JP2005023025A - Oxidation hair dye or bleaching agent composition - Google Patents
Oxidation hair dye or bleaching agent composition Download PDFInfo
- Publication number
- JP2005023025A JP2005023025A JP2003190836A JP2003190836A JP2005023025A JP 2005023025 A JP2005023025 A JP 2005023025A JP 2003190836 A JP2003190836 A JP 2003190836A JP 2003190836 A JP2003190836 A JP 2003190836A JP 2005023025 A JP2005023025 A JP 2005023025A
- Authority
- JP
- Japan
- Prior art keywords
- agent
- composition
- hair
- dye
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 67
- 239000000118 hair dye Substances 0.000 title claims abstract description 26
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 14
- 230000003647 oxidation Effects 0.000 title claims abstract description 13
- 239000003051 hair bleaching agent Substances 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 91
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 71
- 230000000694 effects Effects 0.000 claims abstract description 31
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920006317 cationic polymer Polymers 0.000 claims abstract description 15
- 239000000975 dye Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 239000000982 direct dye Substances 0.000 claims abstract description 10
- 150000001768 cations Chemical class 0.000 claims abstract description 9
- 150000002500 ions Chemical class 0.000 claims abstract description 9
- 239000003513 alkali Substances 0.000 claims abstract description 8
- 125000000129 anionic group Chemical group 0.000 claims abstract description 8
- 150000001450 anions Chemical class 0.000 claims abstract description 6
- 230000001590 oxidative effect Effects 0.000 claims description 18
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- 125000003277 amino group Chemical group 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
- 239000002585 base Substances 0.000 claims description 7
- 125000001841 imino group Chemical group [H]N=* 0.000 claims description 6
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- 229920006318 anionic polymer Polymers 0.000 claims description 3
- 238000004043 dyeing Methods 0.000 abstract description 11
- 238000011282 treatment Methods 0.000 abstract description 10
- 238000001035 drying Methods 0.000 abstract description 6
- 238000004061 bleaching Methods 0.000 abstract 2
- 239000007844 bleaching agent Substances 0.000 abstract 2
- -1 diallyl quaternary ammonium salt Chemical class 0.000 description 27
- 125000004432 carbon atom Chemical group C* 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 10
- 239000002453 shampoo Substances 0.000 description 10
- 239000000839 emulsion Substances 0.000 description 9
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 7
- 125000002091 cationic group Chemical group 0.000 description 7
- 239000001913 cellulose Substances 0.000 description 7
- 229920002678 cellulose Polymers 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 6
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 238000004042 decolorization Methods 0.000 description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 description 5
- 230000003700 hair damage Effects 0.000 description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 4
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 4
- 238000004945 emulsification Methods 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 230000007794 irritation Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- 239000007800 oxidant agent Substances 0.000 description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000001099 ammonium carbonate Substances 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- 239000007854 depigmenting agent Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 210000004761 scalp Anatomy 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- XGNXYCFREOZBOL-UHFFFAOYSA-N 1,3-benzodioxol-5-amine Chemical compound NC1=CC=C2OCOC2=C1 XGNXYCFREOZBOL-UHFFFAOYSA-N 0.000 description 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 2
- OBCSAIDCZQSFQH-UHFFFAOYSA-N 2-methyl-1,4-phenylenediamine Chemical compound CC1=CC(N)=CC=C1N OBCSAIDCZQSFQH-UHFFFAOYSA-N 0.000 description 2
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 2
- DBFYESDCPWWCHN-UHFFFAOYSA-N 5-amino-2-methylphenol Chemical compound CC1=CC=C(N)C=C1O DBFYESDCPWWCHN-UHFFFAOYSA-N 0.000 description 2
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- PNENOUKIPPERMY-UHFFFAOYSA-N HC Yellow No. 4 Chemical compound OCCNC1=CC=C([N+]([O-])=O)C=C1OCCO PNENOUKIPPERMY-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- LUSZGTFNYDARNI-UHFFFAOYSA-N Sesamol Chemical compound OC1=CC=C2OCOC2=C1 LUSZGTFNYDARNI-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 229920006322 acrylamide copolymer Polymers 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000000981 basic dye Substances 0.000 description 2
- 229940082500 cetostearyl alcohol Drugs 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 125000004966 cyanoalkyl group Chemical group 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 239000000986 disperse dye Substances 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 229960000735 docosanol Drugs 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000001005 nitro dye Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 108090000623 proteins and genes Chemical class 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 229960001755 resorcinol Drugs 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- VIXBPSTZNCRCJE-UHFFFAOYSA-N 1,3-bis[4-amino-n-(2-hydroxyethyl)anilino]propan-2-ol Chemical compound C1=CC(N)=CC=C1N(CCO)CC(O)CN(CCO)C1=CC=C(N)C=C1 VIXBPSTZNCRCJE-UHFFFAOYSA-N 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- FBMQNRKSAWNXBT-UHFFFAOYSA-N 1,4-diaminoanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2N FBMQNRKSAWNXBT-UHFFFAOYSA-N 0.000 description 1
