JP2005514466A5 - - Google Patents
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- Publication number
- JP2005514466A5 JP2005514466A5 JP2003515576A JP2003515576A JP2005514466A5 JP 2005514466 A5 JP2005514466 A5 JP 2005514466A5 JP 2003515576 A JP2003515576 A JP 2003515576A JP 2003515576 A JP2003515576 A JP 2003515576A JP 2005514466 A5 JP2005514466 A5 JP 2005514466A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- bis
- bisphenol
- independently
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 claims 29
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 18
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims 16
- 238000000034 method Methods 0.000 claims 13
- 125000000753 cycloalkyl group Chemical group 0.000 claims 10
- 125000003118 aryl group Chemical group 0.000 claims 8
- -1 diaryl carbonates Chemical class 0.000 claims 8
- 239000000203 mixture Substances 0.000 claims 8
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims 7
- 150000004023 quaternary phosphonium compounds Chemical class 0.000 claims 6
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims 5
- 229930185605 Bisphenol Natural products 0.000 claims 5
- 229910001413 alkali metal ion Inorganic materials 0.000 claims 4
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 claims 4
- 125000000217 alkyl group Chemical group 0.000 claims 4
- 150000001491 aromatic compounds Chemical class 0.000 claims 4
- 239000003054 catalyst Substances 0.000 claims 4
- 125000004093 cyano group Chemical group *C#N 0.000 claims 4
- 125000005843 halogen group Chemical group 0.000 claims 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 4
- 238000010438 heat treatment Methods 0.000 claims 3
- 239000002994 raw material Substances 0.000 claims 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims 2
- 125000004644 alkyl sulfinyl group Chemical group 0.000 claims 2
- 150000001449 anionic compounds Chemical class 0.000 claims 2
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 claims 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 2
- 229910001412 inorganic anion Inorganic materials 0.000 claims 2
- 150000002891 organic anions Chemical class 0.000 claims 2
- 125000006736 (C6-C20) aryl group Chemical group 0.000 claims 1
- HCNHNBLSNVSJTJ-UHFFFAOYSA-N 1,1-Bis(4-hydroxyphenyl)ethane Chemical compound C=1C=C(O)C=CC=1C(C)C1=CC=C(O)C=C1 HCNHNBLSNVSJTJ-UHFFFAOYSA-N 0.000 claims 1
- YFWYLKADCOMBDO-UHFFFAOYSA-N 2-butan-2-yl-4-[1-(3-butan-2-yl-4-hydroxyphenyl)propyl]phenol Chemical compound C1=C(O)C(C(C)CC)=CC(C(CC)C=2C=C(C(O)=CC=2)C(C)CC)=C1 YFWYLKADCOMBDO-UHFFFAOYSA-N 0.000 claims 1
- ZDRSNHRWLQQICP-UHFFFAOYSA-N 2-tert-butyl-4-[2-(3-tert-butyl-4-hydroxyphenyl)propan-2-yl]phenol Chemical compound C1=C(O)C(C(C)(C)C)=CC(C(C)(C)C=2C=C(C(O)=CC=2)C(C)(C)C)=C1 ZDRSNHRWLQQICP-UHFFFAOYSA-N 0.000 claims 1
- NZGQHKSLKRFZFL-UHFFFAOYSA-N 4-(4-hydroxyphenoxy)phenol Chemical compound C1=CC(O)=CC=C1OC1=CC=C(O)C=C1 NZGQHKSLKRFZFL-UHFFFAOYSA-N 0.000 claims 1
- SVOBELCYOCEECO-UHFFFAOYSA-N 4-[1-(4-hydroxy-3-methylphenyl)cyclohexyl]-2-methylphenol Chemical compound C1=C(O)C(C)=CC(C2(CCCCC2)C=2C=C(C)C(O)=CC=2)=C1 SVOBELCYOCEECO-UHFFFAOYSA-N 0.000 claims 1
- OVVCSFQRAXVPGT-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)cyclopentyl]phenol Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCC1 OVVCSFQRAXVPGT-UHFFFAOYSA-N 0.000 claims 1
- YUFSSFBVBVYGGK-UHFFFAOYSA-N 4-[2-(4-hydroxy-3-methylphenyl)propan-2-yl]-2-methylphenol;4-[(4-hydroxyphenyl)methyl]phenol Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1.C1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=CC=2)=C1 YUFSSFBVBVYGGK-UHFFFAOYSA-N 0.000 claims 1
