JP2004531575A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2004531575A5 JP2004531575A5 JP2003506843A JP2003506843A JP2004531575A5 JP 2004531575 A5 JP2004531575 A5 JP 2004531575A5 JP 2003506843 A JP2003506843 A JP 2003506843A JP 2003506843 A JP2003506843 A JP 2003506843A JP 2004531575 A5 JP2004531575 A5 JP 2004531575A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- mixtures
- carbonylation
- iodide
- viii metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims 23
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 15
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 15
- 230000006315 carbonylation Effects 0.000 claims 15
- 238000005810 carbonylation reaction Methods 0.000 claims 15
- 239000000203 mixture Substances 0.000 claims 15
- 239000007789 gas Substances 0.000 claims 10
- 229910052751 metal Inorganic materials 0.000 claims 10
- 239000002184 metal Substances 0.000 claims 10
- 150000004820 halides Chemical class 0.000 claims 9
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 claims 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 8
- GZUXJHMPEANEGY-UHFFFAOYSA-N bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 claims 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 8
- 239000003054 catalyst Substances 0.000 claims 7
- 239000000376 reactant Substances 0.000 claims 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims 5
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims 5
- 125000004432 carbon atom Chemical group C* 0.000 claims 5
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 5
- 229910052721 tungsten Inorganic materials 0.000 claims 5
- 239000010937 tungsten Substances 0.000 claims 5
- 229910000042 hydrogen bromide Inorganic materials 0.000 claims 4
- 229910000043 hydrogen iodide Inorganic materials 0.000 claims 4
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 claims 4
- 229940102396 methyl bromide Drugs 0.000 claims 4
- 229910052763 palladium Inorganic materials 0.000 claims 4
- 229910052697 platinum Inorganic materials 0.000 claims 4
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 claims 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 3
- 229910052799 carbon Inorganic materials 0.000 claims 3
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 3
- 239000000463 material Substances 0.000 claims 3
- 239000011949 solid catalyst Substances 0.000 claims 3
- IQRUSQUYPCHEKN-UHFFFAOYSA-N 2-iodobutane Chemical compound CCC(C)I IQRUSQUYPCHEKN-UHFFFAOYSA-N 0.000 claims 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical group COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims 2
- 125000005233 alkylalcohol group Chemical group 0.000 claims 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 2
- 229910052794 bromium Inorganic materials 0.000 claims 2
- RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 claims 2
- KMGBZBJJOKUPIA-UHFFFAOYSA-N butyl iodide Chemical compound CCCCI KMGBZBJJOKUPIA-UHFFFAOYSA-N 0.000 claims 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical group II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims 2
- HVTICUPFWKNHNG-UHFFFAOYSA-N iodoethane Chemical compound CCI HVTICUPFWKNHNG-UHFFFAOYSA-N 0.000 claims 2
- XJTQJERLRPWUGL-UHFFFAOYSA-N iodomethylbenzene Chemical compound ICC1=CC=CC=C1 XJTQJERLRPWUGL-UHFFFAOYSA-N 0.000 claims 2
- PVWOIHVRPOBWPI-UHFFFAOYSA-N n-propyl iodide Chemical compound CCCI PVWOIHVRPOBWPI-UHFFFAOYSA-N 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- 239000007787 solid Substances 0.000 claims 2
