を記録した:
・T=19秒:コポリエステル層に着火する。火炎はサンプルの露出端に残っている。
・T=20秒:ブンゼン火炎をサンプルから除去する。コポリエステルが滴り落ちるが、また消炎しない。火炎は広がらない。
・T=29秒:サンプルが完全に消炎する。露出端を越える火炎の広がりは観察されない。
押出Spectarコポリエステルの基層(base layer)並びにEMAフィルム(Eastman Chemical Company製のEMAC樹脂から製造)の接着層及びXorel布(Carnegie Fabrics製)を有する全厚1/8”の積層体を形成し、ASTM D 635−98の試験:Standard Test Method for Rate of Burning and/or Extent and Time of Burning of Self−supporting Plastics in a Horizontal Positionによる試験のために、SGS U.S. Testing Companyに送った。以下の結果が得られた。
UBC Standard 26−7により、試験した材料はCC1分類に適合する。
*平均後に、5の最も近い倍数に丸めた。
Claims (18)
- a)ポリエステル又はコポリエステルを含んでなり、内面及び外面を有する第1ポリマー層;
b)アルキルアクリレートコポリマーから本質的になり、第1ポリマー層の内面に隣接する第1面と第2面とを有するタイ層;並びに
c)ポリオレフィンを含む内面及び外面を有し、タイ層の第2面が第2ポリマー層の内面に隣接する第2ポリマー層
を含んでなるポリエステル又はコポリエステル/ポリオレフィン積層体。 - 前記積層体が、UBC 標準(Standard)26−7によって定義されたCC1分類が必要な用途に適している請求項1に記載の積層体。
- 前記タイ層がエチレン−アクリル酸メチルコポリマー、エチレン−アクリル酸エチルコポリマー、エチレン−アクリル酸ブチルコポリマー又はエチレン−メタクリル酸メチルコポリマーのうち1種又はそれ以上を含む請求項1に記載の積層体。
- 前記第2ポリマー層がポリエチレン、ポリプロピレン、ポリ−1−ブテン又はエチレンポリマーのうち1種又はそれ以上を含む請求項1に記載の積層体。
- 前記第2ポリマー層がポリエチレン織布、ポリエチレンフィルム又はポリエチレンシート材料を含む請求項1に記載の積層体。
- 前記第1ポリマー層が約0.080〜約0.250インチの厚さを有する請求項1に記載の積層体。
- 前記第2ポリマー層が約0.001〜約0.020インチの厚さを有する請求項1に記載の積層体。
- 前記タイ層が約0.0005〜約0.020インチの厚さを有する請求項1に記載の積層体。
- a)ポリエステル又はコポリエステルを含んでなり、内面及び外面を有する第1ポリマー層を用意し;
b)アルキルアクリレートコポリマーから本質的になり、第1面と第2面を有するタイ層を用意し;
c)ポリオレフィンを含み、内面及び外面を有する第2ポリマー層を用意し;
d)第1ポリマー層と第2ポリマー層との間で、第1ポリマー層の内面又は第2ポリマー層の内面のうち1つ又はそれ以上に、タイ層を適用して、第1ポリマー層と第2ポリマー層とを互いに隣接面接触させ、それによってプレラミネートを形成せしめ;そして
e)積層材料を形成するのに充分な熱及び/又は圧力を前記プレラミネートに適用する
ことを含んでなる積層体の製造方法。 - 前記タイ層をシートの形態で適用する請求項9に記載の方法。
- 前記タイ層を押出によって適用する請求項9に記載の方法。
- 前記積層体がUBC 標準(Standard)26−7によって定義されるCC1分類を必要とする用途に使用するのに適する請求項9に記載の方法。
- 前記アルキルアクリレートコポリマーがエチレン−アクリル酸メチルコポリマー、エチレン−アクリル酸エチルコポリマー、エチレン−アクリル酸ブチルコポリマー又はエチレン−メタクリル酸メチルコポリマーのうち1種又はそれ以上を含む請求項9に記載の方法。
- 前記第2ポリマー層がポリエチレン、ポリプロピレン、ポリ−1−ブテン又はエチレンポリマーのうち1種又はそれ以上を含む請求項9に記載の方法。
- 前記第2ポリマー層がポリエチレン織布、ポリエチレンフィルム又はポリエチレンシート材料を含む請求項9に記載の方法。
- 前記第1ポリマー層が約0.080〜約0.250インチの厚さを有する請求項9に記載の方法。
- 前記第2ポリマー層が約0.001〜約0.020インチの厚さを有する請求項9に記載の方法。
- 前記タイ層が約0.0005〜約0.020インチの厚さを有する請求項9に記載の方法。
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US35446902P | 2002-02-06 | 2002-02-06 | |
PCT/US2003/003237 WO2003066329A1 (en) | 2002-02-06 | 2003-02-03 | Polyester or copolyester/polyolefin laminate structures and methods of making the same |
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JP2005516800A true JP2005516800A (ja) | 2005-06-09 |
JP2005516800A5 JP2005516800A5 (ja) | 2006-03-09 |
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JP2003565734A Pending JP2005516800A (ja) | 2002-02-06 | 2003-02-03 | ポリエステル若しくはコポリエステル/ポリオレフィン積層構造及びその製造方法 |
Country Status (5)
Country | Link |
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US (1) | US7037576B2 (ja) |
EP (1) | EP1472086A1 (ja) |
JP (1) | JP2005516800A (ja) |
AU (1) | AU2003216159A1 (ja) |
WO (1) | WO2003066329A1 (ja) |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6718888B2 (en) * | 2000-04-11 | 2004-04-13 | Nextreme, Llc | Thermoformed platform |
US8347794B2 (en) | 2000-04-11 | 2013-01-08 | Nextreme, Llc | Fire resistant pallet |
US7975404B2 (en) * | 2004-07-01 | 2011-07-12 | Stanbee Company, Inc. | Stiffeners for use in footwear |
ES2360116T3 (es) * | 2004-07-01 | 2011-06-01 | Stanbee Company, Inc. | Refuerzos para calzado. |
US20060105166A1 (en) * | 2004-11-17 | 2006-05-18 | Lischefski Andrew J | Breathable packaging film having enhanced thermoformability |