- QHJPJZROUNGTRJ-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)octan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(CCCCCC)C1=CC=C(O)C=C1 QHJPJZROUNGTRJ-UHFFFAOYSA-N 0.000 claims 1
- HTVITOHKHWFJKO-UHFFFAOYSA-N Bisphenol B Chemical compound C=1C=C(O)C=CC=1C(C)(CC)C1=CC=C(O)C=C1 HTVITOHKHWFJKO-UHFFFAOYSA-N 0.000 claims 1
- 125000003860 C1-C20 alkoxy group Chemical group 0.000 claims 1
- WSNMPAVSZJSIMT-UHFFFAOYSA-N COc1c(C)c2COC(=O)c2c(O)c1CC(O)C1(C)CCC(=O)O1 Chemical compound COc1c(C)c2COC(=O)c2c(O)c1CC(O)C1(C)CCC(=O)O1 WSNMPAVSZJSIMT-UHFFFAOYSA-N 0.000 claims 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims 1
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims 1
- 125000004442 acylamino group Chemical group 0.000 claims 1
- 125000002723 alicyclic group Chemical group 0.000 claims 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims 1
- 125000004457 alkyl amino carbonyl group Chemical group 0.000 claims 1
- 125000003282 alkyl amino group Chemical group 0.000 claims 1
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims 1
- 125000004414 alkyl thio group Chemical group 0.000 claims 1
- 125000005100 aryl amino carbonyl group Chemical group 0.000 claims 1
- 125000001769 aryl amino group Chemical group 0.000 claims 1
- 125000005161 aryl oxy carbonyl group Chemical group 0.000 claims 1
- 125000005135 aryl sulfinyl group Chemical group 0.000 claims 1
- 125000004391 aryl sulfonyl group Chemical group 0.000 claims 1
- 125000005110 aryl thio group Chemical group 0.000 claims 1
- 125000004104 aryloxy group Chemical group 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 1
- 125000000000 cycloalkoxy group Chemical group 0.000 claims 1
- 125000006310 cycloalkyl amino group Chemical group 0.000 claims 1
- 125000005167 cycloalkylaminocarbonyl group Chemical group 0.000 claims 1
- 125000005144 cycloalkylsulfonyl group Chemical group 0.000 claims 1
- 125000005366 cycloalkylthio group Chemical group 0.000 claims 1
- NXPPAOGUKPJVDI-UHFFFAOYSA-N naphthalene-1,2-diol Chemical compound C1=CC=CC2=C(O)C(O)=CC=C21 NXPPAOGUKPJVDI-UHFFFAOYSA-N 0.000 claims 1
- 125000004430 oxygen atom Chemical group O* 0.000 claims 1
- GJVFBWCTGUSGDD-UHFFFAOYSA-L pentamethonium bromide Chemical compound [Br-].[Br-].C[N+](C)(C)CCCCC[N+](C)(C)C GJVFBWCTGUSGDD-UHFFFAOYSA-L 0.000 claims 1
- 150000002989 phenols Chemical class 0.000 claims 1
- 229920000515 polycarbonate Polymers 0.000 claims 1
- 239000004417 polycarbonate Substances 0.000 claims 1
- 239000001294 propane Substances 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 125000004434 sulfur atom Chemical group 0.000 claims 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/911,443 US6548623B2 (en) | 2001-07-24 | 2001-07-24 | Method of polycarbonate preparation |
| PCT/US2002/015364 WO2003010218A1 (en) | 2001-07-24 | 2002-05-13 | Method of polycarbonate preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2005514466A JP2005514466A (ja) | 2005-05-19 |
| JP2005514466A5 true JP2005514466A5 (enExample) | 2005-12-22 |
Family
ID=25430240
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003515576A Pending JP2005514466A (ja) | 2001-07-24 | 2002-05-13 | ポリカーボネート製造方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6548623B2 (enExample) |
| EP (2) | EP1414887B1 (enExample) |
| JP (1) | JP2005514466A (enExample) |
| KR (1) | KR100880311B1 (enExample) |
| CN (1) | CN100343303C (enExample) |
| AT (2) | ATE301149T1 (enExample) |
| DE (2) | DE60230199D1 (enExample) |
| TW (1) | TW593424B (enExample) |
| WO (1) | WO2003010218A1 (enExample) |
Families Citing this family (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030139529A1 (en) * | 2001-11-02 | 2003-07-24 | General Electric Company | Method of making block copolymers by solid state polymerization |