- -1 alkane polyols Chemical class 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 150000001350 alkyl halides Chemical class 0.000 claims 1
- 150000001502 aryl halides Chemical class 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 229910000039 hydrogen halide Inorganic materials 0.000 claims 1
- 239000012433 hydrogen halide Substances 0.000 claims 1
- 229940071870 hydroiodic acid Drugs 0.000 claims 1
- 229910052740 iodine Inorganic materials 0.000 claims 1
- 229920000570 polyether Polymers 0.000 claims 1
- 229920005862 polyol Polymers 0.000 claims 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/884,938 US6646154B2 (en) | 2001-06-20 | 2001-06-20 | Method for carbonylation of lower alkyl alcohols using tungsten promoted group VIII catalyst |
| PCT/US2002/018990 WO2003000639A1 (en) | 2001-06-20 | 2002-06-17 | Vapor-phase carbonylation of lower alkyl alcohols using tungsten promoted group viii catalyst |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004531575A JP2004531575A (ja) | 2004-10-14 |
| JP2004531575A5 true JP2004531575A5 (enExample) | 2006-01-05 |
| JP4188817B2 JP4188817B2 (ja) | 2008-12-03 |
Family
ID=25385766
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003506843A Expired - Fee Related JP4188817B2 (ja) | 2001-06-20 | 2002-06-17 | タングステン促進第ｖｉｉｉ族触媒を用いた低級アルキルアルコールの気相カルボニル化 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6646154B2 (enExample) |
| EP (1) | EP1397338B1 (enExample) |
| JP (1) | JP4188817B2 (enExample) |
| CN (1) | CN1255373C (enExample) |
| AT (1) | ATE414684T1 (enExample) |
| DE (1) | DE60229937D1 (enExample) |
| WO (1) | WO2003000639A1 (enExample) |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3717670A (en) | 1968-08-02 | 1973-02-20 | Monsanto Co | Production of carboxylic acids and esters |
| US3772380A (en) | 1970-03-12 | 1973-11-13 | Monsanto Co | Production of carboxylic acids and esters |
| US3689533A (en) | 1971-03-15 | 1972-09-05 | Monsanto Co | Production of carboxylic acids and esters |
| US4417077A (en) | 1980-10-01 | 1983-11-22 | University Of Illinois Foundation | Heterogeneous anionic transition metal catalysts |
| US4612387A (en) | 1982-01-04 | 1986-09-16 | Air Products And Chemicals, Inc. | Production of carboxylic acids and esters |
| US4625049A (en) | 1982-06-30 | 1986-11-25 | Chevron Research Company | Alcohol carbonylation process using a bimetallic nickel catalyst |
| DE3463257D1 (en) | 1983-03-25 | 1987-05-27 | Texaco Development Corp | A process for producing carboxylic acids by carbonylation of alkanols over a carbon catalyst |
| US4625050A (en) | 1983-06-23 | 1986-11-25 | Chevron Research Company | Ether homologation to esters and alcohols using a heterogeneous sulfided catalyst |
| DE3323654A1 (de) | 1983-07-01 | 1985-01-03 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von essigsaeure und methylacetat |
| US5144068A (en) | 1984-05-03 | 1992-09-01 | Hoechst Celanese Corporation | Methanol carbonylation process |
| EP0203286B1 (de) | 1985-03-27 | 1988-09-14 | Hoechst Aktiengesellschaft | Trägerkatalysator und Verfahren zur Herstellung von Monocarbonsäureanhydriden |
| DE3643894A1 (de) | 1986-12-22 | 1988-06-23 | Degussa | Rhodium-haltige organopolysiloxan-ammoniumverbindungen, verfahren zu ihrer herstellung und verwendung |
| US5185462A (en) | 1987-01-08 | 1993-02-09 | Bp Chemicals Limited | Production of carboxylic acids and esters thereof |
| GB8807284D0 (en) | 1988-03-26 | 1988-04-27 | Bp Chem Int Ltd | Chemical process |
| US5218140A (en) | 1988-08-02 | 1993-06-08 | Union Carbide Chemicals & Plastics Technology Corporation | Carbonylation reaction and catalyst therefor |
