JP2004532910A5 - - Google Patents
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- JP2004532910A5 JP2004532910A5 JP2002576505A JP2002576505A JP2004532910A5 JP 2004532910 A5 JP2004532910 A5 JP 2004532910A5 JP 2002576505 A JP2002576505 A JP 2002576505A JP 2002576505 A JP2002576505 A JP 2002576505A JP 2004532910 A5 JP2004532910 A5 JP 2004532910A5
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- Prior art keywords
- fiber
- base material
- fiber substrate
- water
- chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000835 fiber Substances 0.000 claims 38
- 239000000758 substrate Substances 0.000 claims 27
- 239000000463 material Substances 0.000 claims 19
- 239000000178 monomer Substances 0.000 claims 12
- 229920000642 polymer Polymers 0.000 claims 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 9
- 239000000203 mixture Substances 0.000 claims 8
- 150000002500 ions Chemical class 0.000 claims 7
- 150000003839 salts Chemical class 0.000 claims 7
- 239000011780 sodium chloride Substances 0.000 claims 7
- 239000002904 solvent Substances 0.000 claims 7
- 239000011230 binding agent Substances 0.000 claims 5
- 239000000243 solution Substances 0.000 claims 5
- 229920003118 cationic copolymer Polymers 0.000 claims 4
- 230000002209 hydrophobic Effects 0.000 claims 4
- 238000009736 wetting Methods 0.000 claims 4
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims 3
- 125000000217 alkyl group Chemical group 0.000 claims 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical group CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims 3
- 125000002091 cationic group Chemical group 0.000 claims 3
- 239000002657 fibrous material Substances 0.000 claims 3
- -1 hydroxyalkyl acrylate Chemical compound 0.000 claims 3
- 239000002184 metal Substances 0.000 claims 3
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical group [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 claims 3
- 229920000126 Latex Polymers 0.000 claims 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N Methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims 2
- 239000002202 Polyethylene glycol Substances 0.000 claims 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 2
- 150000003926 acrylamides Chemical class 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical class C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- 229920001577 copolymer Polymers 0.000 claims 2
- 238000009472 formulation Methods 0.000 claims 2
- 239000004816 latex Substances 0.000 claims 2
- 229920001223 polyethylene glycol Polymers 0.000 claims 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N 2-hydroxyethyl 2-methylacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N Butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N Chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 claims 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L MgCl2 Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinylpyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims 1
- 239000002174 Styrene-butadiene Substances 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- ZGCZDEVLEULNLJ-UHFFFAOYSA-M benzyl-dimethyl-(2-prop-2-enoyloxyethyl)azanium;chloride Chemical compound [Cl-].C=CC(=O)OCC[N+](C)(C)CC1=CC=CC=C1 ZGCZDEVLEULNLJ-UHFFFAOYSA-M 0.000 claims 1
