JP2004503412A - シリカで充填されたエラストマー組成物を製造する方法 - Google Patents
シリカで充填されたエラストマー組成物を製造する方法 Download PDFInfo
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- JP2004503412A JP2004503412A JP2002510592A JP2002510592A JP2004503412A JP 2004503412 A JP2004503412 A JP 2004503412A JP 2002510592 A JP2002510592 A JP 2002510592A JP 2002510592 A JP2002510592 A JP 2002510592A JP 2004503412 A JP2004503412 A JP 2004503412A
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- Prior art keywords
- rubber
- silica
- blend
- styrene
- isoprene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 260
- 239000000203 mixture Substances 0.000 title claims abstract description 193
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 129
- 229920001971 elastomer Polymers 0.000 title claims abstract description 123
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- 239000000806 elastomer Substances 0.000 title claims description 31
- 239000005060 rubber Substances 0.000 claims abstract description 93
- 229920001577 copolymer Polymers 0.000 claims abstract description 73
- 238000002156 mixing Methods 0.000 claims abstract description 46
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 38
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims abstract description 22
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920001897 terpolymer Polymers 0.000 claims abstract description 11
- VDQOXWRCEPPGRE-UHFFFAOYSA-N 1-(2-bromoethenyl)-4-methylbenzene Chemical compound CC1=CC=C(C=CBr)C=C1 VDQOXWRCEPPGRE-UHFFFAOYSA-N 0.000 claims abstract description 8
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 claims abstract description 7
- HKMVWLQFAYGKSI-UHFFFAOYSA-N 3-triethoxysilylpropyl thiocyanate Chemical compound CCO[Si](OCC)(OCC)CCCSC#N HKMVWLQFAYGKSI-UHFFFAOYSA-N 0.000 claims abstract description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 5
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 51
- 239000005062 Polybutadiene Substances 0.000 claims description 29
- 229920002857 polybutadiene Polymers 0.000 claims description 28
- 239000000945 filler Substances 0.000 claims description 27
- 239000007822 coupling agent Substances 0.000 claims description 25
- 239000006229 carbon black Substances 0.000 claims description 22
- 229920003052 natural elastomer Polymers 0.000 claims description 22
- 229920001194 natural rubber Polymers 0.000 claims description 22
- 244000043261 Hevea brasiliensis Species 0.000 claims description 21
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 18
- 229920001195 polyisoprene Polymers 0.000 claims description 17
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 15
- 229920005549 butyl rubber Polymers 0.000 claims description 14
- 229920005683 SIBR Polymers 0.000 claims description 11
- VLLYOYVKQDKAHN-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene Chemical compound C=CC=C.CC(=C)C=C VLLYOYVKQDKAHN-UHFFFAOYSA-N 0.000 claims description 11
- -1 alkoxy silane, methacrylate Chemical compound 0.000 claims description 10
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 claims description 9
- 229920003049 isoprene rubber Polymers 0.000 claims description 9
- 229920000459 Nitrile rubber Polymers 0.000 claims description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- 239000011593 sulfur Substances 0.000 claims description 7
- 239000003963 antioxidant agent Substances 0.000 claims description 6
- 150000001282 organosilanes Chemical class 0.000 claims description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 3
- 125000005843 halogen group Chemical group 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 2