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-dioxonaphthalene Natural products C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 1
- BOKGTLAJQHTOKE-UHFFFAOYSA-N 1,5-dihydroxynaphthalene Chemical compound C1=CC=C2C(O)=CC=CC2=C1O BOKGTLAJQHTOKE-UHFFFAOYSA-N 0.000 description 1
- OQWWMUWGSBRNMA-UHFFFAOYSA-N 1-(2,4-diaminophenoxy)ethanol Chemical compound CC(O)OC1=CC=C(N)C=C1N OQWWMUWGSBRNMA-UHFFFAOYSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- RECMXJOGNNTEBG-UHFFFAOYSA-N 1-phenylmethoxyethanol Chemical compound CC(O)OCC1=CC=CC=C1 RECMXJOGNNTEBG-UHFFFAOYSA-N 0.000 description 1
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- 229940113489 2,4-diaminophenoxyethanol Drugs 0.000 description 1
- MJMRSGYLARBUDK-UHFFFAOYSA-N 2,4-dimethoxybenzene-1,3-diamine Chemical compound COC1=CC=C(N)C(OC)=C1N MJMRSGYLARBUDK-UHFFFAOYSA-N 0.000 description 1
- SYEYEGBZVSWYPK-UHFFFAOYSA-N 2,5,6-triamino-4-hydroxypyrimidine Chemical compound NC1=NC(N)=C(N)C(O)=N1 SYEYEGBZVSWYPK-UHFFFAOYSA-N 0.000 description 1
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- MJAVQHPPPBDYAN-UHFFFAOYSA-N 2,6-dimethylbenzene-1,4-diamine Chemical compound CC1=CC(N)=CC(C)=C1N MJAVQHPPPBDYAN-UHFFFAOYSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
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- NZKTVPCPQIEVQT-UHFFFAOYSA-N 2-[4-[(4-aminophenyl)diazenyl]-n-(2-hydroxyethyl)anilino]ethanol Chemical compound C1=CC(N)=CC=C1N=NC1=CC=C(N(CCO)CCO)C=C1 NZKTVPCPQIEVQT-UHFFFAOYSA-N 0.000 description 1
- LMKFATMCEGPAPC-UHFFFAOYSA-N 2-[4-amino-n-(2-hydroxyethyl)-2-nitroanilino]ethanol Chemical compound NC1=CC=C(N(CCO)CCO)C([N+]([O-])=O)=C1 LMKFATMCEGPAPC-UHFFFAOYSA-N 0.000 description 1
- ISCYHXYLVTWDJT-UHFFFAOYSA-N 2-[4-amino-n-(2-hydroxyethyl)anilino]ethanol Chemical compound NC1=CC=C(N(CCO)CCO)C=C1 ISCYHXYLVTWDJT-UHFFFAOYSA-N 0.000 description 1
- HCPJEHJGFKWRFM-UHFFFAOYSA-N 2-amino-5-methylphenol Chemical compound CC1=CC=C(N)C(O)=C1 HCPJEHJGFKWRFM-UHFFFAOYSA-N 0.000 description 1
- ALQKEYVDQYGZDN-UHFFFAOYSA-N 2-amino-6-methylphenol Chemical compound CC1=CC=CC(N)=C1O ALQKEYVDQYGZDN-UHFFFAOYSA-N 0.000 description 1
- JCBPETKZIGVZRE-UHFFFAOYSA-N 2-aminobutan-1-ol Chemical compound CCC(N)CO JCBPETKZIGVZRE-UHFFFAOYSA-N 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- BMTSZVZQNMNPCT-UHFFFAOYSA-N 2-aminopyridin-3-ol Chemical compound NC1=NC=CC=C1O BMTSZVZQNMNPCT-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- MGLZGLAFFOMWPB-UHFFFAOYSA-N 2-chloro-1,4-phenylenediamine Chemical compound NC1=CC=C(N)C(Cl)=C1 MGLZGLAFFOMWPB-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
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- VHNQIURBCCNWDN-UHFFFAOYSA-N pyridine-2,6-diamine Chemical compound NC1=CC=CC(N)=N1 VHNQIURBCCNWDN-UHFFFAOYSA-N 0.000 description 1
- PZRKPUQWIFJRKZ-UHFFFAOYSA-N pyrimidine-2,4,5,6-tetramine Chemical compound NC1=NC(N)=C(N)C(N)=N1 PZRKPUQWIFJRKZ-UHFFFAOYSA-N 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical class C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- NWKBFCIAPOSTKG-UHFFFAOYSA-M trimethyl-[3-[(3-methyl-5-oxo-1-phenyl-4h-pyrazol-4-yl)diazenyl]phenyl]azanium;chloride Chemical compound [Cl-].CC1=NN(C=2C=CC=CC=2)C(=O)C1N=NC1=CC=CC([N+](C)(C)C)=C1 NWKBFCIAPOSTKG-UHFFFAOYSA-M 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【０００１】
【発明の属する技術分野】
本発明は、髪に塗布された組成物をすすぎ流す時からシャンプー処理を経て髪を乾燥するまでの髪が濡れている段階において、髪のきしみ感や絡まりを防止する効果に特に優れ、髪につやとまとまり易さを付与すると共に、染毛力・脱色力が良好な酸化染毛剤又は脱色剤組成物に関する。
【０００２】
【従来の技術】
毛髪の脱色及び染色には、アルカリ剤、酸化剤等の共存下での酸化反応によって毛髪を脱色ないし染色する、酸化性の染毛剤又は脱色剤が広く使用されている。しかし、酸化性の染毛剤又は脱色剤は、毛髪損傷を引き起こし易く、水洗、シャンプー又は乾燥時に、髪の絡まり、きしみ感、硬さ、ごわつき等を生じたり、髪の色、ツヤがなくなったり、まとまりが悪くなったりしてしまうという問題がある。また、酸化染毛剤や脱色剤の使用者の髪は、度重なる施術等により損傷を受けている場合が多いが、損傷した髪ではきしみ感や絡まりの問題はより大きなものであった。
【０００３】
これに対し、カチオン性ポリマーを含有する酸化染毛剤による処理に続けて、アニオン界面活性剤を含有するシャンプーを使用することにより、濡れた髪のほどけ易さ及び乾いた髪に対する良好な化粧特性（つや、柔らかさ等）が得られることが知られている（特許文献１参照）。しかしながら、この方法は、特にシャンプー後の髪の濡れている時点におけるきしみ感や絡まりを防止する効果において満足し得るものではなかった。
【０００４】
【特許文献１】
米国特許第４３６２５２８号明細書
【０００５】
【発明が解決しようとする課題】
酸化染毛剤又は脱色剤の使用者は、シャンプー後の髪の濡れている時点におけるきしみ感や絡まりによって、染毛又は脱色処理による髪のダメージを最も感じるため、この時にきしみ感や絡まりを抑えられる酸化染毛剤及び脱色剤が待望されていた。従って本発明は、髪に塗布された組成物をすすぎ流す時からシャンプー処理を経て髪を乾燥するまでの髪が濡れている段階において、髪のきしみ感や絡まりを防止する効果が特に優れ、髪につやとまとまりやすさを付与すると共に、染毛力・脱色力が良好な酸化染毛剤又は脱色剤組成物を提供することを目的とする。
【０００６】
【課題を解決するための手段】
本発明者は、酸化染毛剤又は脱色剤組成物に、不揮発性シリコーンとカチオン性ポリマーを含有させ、更に当該組成物中のアニオン基剤の含有量をカチオン性ポリマーの含有量と一定の関係を満たす範囲とすることにより、上記課題を解決できることを見出した。
【０００７】
本発明は、アルカリ剤及び酸化染料中間体又は直接染料を含有する第１剤（脱色剤の場合は酸化染料中間体及び直接染料は含有しない）と過酸化水素を含有する第２剤を混合して用いる組成物であって、更に次の成分（Ａ）〜（Ｃ）
（Ａ）不揮発性シリコーン
（Ｂ）カチオン性ポリマー
（Ｃ）水
を含有し、当該組成物中の
（Ｄ）アニオン界面活性剤及びアニオン性ポリマーから選ばれるアニオン基剤
の含有量が、成分（Ｂ）の含有量に対して、次の関係
「成分（Ｄ）の陰イオン活量濃度／成分（Ｂ）の陽イオン活量濃度≦０．８」
（イオン活量濃度とは、「モル濃度×イオン価数」を意味する）
を満たし、混合後のｐＨが８〜１２である酸化染毛剤又は脱色剤組成物を提供するものである。
【０００８】
【発明の実施の形態】
本発明の酸化染毛剤又は脱色剤組成物は、アルカリ剤を含有する第１剤と酸化剤を含有する第２剤よりなる二剤型、又は、更に第３剤として過硫酸塩等の造粒物からなる粉末状酸化剤を組み合わせてなる三剤型の形態をとる。以下、本発明において「全組成物」とは、二剤型の場合には第１剤及び第２剤を混合した使用直前の組成物全体をいい、三剤型の場合は、第１剤、第２剤及び第３剤を混合した使用直前の組成物全体をいう。
【０００９】
〔成分（Ａ）：不揮発性シリコーン〕
成分（Ａ）の不揮発性シリコーンは、第１剤、第２剤及び第３剤のいずれか１以上に含まれる。不揮発性シリコーンは、髪に塗布された組成物をすすぎ流す時からシャンプー処理を経て髪を乾燥するまでの髪が濡れている段階において、髪のきしみ感や絡まりを防止するために必要であり、更には乾燥後の毛髪に対しても色の鮮明さや深み、ツヤ、柔らかさ、滑らかさ、ボリューム感（ボディ）、まとまり易さ及び保湿性を与えることにも寄与する。不揮発性シリコーンとしては、アミノ変性シリコーン、フッ素変性シリコーン、アルコール変性シリコーン、ポリエーテル変性シリコーン、エポキシ変性シリコーン、アルキル変性シリコーン等の変性シリコーン、鎖状のジメチルポリシロキサン、メチルフェニルポリシロキサンが挙げられ、２種以上を併用することもできる。中でもアミノ変性シリコーンを少なくとも１種使用することが好ましく、特にアミノ変性シリコーンと高重合シリコーンを併用することが好ましい。
【００１０】
（アミノ変性シリコーン）
アミノ変性シリコーンとしては、アミノ基又はアンモニウム基を有していればよく、末端水酸基の全て又は一部がメチル基等で封鎖されたアミノ変性シリコーンオイル、末端が封鎖されていないアモジメチコーンのどちらでもよい。例えば、好ましいアミノ変性シリコーンとしては、以下の一般式（１）で表されるものが挙げられる。
【００１１】
【化１】
〔式中、Ｒ０は水酸基、水素原子又はＲを示し、Ｒは置換又は非置換の炭素数１〜２０の一価炭化水素基を示し、ＡはＲ、基−Ｒ′−（ＮＨＣＨ２ＣＨ２）ｎＮＨ２、基ＯＲ又は水酸基を示し、Ｒ′は炭素数１〜８の二価炭化水素基を示し、ｎは０〜３の数を示し、ｐ及びｑはその和が数平均で１０以上１０００未満、好ましくは３０以上１０００未満、更に好ましくは４０以上８００未満となる数を示す。アミノ当量は２００ｇ／ｍｏｌ〜３万ｇ／ｍｏｌ、好ましくは５００ｇ／ｍｏｌ〜１万ｇ／ｍｏｌ、更に好ましくは６００ｇ／ｍｏｌ〜５０００ｇ／ｍｏｌである。〕
【００１３】
