JP2004534140A5 - - Google Patents
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- Publication number
- JP2004534140A5 JP2004534140A5 JP2003512310A JP2003512310A JP2004534140A5 JP 2004534140 A5 JP2004534140 A5 JP 2004534140A5 JP 2003512310 A JP2003512310 A JP 2003512310A JP 2003512310 A JP2003512310 A JP 2003512310A JP 2004534140 A5 JP2004534140 A5 JP 2004534140A5
- Authority
- JP
- Japan
- Prior art keywords
- synthesis
- paa
- block polymer
- star
- ethylpropionyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 3
- 230000002194 synthesizing Effects 0.000 description 3
- 230000035980 PAA Effects 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- 229920001888 polyacrylic acid Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- APKCWEOABJGYMP-UHFFFAOYSA-N O-ethyl pentanoylsulfanylmethanethioate Chemical compound CCCCC(=O)SC(=S)OCC APKCWEOABJGYMP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical group CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N iso-propanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N precursor Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Description
例1
この例の課題は、スター構造ブロック重合体からのゲルの形成にある。
1/スターブロック重合体の合成
a)前駆物質アーム:PAA 5k −PAM 60k の合成
これは、二重ジャケット付反応器においてバッチ法に従って70℃で実施される。
・第一段階:PAA 5k −Xの合成
出発材料として、アクリル酸、水、S−エチルプロピオニルO−エチルキサンテート及びイソプロパノールを4,4−アゾ−ビス−4−シアノペンタン酸(以下、ACPと略記する)(キサンテート官能基Xに対して50%)と一緒に導入する。かくして、この混合物を70℃で6時間加熱する。
この例の課題は、スター構造ブロック重合体からのゲルの形成にある。
1/スターブロック重合体の合成
a)前駆物質アーム:PAA 5k −PAM 60k の合成
これは、二重ジャケット付反応器においてバッチ法に従って70℃で実施される。
・第一段階:PAA 5k −Xの合成
出発材料として、アクリル酸、水、S−エチルプロピオニルO−エチルキサンテート及びイソプロパノールを4,4−アゾ−ビス−4−シアノペンタン酸(以下、ACPと略記する)(キサンテート官能基Xに対して50%)と一緒に導入する。かくして、この混合物を70℃で6時間加熱する。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/904,947 US6559233B2 (en) | 2001-07-13 | 2001-07-13 | Composition comprising a copolymer at least two charged blocks and type of opposite charge |
PCT/FR2002/002481 WO2003006549A1 (fr) | 2001-07-13 | 2002-07-12 | Composition comprenant un copolymere portant au moins deux blocs ioniquement charges et un compose de charge ionique opposee |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2004534140A JP2004534140A (ja) | 2004-11-11 |
JP2004534140A5 true JP2004534140A5 (ja) | 2008-01-17 |
JP4313192B2 JP4313192B2 (ja) | 2009-08-12 |
Family
ID=25420020
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2003512310A Expired - Fee Related JP4313192B2 (ja) | 2001-07-13 | 2002-07-12 | 少なくとも2個のイオン帯電ブロックを有する共重合体と反対電荷を有する化合物とを含む組成物 |
Country Status (6)
Country | Link |
---|---|
US (1) | US6559233B2 (ja) |
EP (1) | EP1406970B1 (ja) |
JP (1) | JP4313192B2 (ja) |
AT (1) | ATE538174T1 (ja) |
ES (1) | ES2379344T3 (ja) |
WO (1) | WO2003006549A1 (ja) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE388970T1 (de) * | 2001-05-04 | 2008-03-15 | Rhodia Chimie Sa | Blockcopolymer-tenside durch eine kontrollierte radikalpolymerisation hergestellt |
AU2002358687A1 (en) * | 2001-12-12 | 2003-06-23 | Rhodia Chimie | Cosmetic composition comprising a block copolymer |
FR2837208B1 (fr) * | 2002-03-13 | 2004-06-18 | Rhodia Chimie Sa | Utilisation de copolymeres a blocs portant des fonctions phosphates et/ou phosphonates comme promoteurs d'adhesion ou comme agents de protection contre la corrosion d'une surface metallique |
US6784267B1 (en) * | 2002-07-25 | 2004-08-31 | Nalco Company | Polymers containing hyperbranched monomers |
