JP2004532731A5 - - Google Patents
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- Publication number
- JP2004532731A5 JP2004532731A5 JP2003507044A JP2003507044A JP2004532731A5 JP 2004532731 A5 JP2004532731 A5 JP 2004532731A5 JP 2003507044 A JP2003507044 A JP 2003507044A JP 2003507044 A JP2003507044 A JP 2003507044A JP 2004532731 A5 JP2004532731 A5 JP 2004532731A5
- Authority
- JP
- Japan
- Prior art keywords
- tin
- catalyst system
- carbonylation catalyst
- group
- iridium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000006315 carbonylation Effects 0.000 claims 9
- 238000005810 carbonylation reaction Methods 0.000 claims 9
- 239000003054 catalyst Substances 0.000 claims 9
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 5
- 239000000203 mixture Substances 0.000 claims 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- 229910052741 iridium Inorganic materials 0.000 claims 3
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims 3
- OQBLGYCUQGDOOR-UHFFFAOYSA-L 1,3,2$l^{2}-dioxastannolane-4,5-dione Chemical compound O=C1O[Sn]OC1=O OQBLGYCUQGDOOR-UHFFFAOYSA-L 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical class CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 claims 2
- 229910021638 Iridium(III) chloride Inorganic materials 0.000 claims 2
- 229910021626 Tin(II) chloride Inorganic materials 0.000 claims 2
- GZUXJHMPEANEGY-UHFFFAOYSA-N bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 150000001721 carbon Chemical group 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- 150000004820 halides Chemical class 0.000 claims 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims 2
- 239000000376 reactant Substances 0.000 claims 2
- 235000011150 stannous chloride Nutrition 0.000 claims 2
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical group [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 claims 2
- DANYXEHCMQHDNX-UHFFFAOYSA-K trichloroiridium Chemical compound Cl[Ir](Cl)Cl DANYXEHCMQHDNX-UHFFFAOYSA-K 0.000 claims 2
- IQRUSQUYPCHEKN-UHFFFAOYSA-N 2-iodobutane Chemical compound CCC(C)I IQRUSQUYPCHEKN-UHFFFAOYSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 150000001350 alkyl halides Chemical class 0.000 claims 1
- 125000005233 alkylalcohol group Chemical group 0.000 claims 1
- -1 aryl carboxylate Chemical class 0.000 claims 1
- 150000001502 aryl halides Chemical class 0.000 claims 1
- RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 claims 1
- KMGBZBJJOKUPIA-UHFFFAOYSA-N butyl iodide Chemical compound CCCCI KMGBZBJJOKUPIA-UHFFFAOYSA-N 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 229910000042 hydrogen bromide Inorganic materials 0.000 claims 1
- 229910000039 hydrogen halide Inorganic materials 0.000 claims 1
- 239000012433 hydrogen halide Substances 0.000 claims 1
- 229910000043 hydrogen iodide Inorganic materials 0.000 claims 1
- 229940071870 hydroiodic acid Drugs 0.000 claims 1
- HVTICUPFWKNHNG-UHFFFAOYSA-N iodoethane Chemical compound CCI HVTICUPFWKNHNG-UHFFFAOYSA-N 0.000 claims 1
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 claims 1
- XJTQJERLRPWUGL-UHFFFAOYSA-N iodomethylbenzene Chemical compound ICC1=CC=CC=C1 XJTQJERLRPWUGL-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 229940102396 methyl bromide Drugs 0.000 claims 1
- PVWOIHVRPOBWPI-UHFFFAOYSA-N n-propyl iodide Chemical compound CCCI PVWOIHVRPOBWPI-UHFFFAOYSA-N 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical compound [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 claims 1