アミノ変性シリコーンの好適な市販品の具体例としては、ＳＦ８４５１Ｃ（東レ・ダウコーニング・シリコーン社，粘度６００ｍｍ２／ｓ，アミノ当量１７００ｇ／ｍｏｌ）、ＳＦ８４５２Ｃ（東レ・ダウコーニング・シリコーン社，粘度７００ｍｍ２／ｓ，アミノ当量６４００ｇ／ｍｏｌ）、ＳＦ８４５７Ｃ（東レ・ダウコーニング・シリコーン社，粘度１２００ｍｍ２／ｓ，アミノ当量１８００ｇ／ｍｏｌ）、ＫＦ８００３（ＧＥ東芝シリコーン社，粘度１８５０ｍｍ２／ｓ，アミノ当量２０００ｇ／ｍｏｌ）、ＫＦ８６７（ＧＥ東芝シリコーン社，粘度１３００ｍｍ２／ｓ，アミノ当量１７００ｇ／ｍｏｌ）等のアミノ変性シリコーンオイルや、ＳＭ８７０４Ｃ（東レ・ダウコーニング・シリコーン社，アミノ当量１８００ｇ／ｍｏｌ）等のアモジメチコーンエマルションが挙げられる。また、アミノ変性シリコーンオイルは、エマルションの形で配合してもよい。アミノ変性シリコーンのエマルションは、機械的乳化（アミノ変性シリコーンと水との高剪断機械混合）、化学的乳化（アミノ変性シリコーンを水及び乳化剤で乳化）、若しくはこれらの組み合わせによって、又は乳化重合によっても調製することができる。
【００１４】
〔高重合シリコーン〕
ここで、高重合シリコーンとは、数平均重合度１０００以上のシリコーンを指し、更には数平均重合度１５００以上、特に２０００以上２００００未満のシリコーンが好ましい。高重合シリコーン類としては、ジメチルポリシロキサン（ＩＮＣＩ名：ジメチコーン）、メチルフェニルポリシロキサン、ヒドロキシ末端基を有するジメチルポリシロキサン（ＩＮＣＩ名：ジメチコノール）、ＷＯ９６／３１１８８に記載されているわずかに架橋されたシリコーンガム等が好ましいものとして挙げられる。
【００１５】
数平均重合度が１０００以上である高重合シリコーンの市販品の具体例としては、ＳＨ２００−１，０００，０００ｃｓ（東レ・ダウコーニング・シリコーン社）、ＴＳＦ４５１−１００ＭＡ（ＧＥ東芝シリコーン社）、ＢＹ１１−０２６（東レ・ダウコーニング・シリコーン社；高重合シリコーンの低粘度シリコーンによる希釈溶液）、ＫＦ９００８（信越シリコーン社；高重合シリコーンの環状シリコーンによる希釈溶液）、ＢＹ２２−０５０Ａ（東レ・ダウコーニング・シリコーン社；高重合シリコーンのカチオンエマルション）、ＢＹ２２−０６０（東レ・ダウコーニング・シリコーン社；高重合シリコーンを低粘度シリコーンで希釈した溶液のカチオンエマルション）、ＢＹ２２−０２０（東レ・ダウコーニング・シリコーン社；高重合シリコーンを流動パラフィンで希釈した溶液のカチオンエマルション）、ＫＭ９０４（信越シリコーン社；高重合シリコーンを低粘度シリコーンで希釈した溶液のカチオンエマルション）等が挙げられる。
【００１６】
成分（Ａ）の含有量は、十分な効果発現の点から、全組成物中の０．０２〜４０重量％が好ましく、更には０．１〜２０重量％、特に０．２〜１５重量％が好ましい。また、成分（Ａ）は、次式で表される換算アミノ当量が、５００〜１０万ｇ／ｍｏｌとなる範囲で使用することが好ましく、更には１０００〜８万ｇ／ｍｏｌ、特に２０００〜５万ｇ／ｍｏｌとなる範囲で使用することが好ましい。
【００１７】
換算アミノ当量（ｇ／ｍｏｌ）＝〔全組成物１ｇ中の全シリコーン類の総重量（ｇ／ｇ）〕／〔全組成物１ｇ中のアミノ変性シリコーンのアミノ基、イミノ基及びアンモニウム基の総モル数（ｍｏｌ／ｇ）〕
【００１８】
ここで、「全組成物１ｇ中の全シリコーン類の総重量（ｇ／ｇ）」、並びに「全組成物１ｇ中のアミノ変性シリコーンのアミノ基、イミノ基及びアンモニウム基の総モル数（ｍｏｌ／ｇ）」は、以下のようにして求める。
【００１９】
まず、第１剤と第２剤（三剤式の場合には、更に第３剤）の各々からシリコーン類を分画し、各剤中の全シリコーン類の総重量（ｇ）及びアミノ変性シリコーンのアミノ基、イミノ基及びアンモニウム基の総モル数（ｍｏｌ）を定量する。次に全組成物における各剤の混合比率を勘案し、全組成物１ｇ中の全シリコーン類の総重量（ｇ／ｇ）、並びに全組成物１ｇ中のアミノ変性シリコーンのアミノ基、イミノ基及びアンモニウム基の総モル数（ｍｏｌ／ｇ）を算出する。最後に前記の換算アミノ当量算出式を用いて、換算アミノ当量（ｇ／ｍｏｌ）を算出する。
【００２０】
〔成分（Ｂ）：カチオン性ポリマー〕
成分（Ｂ）のカチオン性ポリマーは、第１剤、第２剤及び第３剤のいずれか１以上に含まれるが、各組成物の安定性向上の点から、成分（Ｄ）とは別の剤に含有させるのが好ましい。カチオン性ポリマーは、髪に塗布された組成物をすすぎ流す時からシャンプー処理を経て髪を乾燥するまでの髪が濡れている段階において、髪のきしみ感や絡まりを防止するために必要であり、更には乾燥時の毛髪にツヤ、柔らかさ、滑らかさ、ボリューム感（ボディ）、まとまり易さ及び保湿性を与える効果に寄与する。
【００２１】
カチオン性ポリマーとは、カチオン基又はカチオン基にイオン化され得る基を有するポリマーをいい、全体としてカチオン性となる両性ポリマーも含まれる。すなわち、カチオン性ポリマーとしては、ポリマー鎖の側鎖にアミノ基又はアンモニウム基を含むか、又はジアリル４級アンモニウム塩を構成単位として含む水溶液のもの、例えばカチオン化セルロース誘導体、カチオン性澱粉、カチオン化グアーガム誘導体、ジアリル４級アンモニウム塩の重合体又は共重合体、４級化ポリビニルピロリドン誘導体等が挙げられる。これらのうち、前述の効果及び剤の安定性の点から、ジアリル４級アンモニウム塩を構成単位として含むポリマー、４級化ポリビニルピロリドン誘導体、カチオン化セルロース誘導体が好ましく、ジアリル４級アンモニウム塩の重合体又は共重合体、カチオン化セルロース誘導体がより好ましく、ジアリル４級アンモニウム塩の重合体又は共重合体が最も好ましい。
【００２２】
ジアリル４級アンモニウム塩の重合体の骨格としては、次の一般式（２）又は（３）で示されるものが好ましい。
【００２３】
【化２】
〔式中、Ｒ１及びＲ２は同一でも異なってもよく、水素原子、炭素数１〜１８のアルキル基、アリール基（フェニル基等）、ヒドロキシアルキル基、アミドアルキル基、シアノアルキル基、アルコキシアルキル基又はカルボアルコキシアルキル基を示し、Ｒ３及びＲ４は同一でも異なってもよく、水素原子、炭素数１〜３のアルキル基又はフェニル基を示し、Ｘ−は陰イオン（塩化物イオン、臭化物イオン、ヨウ化物イオン、硫酸アニオン、スルホン酸アニオン、メチル硫酸アニオン、リン酸アニオン、硝酸アニオン等）を示す。〕
【００２５】
ジアリル４級アンモニウム塩と共重合体を構成するモノマーとしては、アクリル酸、メタクリル酸又はこれらの塩、アクリルアミドが挙げられ、特にアクリル酸、メタクリル酸又はこれらの塩が好ましい。アクリル酸、メタクリル酸又はこれらの塩とジアリル４級アンモニウム塩との共重合体は、ジアリル４級アンモニウム塩の構成比率が高く、全体としてカチオン性ポリマーとなる。
【００２６】
ジアリル４級アンモニウム塩の重合体又は共重合体の具体例としては、塩化ジメチルジアリルアンモニウム重合体（ポリクオタニウム−６，例えばマーコート１００；ＯＮＤＥＯ Ｎａｌｃｏ社）、塩化ジメチルジアリルアンモニウム／アクリル酸共重合体（ポリクオタニウム−２２，例えばマーコート２８０，同２９５；ＯＮＤＥＯ Ｎａｌｃｏ社）、塩化ジメチルジアリルアンモニウム／アクリルアミド共重合体（ポリクオタニウム−７，例えばマーコート５５０；ＯＮＤＥＯ Ｎａｌｃｏ社）等が挙げられ、なかでもマーコート２８０、同２９５が好ましい。
【００２７】
４級化ポリビニルピロリドン誘導体としては、次の一般式（４）で表されるものが好ましい。
【００２８】
【化３】
〔式中、Ｒ５は水素原子又は炭素数１〜３のアルキル基、Ｒ６、Ｒ７及びＲ８は同一でも異なってもよく、水素原子、炭素数１〜４のアルキル基、ヒドロキシアルキル基、アミドアルキル基、シアノアルキル基、アルコキシアルキル基又はカルボアルコキシアルキル基を示し、Ｙは酸素原子又はイミノ基を示し、ｒは１〜１０の整数を示し、ｓとｔはその和が２０〜８０００となる数を示し、Ｘ−は前記と同じ意味を示す。〕
【００３０】
本発明で用いられる４級化ポリビニルピロリドン誘導体の分子量としては１万〜２００万、特に５万〜１５０万が好ましい。市販品としては、ガフコート７３４、同７５５、同７５５Ｎ（以上、アイエスピー・ジャパン社）等が挙げられる。
【００３１】
カチオン化セルロース誘導体としては、例えば次の一般式（５）で表されるものが好ましい。
【００３２】
【化４】
〔式中、Ａはアンヒドログルコース単位の残基を示し、ｆは５０〜２万の整数を示し、Ｒ９は、それぞれ次の一般式（６）で表される置換基を示す。〕
【００３４】
【化５】
〔式中、Ｒ１０及びＲ１１は炭素数２又は３のアルキレン基を示し、ｇは０〜１０の整数を示し、ｈは０〜３の整数を示し、ｉは０〜１０の整数を示し、Ｒ１２は炭素数１〜３のアルキレン基又はヒドロキシアルキレン基を、Ｒ１３、Ｒ１４及びＲ１５は同一でも異なってもよく、炭素数１０までのアルキル基、アリール基又はアラルキル基を示し、また式中の窒素原子を含む複素環を形成してもよい。Ｘ−は前記と同じ意味を示す。〕
【００３６】
カチオン化セルロース誘導体のカチオン置換度、すなわちアンヒドログルコース単位当りのｈの平均値は、０．０１〜１、特に０．０２〜０．５が好ましい。また、ｇ＋ｉの合計は平均１〜３である。カチオン置換度は、０．０１未満では十分でなく、また１を超えてもかまわないが反応収率の点より１以下が好ましい。ここで用いるカチオン化セルロース誘導体の分子量は１０万〜３００万が好ましい。市販品としては、レオガードＧ、同ＧＰ（以上、ライオン社）、ポリマーＪＲ−１２５、同ＪＲ−４００、同ＪＲ−３０Ｍ、同ＬＲ−４００、同ＬＲ−３０Ｍ（以上、ユニオンカーバイド社）等が挙げられる。その他のカチオン化セルロース誘導体としてはヒドロキシエチルセルロースジメチルジアリルアンモニウムクロリドが挙げられ、市販品としてはセルコートＨ−１００、同Ｌ−２００（以上、ナショナルスターチアンドケミカル社）等が挙げられる。
【００３７】
これらカチオン性ポリマーは、成分（Ｂ）として２種以上を併用してもよく、またその含有量は、全組成物中の０．００１〜２０重量％が好ましく、更には０．０１〜１０重量％、特に０．０５〜５重量％が好ましい。
【００３８】
〔成分（Ｃ）：水〕
成分（Ｃ）の水の含有量は、全組成物中の２０重量％以上が好ましい。
【００３９】
〔成分（Ｄ）：アニオン基剤〕
成分（Ｄ）のアニオン基剤を含有させる場合、第１剤、第２剤及び第３剤のいずれか１以上に含有させることができるが、各組成物の安定性向上の点から、成分（Ｂ）とは別の剤に含有させるのが好ましい。アニオン性基剤としては、アニオン界面活性剤として、ラウリル硫酸ナトリウム等のアルキル硫酸エステル塩、ポリオキシエチレンラウリル硫酸ナトリウム等のアルキルエーテル硫酸エステル塩、Ｎ−ラウロイルグルタミン酸モノナトリウム等のＮ−アシル化グルタミン酸塩、Ｎ−アシル化サルコシン酸塩、アルキルエーテルリン酸エステル塩、アルキルエーテルスルホコハク酸塩、アルキルベンゼンスルホン酸塩、脂肪酸塩等が挙げられる。脂肪酸塩は、第２剤にオレイン酸、ステアリン酸、イソステアリン酸、ラウリン酸、ミリスチン酸、ベヘン酸等の脂肪酸として配合し、第１剤中のアンモニア等のアルカリで中和することによって形成させることもできる。また、アニオン性ポリマーとして、カルボキシメチルセルロース、カルボキシビニルポリマー、ポリアクリル酸、ポリメタクリル酸及びこれらの誘導体等が挙げられる。
【００４０】
成分（Ｄ）のアニオン基剤は、成分（Ｂ）のカチオン性ポリマーとのイオン活量濃度の比率「成分（Ｄ）の陰イオン活量濃度／成分（Ｂ）の陽イオン活量濃度」（以下、「イオン活量濃度比」という）が、０．８以下となる範囲で含有させることが、髪に塗布された組成物をすすぎ流す時からシャンプー処理を経て髪を乾燥するまでの髪が濡れている段階において、髪のきしみ感や絡まりを防止するために必要であり、イオン活量濃度比が０．００１以上０．６５以下、特に０．０１以上０．４以下となる範囲で含有させることが好ましい。ここで、カチオン性ポリマーがカチオンユニットとアニオンユニットの両方を有する場合は、ポリマー内の両イオン性を相殺した後の残りのイオン性を用いて陽イオン活量濃度を求める。
【００４１】
〔アルカリ剤〕
アルカリ剤は、第１剤に含まれる。アルカリ剤としては、アンモニア；モノエタノールアミン、イソプロパノールアミン、２−アミノ−２−メチルプロパノール、２−アミノブタノール等のアルカノールアミン；１，３−プロパンジアミン等のアルカンジアミン；水酸化ナトリウム、水酸化カリウム等の無機塩基；炭酸グアニジン、炭酸ナトリウム、炭酸カリウム、炭酸水素ナトリウム、炭酸水素カリウム等の炭酸塩等が挙げられる。これらのアルカリ剤は、２種以上を併用してもよく、またその含有量は、十分な脱色・染毛効果の点、及び毛髪損傷や頭皮刺激の低減の点から、全組成物中の０．０５〜１５重量％が好ましく、更には０．１〜１０重量％、特に０．２〜５重量％が好ましい。
【００４２】
上記アルカリ剤のうち、アンモニア及びアルカノールアミンが好ましく、アルカノールアミンとしてはモノエタノールアミンが好ましい。更には、それらの塩を併用することが好ましく、炭酸アンモニウム、炭酸水素アンモニウム、塩化アンモニウムが特に好ましい。更には、これらの含有量が下記範囲であることが最も好ましい。
【００４３】
全組成物中の（ａ）アンモニア及びその塩をアンモニアとして換算した場合の含有量と、（ｂ）モノエタノールアミン及びその塩をモノエタノールアミンとして換算した場合の含有量の合計が、十分な脱色・染毛効果の点、及び毛髪損傷や頭皮刺激、嗅覚刺激の低減の点から、全組成物中の０．０５〜１５重量％であることが好ましく、更には０．１〜１０重量％、特に０．２〜５重量％であることが好ましい。また、（ａ）／（ｂ）の比が、０．０１：１〜２．０：１であることが好ましく、更には０．０２：１〜１：１、特に０．０５：１〜０．５：１であることが好ましい。