- JHXWINGYJFCASF-UHFFFAOYSA-N 1-trimethoxysilylpropane-2-thiol Chemical compound CO[Si](OC)(OC)CC(C)S JHXWINGYJFCASF-UHFFFAOYSA-N 0.000 claims description 2
- TVYXSFBEKKZTSF-UHFFFAOYSA-N 2-chloropropyl(triethoxy)silane Chemical compound CCO[Si](CC(C)Cl)(OCC)OCC TVYXSFBEKKZTSF-UHFFFAOYSA-N 0.000 claims description 2
- JSYFUEKVXFEXSX-UHFFFAOYSA-N 2-chloropropyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CC(C)Cl JSYFUEKVXFEXSX-UHFFFAOYSA-N 0.000 claims description 2
- PGPAJJPJQNBBDR-UHFFFAOYSA-N 2-methyl-4-trimethoxysilylhex-1-en-3-one Chemical compound CC(=C)C(=O)C(CC)[Si](OC)(OC)OC PGPAJJPJQNBBDR-UHFFFAOYSA-N 0.000 claims description 2
- KQVVPOMBWBKNRS-UHFFFAOYSA-N 3-(1,3-benzothiazol-2-yl)propyl-triethoxysilane Chemical compound C1=CC=C2SC(CCC[Si](OCC)(OCC)OCC)=NC2=C1 KQVVPOMBWBKNRS-UHFFFAOYSA-N 0.000 claims description 2
- KSCAZPYHLGGNPZ-UHFFFAOYSA-N 3-chloropropyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)CCCCl KSCAZPYHLGGNPZ-UHFFFAOYSA-N 0.000 claims description 2
- OXYZDRAJMHGSMW-UHFFFAOYSA-N 3-chloropropyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCCCl OXYZDRAJMHGSMW-UHFFFAOYSA-N 0.000 claims description 2
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 claims description 2
- FSPIGXNLDXWYKZ-UHFFFAOYSA-N CCO[Si](CCC[S+]=C(N(C)C)SSSSC(N(C)C)=[S+]CCC[Si](OCC)(OCC)OCC)(OCC)OCC Chemical compound CCO[Si](CCC[S+]=C(N(C)C)SSSSC(N(C)C)=[S+]CCC[Si](OCC)(OCC)OCC)(OCC)OCC FSPIGXNLDXWYKZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000003973 alkyl amines Chemical class 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 150000001343 alkyl silanes Chemical class 0.000 claims description 2
- 150000001356 alkyl thiols Chemical class 0.000 claims description 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 2
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 claims description 2
- 230000026030 halogenation Effects 0.000 claims description 2
- 238000005658 halogenation reaction Methods 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 125000000018 nitroso group Chemical group N(=O)* 0.000 claims description 2
- RGVRXQRVWRZQRY-UHFFFAOYSA-N s-(carbamoyltrisulfanyl) carbamothioate Chemical compound NC(=O)SSSSC(N)=O RGVRXQRVWRZQRY-UHFFFAOYSA-N 0.000 claims description 2
- ASAOXGWSIOQTDI-UHFFFAOYSA-N triethoxy-[2-(2-triethoxysilylethyltetrasulfanyl)ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCSSSSCC[Si](OCC)(OCC)OCC ASAOXGWSIOQTDI-UHFFFAOYSA-N 0.000 claims description 2
- JSXKIRYGYMKWSK-UHFFFAOYSA-N trimethoxy-[2-(2-trimethoxysilylethyltetrasulfanyl)ethyl]silane Chemical compound CO[Si](OC)(OC)CCSSSSCC[Si](OC)(OC)OC JSXKIRYGYMKWSK-UHFFFAOYSA-N 0.000 claims description 2
- JTTSZDBCLAKKAY-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSSSCCC[Si](OC)(OC)OC JTTSZDBCLAKKAY-UHFFFAOYSA-N 0.000 claims description 2
- UXCIYFROPFBGDZ-UHFFFAOYSA-N 2-methylthiirane-2-carboxylic acid Chemical compound OC(=O)C1(C)CS1 UXCIYFROPFBGDZ-UHFFFAOYSA-N 0.000 claims 1
- IABJHLPWGMWHLX-UHFFFAOYSA-N 3-(1,3-benzothiazol-2-yl)propyl-trimethoxysilane Chemical compound C1=CC=C2SC(CCC[Si](OC)(OC)OC)=NC2=C1 IABJHLPWGMWHLX-UHFFFAOYSA-N 0.000 claims 1
- SKFGZHGVWONCTD-UHFFFAOYSA-N CN(C)C(SSSSC(N(C)C)=[S+]CCC[Si](OC)(OC)OC)=[S+]CCC[Si](OC)(OC)OC Chemical compound CN(C)C(SSSSC(N(C)C)=[S+]CCC[Si](OC)(OC)OC)=[S+]CCC[Si](OC)(OC)OC SKFGZHGVWONCTD-UHFFFAOYSA-N 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 238000010074 rubber mixing Methods 0.000 claims 1
- FPBXRRDHCADTAL-UHFFFAOYSA-N triethoxy(3-nitropropyl)silane Chemical compound CCO[Si](OCC)(OCC)CCC[N+]([O-])=O FPBXRRDHCADTAL-UHFFFAOYSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 39