| US8227411B2 (en) | 2002-08-20 | 2012-07-24 | BioSurface Engineering Technologies, Incle | FGF growth factor analogs |
| US7151189B2 (en) | 2003-06-19 | 2006-12-19 | General Electric Company | Method and apparatus for waste stream recovery |
| US7258923B2 (en) | 2003-10-31 | 2007-08-21 | General Electric Company | Multilayered articles and method of manufacture thereof |
| US7138479B2 (en) * | 2003-12-31 | 2006-11-21 | General Electric Company | Aliphatic diol polycarbonates and their preparation |
| US20050165148A1 (en) * | 2004-01-28 | 2005-07-28 | Bogerd Jos V.D. | Infra-red radiation absorption articles and method of manufacture thereof |
| CN100577710C (zh) * | 2004-04-20 | 2010-01-06 | 沙伯基础创新塑料知识产权有限公司 | 在低温下用于制备聚碳酸酯低聚物混合物以制造聚碳酸酯的方法 |
| US7041775B2 (en) * | 2004-04-20 | 2006-05-09 | General Electric Company | Method for preparing a polycarbonate oligomer mixture at low temperature for manufacturing polycarbonate |
| AU2005254382B2 (en) * | 2004-06-17 | 2008-07-10 | Asahi Kasei Chemicals Corporation | Process for producing aromatic carbonate |
| US7312352B2 (en) * | 2004-08-02 | 2007-12-25 | Paul William Buckley | Method of preparing ester-substituted diaryl carbonates |
| US7105626B2 (en) * | 2004-09-10 | 2006-09-12 | General Electric Company | Method for incorporating alkyl ester endgroups to improve the release properties of melt polycarbonate |
| US7132498B2 (en) * | 2004-09-27 | 2006-11-07 | General Electric Company | Process to make polycarbonate from bismethylsalicylcarbonate (BMSC) |
| US7183371B2 (en) † | 2004-11-01 | 2007-02-27 | General Electric Company | Method for making polycarbonate |
| US7189869B2 (en) * | 2004-11-01 | 2007-03-13 | General Electric Company | Method for making polycarbonate |
| US7230066B2 (en) * | 2004-12-16 | 2007-06-12 | General Electric Company | Polycarbonate—ultem block copolymers |
| US7399571B2 (en) * | 2005-05-06 | 2008-07-15 | General Electric Company | Multilayered articles and method of manufacture thereof |
| US8900693B2 (en) * | 2005-07-13 | 2014-12-02 | Sabic Global Technologies B.V. | Polycarbonate compositions having infrared absorbance, method of manufacture, and articles prepared therefrom |
| US20070057400A1 (en) * | 2005-09-09 | 2007-03-15 | General Electric Company | Polycarbonate useful in making solvent cast films |
| US7348394B2 (en) * | 2005-10-28 | 2008-03-25 | General Electric Company | Methods for preparing transparent articles from biphenol polycarbonate copolymers |
| US7528214B2 (en) * | 2005-10-28 | 2009-05-05 | Sabic Innovative Plastics Ip B.V. | Methods for preparing transparent articles from hydroquinone polycarbonate copolymers |
| US7365149B2 (en) * | 2005-12-12 | 2008-04-29 | Hans-Peter Brack | Equipment cleaning in the manufacture of polycarbonates |
| US7485695B2 (en) * | 2005-12-21 | 2009-02-03 | Sabic Innovative Plastics Ip B.V | Polycarbonates containing low levels of methyl salicylate prepared by a melt polymerization in a reactive extruder |
| US7485694B2 (en) * | 2005-12-21 | 2009-02-03 | Sabic Innovative Plastics Ip B.V. | Polycarbonates containing low levels of methyl salicylate prepared by a melt polymerization in a reactive extruder |
| WO2007077567A1 (en) * | 2005-12-30 | 2007-07-12 | Council Of Scientific And Industrial Research | Multifunctional alcohols obtained from cardanol, multifunctional acrylic crosslinker and pendant phosphorous flame retardant derivatives thereof |
| US7498399B2 (en) * | 2006-05-31 | 2009-03-03 | Sabic Innovative Plastics Ip B.V. | Method of preparing ester-substituted diaryl carbonates |
| US7495064B2 (en) * | 2006-06-26 | 2009-02-24 | Sabic Innovative Plastics Ip Bv | Manufacture of polycarbonates |