【００４４】
〔酸化染料中間体又は直接染料〕
本発明の組成物が、脱色剤組成物である場合には、染料は含有せず、染毛剤組成物である場合には、第１剤に酸化染料中間体又は直接染料を含有する。
【００４５】
酸化染料中間体としては、通常染毛剤に使用されている公知のプレカーサー及びカプラーを用いることができる。プレカーサーとしては、例えばパラフェニレンジアミン、トルエン−２，５−ジアミン、２−クロロ−パラフェニレンジアミン、Ｎ−メトキシエチル−パラフェニレンジアミン、Ｎ，Ｎ−ビス（２−ヒドロキシエチル）−パラフェニレンジアミン、２−（２−ヒドロキシエチル）−パラフェニレンジアミン、２，６−ジメチル−パラフェニレンジアミン、４，４′−ジアミノジフェニルアミン、１，３−ビス（Ｎ−（２−ヒドロキシエチル）−Ｎ−（４−アミノフェニル）アミノ）−２−プロパノール、ＰＥＧ−３，３，２′−パラフェニレンジアミン、パラアミノフェノール、パラメチルアミノフェノール、３−メチル−４−アミノフェノール、２−アミノメチル−４−アミノフェノール、２−（２−ヒドロキシエチルアミノメチル）−４−アミノフェノール、オルトアミノフェノール、２−アミノ−５−メチルフェノール、２−アミノ−６−メチルフェノール、２−アミノ−５−アセタミドフェノール、３，４−ジアミノ安息香酸、５−アミノサリチル酸、２，４，５，６−テトラアミノピリミジン、２，５，６−トリアミノ−４−ヒドロキシピリミジン、４，５−ジアミノ−１−（４′−クロロベンジル）ピラゾール、４，５−ジアミノ−１−ヒドロキシエチルピラゾールとこれらの塩等が挙げられる。
【００４６】
また、カプラーとしては、例えばメタフェニレンジアミン、２，４−ジアミノフェノキシエタノール、２−アミノ−４−（２−ヒドロキシエチルアミノ）アニソール、２，４−ジアミノ−５−メチルフェネトール、２，４−ジアミノ−５−（２−ヒドロキシエトキシ）トルエン、２，４−ジメトキシ−１，３−ジアミノベンゼン、２，６−ビス（２−ヒドロキシエチルアミノ）トルエン、２，４−ジアミノ−５−フルオロトルエン、１，３−ビス（２，４−ジアミノフェノキシ）プロパン、メタアミノフェノール、２−メチル−５−アミノフェノール、２−メチル−５−（２−ヒドロキシエチルアミノ）フェノール、２，４−ジクロロ−３−アミノフェノール、２−クロロ−３−アミノ−６−メチルフェノール、２−メチル−４−クロロ−５−アミノフェノール、Ｎ−シクロペンチル−メタアミノフェノール、２−メチル−４−メトキシ−５−（２−ヒドロキシエチルアミノ）フェノール、２−メチル−４−フルオロ−５−アミノフェノール、レゾルシン、２−メチルレゾルシン、４−クロロレゾルシン、１−ナフトール、１，５−ジヒドロキシナフタレン、１，７−ジヒドロキシナフタレン、２，７−ジヒドロキシナフタレン、２−イソプロピル−５−メチルフェノール、４−ヒドロキシインドール、５−ヒドロキシインドール、６−ヒドロキシインドール、７−ヒドロキシインドール、６−ヒドロキシベンゾモルホリン、３，４−メチレンジオキシフェノール、２−ブロモ−４，５−メチレンジオキシフェノール、３，４−メチレンジオキシアニリン、１−（２−ヒドロキシエチル）アミノ−３，４−メチレンジオキシベンゼン、２，６−ジヒドロキシ−３，４−ジメチルピリジン、２，６−ジメトキシ−３，５−ジアミノピリジン、２，３−ジアミノ−６−メトキシピリジン、２−メチルアミノ−３−アミノ−６−メトキシピリジン、２−アミノ−３−ヒドロキシピリジン、２，６−ジアミノピリジンとこれらの塩等が挙げられる。
【００４７】
プレカーサーとカプラーは、それぞれ２種以上を併用してもよく、その含有量は、それぞれ全組成物中の０．０１〜５重量％、特に０．１〜４重量％が好ましい。
【００４８】
直接染料としては、ニトロ染料、分散染料、塩基性染料等が挙げられる。ニトロ染料としては、２−ニトロ−パラフェニレンジアミン、２−アミノ−６−クロロ−４−ニトロフェノール、３−ニトロ−パラヒドロキシエチルアミノフェノール、４−ニトロ−オルトフェニレンジアミン、４−アミノ−３−ニトロフェノール、４−ヒドロキシプロピルアミノ−３−ニトロフェノール、ＨＣブルーＮｏ．２、ＨＣオレンジＮｏ．１、ＨＣレッドＮｏ．１、ＨＣイエローＮｏ．２、ＨＣイエローＮｏ．４、ＨＣイエローＮｏ．５、ＨＣレッドＮｏ．３、Ｎ，Ｎ−ビス−（２−ヒドロキシエチル）−２−ニトロ−パラフェニレンジアミン等が挙げられ、分散染料としては、ディスパーズバイオレット１、ディスパーズブルー１、ディスパーズブラック９等が挙げられ、塩基性染料としては、ベーシックブルー９９、ベーシックブラウン１６、ベーシックブラウン１７、ベーシックレッド７６、ベーシックレッド５１、ベーシックイエロー５７、ベーシックイエロー８７、ベーシックオレンジ３１等が挙げられる。
【００４９】
直接染料は、２種以上を併用してもよく、酸化染料中間体と併用してもよい。またその含有量は、全組成中に０．００１〜５重量％、特に０．０１〜３重量％が好ましい。
【００５０】
〔過酸化水素〕
過酸化水素は、第２剤に含まれる。過酸化水素の含有量は、十分な脱色・染毛効果、及び毛髪損傷や頭皮刺激の低減の点から、全組成物中の０．１〜１０重量％が好ましく、特に１〜５重量％が好ましい。
【００５１】
〔高級アルコール〕
本発明の組成物には、感触改善、安定性の観点から、第１剤、第２剤及び第３剤のいずれか１以上に、高級アルコールを含有させることが好ましい。これらは、界面活性剤と構造体を形成して分離を防ぐと共に、すすぎ時の感触を改善する効果がある。
【００５２】
高級アルコールとしては、炭素数８〜２２、特に１６〜２２のものが好ましく、具体的には、セチルアルコール、ステアリルアルコール、ベヘニルアルコール等、及びこれらの混合物が挙げられる。特に感触面からベヘニルアルコールが好ましい。
【００５３】
高級アルコールは、２種以上を併用してもよく、またその含有量は、全組成物中の０．０１〜２０重量％、特に０．１〜１０重量％が好ましい。
【００５４】
〔界面活性剤〕
本発明の酸化染毛剤又は脱色剤組成物は、乳化物であることが好ましく、シリコーン類や高級アルコール類の乳化のため、第１剤及び第２剤のいずれか一方又は両方に、界面活性剤を含有させることが好ましい。界面活性剤としては、安定性の観点より、非イオン界面活性剤、例えば炭素数１２〜２２の直鎖又は分岐鎖のアルキル基を有するアルコキシ化（例えばエトキシ化又はプロポキシ化）高級アルコール、具体的には、ポリオキシエチレン（２〜４０）アルキルエーテル等を全組成物中に１〜４０重量％程度、好ましくは２〜２０重量％程度用いることができる。また、感触面を考慮すれば、更にモノ長鎖アルキルトリメチルアンモニウム塩等のカチオン界面活性剤を併用することが好ましい。ここで、モノ長鎖アルキルトリメチルアンモニウム塩としては、感触、乳化性能の面から、塩化ベヘニルトリメチルアンモニウムが好ましい。これらの使用比率は、（カチオン界面活性剤）／（非イオン界面活性剤＋カチオン界面活性剤）の重量比が、０．８以下、更に０．６以下、特に０．４以下であるのが好ましい。
【００５５】
界面活性剤と高級アルコールの重量比を、１０：１〜１：１０、好ましくは４：１〜１：８、特に１：１〜１：４とすると、混合前の第１剤又は第２剤をクリーム状にすることができる。
【００５６】
〔有機溶剤〕
本発明の組成物には、媒体として、成分（Ｃ）の水に加え、有機溶剤を含有させることができる。有機溶剤としては、エタノール、２−プロパノール等の低級アルカノール類、ベンジルアルコール、ベンジルオキシエタノール等の芳香族アルコール類、プロピレングリコール、１，３−ブタンジオール、ジエチレングリコール、グリセリン等のポリオール類、エチルセロソルブ、ブチルセロソルブ、ベンジルセロソルブ等のセロソルブ類、エチルカルビトール、ブチルカルビトール等のカルビトール類が挙げられる。
【００５７】
〔剤型等〕
本発明の組成物は、現在広く利用されている酸化染毛剤又は脱色剤と同様に、アルカリ剤を含有する第１剤と過酸化水素等の酸化剤を含有する第２剤よりなる二剤型として、又は脱色力向上のため、更に第３剤として過硫酸塩（過硫酸アンモニウム、過硫酸カリウム、過硫酸ナトリウム等）等の造粒物からなる粉末状酸化剤を組み合わせてなる三剤型として提供される。第１剤及び第２剤の剤形は、例えば、液状、乳液状、クリーム状、ゲル状、ペースト状、ムース状などとすることができ、エアゾール形態とすることもできる。第１剤と第２剤（三剤型の場合は更に第３剤）を混合し、毛髪に塗布したときに液だれしにくいような粘度になることが望ましく、２５℃、ヘリカルスタンド付きＢ型回転粘度計（Ｂ８Ｒ型粘度計，ＴＯＫＩＭＥＣ社）で測定した粘度が２０００〜１０万ｍｍ２／ｓが好ましい。ここで、粘度は、ローターＴ−Ｃを用い、１０ｒｐｍ、１分間回転させた後の値とする。
【００５８】
〔ｐＨ〕
本発明の組成物のｐＨ（２５℃）は、脱色・染毛効果と皮膚刺激性の点から、使用時（混合時）において、８〜１２とされるが、８〜１０が好ましい。ｐＨ調整剤としては、前記のアルカリ剤のほか、塩酸、リン酸等の無機酸、クエン酸、グリコール酸、乳酸等の有機酸、リン酸二水素一カリウム、リン酸一水素二ナトリウム等のリン酸塩等が挙げられる。
【００５９】
〔その他任意成分〕
本発明の組成物には、上記成分のほかに通常化粧品原料として用いられる他の成分を加えることができる。このような任意成分としては、環状ポリシロキサン、炭化水素類、動植物油脂、成分（Ｂ）及び（Ｄ）以外の天然又は合成の高分子、エーテル類、蛋白誘導体、加水分解蛋白、アミノ酸類、防腐剤、キレート剤、安定化剤、酸化防止剤、植物性抽出物、生薬抽出物、ビタミン類、香料、紫外線吸収剤が挙げられる。
【００６０】
〔処理法〕
本発明の組成物を用いて毛髪を染色又は脱色処理するには、例えば本発明の組成物の第１剤と第２剤（三剤型の場合は更に第３剤）を使用直前に混合した後、毛髪に適用し、所定時間放置後、洗い流し、乾燥すればよい。毛髪への適用温度は１５〜４５℃、適用時間は３〜４５分間、特に５〜３０分間が好ましい。この場合、まず酸化染毛剤又は脱色剤組成物を水で軽く洗い流した後、アニオン界面活性剤を含有するシャンプーを用いて洗髪し、次いで水洗すると、カチオン性ポリマーは適度に流出し、シリコーン類は適度に毛髪に残留し、良好なコンディショニング効果を示す。シャンプーとしては、ラウリルエトキシ（１〜３）硫酸ナトリウム等のアニオン界面活性剤を５〜２０重量％程度含有する一般的な水性シャンプーが好適である。
【００６１】
【実施例】
実施例１
常法に従い、下記組成の第１剤及び第２剤からなる染毛剤組成物を調製した。
【００６２】
・第１剤（クリーム状） （重量％）
強アンモニア水（２８重量％） １．５
モノエタノールアミン ３．０
炭酸水素アンモニウム ０．５
塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体液
（８．５重量％）＊１ ２．０
塩化ジメチルジアリルアンモニウム・アクリル酸共重合体液
（４０重量％）＊２ ２．０
アモジメチコーン（４０重量％エマルジョン）＊３ １．０
高重合ジメチルポリシロキサン（数平均重合度２７００） １．５
ジメチルポリシロキサン（数平均重合度５５０） ４．０
セトステアリルアルコール ７．０
オクチルドデカノール １．０
ポリオキシエチレン（４０）セチルエーテル ２．０
ポリオキシエチレン（２）セチルエーテル １．０
塩化ステアリルトリメチルアンモニウム液（２８重量％） ３．０
塩化ジアルキル（１２−１８）ジメチルアンモニウム液（７５重量％） ０．５
プロピレングリコール ３．０
エデト酸四ナトリウム ０．１
アスコルビン酸 ０．３
亜硫酸ナトリウム ０．５
パラフェニレンジアミン ０．４
トルエン−２，５−ジアミン ０．４
パラアミノフェノール ０．５
メタアミノフェノール ０．２
２−メチル−５−アミノフェノール ０．１
レゾルシン ０．４
香料 適量
精製水 バランス
【００６３】
＊１：マーコート５５０（ＯＮＤＥＯ Ｎａｌｃｏ社）
＊２：マーコート２８０（ＯＮＤＥＯ Ｎａｌｃｏ社）
＊３：シリコーンＳＭ８７０４Ｃ（東レ・ダウコーニング・シリコーン社）
【００６４】
・第２剤（クリーム状） （重量％）
過酸化水素水（３５重量％） １６．２
８−キノリノール硫酸塩 ０．０４
ポリオキシエチレン（４０）セチルエーテル １．０
ポリオキシエチレン（２）セチルエーテル １．０
ポリオキシエチレン（２）ラウリルエーテル硫酸ナトリウム ０．１７
セトステアリルアルコール ３．５
リン酸 ｐＨ３．５とする量
精製水 バランス
【００６５】
第１剤と第２剤の混合比 １：１
混合後のｐＨ １０
換算アミノ当量 ２６５５０（ｇ／ｍｏｌ）
イオン活量濃度比 ０．１０
【００６６】
実施例１の染毛剤は、染毛処理を繰り返し損傷を受けている毛髪に対して、塗布した染毛剤をすすぎ流す時からシャンプー処理を経て、髪を乾かし終わるまでの髪が濡れている段階において、きしみ感や絡まりを防止する効果を有する。また、乾燥後の髪にはつやとまとまりやすさを付与し、染毛力も良好である。
【００６７】
【発明の効果】
本発明の酸化染毛剤又は脱色剤組成物は、髪に塗布された組成物をすすぎ流す時からシャンプー処理を経て髪を乾燥するまでの髪が濡れている段階において、髪のきしみ感や絡まりを防止する効果に特に優れ、髪につやとまとまり易さを付与すると共に、染毛力・脱色力も良好である。[0001]
BACKGROUND OF THE INVENTION