- CRGOPMLUWCMMCK-UHFFFAOYSA-M benzyl-dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)CC1=CC=CC=C1 CRGOPMLUWCMMCK-UHFFFAOYSA-M 0.000 claims 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L cacl2 Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 239000000839 emulsion Substances 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 239000005038 ethylene vinyl acetate Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000004745 nonwoven fabric Substances 0.000 claims 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims 1
- 229920005670 poly(ethylene-vinyl chloride) Polymers 0.000 claims 1
- 229920000728 polyester Polymers 0.000 claims 1
- 229920000915 polyvinyl chloride Polymers 0.000 claims 1
- 239000004800 polyvinyl chloride Substances 0.000 claims 1
- 239000011115 styrene butadiene Substances 0.000 claims 1
- 229920003048 styrene butadiene rubber Polymers 0.000 claims 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims 1
- 229920001897 terpolymer Polymers 0.000 claims 1
- 210000001519 tissues Anatomy 0.000 claims 1
- FZGFBJMPSHGTRQ-UHFFFAOYSA-M trimethyl(2-prop-2-enoyloxyethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCOC(=O)C=C FZGFBJMPSHGTRQ-UHFFFAOYSA-M 0.000 claims 1
- XYFKGIWPDOFXJH-UHFFFAOYSA-M trimethyl-[3-(2-methylprop-2-enoyloxy)-1-phenylpropyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCCC([N+](C)(C)C)C1=CC=CC=C1 XYFKGIWPDOFXJH-UHFFFAOYSA-M 0.000 claims 1
- OEIXGLMQZVLOQX-UHFFFAOYSA-N trimethyl-[3-(prop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCNC(=O)C=C OEIXGLMQZVLOQX-UHFFFAOYSA-N 0.000 claims 1
- SZYJELPVAFJOGJ-UHFFFAOYSA-N trimethylamine hydrochloride Chemical compound Cl.CN(C)C SZYJELPVAFJOGJ-UHFFFAOYSA-N 0.000 claims 1
- 239000002759 woven fabric Substances 0.000 claims 1
Claims (32)
- 繊維材料と、
該繊維材料を結合して一体構造のウェブにするポリマー組成物と、を備え、
該ポリマー組成物は、少なくともカチオン第4級アンモニウムモノマーと、1つか、それ以上の疎水性モノマーから形成されたカチオン・コポリマーからなることを特徴とする繊維基材。 - 前記カチオン第4級アンモニウムモノマーが、[2−(メタクリロイロキシ)エチル]塩化トリメチルアンモニウムと、(3−アクリルアミドプロピル)塩化トリメチルアンモニウムと、N、N−ジアリルジメチル塩化アンモニウム、アクリロキシエチルトリメチル塩化アンモニウム、アクリロキシエチルジメチルベンジル塩化アンモニウム、メタクリロキシエチルトリメチルベンジル塩化アンモニウム、メタクリロエチルジメチル塩化アンモニウム及びメタクリロキシエチルジメチルベンジル塩化アンモニウムからなる群から選択されるものであることを特徴とする請求項1に記載の繊維基材。
- 前記カチオン第4級アンモニウムモノマーは、[2−(メタクリロイロキシ)エチル]トリメチル塩化アンモニウムであることを特徴とする請求項2に記載の繊維基材。
- 前記少なくとも1つの疎水性モノマーは、n−アルキル置換モノマー単位、分岐アルキル置換モノマー単位、分岐アルキル置換モノマー単位、置換アクリルアミド及びアクリルエステルからなる群から選択されるものであることを特徴とする請求項1に記載の繊維基材。
- 前記少なくとも1つの疎水性モノマーは、n−アルキル及び分岐アルキル置換モノマー単位からなる群から選択されるものであることを特徴とする請求項1に記載の繊維基材。
- 前記少なくとも1つの疎水性モノマーは、n−ブチルアクリレート及び2−エチルヘキシルアクリレートからなる群から選択されるものであることを特徴とする請求項1に記載の繊維基材。
- 前記コポリマーは少なくとも1つの水溶性または親水性モノマーを含むように形成されていることを特徴とする請求項1に記載の繊維基材。
- 前記少なくとも1つの水溶性又は親水性モノマーは、アクリルアミド、メタアクリルアミド、置換アクリルアミド、置換メタアクリルアミド、ヒドロキシアルキルアクリレート、ヒドロキシアルキルメタアクリレート、ポリエチレングリコールアクリレート、ポリエチレングリコルメタアクレート及びビニルピロリドンからなる群から選択されるものであることを特徴とする請求項7に記載の繊維基材。
- 前記ポリマー組成物は少なくとも1つのコバインダポリマーを備えることを特徴とする請求項1に記載の繊維基材。
- 前記コバインダポリマーは、ポリ(エチレン−ビニルアセテート)、ポリ(スチレンーブタジエン)、ポリ(スチレン−アクリル)、ビニルアクリルターポリマー、ネオプレン、ポリエステルラテックス、アクリル乳液ラテックス、塩化ポリビニル、及びエチレンビニル塩化コポリマーからなる群から選択されるものであることを特徴とする請求項9に記載の繊維基材。
- 前記ポリマー組成物は、少なくとも一つの非架橋コバインダポリマーを備えることを特徴とする請求項1に記載の繊維基材。
- 前記ポリマー組成物において、前記非架橋コバインダポリマーが、前記カチオンコポリマー内に分散されており、前記カチオンコポリマーが連続相であり、前記コバインダポリマーは不連続相であることを特徴とする請求項11に記載の繊維基材。
- 前記コポリマーは、[2−(メタアクリロイロキシ)エチル]塩化トリメチルアンモニウム、n−ブチルアクリレート、及び2−エチルヘキシルアクリレートから形成されるものであることを特徴とする請求項1に記載の繊維基材。
- 前記前記コポリーは、2−(メタアクリロイロキシ)エチル]塩化トリメチルアンモニウム、n−ブチルアクリレート、及び2−エチルヘキシルアクリレート及びアクリルアミドから形成されるものであることを特徴とする請求項1に記載の繊維基材。
- 前記カチオンコポリマーの存在で水内で錯アニオンを形成できる二価金属塩を備えることを特徴とする請求項1から14のいずれかに記載の繊維基材。