| US7645851B2 (en) * | 2006-06-30 | 2010-01-12 | Sabic Innovative Plastics Ip B.V. | Polycarbonate with reduced color |
| US7498400B2 (en) * | 2006-06-30 | 2009-03-03 | Sabic Innovative Plastics Ip B.V. | Method of preparing polycarbonate |
| US7482423B2 (en) * | 2006-06-30 | 2009-01-27 | Sabic Innovative Plastics Ip B.V. | Polycarbonates and method of preparing same |
| US7541420B2 (en) * | 2006-06-30 | 2009-06-02 | Sabic Innovative Plastics Ip B.V. | Method for making molded polycarbonate articles with improved color |
| US8871865B2 (en) * | 2006-08-01 | 2014-10-28 | Sabic Global Technologies B.V. | Flame retardant thermoplastic polycarbonate compositions |
| US8030400B2 (en) * | 2006-08-01 | 2011-10-04 | Sabic Innovative Plastics Ip B.V. | Thermoplastic polycarbonate compositions with improved chemical and scratch resistance |
| US20080287640A1 (en) * | 2007-05-15 | 2008-11-20 | General Electric Company | Process for the production of polycarbonate using an ester substituted diaryl carbonate |
| US20090043069A1 (en) * | 2007-08-06 | 2009-02-12 | General Electric Company | Activated esters for synthesis of sulfonated telechelic polycarbonates |
| US7687595B2 (en) * | 2007-08-06 | 2010-03-30 | Sabic Innovative Plastics Ip B.V. | Sulfonated telechelic polycarbonates |
| US7632913B2 (en) * | 2007-09-28 | 2009-12-15 | Sabic Innovative Plastics Ip B.V. | Method of producing polycarbonate in a flash devolatilization system |
| US7619053B2 (en) * | 2007-09-28 | 2009-11-17 | Sabic Innovative Plastics Ip B.V. | Monomer solution for producing polycarbonate |
| US7601794B2 (en) * | 2007-09-28 | 2009-10-13 | Sabic Innovative Plastics Ip B.V. | Monomer solution for producing polycarbonate |
| DE102008011903A1 (de) * | 2008-02-29 | 2009-09-03 | Bayer Materialscience Ag | Polycarbonate mit cyclischen Oligomeren und verbessertem Fließverhalten |
| US7615605B2 (en) * | 2008-03-26 | 2009-11-10 | Sabic Innovative Plastics Ip B.V. | Monomer solution for producing polycarbonate |
| DE102008019503A1 (de) | 2008-04-18 | 2009-10-22 | Bayer Materialscience Ag | Polycarbonate mit Umlagerungsstrukturen, cyclischen und linearen Oligomeren sowie verbessertem Fließverhalten |
| US7671165B2 (en) * | 2008-05-16 | 2010-03-02 | Sabic Innovative Plastics Ip B.V. | Method of forming polycarbonate |
| US7674872B2 (en) * | 2008-06-17 | 2010-03-09 | Sabic Innovative Plastics Ip B.V. | Method of producing high molecular weight polymer |
| US7547799B1 (en) | 2008-06-20 | 2009-06-16 | Sabic Innovative Plastics Ip B.V. | Method for producing phenolic compound |
| US8058469B2 (en) * | 2008-11-03 | 2011-11-15 | Sabic Innovative Plastics Ip B.V. | Method for making carbamates, ureas and isocyanates |
| US7659359B1 (en) | 2008-11-18 | 2010-02-09 | Sabic Innovative Plastics Ip B.V. | Stabilization of isosorbide-based polycarbonate |
| US7977447B2 (en) * | 2008-11-18 | 2011-07-12 | Sabic Innovative Plastics Ip B.V. | Method for making carbonates and esters |
| ES2698840T3 (es) * | 2010-04-14 | 2019-02-06 | Mitsubishi Chem Corp | Policarbonato diol, procedimiento para producir el mismo, y poliuretano y composición polimérica curable por radiación actínica ambos formados utilizando el mismo |
| US8343608B2 (en) | 2010-08-31 | 2013-01-01 | General Electric Company | Use of appended dyes in optical data storage media |
| JP6212854B2 (ja) * | 2012-11-17 | 2017-10-18 | 三菱瓦斯化学株式会社 | ポリカーボネート共重合体 |
| WO2015155737A1 (en) * | 2014-04-11 | 2015-10-15 | Sabic Global Technologies B.V. | A system and process for producing various molecular weight melt polycarbonates |
| US10106648B2 (en) | 2014-11-19 | 2018-10-23 | Sabic Global Technologies B.V. | Method of polymerizing end-capped polycarbonate and end-capped polycarbonates derived therefrom |