| GB9013116D0 (en) | 1990-06-12 | 1990-08-01 | British Petroleum Co Plc | Carbonylation of methanol |
| US5414161A (en) | 1992-06-30 | 1995-05-09 | Korea Institute Of Science And Technology | Process for the preparation of ethanol from methanol |
| US5488143A (en) | 1992-06-30 | 1996-01-30 | Korea Institute Of Science And Technology | Processes for the carbonylation of methanol to form acetic acid, methyl acetate and acetic anhydride |
| GB9223170D0 (en) | 1992-11-05 | 1992-12-16 | British Petroleum Co Plc | Process for preparing carboxylic acids |
| US5510524A (en) | 1995-02-21 | 1996-04-23 | Bp Chemicals Limited | Process for the production of a carboxylic acid |
| US5696284A (en) | 1995-06-21 | 1997-12-09 | Bp Chemicals Limited | Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof |
| GB9517184D0 (en) | 1995-08-22 | 1995-10-25 | Bp Chem Int Ltd | Process |
| US5900505A (en) | 1997-02-04 | 1999-05-04 | Eastman Chemical Company | Heterogeneous vapor phase carbonylation process |
| WO1998033590A1 (en) | 1997-02-04 | 1998-08-06 | Eastman Chemical Company | Carbonylation catalyst |
| WO2000048979A1 (en) | 1999-02-16 | 2000-08-24 | Eastman Chemical Company | Catalyst having solid and vaporous component for the carbonylation of lower alkyl alcohols |
| US6160163A (en) | 1999-02-16 | 2000-12-12 | Eastman Chemical Company | Method for the vapor-phase carbonylation of lower aliphatic alcohols using a supported platinum catalyst and halide promoter |
-
2001
- 2001-06-20 US US09/884,938 patent/US6646154B2/en not_active Expired - Fee Related
-
2002
- 2002-06-17 CN CN02812378.6A patent/CN1255373C/zh not_active Expired - Fee Related
- 2002-06-17 AT AT02746543T patent/ATE414684T1/de not_active IP Right Cessation
- 2002-06-17 DE DE60229937T patent/DE60229937D1/de not_active Expired - Lifetime
- 2002-06-17 WO PCT/US2002/018990 patent/WO2003000639A1/en not_active Ceased
- 2002-06-17 EP EP02746543A patent/EP1397338B1/en not_active Expired - Lifetime
- 2002-06-17 JP JP2003506843A patent/JP4188817B2/ja not_active Expired - Fee Related
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2004529769A5 (enExample) | ||
| JPH11315046A (ja) | 酢酸製造のための無水カルボニル化法 | |
| JPH09124543A5 (enExample) | ||
| JP2003530378A5 (enExample) | ||
| JP2004531576A5 (enExample) | ||
| JP2003507445A5 (enExample) | ||
| JP2002537277A5 (enExample) | ||
| JP2003507446A5 (enExample) | ||
| JP4485787B2 (ja) | 低級アルキルアルコールのカルボニル化用錫促進イリジウム触媒 | |
| JP2004531575A5 (enExample) | ||
| KR20010051596A (ko) | 아세트산의 제조 방법 | |
| JPH0343257B2 (enExample) | ||
| US6509293B1 (en) | Gold based heterogeneous carbonylation catalysts | |
| EP0060695B1 (en) | Process for the coproduction of a c2 to c10 monocarboxylic acid and formic acid | |
| CA1304749C (en) | Process for the co-production of aromatic carboxylates and alkyl iodides | |
| EP0075335B1 (en) | Process for the co-production of carboxylic acids and carboxylic acid esters | |
| EP0247159B1 (en) | Process for the co-production of aromatic carboxylates and alkyl iodides | |
| CN1370096A (zh) | 第4族金属改进的铱羰基化催化剂 | |
| CA1304748C (en) | Process for the co-production of aromatic carboxylates and alkyl iodides | |
| JPH0125729B2 (enExample) | ||
| JPH0643364B2 (ja) | β，γ―不飽和酸の製造方法 | |
| JPH01501865A (ja) | 芳香族カルボキシレート及び沃化アルキルの共製造方法 | |
| US6506933B1 (en) | Vapor phase carbonylation process using gold catalysts | |
| CN1555353A (zh) | 采用金催化剂的汽相羰基化工艺 | |
| US4912250A (en) | Process for the co-production of aromatic carboxylate and alkyl iodide |