The present invention is particularly excellent in the effect of preventing squeaking and tangling of the hair in the stage where the hair is wet from the time of rinsing the composition applied to the hair until the hair is dried through the shampoo treatment. The present invention relates to an oxidative hair dye or a decolorizing agent composition that imparts glossiness and ease of uniting and has good hair dyeing power and decoloring power.
[0002]
[Prior art]
For decolorization and dyeing of hair, an oxidative hair dye or decoloring agent that decolorizes or dyes hair by an oxidation reaction in the presence of an alkali agent, an oxidizing agent or the like is widely used. However, oxidative hair dyes or depigmenting agents are liable to cause hair damage and may cause hair entanglement, squeakiness, firmness, and stiffness when washed with water, shampoo or dryness, and hair color and gloss may be lost. There is a problem that the unity becomes worse. Further, the hair of users of oxidative hair dyes and depigmenting agents is often damaged by repeated treatments and the like, but the problem of squeakiness and entanglement is greater with damaged hair.
[0003]
In contrast, by using a shampoo containing an anionic surfactant following treatment with an oxidative hair dye containing a cationic polymer, it is easy to unwind wet hair and has good cosmetic properties for dry hair. (Gloss, softness, etc.) are known to be obtained (see Patent Document 1). However, this method is not satisfactory in the effect of preventing squeak and tangling particularly when the hair is wet after shampooing.
[0004]
[Patent Document 1]
US Pat. No. 4,362,528
[Problems to be solved by the invention]
Users of oxidative hair dyes or depigmenters feel the most of hair damage due to hair dyeing or decoloring treatment due to the squeaky feeling or entanglement when the hair is wet after shampooing. There has been a long-awaited oxidation hair dye and decoloring agent. Therefore, the present invention is particularly effective in preventing the squeaky and tangled hair in the stage where the hair is wet from the time of rinsing the composition applied to the hair until the hair is dried through the shampoo treatment. An object of the present invention is to provide an oxidative hair dye or a decoloring agent composition that imparts easy glossiness and unity and has good hair dyeing power and decoloring power.
[0006]
[Means for Solving the Problems]
The present inventor makes the oxidative hair dye or decolorant composition contain a non-volatile silicone and a cationic polymer, and the content of the anionic base in the composition has a certain relationship with the content of the cationic polymer. It was found that the above-mentioned problems can be solved by setting the range to satisfy the above.
[0007]
In the present invention, a first agent containing an alkali agent and an oxidation dye intermediate or a direct dye (in the case of a decoloring agent, does not contain an oxidation dye intermediate and a direct dye) and a second agent containing hydrogen peroxide are mixed. And the following components (A) to (C)
(A) Non-volatile silicone (B) Cationic polymer (C) Water is contained, and the content of an anionic base selected from (D) anionic surfactant and anionic polymer in the composition is component (B ) Content, the following relationship “component (D) anion activity concentration / component (B) cation activity concentration ≦ 0.8”
(The ion activity concentration means “molar concentration × ion valence”)
And an oxidative hair dye or a decoloring agent composition having a pH of 8 to 12 after mixing.
[0008]
DETAILED DESCRIPTION OF THE INVENTION
The oxidative hair dye or depigmenting composition of the present invention is a two-component type comprising a first agent containing an alkaline agent and a second agent containing an oxidant, or a persulfate as a third agent. It takes the form of a three-part type formed by combining powdery oxidizers composed of granules. Hereinafter, the “total composition” in the present invention refers to the whole composition immediately before use in which the first agent and the second agent are mixed in the case of the two-agent type, and in the case of the three-agent type, the first agent, The entire composition immediately before use in which the second agent and the third agent are mixed.
[0009]
[Component (A): Nonvolatile silicone]
The non-volatile silicone of component (A) is contained in one or more of the first agent, the second agent, and the third agent. Non-volatile silicone is necessary to prevent squeaky and tangled hair at the stage where the hair is wet, from rinsing the composition applied to the hair to shampooing and drying the hair, Furthermore, it contributes to giving the hair vividness and depth, gloss, softness, smoothness, volume feeling (body), ease of uniting, and moisture retention to the hair after drying. Nonvolatile silicones include amino-modified silicones, fluorine-modified silicones, alcohol-modified silicones, polyether-modified silicones, epoxy-modified silicones, alkyl-modified silicones and other modified silicones, chain dimethylpolysiloxanes, and methylphenylpolysiloxanes. Two or more kinds can be used in combination. Among these, it is preferable to use at least one amino-modified silicone, and it is particularly preferable to use an amino-modified silicone and a highly polymerized silicone in combination.
[0010]
(Amino-modified silicone)
The amino-modified silicone may have an amino group or an ammonium group, and may be either an amino-modified silicone oil in which all or part of the terminal hydroxyl group is blocked with a methyl group or the like, or amodimethicone in which the terminal is not blocked. . For example, preferable amino-modified silicones include those represented by the following general formula (1).