- 238000009472 formulation Methods 0.000 description 29
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 28
- 229910000077 silane Inorganic materials 0.000 description 28
- 235000019241 carbon black Nutrition 0.000 description 16
- 239000004594 Masterbatch (MB) Substances 0.000 description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 10
- 150000001993 dienes Chemical class 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- 230000003993 interaction Effects 0.000 description 8
- 238000005096 rolling process Methods 0.000 description 8
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 7
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- 239000010703 silicon Substances 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 7
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 6
- 239000011787 zinc oxide Substances 0.000 description 6
- 238000004132 cross linking Methods 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 238000004073 vulcanization Methods 0.000 description 5
- 239000006057 Non-nutritive feed additive Substances 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
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- 125000003118 aryl group Chemical group 0.000 description 4
- 239000004927 clay Substances 0.000 description 4
- 239000012764 mineral filler Substances 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 239000004848 polyfunctional curative Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 229920003211 cis-1,4-polyisoprene Polymers 0.000 description 3
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 3
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- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- HHZDRADWWVVISO-UHFFFAOYSA-N 2-methyl-3-(3-trimethoxysilylpropyl)thiirane-2-carboxylic acid Chemical compound CO[Si](OC)(OC)CCCC1SC1(C)C(O)=O HHZDRADWWVVISO-UHFFFAOYSA-N 0.000 description 2
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical compound CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 2
- RUROFEVDCUGKHD-UHFFFAOYSA-N 3-bromoprop-1-enylbenzene Chemical compound BrCC=CC1=CC=CC=C1 RUROFEVDCUGKHD-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
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- UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 description 2
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- PGAXJQVAHDTGBB-UHFFFAOYSA-N dibutylcarbamothioylsulfanyl n,n-dibutylcarbamodithioate Chemical compound CCCCN(CCCC)C(=S)SSC(=S)N(CCCC)CCCC PGAXJQVAHDTGBB-UHFFFAOYSA-N 0.000 description 2
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- 239000008117 stearic acid Substances 0.000 description 2
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- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 2
- 229960002447 thiram Drugs 0.000 description 2
- IFNXAMCERSVZCV-UHFFFAOYSA-L zinc;2-ethylhexanoate Chemical compound [Zn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O IFNXAMCERSVZCV-UHFFFAOYSA-L 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- 238000011925 1,2-addition Methods 0.000 description 1
- ZARCFEHBDQIZSJ-UHFFFAOYSA-N 1-triethoxysilylpropane-2-thiol Chemical compound CCO[Si](CC(C)S)(OCC)OCC ZARCFEHBDQIZSJ-UHFFFAOYSA-N 0.000 description 1
- MHNNAWXXUZQSNM-UHFFFAOYSA-N 2-methylbut-1-ene Chemical compound CCC(C)=C MHNNAWXXUZQSNM-UHFFFAOYSA-N 0.000 description 1
