WO2001096463A3 - Method for preparing silica filled elastomeric compositions - Google Patents

Method for preparing silica filled elastomeric compositions Download PDF

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Publication number
WO2001096463A3
WO2001096463A3 PCT/US2001/014975 US0114975W WO0196463A3 WO 2001096463 A3 WO2001096463 A3 WO 2001096463A3 US 0114975 W US0114975 W US 0114975W WO 0196463 A3 WO0196463 A3 WO 0196463A3
Authority
WO
WIPO (PCT)
Prior art keywords
silica
copolymer
para
general purpose
mixing
Prior art date
Application number
PCT/US2001/014975
Other languages
French (fr)
Other versions
WO2001096463A2 (en
Inventor
Wai Keung Wong
Hsien-Chang Wang
Timothy A Mills
Original Assignee
Exxonmobil Chem Patents Inc
Wai Keung Wong
Wang Hsien Chang
Timothy A Mills
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/592,757 external-priority patent/US6624220B1/en
Priority to JP2002510592A priority Critical patent/JP2004503412A/en
Priority to CA002413094A priority patent/CA2413094A1/en
Priority to HU0302341A priority patent/HUP0302341A2/en
Priority to US10/297,689 priority patent/US20040014869A1/en
Priority to PL35996801A priority patent/PL359968A1/en
Application filed by Exxonmobil Chem Patents Inc, Wai Keung Wong, Wang Hsien Chang, Timothy A Mills filed Critical Exxonmobil Chem Patents Inc
Priority to AU2001259675A priority patent/AU2001259675A1/en
Priority to EP01933233A priority patent/EP1309657A2/en
Priority to BR0111626-6A priority patent/BR0111626A/en
Priority to MXPA02012466A priority patent/MXPA02012466A/en
Publication of WO2001096463A2 publication Critical patent/WO2001096463A2/en
Publication of WO2001096463A3 publication Critical patent/WO2001096463A3/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • C08K5/541Silicon-containing compounds containing oxygen
    • C08K5/5415Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • C08K5/5419Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/74Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
    • B29B7/7476Systems, i.e. flow charts or diagrams; Plants
    • B29B7/7495Systems, i.e. flow charts or diagrams; Plants for mixing rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C08L23/22Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • C08L23/283Halogenated homo- or copolymers of iso-olefins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

A process for preparing a cross-linked blend comprising a) mixing a copolymer of a C4 to C7 isoolefin and a para-alkylstyrene with silica, b) separately mixing a general purpose rubber with silica, wherein one or more silane coupling agents is mixed with at least one of the silica/copolymer or silica/general purpose rubber blends, and c) mixing the silica/copolymer blend with the silica/general purpose rubber blend. Typical silane coupling agents include bis(3-triethoxysilylpropyl) tetrasulfide, 3-thiocyanatopropyl-triethoxysilane, 3-mercaptopropyl-trimethoxy silane, and one embodiment of the copolymer is a terpolymer of isobutylene, para-methylstyrene, and bromo-para-methylstyrene.
PCT/US2001/014975 2000-06-13 2001-05-09 Method for preparing silica filled elastomeric compositions WO2001096463A2 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
MXPA02012466A MXPA02012466A (en) 2000-06-13 2001-05-09 Method for preparing silica filled elastomeric compositions.
CA002413094A CA2413094A1 (en) 2000-06-13 2001-05-09 Method for preparing silica filled elastomeric compositions
HU0302341A HUP0302341A2 (en) 2000-06-13 2001-05-09 Method for preparing silica filled elastomeric compositions
US10/297,689 US20040014869A1 (en) 2001-05-09 2001-05-09 Method for preparing silica filled elastomeric compositions
PL35996801A PL359968A1 (en) 2000-06-13 2001-05-09 Method for preparing silica filled elastomeric compositions
JP2002510592A JP2004503412A (en) 2000-06-13 2001-05-09 Method for producing an elastomer composition filled with silica
AU2001259675A AU2001259675A1 (en) 2000-06-13 2001-05-09 Method for preparing silica filled elastomeric compositions
EP01933233A EP1309657A2 (en) 2000-06-13 2001-05-09 Method for preparing silica filled elastomeric compositions
BR0111626-6A BR0111626A (en) 2000-06-13 2001-05-09 Process for the preparation of silica-charged elastomeric compositions

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US21104900P 2000-06-13 2000-06-13
US09/592,757 US6624220B1 (en) 1997-12-15 2000-06-13 Transparent and colorable elastomeric compositions
US60/211,049 2000-06-13
US09/592,757 2000-06-13

Publications (2)

Publication Number Publication Date
WO2001096463A2 WO2001096463A2 (en) 2001-12-20
WO2001096463A3 true WO2001096463A3 (en) 2002-05-23

Family

ID=26905764

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2001/014975 WO2001096463A2 (en) 2000-06-13 2001-05-09 Method for preparing silica filled elastomeric compositions

Country Status (14)