[0011]
[Chemical 1]
[Wherein R 0 represents a hydroxyl group, a hydrogen atom or R, R represents a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms, A represents R, a group —R ′-(NHCH 2 CH 2 ) n NH 2 , a group OR or a hydroxyl group, R ′ represents a divalent hydrocarbon group having 1 to 8 carbon atoms, n represents a number of 0 to 3, and p and q are the number average of the sum. The number is from 10 to less than 1000, preferably from 30 to less than 1000, and more preferably from 40 to less than 800. The amino equivalent is 200 g / mol to 30,000 g / mol, preferably 500 g / mol to 10,000 g / mol, and more preferably 600 g / mol to 5000 g / mol. ]
[0013]
Specific examples of suitable commercially available amino-modified silicone include SF8451C (Toray Dow Corning Silicone, viscosity 600 mm 2 / s, amino equivalent 1700 g / mol), SF8452C (Toray Dow Corning Silicone, viscosity 700 mm 2). / S, amino equivalent 6400 g / mol), SF8457C (Toray Dow Corning Silicone, viscosity 1200 mm 2 / s, amino equivalent 1800 g / mol), KF8003 (GE Toshiba Silicone, viscosity 1850 mm 2 / s, amino equivalent 2000 g / mol), KF867 (GE Toshiba Silicone Co., Ltd., viscosity 1300 mm 2 / s, amino equivalent 1700 g / mol), etc., and SM8704C (Toray Dow Corning Silicone, amino equivalent 1800 g / mol). mol) and the like. The amino-modified silicone oil may be blended in the form of an emulsion. Emulsions of amino-modified silicones can be obtained by mechanical emulsification (high shear mechanical mixing of amino-modified silicone and water), chemical emulsification (emulsification of amino-modified silicone with water and emulsifier), or combinations thereof, or by emulsion polymerization. Can be prepared.
[0014]
[Highly polymerized silicone]
Here, the highly polymerized silicone refers to a silicone having a number average polymerization degree of 1000 or more, more preferably a silicone having a number average polymerization degree of 1500 or more, particularly 2000 or more and less than 20000. Highly polymerized silicones include dimethylpolysiloxane (INCI name: dimethicone), methylphenylpolysiloxane, dimethylpolysiloxane having hydroxy end groups (INCI name: dimethiconol), slightly crosslinked as described in WO 96/31188. Silicone gum and the like are preferred.
[0015]
Specific examples of commercially available highly polymerized silicones having a number average degree of polymerization of 1000 or more include SH200-1,000,000cs (Toray Dow Corning Silicone), TSF451-100MA (GE Toshiba Silicone), BY11- 026 (Toray Dow Corning Silicone; diluted solution of highly polymerized silicone with low viscosity silicone), KF9008 (Shin-Etsu Silicone; diluted solution of highly polymerized silicone with cyclic silicone), BY22-050A (Toray Dow Corning Silicone) A cationic emulsion of a highly polymerized silicone), BY22-060 (Toray Dow Corning Silicone; a cationic emulsion of a solution obtained by diluting a highly polymerized silicone with a low viscosity silicone), BY22-020 (Toray Dow Corning Silicone; Cationic emulsion) of the solution polymerization silicone diluted with liquid paraffin, KM904 (Shin-Etsu Silicone Co., and the like solution cation emulsion diluted highly polymerized silicone with low viscosity silicone).
[0016]
The content of the component (A) is preferably 0.02 to 40% by weight, more preferably 0.1 to 20% by weight, particularly 0.2 to 15% by weight in the total composition, from the viewpoint of sufficient effect expression. Is preferred. Moreover, it is preferable to use a component (A) in the range from which the conversion amino equivalent represented by following Formula becomes 500-100,000g / mol, Furthermore, 1000-80,000g / mol, Furthermore, 2000-5 are preferable. It is preferable to use in the range of 10,000 g / mol.
[0017]
Equivalent amino equivalent (g / mol) = [total weight of all silicones in 1 g of total composition (g / g)] / [total of amino group, imino group and ammonium group of amino-modified silicone in 1 g of total composition Number of moles (mol / g)]
[0018]
Here, “total weight (g / g) of all silicones in 1 g of total composition” and “total number of moles of amino groups, imino groups and ammonium groups of amino-modified silicone in 1 g of total composition (mol / mol) g) "is obtained as follows.
[0019]
First, silicones are fractionated from each of the first agent and the second agent (in the case of a three-agent type, the third agent), and the total weight (g) of all silicones in each agent and amino-modified silicone The total number of moles (mol) of amino group, imino group and ammonium group is determined. Next, considering the mixing ratio of each agent in the whole composition, the total weight (g / g) of all silicones in 1 g of the whole composition, and the amino group, imino group of amino-modified silicone in 1 g of the whole composition, and The total number of moles of ammonium groups (mol / g) is calculated. Finally, the converted amino equivalent (g / mol) is calculated using the converted amino equivalent calculation formula.
[0020]
[Component (B): Cationic polymer]
The cationic polymer of the component (B) is contained in any one or more of the first agent, the second agent, and the third agent, but is different from the component (D) from the viewpoint of improving the stability of each composition. It is preferable to make it contain in an agent. The cationic polymer is necessary in order to prevent the hair from being squeaked and entangled in the stage where the hair is wet from the time of rinsing the composition applied to the hair to shampooing and drying the hair, Furthermore, it contributes to the effect of giving gloss, softness, smoothness, volume feeling (body), ease of uniting and moisture retention to the hair when dried.
[0021]
The cationic polymer refers to a polymer having a cationic group or a group that can be ionized into a cationic group, and includes an amphoteric polymer that becomes cationic as a whole. That is, as the cationic polymer, an aqueous solution containing an amino group or an ammonium group in the side chain of the polymer chain or containing a diallyl quaternary ammonium salt as a structural unit, such as a cationized cellulose derivative, a cationic starch, a cationization Examples include guar gum derivatives, diallyl quaternary ammonium salt polymers or copolymers, and quaternized polyvinylpyrrolidone derivatives. Among these, from the viewpoint of the above-mentioned effects and the stability of the agent, a polymer containing a diallyl quaternary ammonium salt as a structural unit is preferably a quaternized polyvinylpyrrolidone derivative or a cationized cellulose derivative, and a diallyl quaternary ammonium salt polymer. Or a copolymer and a cationized cellulose derivative are more preferable, and a polymer or copolymer of diallyl quaternary ammonium salt is most preferable.
[0022]
As the skeleton of the diallyl quaternary ammonium salt polymer, one represented by the following general formula (2) or (3) is preferable.
[0023]
[Chemical 2]
[Wherein, R 1 and R 2 may be the same or different, and are a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an aryl group (such as a phenyl group), a hydroxyalkyl group, an amidoalkyl group, a cyanoalkyl group, an alkoxy group. Represents an alkyl group or a carboalkoxyalkyl group, R 3 and R 4 may be the same or different, each represents a hydrogen atom, an alkyl group having 1 to 3 carbon atoms or a phenyl group, and X − represents an anion (chloride ion, Bromide ion, iodide ion, sulfate anion, sulfonate anion, methyl sulfate anion, phosphate anion, nitrate anion, etc.). ]
[0025]
Examples of the monomer constituting the copolymer with the diallyl quaternary ammonium salt include acrylic acid, methacrylic acid or salts thereof, and acrylamide, and acrylic acid, methacrylic acid or salts thereof are particularly preferable. A copolymer of acrylic acid, methacrylic acid or a salt thereof and a diallyl quaternary ammonium salt has a high constituent ratio of diallyl quaternary ammonium salt, and becomes a cationic polymer as a whole.
[0026]
Specific examples of the polymer or copolymer of diallyl quaternary ammonium salt include dimethyldiallylammonium chloride polymer (polyquaternium-6, such as Marquat 100; ONDEO Nalco), dimethyldiallylammonium chloride / acrylic acid copolymer (polyquaternium). -22, for example, Marquat 280, 295; ONDEO Nalco), dimethyldiallylammonium chloride / acrylamide copolymer (Polyquaternium-7, for example, Marquat 550; ONDEO Nalco), and the like. preferable.
[0027]
As the quaternized polyvinyl pyrrolidone derivative, those represented by the following general formula (4) are preferable.
[0028]
[Chemical 3]
[Wherein, R 5 is a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, R 6 , R 7 and R 8 may be the same or different, and a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or a hydroxyalkyl group. , An amide alkyl group, a cyanoalkyl group, an alkoxyalkyl group or a carboalkoxyalkyl group, Y represents an oxygen atom or an imino group, r represents an integer of 1 to 10, and s and t have a sum of 20 to 8000. X − represents the same meaning as described above. ]
[0030]
The molecular weight of the quaternized polyvinylpyrrolidone derivative used in the present invention is preferably 10,000 to 2,000,000, particularly preferably 50,000 to 1,500,000. Examples of commercially available products include Guffcoat 734, 755, and 755N (above, IPS Japan Ltd.).
[0031]
As a cationized cellulose derivative, what is represented, for example by following General formula (5) is preferable.
[0032]
[Formula 4]
[Wherein, A represents a residue of an anhydroglucose unit, f represents an integer of 50 to 20,000, and R 9 represents a substituent represented by the following general formula (6). ]
[0034]
[Chemical formula 5]
Wherein, R 10 and R 11 represents an alkylene group having 2 or 3 carbon atoms, g represents an integer of 0, h is an integer of 0 to 3, i is an integer of 0 , R 12 represents an alkylene group having 1 to 3 carbon atoms or a hydroxyalkylene group, R 13 , R 14 and R 15 may be the same or different and each represents an alkyl group, aryl group or aralkyl group having up to 10 carbon atoms, Moreover, you may form the heterocyclic ring containing the nitrogen atom in a formula. X − has the same meaning as described above. ]
[0036]
The cation substitution degree of the cationized cellulose derivative, that is, the average value of h per anhydroglucose unit is preferably 0.01 to 1, particularly 0.02 to 0.5. Moreover, the sum total of g + i is 1-3 on average. The degree of cation substitution is not sufficient if it is less than 0.01, and may exceed 1, but 1 or less is preferable from the viewpoint of reaction yield. The molecular weight of the cationized cellulose derivative used here is preferably 100,000 to 3,000,000. Commercially available products include Leo Guard G, GP (above, Lion), Polymer JR-125, JR-400, JR-30M, LR-400, LR-30M (above, Union Carbide). Can be mentioned. Examples of other cationized cellulose derivatives include hydroxyethyl cellulose dimethyl diallylammonium chloride, and examples of commercially available products include Cellcoat H-100 and L-200 (National Starch and Chemical Co., Ltd.).
[0037]
These cationic polymers may be used in combination of two or more as the component (B), and the content thereof is preferably 0.001 to 20% by weight, more preferably 0.01 to 10% by weight in the total composition. %, Particularly 0.05 to 5% by weight is preferred.
[0038]
[Component (C): Water]
The content of water of component (C) is preferably 20% by weight or more based on the total composition.