US7468413B2 (en) * | 2004-01-30 | 2008-12-23 | Khodia Inc. | Rare earth aggregate formulation using di-block copolmers |
FR2868784B1 (fr) * | 2004-04-09 | 2006-05-26 | Oreal | Copolymere sequence, composition le comprenant et procede de traitement cosmetique |
US7838596B2 (en) * | 2005-09-16 | 2010-11-23 | Eastman Chemical Company | Late addition to effect compositional modifications in condensation polymers |
FR2897057B1 (fr) * | 2006-02-06 | 2008-06-13 | Lafarge Sa | Adjuvant pour compositions hydrauliques. |
EP2046850A1 (en) * | 2006-08-03 | 2009-04-15 | Ciba Holding Inc. | Block copolymers of diallyldialkylammonium derivatives |
US8283384B2 (en) | 2008-01-24 | 2012-10-09 | University Of Utah Research Foundation | Adhesive complex coacervates and methods of making and using thereof |
CN101978040A (zh) | 2008-01-24 | 2011-02-16 | 犹他卅大学研究基金会 | 胶粘复合凝聚物及其制备和使用方法 |
FR2934505B1 (fr) * | 2008-08-01 | 2011-12-16 | Rhodia Operations | Synthese de particules composites mineral/organique par formation d'un materiau mineral au sein d'un polymere |
US10392573B2 (en) * | 2008-10-17 | 2019-08-27 | Ecolab Usa Inc. | Method of controlling gas hydrates in fluid systems |
US8921478B2 (en) | 2008-10-17 | 2014-12-30 | Nalco Company | Method of controlling gas hydrates in fluid systems |
CA2788998A1 (en) * | 2010-02-26 | 2011-09-01 | University Of Utah Research Foundation | Adhesive complex coacervates produced from electrostatically associated block copolymers and methods for making and using the same |
CN103025360A (zh) | 2010-05-24 | 2013-04-03 | 犹他大学研究基金会 | 增强的粘合剂复合物凝聚层和其制备和使用方法 |
WO2012065148A2 (en) | 2010-11-12 | 2012-05-18 | University Of Utah Research Foundation | Simple adhesive coacervates and methods of making and using thereof |
US8618025B2 (en) | 2010-12-16 | 2013-12-31 | Nalco Company | Composition and method for reducing hydrate agglomeration |
WO2014123665A1 (en) | 2013-02-06 | 2014-08-14 | Kci Licensing, Inc. | Polymers, preparation and use thereof |
EP3632478B1 (en) | 2014-07-14 | 2022-09-28 | University of Utah Research Foundation | In situ solidifying solution and methods of making and using thereof |
JP6275282B2 (ja) | 2015-01-13 | 2018-02-07 | 三菱電機株式会社 | 半導体装置、その製造方法および半導体モジュール |
WO2019147922A2 (en) | 2018-01-26 | 2019-08-01 | Fluidx Medical Technology, Llc | Apparatus and method of using in situ solidifying complex coacervates for vascular occlusion |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5632998A (en) * | 1996-03-15 | 1997-05-27 | The Procter & Gamble Company | Personal care compositions containing hydrophobic graft copolymer and hydrophobic, volatile solvent |
US5785979A (en) * | 1997-01-21 | 1998-07-28 | The Procter & Gamble Company | Personal cleansing compositions |
-
2001
- 2001-07-13 US US09/904,947 patent/US6559233B2/en not_active Expired - Lifetime
-
2002
- 2002-07-12 EP EP02764982A patent/EP1406970B1/fr not_active Expired - Lifetime
- 2002-07-12 AT AT02764982T patent/ATE538174T1/de active
- 2002-07-12 WO PCT/FR2002/002481 patent/WO2003006549A1/fr active Application Filing
- 2002-07-12 JP JP2003512310A patent/JP4313192B2/ja not_active Expired - Fee Related
- 2002-07-12 ES ES02764982T patent/ES2379344T3/es not_active Expired - Lifetime
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