JP2004500359A - １５族化合物から誘導されるオレフィン重合助触媒及びその使用法 - Google Patents

１５族化合物から誘導されるオレフィン重合助触媒及びその使用法 Download PDF

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JP2004500359A
JP2004500359A JP2001543547A JP2001543547A JP2004500359A JP 2004500359 A JP2004500359 A JP 2004500359A JP 2001543547 A JP2001543547 A JP 2001543547A JP 2001543547 A JP2001543547 A JP 2001543547A JP 2004500359 A JP2004500359 A JP 2004500359A
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tetrakis
methyl
ammonium
borate
propyl
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JP2004500359A5 (https=
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ロドリゲス、ジョージ
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エクソンモービル・ケミカル・パテンツ・インク
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/325—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals directly attached to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D205/00—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom
    • C07D205/02—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D205/04—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/04—Indoles; Hydrogenated indoles
    • C07D209/08—Indoles; Hydrogenated indoles with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to carbon atoms of the hetero ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/06—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by halogen atoms or nitro radicals
    • C07D295/073—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by halogen atoms or nitro radicals with the ring nitrogen atoms and the substituents separated by carbocyclic rings or by carbon chains interrupted by carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/027—Organoboranes and organoborohydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C07F9/5442—Aromatic phosphonium compounds (P-C aromatic linkage)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2001543547A 1999-12-09 2000-12-11 １５族化合物から誘導されるオレフィン重合助触媒及びその使用法 Withdrawn JP2004500359A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US16987699P 1999-12-09 1999-12-09
US16976899P 1999-12-09 1999-12-09
PCT/US2000/033590 WO2001042249A1 (en) 1999-12-09 2000-12-11 Olefin polymerization cocatalysts derived from group-15 compounds and processes using them

Publications (2)

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JP2004500359A true JP2004500359A (ja) 2004-01-08
JP2004500359A5 JP2004500359A5 (https=) 2008-02-21

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JP2001543547A Withdrawn JP2004500359A (ja) 1999-12-09 2000-12-11 １５族化合物から誘導されるオレフィン重合助触媒及びその使用法

Country Status (11)

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EP (2) EP1252166B1 (https=)
JP (1) JP2004500359A (https=)
KR (1) KR20020060989A (https=)
CN (1) CN1413217A (https=)
AT (1) ATE309252T1 (https=)
BR (1) BR0016270A (https=)
CA (1) CA2391855A1 (https=)
DE (1) DE60023945T2 (https=)
ES (1) ES2249320T3 (https=)
MX (1) MXPA02005642A (https=)
WO (1) WO2001042249A1 (https=)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013501843A (ja) * 2009-08-14 2013-01-17 エクソンモービル・ケミカル・パテンツ・インク 触媒系、オレフィン重合方法、及びそれから製造されたポリマー組成物
JP2022511901A (ja) * 2019-05-17 2022-02-01 エルジー・ケム・リミテッド 無水炭化水素溶媒を用いた助触媒化合物の製造方法
JPWO2022045175A1 (https=) * 2020-08-28 2022-03-03
JP2022069397A (ja) * 2020-10-23 2022-05-11 三井化学株式会社 第１３族元素含有化合物、オレフィン重合用触媒、およびオレフィン重合体の製造方法

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GB0021301D0 (en) * 2000-08-30 2000-10-18 Borealis Tech Oy Supported catalyst
EP1406761B1 (en) * 2001-06-20 2016-11-02 ExxonMobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
CN101624397A (zh) * 2003-05-12 2010-01-13 住友化学株式会社 发光聚合物组合物
US7872086B2 (en) 2008-01-17 2011-01-18 Tonen Chemical Corporation Polymeric material and its manufacture and use
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
WO2009123609A1 (en) 2008-03-31 2009-10-08 Advanced Elastomer Systems, L.P. Thermoplastic vulcanizates
US7799879B2 (en) 2008-08-01 2010-09-21 Exxonmobil Chemical Patents Inc. Catalyst system and process for olefin polymerization
CN102112499B (zh) * 2008-08-01 2014-02-05 埃克森美孚化学专利公司 催化剂体系和用于烯烃聚合的方法
ES2798272T3 (es) 2011-11-08 2020-12-10 Univation Tech Llc Métodos de preparación de un sistema catalítico
JP7216184B2 (ja) 2018-07-23 2023-01-31 エクソンモービル・ケミカル・パテンツ・インク バイモーダルゴム、熱可塑性加硫物の調製およびそれから作られた物品
EP4176005A1 (en) 2020-07-02 2023-05-10 Celanese International Corporation Thermoplastic vulcanizate compositions containing metallocene multimodal copolymer rubber and processes for making same