[0039]
[Component (D): Anionic base]
When the anionic base of the component (D) is contained, it can be contained in any one or more of the first agent, the second agent, and the third agent. From the viewpoint of improving the stability of each composition, the component ( It is preferable to make it contain in the agent different from B). Examples of anionic bases include alkyl sulfates such as sodium lauryl sulfate, alkyl ether sulfates such as sodium polyoxyethylene lauryl sulfate, and N-acylated glutamic acids such as monosodium N-lauroyl glutamate. Examples thereof include salts, N-acylated sarcosine salts, alkyl ether phosphate esters, alkyl ether sulfosuccinates, alkyl benzene sulfonates, and fatty acid salts. Fatty acid salt is formed by blending into the second agent as a fatty acid such as oleic acid, stearic acid, isostearic acid, lauric acid, myristic acid, behenic acid, etc., and neutralizing with an alkali such as ammonia in the first agent. You can also. Examples of the anionic polymer include carboxymethyl cellulose, carboxyvinyl polymer, polyacrylic acid, polymethacrylic acid, and derivatives thereof.
[0040]
The anionic base of component (D) is a ratio of the ionic activity concentration with the cationic polymer of component (B) “anion activity concentration of component (D) / cation activity concentration of component (B)” ( (Hereinafter referred to as “ion activity concentration ratio”) is within the range of 0.8 or less, the hair from the time of rinsing the composition applied to the hair through the shampoo treatment until the hair is dried Necessary for preventing hair from being squeaky or tangled in the wet stage, and contained in a range where the ion activity concentration ratio is 0.001 to 0.65, particularly 0.01 to 0.4. It is preferable to make it. Here, when a cationic polymer has both a cation unit and an anion unit, a cation activity density | concentration is calculated | required using the remaining ionicity after offsetting the amphoteric nature in a polymer.
[0041]
(Alkaline agent)
The alkaline agent is included in the first agent. Examples of the alkaline agent include ammonia; alkanolamines such as monoethanolamine, isopropanolamine, 2-amino-2-methylpropanol, and 2-aminobutanol; alkanediamines such as 1,3-propanediamine; sodium hydroxide and potassium hydroxide. Inorganic bases such as guanidine carbonate, sodium carbonate, potassium carbonate, sodium hydrogen carbonate, potassium hydrogen carbonate and the like. Two or more of these alkali agents may be used in combination, and the content thereof is 0% in the total composition from the viewpoint of sufficient decolorization / hair dyeing effect and reduction of hair damage and scalp irritation. 0.05 to 15% by weight is preferable, further 0.1 to 10% by weight, particularly 0.2 to 5% by weight is preferable.
[0042]
Of the alkali agents, ammonia and alkanolamine are preferable, and monoethanolamine is preferable as the alkanolamine. Furthermore, these salts are preferably used in combination, and ammonium carbonate, ammonium hydrogen carbonate, and ammonium chloride are particularly preferable. Furthermore, the content of these is most preferably in the following range.
[0043]
The total amount of (a) content when ammonia and its salt are converted as ammonia in the entire composition and (b) content when monoethanolamine and its salt are converted as monoethanolamine is sufficient decolorization -From the point of hair dyeing effect and the point of reduction of hair damage, scalp irritation, and olfactory irritation, it is preferably 0.05 to 15% by weight, more preferably 0.1 to 10% by weight in the total composition, In particular, the content is preferably 0.2 to 5% by weight. The ratio of (a) / (b) is preferably 0.01: 1 to 2.0: 1, more preferably 0.02: 1 to 1: 1, particularly 0.05: 1 to 0. Preferably it is 5: 1.
[0044]
[Oxidized dye intermediate or direct dye]
When the composition of the present invention is a depigmenting agent composition, it contains no dye, and when it is a hair dye composition, the first agent contains an oxidation dye intermediate or a direct dye.
[0045]
As the oxidation dye intermediate, known precursors and couplers usually used in hair dyes can be used. Examples of the precursor include paraphenylenediamine, toluene-2,5-diamine, 2-chloro-paraphenylenediamine, N-methoxyethyl-paraphenylenediamine, N, N-bis (2-hydroxyethyl) -paraphenylenediamine, 2- (2-hydroxyethyl) -paraphenylenediamine, 2,6-dimethyl-paraphenylenediamine, 4,4'-diaminodiphenylamine, 1,3-bis (N- (2-hydroxyethyl) -N- (4 -Aminophenyl) amino) -2-propanol, PEG-3,3,2'-paraphenylenediamine, paraaminophenol, paramethylaminophenol, 3-methyl-4-aminophenol, 2-aminomethyl-4-aminophenol 2- (2-hydroxyethylaminomethyl) -4 Aminophenol, orthoaminophenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol, 2-amino-5-acetamidophenol, 3,4-diaminobenzoic acid, 5-aminosalicylic acid, 2 , 4,5,6-tetraaminopyrimidine, 2,5,6-triamino-4-hydroxypyrimidine, 4,5-diamino-1- (4'-chlorobenzyl) pyrazole, 4,5-diamino-1-hydroxy Examples thereof include ethylpyrazole and salts thereof.
[0046]
Examples of couplers include metaphenylenediamine, 2,4-diaminophenoxyethanol, 2-amino-4- (2-hydroxyethylamino) anisole, 2,4-diamino-5-methylphenetole, and 2,4-diamino. -5- (2-hydroxyethoxy) toluene, 2,4-dimethoxy-1,3-diaminobenzene, 2,6-bis (2-hydroxyethylamino) toluene, 2,4-diamino-5-fluorotoluene, , 3-bis (2,4-diaminophenoxy) propane, metaaminophenol, 2-methyl-5-aminophenol, 2-methyl-5- (2-hydroxyethylamino) phenol, 2,4-dichloro-3- Aminophenol, 2-chloro-3-amino-6-methylphenol, 2-methyl-4-chloro-5 Aminophenol, N-cyclopentyl-metaaminophenol, 2-methyl-4-methoxy-5- (2-hydroxyethylamino) phenol, 2-methyl-4-fluoro-5-aminophenol, resorcin, 2-methylresorcin, 4-chlororesorcin, 1-naphthol, 1,5-dihydroxynaphthalene, 1,7-dihydroxynaphthalene, 2,7-dihydroxynaphthalene, 2-isopropyl-5-methylphenol, 4-hydroxyindole, 5-hydroxyindole, 6 -Hydroxyindole, 7-hydroxyindole, 6-hydroxybenzomorpholine, 3,4-methylenedioxyphenol, 2-bromo-4,5-methylenedioxyphenol, 3,4-methylenedioxyaniline, 1- (2 -Hydroxye L) Amino-3,4-methylenedioxybenzene, 2,6-dihydroxy-3,4-dimethylpyridine, 2,6-dimethoxy-3,5-diaminopyridine, 2,3-diamino-6-methoxypyridine, Examples include 2-methylamino-3-amino-6-methoxypyridine, 2-amino-3-hydroxypyridine, 2,6-diaminopyridine, and salts thereof.
[0047]
Two or more precursors and couplers may be used in combination, and the content thereof is preferably 0.01 to 5% by weight, particularly 0.1 to 4% by weight, based on the total composition.
[0048]
Examples of direct dyes include nitro dyes, disperse dyes, and basic dyes. Nitro dyes include 2-nitro-paraphenylenediamine, 2-amino-6-chloro-4-nitrophenol, 3-nitro-parahydroxyethylaminophenol, 4-nitro-orthophenylenediamine, 4-amino-3- Nitrophenol, 4-hydroxypropylamino-3-nitrophenol, HC Blue No. 2, HC Orange No. 1, HC Red No. 1, HC Yellow No. 1 2, HC Yellow No. 4. HC Yellow No. 4 5, HC Red No. 3, N, N-bis- (2-hydroxyethyl) -2-nitro-paraphenylenediamine and the like, and disperse dyes include Disperse Violet 1, Disperse Blue 1, Disperse Black 9 and the like. Examples of basic dyes include Basic Blue 99, Basic Brown 16, Basic Brown 17, Basic Red 76, Basic Red 51, Basic Yellow 57, Basic Yellow 87, Basic Orange 31 and the like.
[0049]
Two or more direct dyes may be used in combination, or may be used in combination with an oxidation dye intermediate. The content thereof is preferably 0.001 to 5% by weight, particularly 0.01 to 3% by weight in the total composition.
[0050]
〔hydrogen peroxide〕
Hydrogen peroxide is contained in the second agent. The content of hydrogen peroxide is preferably 0.1 to 10% by weight, particularly 1 to 5% by weight in the total composition from the viewpoint of sufficient decolorization / hair dyeing effect and reduction of hair damage and scalp irritation. preferable.
[0051]
[Higher alcohol]
The composition of the present invention preferably contains a higher alcohol in any one or more of the first agent, the second agent, and the third agent from the viewpoint of improvement in feel and stability. These have the effect of forming a structure with a surfactant to prevent separation and improving the feel during rinsing.
[0052]
As the higher alcohol, those having 8 to 22 carbon atoms, particularly 16 to 22 carbon atoms are preferable, and specific examples include cetyl alcohol, stearyl alcohol, behenyl alcohol, and the like, and mixtures thereof. In particular, behenyl alcohol is preferable in terms of touch.
[0053]
Two or more higher alcohols may be used in combination, and the content thereof is preferably 0.01 to 20% by weight, particularly preferably 0.1 to 10% by weight, based on the total composition.
[0054]
[Surfactant]
The oxidative hair dye or decoloring agent composition of the present invention is preferably an emulsion, and in order to emulsify silicones and higher alcohols, either or both of the first agent and the second agent have a surface activity. It is preferable to contain an agent. As the surfactant, from the viewpoint of stability, a nonionic surfactant, for example, an alkoxylation (for example, ethoxylation or propoxylation) higher alcohol having a linear or branched alkyl group having 12 to 22 carbon atoms, specifically, For example, polyoxyethylene (2-40) alkyl ether or the like can be used in the total composition in an amount of about 1 to 40% by weight, preferably about 2 to 20% by weight. In consideration of the feel, it is preferable to further use a cationic surfactant such as a mono long chain alkyltrimethylammonium salt. Here, as the mono long-chain alkyltrimethylammonium salt, behenyltrimethylammonium chloride is preferable from the viewpoint of feel and emulsification performance. The weight ratio of (cationic surfactant) / (nonionic surfactant + cationic surfactant) is 0.8 or less, further 0.6 or less, especially 0.4 or less. preferable.
[0055]
When the weight ratio of the surfactant to the higher alcohol is 10: 1 to 1:10, preferably 4: 1 to 1: 8, particularly 1: 1 to 1: 4, the first agent or the second agent before mixing. Can be creamed.
[0056]
〔Organic solvent〕
The composition of the present invention can contain an organic solvent as a medium in addition to the water of component (C). Examples of the organic solvent include lower alkanols such as ethanol and 2-propanol, aromatic alcohols such as benzyl alcohol and benzyloxyethanol, polyols such as propylene glycol, 1,3-butanediol, diethylene glycol and glycerin, ethyl cellosolve, Examples thereof include cellosolves such as butyl cellosolve and benzyl cellosolve, and carbitols such as ethyl carbitol and butyl carbitol.