- 239000012808 vapor phase Substances 0.000 claims 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/885,473 US6548444B2 (en) | 2001-06-20 | 2001-06-20 | Tin promoted iridium catalyst for carbonylation of lower alkyl alcohols |
| PCT/US2002/018989 WO2003000409A1 (en) | 2001-06-20 | 2002-06-17 | Tin promoted iridium catalyst for carbonylation of lower alkyl alcohols |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004532731A JP2004532731A (ja) | 2004-10-28 |
| JP2004532731A5 true JP2004532731A5 (enExample) | 2006-01-05 |
| JP4485787B2 JP4485787B2 (ja) | 2010-06-23 |
Family
ID=25386976
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003507044A Expired - Fee Related JP4485787B2 (ja) | 2001-06-20 | 2002-06-17 | 低級アルキルアルコールのカルボニル化用錫促進イリジウム触媒 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6548444B2 (enExample) |
| EP (1) | EP1397207B1 (enExample) |
| JP (1) | JP4485787B2 (enExample) |
| CN (1) | CN100448531C (enExample) |
| AT (1) | ATE393663T1 (enExample) |
| DE (1) | DE60226320T2 (enExample) |
| WO (1) | WO2003000409A1 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7465822B2 (en) | 2005-05-05 | 2008-12-16 | Bp Chemicals Ltd. | Process for carbonylation of alkyl ethers |
| US20060252959A1 (en) * | 2005-05-05 | 2006-11-09 | The Regents Of The University Of California | Process for carbonylation of alkyl ethers |
| DE102005024049A1 (de) * | 2005-05-25 | 2006-11-30 | Robert Bosch Gmbh | Kraftstoff-Einspritzvorrichtung, insbesondere für eine Brennkraftmaschine mit Kraftstoff-Direkteinspritzung |
| US7507855B2 (en) * | 2006-12-15 | 2009-03-24 | The Regents Of The University Of California | Process for carbonylation of aliphatic alcohols and/or ester derivatives thereof |
| EP2199272A1 (en) * | 2008-11-27 | 2010-06-23 | BP Chemicals Limited | Carbonylation process |
| CN102564056B (zh) * | 2011-11-27 | 2014-04-16 | 张周卫 | Lng低温液化混合制冷剂多股流螺旋缠绕管式主换热装备 |
| US9421522B2 (en) | 2011-12-28 | 2016-08-23 | Eastman Chemical Company | Iridium catalysts for carbonylation |
| CN107486191B (zh) * | 2016-06-12 | 2020-06-23 | 中国科学院大连化学物理研究所 | 一种酸处理炭载体负载的铱基催化剂及其制备方法和应用 |
| CN110947386A (zh) * | 2019-11-21 | 2020-04-03 | 太原理工大学 | 一种二氧化碳加氢合成低碳醇催化剂的制备方法 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3717670A (en) | 1968-08-02 | 1973-02-20 | Monsanto Co | Production of carboxylic acids and esters |
| US3772380A (en) | 1970-03-12 | 1973-11-13 | Monsanto Co | Production of carboxylic acids and esters |
| US3689533A (en) | 1971-03-15 | 1972-09-05 | Monsanto Co | Production of carboxylic acids and esters |
| US3972805A (en) * | 1973-03-22 | 1976-08-03 | Universal Oil Products Company | Hydrocarbon conversion with an acidic, sulfur-free trimetallic catalytic composite |
| US4134912A (en) * | 1976-11-08 | 1979-01-16 | Halcon International, Inc. | Process for preparing carboxylic acids |
| US4417077A (en) | 1980-10-01 | 1983-11-22 | University Of Illinois Foundation | Heterogeneous anionic transition metal catalysts |
| US4612387A (en) | 1982-01-04 | 1986-09-16 | Air Products And Chemicals, Inc. | Production of carboxylic acids and esters |
| DE3463257D1 (en) | 1983-03-25 | 1987-05-27 | Texaco Development Corp | A process for producing carboxylic acids by carbonylation of alkanols over a carbon catalyst |
| US4625050A (en) | 1983-06-23 | 1986-11-25 | Chevron Research Company | Ether homologation to esters and alcohols using a heterogeneous sulfided catalyst |
| DE3323654A1 (de) | 1983-07-01 | 1985-01-03 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von essigsaeure und methylacetat |