| TWI693244B (zh) * | 2015-01-20 | 2020-05-11 | 德商科思創德意志股份有限公司 | 藉由轉酯化方法製備高耐熱之［共］聚碳酸酯 |
| WO2017137951A1 (en) | 2016-02-12 | 2017-08-17 | Sabic Global Technologies B.V. | Inherently healing polycarbonate resins |
| CN108611189B (zh) * | 2016-12-09 | 2023-02-21 | 丰益(上海)生物技术研发中心有限公司 | 一种控制油脂中双酚a和烷基酚的精炼工艺 |
| JP6913514B2 (ja) * | 2017-05-25 | 2021-08-04 | 三菱エンジニアリングプラスチックス株式会社 | ポリカーボネート樹脂組成物、成形品、ポリカーボネート樹脂およびポリカーボネート樹脂の末端封止剤 |
| KR102871455B1 (ko) * | 2018-10-11 | 2025-10-14 | 사빅 글로벌 테크놀러지스 비.브이. | 폴리카보네이트 |
| WO2020074983A1 (en) | 2018-10-11 | 2020-04-16 | Sabic Global Technologies B.V. | Method for the manufacture of polycarbonate |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4217438A (en) | 1978-12-15 | 1980-08-12 | General Electric Company | Polycarbonate transesterification process |
| US4323668A (en) | 1980-12-03 | 1982-04-06 | General Electric Company | (Ortho-alkoxycarbonyaryl)-carbonate transesterification |
| US4948871A (en) * | 1987-09-28 | 1990-08-14 | Asahi Kasei Kogyo Kabushiki Kaisha | Method for producing a crystallized aromatic polycarbonate, and a crystallized aromatic polycarbonate obtained thereby |
| DE68928766T2 (de) * | 1988-09-22 | 1999-03-25 | Ge Plastics Japan Ltd., Tokio/Tokyo | Verfahren zur Herstellung von Polycarbonaten |
| DE4223016C2 (de) * | 1992-07-13 | 1998-01-22 | Bayer Ag | Verfahren zur Herstellung von Polycarbonaten |
| US5509386A (en) | 1992-11-06 | 1996-04-23 | A. E. Bishop Research Pty. Limited | Sealing means for rotary valves |
| DE69605167T2 (de) * | 1995-09-19 | 2000-09-14 | Teijin Ltd., Osaka | Verfahren zur Herstellung von Polycarbonat |
| JP3533297B2 (ja) | 1995-09-19 | 2004-05-31 | 帝人株式会社 | ポリカーボネートの製造方法 |
| JPH10101786A (ja) | 1996-09-30 | 1998-04-21 | Teijin Ltd | ポリカーボネート共重合体およびその製造方法 |
| TW409131B (en) * | 1997-04-18 | 2000-10-21 | Teijin Ltd | Process for producing polycarbonate resin |
| JP4286914B2 (ja) | 1998-03-17 | 2009-07-01 | 帝人株式会社 | 芳香族ポリカーボネートの製造方法 |
| JPH11302228A (ja) | 1998-04-20 | 1999-11-02 | Teijin Ltd | サリチル酸エステル誘導体およびその製造方法 |
| EP1114841B1 (en) | 1999-04-20 | 2003-10-08 | Teijin Limited | Process for producing polyarylate |
| JP4712150B2 (ja) * | 1999-09-21 | 2011-06-29 | 帝人株式会社 | 耐熱安定性に優れた芳香族ポリカーボネート |
| US6252035B1 (en) * | 1999-11-29 | 2001-06-26 | General Electric Company | Salts of chelating agents as polymerization catalysts |
| US6506871B1 (en) * | 2001-07-24 | 2003-01-14 | General Electric Company | Extrusion method for making polycarbonate |
| US6469192B1 (en) * | 2001-07-24 | 2002-10-22 | General Electric Company | Solventless preparation of ester-substituted diaryl carbonates |
-
2001
- 2001-07-24 US US09/911,443 patent/US6548623B2/en not_active Expired - Lifetime
-
2002
- 2002-05-13 CN CNB028186834A patent/CN100343303C/zh not_active Expired - Fee Related
- 2002-05-13 WO PCT/US2002/015364 patent/WO2003010218A1/en not_active Ceased
- 2002-05-13 DE DE60230199T patent/DE60230199D1/de not_active Expired - Lifetime
- 2002-05-13 AT AT02731800T patent/ATE301149T1/de not_active IP Right Cessation
- 2002-05-13 EP EP02731800A patent/EP1414887B1/en not_active Expired - Lifetime
- 2002-05-13 JP JP2003515576A patent/JP2005514466A/ja active Pending
- 2002-05-13 DE DE60205385T patent/DE60205385T2/de not_active Expired - Lifetime
- 2002-05-13 EP EP05010649A patent/EP1577333B1/en not_active Expired - Lifetime
- 2002-05-13 AT AT05010649T patent/ATE416213T1/de not_active IP Right Cessation
- 2002-05-13 KR KR1020047000981A patent/KR100880311B1/ko not_active Expired - Fee Related
- 2002-07-11 TW TW091115452A patent/TW593424B/zh not_active IP Right Cessation
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