[0057]
[Dosage form, etc.]
The composition of the present invention is a two-component composition comprising a first agent containing an alkaline agent and a second agent containing an oxidizing agent such as hydrogen peroxide, as well as the currently used oxidative hair dye or decoloring agent. As a three-part type that combines a powdered oxidizer consisting of a granulated product such as persulfate (ammonium persulfate, potassium persulfate, sodium persulfate, etc.) as a third agent for improving the decolorizing power as a mold Provided. The dosage forms of the first agent and the second agent can be, for example, liquid, emulsion, cream, gel, paste, mousse, etc., and can also be aerosol. It is desirable that the first agent and the second agent (the third agent in the case of the three-agent type) are mixed, and the viscosity should be such that the liquid does not easily drip when applied to the hair. The viscosity measured by a rotational viscometer (B8R type viscometer, TOKIMEC) is preferably 2000 to 100,000 mm 2 / s. Here, the viscosity is the value after rotating at 10 rpm for 1 minute using the rotor TC.
[0058]
[PH]
The pH (25 ° C.) of the composition of the present invention is 8 to 12 at the time of use (during mixing) from the viewpoint of decolorization / hair dyeing effect and skin irritation, but 8 to 10 is preferable. As the pH adjuster, in addition to the above alkali agents, inorganic acids such as hydrochloric acid and phosphoric acid, organic acids such as citric acid, glycolic acid and lactic acid, phosphorous such as dipotassium dihydrogen phosphate, disodium monohydrogen phosphate, etc. Examples include acid salts.
[0059]
[Other optional ingredients]
In addition to the above components, other components that are usually used as cosmetic raw materials can be added to the composition of the present invention. Such optional components include cyclic polysiloxanes, hydrocarbons, animal and vegetable oils and fats, natural or synthetic polymers other than components (B) and (D), ethers, protein derivatives, hydrolyzed proteins, amino acids, antiseptics Agents, chelating agents, stabilizers, antioxidants, botanical extracts, herbal extracts, vitamins, fragrances, and UV absorbers.
[0060]
[Treatment method]
In order to dye or decolorize hair using the composition of the present invention, for example, the first agent and the second agent (or the third agent in the case of the three-component type) of the composition of the present invention are mixed immediately before use. Then, it may be applied to the hair, left for a predetermined time, rinsed and dried. The application temperature to the hair is preferably 15 to 45 ° C., and the application time is preferably 3 to 45 minutes, particularly 5 to 30 minutes. In this case, the oxidative hair dye or decoloring agent composition is first washed lightly with water, then washed with a shampoo containing an anionic surfactant, and then washed with water. Remains moderately in the hair and exhibits a good conditioning effect. As the shampoo, a general aqueous shampoo containing about 5 to 20% by weight of an anionic surfactant such as sodium lauryl ethoxy (1-3) sulfate is suitable.
[0061]
【Example】
Example 1
According to a conventional method, a hair dye composition comprising a first agent and a second agent having the following composition was prepared.
[0062]
・ First agent (cream) (wt%)
Strong ammonia water (28% by weight) 1.5
Monoethanolamine 3.0
Ammonium bicarbonate 0.5
Dimethyldiallylammonium chloride / acrylamide copolymer liquid (8.5% by weight) * 1 2.0
Dimethyldiallylammonium chloride / acrylic acid copolymer liquid (40% by weight) * 2 2.0
Amodimethicone (40% emulsion) * 3 1.0
Highly polymerized dimethylpolysiloxane (number average degree of polymerization 2700) 1.5
Dimethylpolysiloxane (number average degree of polymerization 550) 4.0
Cetostearyl alcohol 7.0
Octyldodecanol 1.0
Polyoxyethylene (40) cetyl ether 2.0
Polyoxyethylene (2) cetyl ether 1.0
Stearyltrimethylammonium chloride solution (28% by weight) 3.0
Dialkyl chloride (12-18) dimethylammonium solution (75% by weight) 0.5
Propylene glycol 3.0
Edetate tetrasodium 0.1
Ascorbic acid 0.3
Sodium sulfite 0.5
Paraphenylenediamine 0.4
Toluene-2,5-diamine 0.4
Paraaminophenol 0.5
Metaaminophenol 0.2
2-Methyl-5-aminophenol 0.1
Resorcin 0.4
Perfume appropriate amount purified water balance [0063]
* 1: Marcote 550 (ONDEO Nalco)
* 2: Marcote 280 (ONDEO Nalco)
* 3: Silicone SM8704C (Toray Dow Corning Silicone)
[0064]
・ Second agent (cream) (wt%)
Hydrogen peroxide solution (35% by weight) 16.2
8-quinolinol sulfate 0.04
Polyoxyethylene (40) cetyl ether 1.0
Polyoxyethylene (2) cetyl ether 1.0
Polyoxyethylene (2) sodium lauryl ether sulfate 0.17
Cetostearyl alcohol 3.5
Phosphoric acid pH 3.5 to make purified water balance [0065]
Mixing ratio of the first agent and the second agent 1: 1
PH after mixing 10
Equivalent amino equivalent 26550 (g / mol)
Ion activity concentration ratio 0.10
[0066]
In the hair dye of Example 1, the hair from the time when the applied hair dye is rinsed off to the hair that has been damaged repeatedly through the shampoo treatment until the hair is completely dried is wet. In the stage, it has the effect of preventing squeak and tangling. In addition, the hair after drying is given glossiness and ease of uniting, and the hair dyeing power is also good.
[0067]
【The invention's effect】
The oxidative hair dye or depigmenting composition of the present invention has a squeaky feeling or entanglement in the stage where the hair is wet from the time of rinsing the composition applied to the hair to the time of drying the hair through the shampoo treatment. In particular, it is excellent in the effect of preventing hair, imparts glossiness and ease of uniting to hair, and has good hair dyeing power and decoloring power.
Claims (3)
（Ａ）不揮発性シリコーン
（Ｂ）カチオン性ポリマー
（Ｃ）水
を含有し、当該組成物中の
（Ｄ）アニオン界面活性剤及びアニオン性ポリマーから選ばれるアニオン基剤
の含有量が、成分（Ｂ）の含有量に対して、次の関係
「成分（Ｄ）の陰イオン活量濃度／成分（Ｂ）の陽イオン活量濃度≦０．８」
（イオン活量濃度とは、「モル濃度×イオン価数」を意味する）
を満たし、混合後のｐＨが８〜１２である酸化染毛剤又は脱色剤組成物。A composition comprising a first agent containing an alkali agent and an oxidation dye intermediate or a direct dye (in the case of a decoloring agent, not containing an oxidation dye intermediate and a direct dye) and a second agent containing hydrogen peroxide. In addition, the following components (A) to (C)
(A) Non-volatile silicone (B) Cationic polymer (C) Water is contained, and the content of an anionic base selected from (D) anionic surfactant and anionic polymer in the composition is component (B ) Content, the following relationship “component (D) anion activity concentration / component (B) cation activity concentration ≦ 0.8”
(The ion activity concentration means “molar concentration × ion valence”)
And an oxidative hair dye or decoloring composition having a pH of 8 to 12 after mixing.
換算アミノ当量（ｇ／ｍｏｌ）＝〔全組成物１ｇ中の全シリコーン類の総重量（ｇ／ｇ）〕／〔全組成物１ｇ中のアミノ変性シリコーンのアミノ基、イミノ基及びアンモニウム基の総モル数（ｍｏｌ／ｇ）〕
で表される換算アミノ当量が５００〜１０万ｇ／ｍｏｌの範囲内となる比率で含有するものである請求項１記載の酸化染毛剤又は脱色剤組成物。Component (A) is converted to the following formula converted amino equivalent (g / mol) = [total weight (g / g) of all silicones in 1 g of the whole composition] / [amino group of amino-modified silicone in 1 g of the whole composition] , Total number of moles of imino group and ammonium group (mol / g)]
The oxidative hair dye or decoloring composition according to claim 1, wherein the converted amino equivalent represented by the formula is contained at a ratio in the range of 500 to 100,000 g / mol.
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| JP2003190836A JP4116938B2 (en) | 2003-07-03 | 2003-07-03 | Oxidative hair dye or decolorant composition |
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| JP4116938B2 JP4116938B2 (en) | 2008-07-09 |
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| JP2006347971A (en) * | 2005-06-17 | 2006-12-28 | Shiseido Co Ltd | Hair bleaching agent composition and hair dye composition |
| JP2007039352A (en) * | 2005-08-01 | 2007-02-15 | Nakano Seiyaku Kk | Two agent type oxidative hair-dyeing/bleaching agent composition |
| JP2008285415A (en) * | 2007-05-15 | 2008-11-27 | Kao Corp | Oxidative hair-dying agent or bleaching agent composition |
| JP2008290954A (en) * | 2007-05-22 | 2008-12-04 | Kao Corp | Oxidation hair-dyeing or bleaching agent composition |
| JP2009196916A (en) * | 2008-02-20 | 2009-09-03 | Arimino Kagaku Kk | Dye-remover composition |
| WO2009059814A3 (en) * | 2007-11-09 | 2009-10-15 | Henkel Ag & Co. Kgaa | Styling agents giving a high degree of hold in humid conditions v |
| WO2010103795A1 (en) * | 2009-03-11 | 2010-09-16 | 花王株式会社 | Two-pack type hair dye product |
| WO2010103796A1 (en) * | 2009-03-11 | 2010-09-16 | 花王株式会社 | Two-pack type hair dye product |
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Cited By (9)
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|---|---|---|---|---|
| JP2006347971A (en) * | 2005-06-17 | 2006-12-28 | Shiseido Co Ltd | Hair bleaching agent composition and hair dye composition |
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| JP2008285415A (en) * | 2007-05-15 | 2008-11-27 | Kao Corp | Oxidative hair-dying agent or bleaching agent composition |
| JP2008290954A (en) * | 2007-05-22 | 2008-12-04 | Kao Corp | Oxidation hair-dyeing or bleaching agent composition |
| WO2009059814A3 (en) * | 2007-11-09 | 2009-10-15 | Henkel Ag & Co. Kgaa | Styling agents giving a high degree of hold in humid conditions v |
| JP2009196916A (en) * | 2008-02-20 | 2009-09-03 | Arimino Kagaku Kk | Dye-remover composition |
| WO2010103795A1 (en) * | 2009-03-11 | 2010-09-16 | 花王株式会社 | Two-pack type hair dye product |
| WO2010103796A1 (en) * | 2009-03-11 | 2010-09-16 | 花王株式会社 | Two-pack type hair dye product |
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