| US5144068A (en) | 1984-05-03 | 1992-09-01 | Hoechst Celanese Corporation | Methanol carbonylation process |
| EP0203286B1 (de) | 1985-03-27 | 1988-09-14 | Hoechst Aktiengesellschaft | Trägerkatalysator und Verfahren zur Herstellung von Monocarbonsäureanhydriden |
| US4677094A (en) * | 1986-09-22 | 1987-06-30 | Uop Inc. | Trimetallic reforming catalyst |
| DE3643894A1 (de) | 1986-12-22 | 1988-06-23 | Degussa | Rhodium-haltige organopolysiloxan-ammoniumverbindungen, verfahren zu ihrer herstellung und verwendung |
| US5185462A (en) | 1987-01-08 | 1993-02-09 | Bp Chemicals Limited | Production of carboxylic acids and esters thereof |
| GB8807284D0 (en) | 1988-03-26 | 1988-04-27 | Bp Chem Int Ltd | Chemical process |
| US5218140A (en) | 1988-08-02 | 1993-06-08 | Union Carbide Chemicals & Plastics Technology Corporation | Carbonylation reaction and catalyst therefor |
| GB9013116D0 (en) | 1990-06-12 | 1990-08-01 | British Petroleum Co Plc | Carbonylation of methanol |
| DE4020941A1 (de) * | 1990-06-30 | 1992-01-02 | Bayer Ag | Verfahren zur herstellung von dialkylcarbonaten |
| US5488143A (en) | 1992-06-30 | 1996-01-30 | Korea Institute Of Science And Technology | Processes for the carbonylation of methanol to form acetic acid, methyl acetate and acetic anhydride |
| US5414161A (en) | 1992-06-30 | 1995-05-09 | Korea Institute Of Science And Technology | Process for the preparation of ethanol from methanol |
| GB9223170D0 (en) | 1992-11-05 | 1992-12-16 | British Petroleum Co Plc | Process for preparing carboxylic acids |
| FR2698351B1 (fr) * | 1992-11-26 | 1995-01-20 | Inst Francais Du Petrole | Procédé pour l'hydrogénation sélective de composés comportant des insaturations endo et exocycliques. |
| US5869729A (en) * | 1993-05-21 | 1999-02-09 | Ube Industries, Ltd. | Method of producing an ester compound |
| US5510524A (en) | 1995-02-21 | 1996-04-23 | Bp Chemicals Limited | Process for the production of a carboxylic acid |
| US6059960A (en) * | 1995-06-05 | 2000-05-09 | Uop Llc | Catalytic reforming utilizing a selective bifunctional multimetallic reforming catalyst |
| US5696284A (en) | 1995-06-21 | 1997-12-09 | Bp Chemicals Limited | Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof |
| GB9517184D0 (en) | 1995-08-22 | 1995-10-25 | Bp Chem Int Ltd | Process |
| US5900505A (en) | 1997-02-04 | 1999-05-04 | Eastman Chemical Company | Heterogeneous vapor phase carbonylation process |
| US6355595B1 (en) * | 1999-08-25 | 2002-03-12 | Eastman Chemical Company | Group 5 metal promoted iridium carbonylation catalyst |
| US6235673B1 (en) * | 2000-04-05 | 2001-05-22 | Eastman Chemical Company | Carbonylation catalyst supported on a carbonized polysulfonated divinylbenzene-styrene copolymer |
| US6613938B2 (en) * | 2001-06-19 | 2003-09-02 | Eastman Chemical Company | Method for carbonylation of lower aliphatic alcohols using tin promoted platinum catalyst |
-
2001
- 2001-06-20 US US09/885,473 patent/US6548444B2/en not_active Expired - Fee Related
-
2002
- 2002-06-17 EP EP02744360A patent/EP1397207B1/en not_active Expired - Lifetime
- 2002-06-17 JP JP2003507044A patent/JP4485787B2/ja not_active Expired - Fee Related
- 2002-06-17 WO PCT/US2002/018989 patent/WO2003000409A1/en not_active Ceased
- 2002-06-17 AT AT02744360T patent/ATE393663T1/de not_active IP Right Cessation
- 2002-06-17 DE DE60226320T patent/DE60226320T2/de not_active Expired - Lifetime
- 2002-06-17 CN CNB028090926A patent/CN100448531C/zh not_active Expired - Fee Related
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