US7959998B2 (en) | 2005-03-02 | 2011-06-14 | Eastman Chemical Company | Transparent, oxygen-scavenging compositions containing polyesters comprising a cyclobutanediol and articles prepared therefrom |
US20100184940A1 (en) * | 2005-03-02 | 2010-07-22 | Eastman Chemical Company | Polyester Compositions Which Comprise Cyclobutanediol and Certain Thermal Stabilizers, and/or Reaction Products Thereof |
US7786252B2 (en) | 2005-03-02 | 2010-08-31 | Eastman Chemical Company | Preparation of transparent multilayered articles |
US20060199871A1 (en) * | 2005-03-02 | 2006-09-07 | Hale Wesley R | Multilayered, transparent articles and a process for their preparation |
US7964258B2 (en) | 2005-03-02 | 2011-06-21 | Eastman Chemical Company | Transparent, oxygen-scavenging compositions and articles prepared therefrom |
US7955674B2 (en) * | 2005-03-02 | 2011-06-07 | Eastman Chemical Company | Transparent polymer blends containing polyesters comprising a cyclobutanediol and articles prepared therefrom |
US7968164B2 (en) | 2005-03-02 | 2011-06-28 | Eastman Chemical Company | Transparent polymer blends and articles prepared therefrom |
US8067525B2 (en) * | 2005-06-17 | 2011-11-29 | Eastman Chemical Company | Film(s) and/or sheet(s) comprising polyester compositions which comprise cyclobutanediol and have a certain combination of inherent viscosity and high glass transition temperature |
US7955533B2 (en) | 2005-03-02 | 2011-06-07 | Eastman Chemical Company | Process for the preparation of transparent shaped articles |
US7959836B2 (en) | 2005-03-02 | 2011-06-14 | Eastman Chemical Company | Process for the preparation of transparent, shaped articles containing polyesters comprising a cyclobutanediol |
KR20080021013A (ko) * | 2005-06-17 | 2008-03-06 | 이스트만 케미칼 컴파니 | 사이클로뷰테인다이올을 포함하는 폴리에스터를 함유하는투명 중합체 블렌드, 및 이로부터 제조된 제품 |
US7704605B2 (en) | 2006-03-28 | 2010-04-27 | Eastman Chemical Company | Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein |
GB2444712B (en) | 2005-08-31 | 2011-01-12 | Transilwrap Co Inc | Intrusion resistant thermal laminating film |
US8586701B2 (en) | 2005-10-28 | 2013-11-19 | Eastman Chemical Company | Process for the preparation of copolyesters based on 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
US8193302B2 (en) | 2005-10-28 | 2012-06-05 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol and certain phosphate thermal stabilizers, and/or reaction products thereof |
ATE505500T1 (de) * | 2005-10-28 | 2011-04-15 | Eastman Chem Co | Polyesterzusammensetzungen mit cyclobutandiol mit hoher glasübergangstemperatur und daraus hergestellte artikel |
US9598533B2 (en) | 2005-11-22 | 2017-03-21 | Eastman Chemical Company | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
US7737246B2 (en) | 2005-12-15 | 2010-06-15 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor |
US9169388B2 (en) | 2006-03-28 | 2015-10-27 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
GB2439728B (en) * | 2006-07-03 | 2010-07-21 | Fuji Seal Int Inc | Heat-shrinkable film |
WO2008106389A1 (en) * | 2007-02-26 | 2008-09-04 | 3Form, Inc. | Formable fused polymer panels containing light refracting films |
US20080227914A1 (en) * | 2007-03-16 | 2008-09-18 | Bfs Diversified Products, Llc | Recycled building material and method thereof |