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- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 238000010348 incorporation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- QPPXVBLDIDEHBA-UHFFFAOYSA-N trimethoxy(3-nitropropyl)silane Chemical compound CO[Si](OC)(OC)CCC[N+]([O-])=O QPPXVBLDIDEHBA-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7476—Systems, i.e. flow charts or diagrams; Plants
- B29B7/7495—Systems, i.e. flow charts or diagrams; Plants for mixing rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
- C08L23/283—Halogenated homo- or copolymers of iso-olefins
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US21104900P | 2000-06-13 | 2000-06-13 | |
US09/592,757 US6624220B1 (en) | 1997-12-15 | 2000-06-13 | Transparent and colorable elastomeric compositions |
PCT/US2001/014975 WO2001096463A2 (en) | 2000-06-13 | 2001-05-09 | Method for preparing silica filled elastomeric compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2004503412A true JP2004503412A (ja) | 2004-02-05 |
Family
ID=26905764
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2002510592A Withdrawn JP2004503412A (ja) | 2000-06-13 | 2001-05-09 | シリカで充填されたエラストマー組成物を製造する方法 |
Country Status (14)
Country | Link |
---|---|
EP (1) | EP1309657A2 (hu) |
JP (1) | JP2004503412A (hu) |
KR (1) | KR20030008157A (hu) |
CN (1) | CN1177893C (hu) |
AU (1) | AU2001259675A1 (hu) |
BR (1) | BR0111626A (hu) |
CA (1) | CA2413094A1 (hu) |
CZ (1) | CZ20024077A3 (hu) |
HU (1) | HUP0302341A2 (hu) |
MX (1) | MXPA02012466A (hu) |
PL (1) | PL359968A1 (hu) |
RU (1) | RU2002134760A (hu) |
TW (1) | TW539710B (hu) |
WO (1) | WO2001096463A2 (hu) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009096147A (ja) * | 2007-10-19 | 2009-05-07 | Sumitomo Rubber Ind Ltd | ブラダー用ゴム組成物およびそれを用いたタイヤ加硫用ブラダー |
JP2011522925A (ja) * | 2008-07-24 | 2011-08-04 | インダストリアス ネグロメックス ソシエダ アノニマ ド キャピタル バリアブル | シリカマスターバッチを製造する方法 |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2383474A1 (en) * | 2002-04-26 | 2003-10-26 | Bayer Inc. | Rubber composition for tire treads |
US7201944B2 (en) * | 2002-12-18 | 2007-04-10 | Bridgestone Firestone North American Tire, Llc | Rubber compositions and articles thereof having improved metal adhesion and metal adhesion retention with bright steel |
FR2856071B1 (fr) * | 2003-06-16 | 2005-08-12 | Atofina | Agent de couplage pour composition elastomerique comprenant une charge renforcante |
KR100738655B1 (ko) | 2005-09-28 | 2007-07-11 | 금호타이어 주식회사 | 점착성이 우수한 타이어 에이펙스용 고무 조성물 |
KR100718168B1 (ko) | 2005-09-30 | 2007-05-15 | 금호타이어 주식회사 | 나노충진제와 커플링제를 포함하는 타이어용 고무조성물 |
WO2008071208A1 (en) * | 2006-12-13 | 2008-06-19 | Pirelli Tyre S.P.A. | Tire and crosslinkable elastomeric composition |
US7625965B2 (en) * | 2007-02-08 | 2009-12-01 | Momentive Performance Materials Inc. | Rubber composition, process of preparing same and articles made therefrom |
KR100871991B1 (ko) * | 2007-09-27 | 2008-12-05 | 금호타이어 주식회사 | 타이어 트레드 고무조성물 |
US7816435B2 (en) * | 2007-10-31 | 2010-10-19 | Momentive Performance Materials Inc. | Halo-functional silane, process for its preparation, rubber composition containing same and articles manufactured therefrom |
PL2819854T3 (pl) * | 2012-03-02 | 2020-11-02 | Cabot Corporation | Kompozyty elastomerowe zawierające zmodyfikowane wypełniacze i elastomery sfunkcjonalizowane |
CA2975175C (en) | 2015-01-28 | 2020-01-28 | Dow Corning Corporation | Elastomeric compositions and their applications |
CN107641228B (zh) * | 2016-07-20 | 2022-10-21 | 中国石油化工股份有限公司 | 有机硅烷的应用和橡胶组合物以及硫化橡胶及其制备方法 |
GB201613399D0 (en) | 2016-08-03 | 2016-09-14 | Dow Corning | Cosmetic composition comprising silicone materials |
GB201613412D0 (en) * | 2016-08-03 | 2016-09-14 | Dow Corning | Elastomeric compositions and their applications |