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Publication number Priority date Publication date Assignee Title
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
JPH04366109A (ja) * 1991-06-12 1992-12-18 Idemitsu Kosan Co Ltd スチレン系重合体の製造方法及びその触媒
JPH07509752A (ja) * 1992-08-05 1995-10-26 エクソン・ケミカル・パテンツ・インク オレフィン重合用の担持されたイオン遷移金属触媒
DE69322225T2 (de) * 1992-09-22 1999-05-12 Idemitsu Kosan Co. Ltd., Tokio/Tokyo Polymerisationskatalysatore und Verfahren zur Herstellung von Polymeren
US5885924A (en) * 1995-06-07 1999-03-23 W. R. Grace & Co.-Conn. Halogenated supports and supported activators
ATE194629T1 (de) * 1996-03-27 2000-07-15 Dow Chemical Co Hochlösliches aktivierungsmittel für olefinpolymerisationskatalysator
EP0914353B1 (en) * 1996-07-23 2002-09-04 The Dow Chemical Company Olefin polymerization catalyst composition comprising group 13 compound
JPH11316434A (ja) * 1998-05-01 1999-11-16 Konica Corp ハロゲン化銀カラー写真感光材料の画像形成方法及び画像情報記録方法

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013501843A (ja) * 2009-08-14 2013-01-17 エクソンモービル・ケミカル・パテンツ・インク 触媒系、オレフィン重合方法、及びそれから製造されたポリマー組成物
JP2022511901A (ja) * 2019-05-17 2022-02-01 エルジー・ケム・リミテッド 無水炭化水素溶媒を用いた助触媒化合物の製造方法
JP7205983B2 (ja) 2019-05-17 2023-01-17 エルジー・ケム・リミテッド 無水炭化水素溶媒を用いた助触媒化合物の製造方法
US12318766B2 (en) 2019-05-17 2025-06-03 Lg Chem, Ltd. Method for preparing cocatalyst compound using anhydrous hydrocarbon solvent
TWI889682B (zh) * 2019-05-17 2025-07-11 南韓商Ｌｇ化學股份有限公司 使用無水烴溶劑製備輔觸媒化合物之方法
JPWO2022045175A1 (https=) * 2020-08-28 2022-03-03
WO2022045175A1 (ja) * 2020-08-28 2022-03-03 Ａｇｃ株式会社 含フッ素アルキルアンモニウムボレート化合物及びその製造方法
JP7720505B2 (ja) 2020-08-28 2025-08-08 Ａｇｃ株式会社 含フッ素アルキルアンモニウムボレート化合物及びその製造方法
US12600805B2 (en) 2020-08-28 2026-04-14 AGC Inc. Fluorine-containing alkyl ammonium borate compound and method for producing same
JP2022069397A (ja) * 2020-10-23 2022-05-11 三井化学株式会社 第１３族元素含有化合物、オレフィン重合用触媒、およびオレフィン重合体の製造方法
JP7713343B2 (ja) 2020-10-23 2025-07-25 三井化学株式会社 第１３族元素含有化合物、オレフィン重合用触媒、およびオレフィン重合体の製造方法

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EP1661900A1 (en) 2006-05-31
ES2249320T3 (es) 2006-04-01
BR0016270A (pt) 2002-08-13
WO2001042249A1 (en) 2001-06-14
EP1252166A1 (en) 2002-10-30
EP1252166B1 (en) 2005-11-09
KR20020060989A (ko) 2002-07-19
MXPA02005642A (es) 2002-09-02
CA2391855A1 (en) 2001-06-14
CN1413217A (zh) 2003-04-23
DE60023945T2 (de) 2006-07-27
DE60023945D1 (de) 2005-12-15
ATE309252T1 (de) 2005-11-15

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