KR20100087171A (ko) | 2007-11-21 | 2010-08-03 | 이스트만 케미칼 컴파니 | 플라스틱 젖병, 다른 취입 성형된 제품, 및 이들의 제조 방법 |
US8501287B2 (en) | 2007-11-21 | 2013-08-06 | Eastman Chemical Company | Plastic baby bottles, other blow molded articles, and processes for their manufacture |
US20090233056A1 (en) * | 2008-03-11 | 2009-09-17 | Anderson Sr Andy W | Polypropylene Laminate Wallcovering |
US8198371B2 (en) | 2008-06-27 | 2012-06-12 | Eastman Chemical Company | Blends of polyesters and ABS copolymers |
US20100099828A1 (en) * | 2008-10-21 | 2010-04-22 | Eastman Chemical Company | Clear Binary Blends of Aliphatic Polyesters and Aliphatic-Aromatic Polyesters |
US8895654B2 (en) | 2008-12-18 | 2014-11-25 | Eastman Chemical Company | Polyester compositions which comprise spiro-glycol, cyclohexanedimethanol, and terephthalic acid |
US8420869B2 (en) | 2010-12-09 | 2013-04-16 | Eastman Chemical Company | Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
US8394997B2 (en) | 2010-12-09 | 2013-03-12 | Eastman Chemical Company | Process for the isomerization of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
US8420868B2 (en) | 2010-12-09 | 2013-04-16 | Eastman Chemical Company | Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
US20130217830A1 (en) | 2012-02-16 | 2013-08-22 | Eastman Chemical Company | Clear Semi-Crystalline Articles with Improved Heat Resistance |
JP2015532223A (ja) * | 2012-10-05 | 2015-11-09 | ユニリーバー・ナームローゼ・ベンノートシヤープ | 包装用新規積層フィルム |
US20160039186A1 (en) * | 2014-08-06 | 2016-02-11 | Bloomer Plastics, Inc. | Vapor Permeable and Liquid Impermeable Film and Carpet Pad Including Same |
MX2020009484A (es) * | 2018-03-29 | 2020-10-22 | Dow Global Technologies Llc | Resina para usar como adhesivo de coextrusion en una estructura multicapa que tiene tereftalato de polietileno. |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6487682A (en) * | 1987-07-29 | 1989-03-31 | Kendall & Co | Adhesive tape |
JPH03138145A (ja) * | 1989-09-22 | 1991-06-12 | Hercules Inc | 延伸ラミネートフィルム |
WO1993006137A1 (en) * | 1991-09-24 | 1993-04-01 | Chevron Research And Technology Company | Copolymers of ethylene and alkyl acrylate, processes for preparing same and high clarity films |
JPH05212834A (ja) * | 1992-02-06 | 1993-08-24 | Toppan Printing Co Ltd | 多層プラスチック構造物 |
JPH06256535A (ja) * | 1992-10-26 | 1994-09-13 | Rohm & Haas Co | ポリオレフィン基体に改良された接着をもたらす方法 |
JPH08309947A (ja) * | 1995-03-16 | 1996-11-26 | Sumitomo Chem Co Ltd | ポリエステル積層フィルムまたはシート |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3668058A (en) * | 1969-07-31 | 1972-06-06 | Tenneco Chem | Matrix material for production of plastic printing plates |
FR2470682A1 (fr) | 1979-12-06 | 1981-06-12 | Saint Gobain | Procede de fabrication de stratifies, stratifies obtenus et colle utilisee dans ce procede |
US4387126A (en) * | 1982-02-10 | 1983-06-07 | Champion International Corporation | Laminated packaging material |
US4666758A (en) | 1984-06-04 | 1987-05-19 | Sierracin Corporation | Low temperature laminatable polyurethane |
US4663417A (en) | 1984-06-04 | 1987-05-05 | Sierracin Corporation | Low temperature laminatable polyurethane |
US4592947A (en) | 1984-06-04 | 1986-06-03 | Sierracin Corporation | Low temperature laminatable polyurethane |
US4705707A (en) * | 1985-12-17 | 1987-11-10 | Presto Products, Incorporated | Polyethylene/polyester nonoriented heat sealable moisture barrier film and bag |