GB201613414D0 (en) | 2016-08-03 | 2016-09-14 | Dow Corning | Elastomeric compositions and their applications |
GB201613397D0 (en) | 2016-08-03 | 2016-09-14 | Dow Corning | Cosmetic composition comprising silicone materials |
GB201707437D0 (en) | 2017-05-09 | 2017-06-21 | Dow Corning | Lamination adhesive compositions and their applications |
GB201707439D0 (en) | 2017-05-09 | 2017-06-21 | Dow Corning | Lamination Process |
JP7209011B2 (ja) * | 2018-04-11 | 2023-01-19 | エクソンモービル ケミカル パテンツ インコーポレイテッド | タイヤトレッド性能改善のためのブチルゴム添加剤 |
US20230039642A1 (en) * | 2019-12-17 | 2023-02-09 | Exxonmobil Chemical Patents Inc. | Functionalized Polymers Tread Additive To Improve Truck And Bus Radial Tire Performance |
CN116285125B (zh) * | 2023-03-28 | 2024-01-19 | 常州窗友塑胶有限公司 | 一种密封胶条及其制备方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2661915B1 (fr) * | 1990-05-11 | 1993-12-24 | Rhone Poulenc Chimie | Composition elastometrique a matrice halogenobutyl renforcee par une charge minerale siliceuse et son utilisation dans l'industrie pneumatique. |
US5162409B1 (en) * | 1991-08-02 | 1997-08-26 | Pirelli Armstrong Tire Corp | Tire tread rubber composition |
CA2125736A1 (en) * | 1994-05-05 | 1995-11-06 | David John Zanzig | Tire tread with quantitative silica reinforcement |
DE69817398T2 (de) * | 1997-12-15 | 2004-06-09 | Exxonmobil Chemical Patents Inc., Baytown | Transparente und färbbare elastomerzusammensetzung |
-
2001
- 2001-05-09 AU AU2001259675A patent/AU2001259675A1/en not_active Abandoned
- 2001-05-09 HU HU0302341A patent/HUP0302341A2/hu unknown
- 2001-05-09 EP EP01933233A patent/EP1309657A2/en not_active Withdrawn
- 2001-05-09 CA CA002413094A patent/CA2413094A1/en not_active Abandoned
- 2001-05-09 PL PL35996801A patent/PL359968A1/xx not_active Application Discontinuation
- 2001-05-09 KR KR1020027016958A patent/KR20030008157A/ko not_active Application Discontinuation
- 2001-05-09 CZ CZ20024077A patent/CZ20024077A3/cs unknown
- 2001-05-09 BR BR0111626-6A patent/BR0111626A/pt not_active IP Right Cessation
- 2001-05-09 CN CNB018110495A patent/CN1177893C/zh not_active Expired - Fee Related
- 2001-05-09 RU RU2002134760/04A patent/RU2002134760A/ru not_active Application Discontinuation
- 2001-05-09 MX MXPA02012466A patent/MXPA02012466A/es not_active Application Discontinuation
- 2001-05-09 WO PCT/US2001/014975 patent/WO2001096463A2/en not_active Application Discontinuation
- 2001-05-09 JP JP2002510592A patent/JP2004503412A/ja not_active Withdrawn
- 2001-06-12 TW TW090114191A patent/TW539710B/zh not_active IP Right Cessation
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009096147A (ja) * | 2007-10-19 | 2009-05-07 | Sumitomo Rubber Ind Ltd | ブラダー用ゴム組成物およびそれを用いたタイヤ加硫用ブラダー |
JP2011522925A (ja) * | 2008-07-24 | 2011-08-04 | インダストリアス ネグロメックス ソシエダ アノニマ ド キャピタル バリアブル | シリカマスターバッチを製造する方法 |
JP2013079400A (ja) * | 2008-07-24 | 2013-05-02 | Industrias Negromex Sa De Cv | シリカ充填ゴムを製造する方法 |
Also Published As
Publication number | Publication date |
---|---|
MXPA02012466A (es) | 2003-04-25 |
WO2001096463A2 (en) | 2001-12-20 |
CN1177893C (zh) | 2004-12-01 |
CN1436210A (zh) | 2003-08-13 |
TW539710B (en) | 2003-07-01 |
BR0111626A (pt) | 2003-05-06 |
HUP0302341A2 (hu) | 2003-10-28 |
EP1309657A2 (en) | 2003-05-14 |
CZ20024077A3 (cs) | 2004-01-14 |
WO2001096463A3 (en) | 2002-05-23 |
KR20030008157A (ko) | 2003-01-24 |
PL359968A1 (en) | 2004-09-06 |
CA2413094A1 (en) | 2001-12-20 |
RU2002134760A (ru) | 2004-07-27 |
AU2001259675A1 (en) | 2001-12-24 |
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