- 前記繊維基材は、少なくとも約5重量パーセントの二価金属塩を含む水溶液内で不溶であり、前記繊維基材は、約200ppmまでの一価または多価イオンの一つまたはそれ以上を含む水内で分散できることを特徴とする請求項15に記載の繊維基材。
- 前記繊維基材は、織布または不織布であることを特徴とする請求項1から16のいずれかに記載の繊維基材。
- 前記繊維基材は、ティッシュウェブであることを特徴とする請求項1から16のいずれかに記載の繊維基材。
- 前記繊維基材は、乾式ウェブであることを特徴とする請求項1から16のいずれかに記載の繊維基材。
- 前記繊維基材は、水交絡されたウェブであることを特徴とする請求項1から16のいずれかに記載の基材。
- 前記繊維基材は、少なくとも約0.5重量パーセントの不溶剤を含む水内で実質的に分散できず、前記繊維基材は実質的に水分散できることを特徴とする請求項1から20のいずれかに記載の繊維基材。
- 前記不溶剤は、1つかそれ以上の多価イオンからなる塩を備え、前記繊維基材は、約200ppmまでの一価または多価イオンの一つまたはそれ以上を含む水内で分散可能であることを特徴とする請求項15に記載の繊維基材。
- 前記繊維基材は、十分な量の不溶剤を含む湿潤溶液によって湿潤にされ、前記バインダ配合物が前記湿潤溶液内で不溶性であることを特徴とする請求項1から22のいずれかに記載の繊維基材。
- 前記不溶剤は、一価または多価イオンを有する塩を備えることを特徴とする請求項23に記載の繊維基材。
- 前記繊維基材は、少なくとも約0.5重量パーセントの二価金属塩を含む湿潤溶液内で不溶であり、前記繊維基材は、約200ppmまでの一価または多価イオンの一つまたはそれ以上を含む水内で分散できることを特徴とする請求項23に記載の繊維基材。
- 前記不溶剤はZnCl2、MgCl2、CaCl2からなる群から選択される塩であることを特徴とする請求項24または25に記載の繊維基材。
- 請求項1から26のいずれかに記載の前記繊維基材からなる水分散可能物品。
- 前記分散可能物品は湿潤ワイプであることを特徴とする請求項27に記載の水溶性物品。
- 前記湿潤ワイプが少なくとも約100g/インチの使用時濡れ引張強度と、約1時間で約50ppmのCa2+及び/またはMg2+イオンの濃度を有する水に浸された後に約30g/インチ未満の引張強度を有するものであることを特徴とする請求項28に記載の水分散性物品。
- 請求項1から14のいずれかに記載のポリマー組成物を繊維材料基材に付与する段階を有する繊維基材を製造する方法。
- 十分な量の不溶剤を含む湿潤溶液を前記基材に付与する段階を備え、前記バインダ配合物は前記湿潤溶液内で不溶性であることを特徴とする請求項30に記載の方法。
- 前記不溶剤は、一価及び/または多価イオンからなる塩であることを特徴とする請求項31に記載の方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/815,261 US20030032352A1 (en) | 2001-03-22 | 2001-03-22 | Water-dispersible, cationic polymers, a method of making same and items using same |
PCT/US2002/004943 WO2002077048A2 (en) | 2001-03-22 | 2002-02-19 | Ion-sensitive cationic polymers and fibrous items using same |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2004532910A JP2004532910A (ja) | 2004-10-28 |
JP2004532910A5 true JP2004532910A5 (ja) | 2006-12-07 |
Family
ID=25217321
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2002576505A Pending JP2004532910A (ja) | 2001-03-22 | 2002-02-19 | 水分散可能なカチオン系ポリマー、その製造方法及びそれを用いる物品 |
Country Status (13)
Country | Link |
---|---|
US (2) | US20030032352A1 (ja) |
EP (1) | EP1379566B1 (ja) |
JP (1) | JP2004532910A (ja) |
KR (1) | KR100849259B1 (ja) |
CN (1) | CN100390212C (ja) |
AR (1) | AR033180A1 (ja) |
AU (1) | AU2002242199B2 (ja) |
BR (1) | BR0208316B1 (ja) |
DE (1) | DE60233122D1 (ja) |
MX (1) | MXPA03008244A (ja) |
RU (1) | RU2003131265A (ja) |
WO (1) | WO2002077048A2 (ja) |
ZA (1) | ZA200307029B (ja) |
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- 2002-02-19 CN CNB028098323A patent/CN100390212C/zh not_active Expired - Lifetime
- 2002-02-19 MX MXPA03008244A patent/MXPA03008244A/es active IP Right Grant
- 2002-02-19 DE DE60233122T patent/DE60233122D1/de not_active Expired - Lifetime
- 2002-02-19 RU RU2003131265/04A patent/RU2003131265A/ru not_active Application Discontinuation
- 2002-02-19 BR BR0208316A patent/BR0208316B1/pt not_active IP Right Cessation
- 2002-02-19 EP EP20020707820 patent/EP1379566B1/en not_active Expired - Lifetime
- 2002-02-19 KR KR1020037012185A patent/KR100849259B1/ko active IP Right Grant
- 2002-02-19 WO PCT/US2002/004943 patent/WO2002077048A2/en active IP Right Grant
- 2002-02-19 JP JP2002576505A patent/JP2004532910A/ja active Pending
- 2002-02-19 AU AU2002242199A patent/AU2002242199B2/en not_active Expired
- 2002-03-19 AR ARP020100979 patent/AR033180A1/es active IP Right Grant
-
2003
- 2003-01-01 ZA ZA200307029A patent/ZA200307029B/en unknown
- 2003-06-26 US US10/607,412 patent/US20040030080A1/en not_active Abandoned
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