JPS63267537A (ja) * | 1987-04-25 | 1988-11-04 | Toyobo Co Ltd | 耐水性高強力積層体 |
US4939009A (en) * | 1988-03-17 | 1990-07-03 | Eastman Kodak Company | Multilayered sheets having excellent adhesion |
US5571878A (en) * | 1991-09-24 | 1996-11-05 | Chevron Chemical Company | Ethylene-alkyl acrylate copolymers and derivatives having improved melt-point temperatures and adhesive strength and processes for preparing same |
WO1994022149A1 (en) * | 1993-03-23 | 1994-09-29 | Tokai Rubber Industries, Ltd. | Insulating tape or sheet |
JP3444976B2 (ja) * | 1994-06-17 | 2003-09-08 | グンゼ株式会社 | 積層フィルム |
US5624524A (en) * | 1994-08-18 | 1997-04-29 | Gordon; Carl C. | Plastic laminate construction and method of making thereof |
US6221191B1 (en) * | 1996-06-07 | 2001-04-24 | Qpf, L.L.C. | Polyester-containing biaxially-oriented polypropylene films and method of making the same |
US5643666A (en) | 1995-12-20 | 1997-07-01 | Eastman Chemical Company | Solid surfaces which are prepared from copolyesters laminated onto a high resolution image |
KR100245074B1 (ko) * | 1997-01-20 | 2000-02-15 | 구광시 | 내충격성 및 내후성이 우수한 폴리에스테르 다층 쉬트 및 그의 제조방법 |
US6025069A (en) | 1998-06-19 | 2000-02-15 | Eastman Chemical Company | Thermoplastic article having high-relief surface |
US5998028A (en) | 1997-08-26 | 1999-12-07 | Eastman Chemical Company | Thermoplastic article having metallic wire, rod or bar embedded therein |
US5958539A (en) | 1997-08-26 | 1999-09-28 | Eastman Chemical Company | Thermoplastic article having textile fiber fabric embedded therein |
US6180749B1 (en) * | 1997-11-19 | 2001-01-30 | Kolon Industries, Inc. | Glass clear heavy gauge sheet with copolyester |
US6045895A (en) * | 1997-12-01 | 2000-04-04 | 3M Innovative Properties Company | Multilayer films having pressure sensitive adhesive layers |
-
2003
- 2003-01-31 US US10/356,011 patent/US7037576B2/en not_active Expired - Fee Related
- 2003-02-03 JP JP2003565734A patent/JP2005516800A/ja active Pending
- 2003-02-03 AU AU2003216159A patent/AU2003216159A1/en not_active Abandoned
- 2003-02-03 EP EP20030737605 patent/EP1472086A1/en not_active Withdrawn
- 2003-02-03 WO PCT/US2003/003237 patent/WO2003066329A1/en active Application Filing
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6487682A (en) * | 1987-07-29 | 1989-03-31 | Kendall & Co | Adhesive tape |
JPH03138145A (ja) * | 1989-09-22 | 1991-06-12 | Hercules Inc | 延伸ラミネートフィルム |
WO1993006137A1 (en) * | 1991-09-24 | 1993-04-01 | Chevron Research And Technology Company | Copolymers of ethylene and alkyl acrylate, processes for preparing same and high clarity films |
JP2002505692A (ja) * | 1991-09-24 | 2002-02-19 | シェブロン ケミカル カンパニー エルエルシー | エチレンとアルキルアクリレートとの共重合体その製造方法及び高透明フイルム |
JPH05212834A (ja) * | 1992-02-06 | 1993-08-24 | Toppan Printing Co Ltd | 多層プラスチック構造物 |
JPH06256535A (ja) * | 1992-10-26 | 1994-09-13 | Rohm & Haas Co | ポリオレフィン基体に改良された接着をもたらす方法 |
JPH08309947A (ja) * | 1995-03-16 | 1996-11-26 | Sumitomo Chem Co Ltd | ポリエステル積層フィルムまたはシート |
Also Published As
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WO2003066329A1 (en) | 2003-08-14 |
AU2003216159A1 (en) | 2003-09-02 |
US7037576B2 (en) | 2006-05-02 |
US20040209097A1 (en) | 2004-10-21 |
EP1472086A1 (en) | 2004-11-03 |
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