Country Link
EP (1) EP1309657A2 (en)
JP (1) JP2004503412A (en)
KR (1) KR20030008157A (en)
CN (1) CN1177893C (en)
AU (1) AU2001259675A1 (en)
BR (1) BR0111626A (en)
CA (1) CA2413094A1 (en)
CZ (1) CZ20024077A3 (en)
HU (1) HUP0302341A2 (en)
MX (1) MXPA02012466A (en)
PL (1) PL359968A1 (en)
RU (1) RU2002134760A (en)
TW (1) TW539710B (en)
WO (1) WO2001096463A2 (en)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2383474A1 (en) * 2002-04-26 2003-10-26 Bayer Inc. Rubber composition for tire treads
US7201944B2 (en) * 2002-12-18 2007-04-10 Bridgestone Firestone North American Tire, Llc Rubber compositions and articles thereof having improved metal adhesion and metal adhesion retention with bright steel
FR2856071B1 (en) * 2003-06-16 2005-08-12 Atofina COUPLING AGENT FOR ELASTOMERIC COMPOSITION COMPRISING A REINFORCING LOAD
KR100738655B1 (en) 2005-09-28 2007-07-11 금호타이어 주식회사 The apex rubber compound with improved tack
KR100718168B1 (en) 2005-09-30 2007-05-15 금호타이어 주식회사 Rubber composition for tire including nano-filler and coupling agent
EP2102017B1 (en) * 2006-12-13 2010-12-01 Pirelli Tyre S.p.A. Tire and crosslinkable elastomeric composition
US7625965B2 (en) * 2007-02-08 2009-12-01 Momentive Performance Materials Inc. Rubber composition, process of preparing same and articles made therefrom
KR100871991B1 (en) * 2007-09-27 2008-12-05 금호타이어 주식회사 Tire tread rubber composition
JP5421525B2 (en) * 2007-10-19 2014-02-19 住友ゴム工業株式会社 Rubber composition for bladder and bladder for tire vulcanization using the same
US7816435B2 (en) * 2007-10-31 2010-10-19 Momentive Performance Materials Inc. Halo-functional silane, process for its preparation, rubber composition containing same and articles manufactured therefrom
CA2724798C (en) * 2008-07-24 2014-08-26 Industrias Negromex, S.A. De C.V. Processes for making silane, hydrophobated silica, silica masterbatch and rubber products
RU2598464C2 (en) * 2012-03-02 2016-09-27 Кабот Корпорейшн Elastomeric composites containing modified fillers and functionalised elastomers
CN112940509B (en) 2015-01-28 2023-03-28 美国陶氏有机硅公司 Elastomer composition and use thereof
CN107641228B (en) * 2016-07-20 2022-10-21 中国石油化工股份有限公司 Use of organosilanes and rubber compositions and vulcanizates and process for their preparation
GB201613397D0 (en) 2016-08-03 2016-09-14 Dow Corning Cosmetic composition comprising silicone materials
GB201613412D0 (en) * 2016-08-03 2016-09-14 Dow Corning Elastomeric compositions and their applications
GB201613399D0 (en) 2016-08-03 2016-09-14 Dow Corning Cosmetic composition comprising silicone materials
GB201613414D0 (en) 2016-08-03 2016-09-14 Dow Corning Elastomeric compositions and their applications
GB201707437D0 (en) 2017-05-09 2017-06-21 Dow Corning Lamination adhesive compositions and their applications
GB201707439D0 (en) 2017-05-09 2017-06-21 Dow Corning Lamination Process
US11834536B2 (en) * 2018-04-11 2023-12-05 Exxonmobil Chemical Patents Inc. Butyl rubber additives for improved tire tread performance
WO2021126629A1 (en) * 2019-12-17 2021-06-24 Exxonmobil Chemical Patents Inc. Functionalized polymers tread additive to improve truck and bus radial tire performance
CN116285125B (en) * 2023-03-28 2024-01-19 常州窗友塑胶有限公司 Sealing adhesive tape and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0527396A1 (en) * 1991-08-02 1993-02-17 Pirelli Armstrong Tire Corporation Tire tread rubber composition
EP0682071A1 (en) * 1994-05-05 1995-11-15 The Goodyear Tire & Rubber Company Tire tread with quantitative silica reinforcement
US5475051A (en) * 1990-05-11 1995-12-12 Rhone-Poulenc Chimie Halobutyl/epoxidized rubber matrices reinforced with siliceous filler materials
WO1999031178A1 (en) * 1997-12-15 1999-06-24 Exxon Chemical Patents Inc. Transparent and colorable elastomeric compositions

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5475051A (en) * 1990-05-11 1995-12-12 Rhone-Poulenc Chimie Halobutyl/epoxidized rubber matrices reinforced with siliceous filler materials
EP0527396A1 (en) * 1991-08-02 1993-02-17 Pirelli Armstrong Tire Corporation Tire tread rubber composition
EP0682071A1 (en) * 1994-05-05 1995-11-15 The Goodyear Tire & Rubber Company Tire tread with quantitative silica reinforcement
WO1999031178A1 (en) * 1997-12-15 1999-06-24 Exxon Chemical Patents Inc. Transparent and colorable elastomeric compositions

Also Published As

Publication number Publication date
CZ20024077A3 (en) 2004-01-14
CN1177893C (en) 2004-12-01
EP1309657A2 (en) 2003-05-14
MXPA02012466A (en) 2003-04-25
HUP0302341A2 (en) 2003-10-28
RU2002134760A (en) 2004-07-27
TW539710B (en) 2003-07-01
CN1436210A (en) 2003-08-13
BR0111626A (en) 2003-05-06
AU2001259675A1 (en) 2001-12-24
WO2001096463A2 (en) 2001-12-20
KR20030008157A (en) 2003-01-24
JP2004503412A (en) 2004-02-05
CA2413094A1 (en) 2001-12-20
PL359968A1 (en) 2004-09-06

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