JP2004190030A5 - - Google Patents
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- Publication number
- JP2004190030A5 JP2004190030A5 JP2003406953A JP2003406953A JP2004190030A5 JP 2004190030 A5 JP2004190030 A5 JP 2004190030A5 JP 2003406953 A JP2003406953 A JP 2003406953A JP 2003406953 A JP2003406953 A JP 2003406953A JP 2004190030 A5 JP2004190030 A5 JP 2004190030A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- independently
- optionally
- alkyl
- nitrile rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003446 ligand Substances 0.000 claims description 18
- 229920000642 polymer Polymers 0.000 claims description 18
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 229920000459 Nitrile rubber Polymers 0.000 claims description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- 239000002131 composite material Substances 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 8
- 229930195733 hydrocarbon Natural products 0.000 claims description 8
- 230000007935 neutral effect Effects 0.000 claims description 8
- -1 phosphinamine Chemical compound 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- 125000003860 C1-C20 alkoxy group Chemical group 0.000 claims description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- 125000003302 alkenyloxy group Chemical group 0.000 claims description 6
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 6
- 125000004644 alkyl sulfinyl group Chemical group 0.000 claims description 6
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims description 6
- 125000004414 alkyl thio group Chemical group 0.000 claims description 6
- 125000000304 alkynyl group Chemical group 0.000 claims description 6
- 125000005133 alkynyloxy group Chemical group 0.000 claims description 6
- 125000000129 anionic group Chemical group 0.000 claims description 6
- 125000004104 aryloxy group Chemical group 0.000 claims description 6
- 150000007942 carboxylates Chemical class 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 238000005984 hydrogenation reaction Methods 0.000 claims description 6
- 229910052762 osmium Inorganic materials 0.000 claims description 6
- 150000003003 phosphines Chemical class 0.000 claims description 6
- 125000003358 C2-C20 alkenyl group Chemical group 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 4
- 150000001450 anions Chemical class 0.000 claims description 4
- 239000003431 cross linking reagent Substances 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 4
- 229910052707 ruthenium Inorganic materials 0.000 claims description 4
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical group [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims description 2
- 125000005078 alkoxycarbonylalkyl group Chemical group 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 125000004103 aminoalkyl group Chemical group 0.000 claims description 2
- RBFQJDQYXXHULB-UHFFFAOYSA-N arsane Chemical compound [AsH3] RBFQJDQYXXHULB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052785 arsenic Inorganic materials 0.000 claims description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 2
- 238000010531 catalytic reduction reaction Methods 0.000 claims description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000007306 functionalization reaction Methods 0.000 claims description 2
- 125000001188 haloalkyl group Chemical group 0.000 claims description 2
- 150000002466 imines Chemical class 0.000 claims description 2
- 238000011065 in-situ storage Methods 0.000 claims description 2
- 239000012442 inert solvent Substances 0.000 claims description 2
- 238000005649 metathesis reaction Methods 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 125000002950 monocyclic group Chemical group 0.000 claims description 2
- 125000005538 phosphinite group Chemical group 0.000 claims description 2
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims description 2
- 125000003367 polycyclic group Chemical group 0.000 claims description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 125000003375 sulfoxide group Chemical group 0.000 claims description 2
- 150000003462 sulfoxides Chemical class 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 2
- 150000003568 thioethers Chemical class 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 239000004971 Cross linker Substances 0.000 claims 2
- 150000002461 imidazolidines Chemical class 0.000 claims 1
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- 241001441571 Hiodontidae Species 0.000 description 1
- WRYCSMQKUKOKBP-UHFFFAOYSA-N Imidazolidine Chemical compound C1CNCN1 WRYCSMQKUKOKBP-UHFFFAOYSA-N 0.000 description 1
- 229920006170 Therban® Polymers 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000002815 homogeneous catalyst Substances 0.000 description 1
- 229920006168 hydrated nitrile rubber Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002413607A CA2413607A1 (en) | 2002-12-05 | 2002-12-05 | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004190030A JP2004190030A (ja) | 2004-07-08 |
| JP2004190030A5 true JP2004190030A5 (https=) | 2007-01-25 |
| JP4667738B2 JP4667738B2 (ja) | 2011-04-13 |
Family
ID=32304018
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003406953A Expired - Fee Related JP4667738B2 (ja) | 2002-12-05 | 2003-12-05 | 低分子量水素化ニトリルゴムの製造方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7381781B2 (https=) |
| EP (3) | EP1621577A3 (https=) |
| JP (1) | JP4667738B2 (https=) |
| CN (3) | CN101016349A (https=) |
| CA (1) | CA2413607A1 (https=) |
| DE (1) | DE60319325T2 (https=) |
| RU (1) | RU2356913C9 (https=) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2409429A1 (en) * | 2002-10-17 | 2004-04-17 | Bayer Inc. | Hydrogenated nitrile rubber composites with improved proccesability |
| CA2462005A1 (en) * | 2004-02-23 | 2005-08-23 | Bayer Inc. | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
| EP1757623A1 (en) * | 2005-07-14 | 2007-02-28 | Lanxess Inc. | Process for the preparation of low mooney nitrile terpolymers |
| ATE538139T1 (de) * | 2005-08-30 | 2012-01-15 | Lanxess Deutschland Gmbh | Verwendung von katalysatoren für den metatheseabbau von nitrilkautschuk |
| DE102006008520A1 (de) | 2006-02-22 | 2007-08-23 | Lanxess Deutschland Gmbh | Neue Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen |
| DE102006008521A1 (de) * | 2006-02-22 | 2007-08-23 | Lanxess Deutschland Gmbh | Verwendung von Katalysatoren mit erhöhter Aktivität für die NBR-Metathese |
| DE102006040569A1 (de) * | 2006-08-30 | 2008-03-06 | Lanxess Deutschland Gmbh | Verfahren zum Metathese-Abbau von Nitrilkautschuken |
| DE102007024008A1 (de) * | 2007-05-22 | 2008-11-27 | Lanxess Deutschland Gmbh | Nitrilkautschuke |
| DE102007039525A1 (de) * | 2007-08-21 | 2009-02-26 | Lanxess Deutschland Gmbh | Verfahren zum Metathese-Abbau von Nitrilkautschuk |
| DE102007039526A1 (de) | 2007-08-21 | 2009-02-26 | Lanxess Deutschland Gmbh | Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen |
| EP2028194B1 (en) | 2007-08-21 | 2010-05-12 | Lanxess Deutschland GmbH | Metathesis of nitrile rubbers in the presence of transition metal complex catalysts |
| EP2072532A1 (en) | 2007-12-21 | 2009-06-24 | Lanxess Deutschland GmbH | A process for removing iron-residues, rhodium- and ruthenium-containing catalyst residues from optionally hydrogenated nitrile rubber |
| CA2646056A1 (en) | 2007-12-21 | 2009-06-21 | Lanxess Deutschland Gmbh | A process for removing ruthenium-containing catalyst residues from optionally hydrogenated nitrile rubber |
| TW200934662A (en) * | 2007-12-28 | 2009-08-16 | Du Pont | Method for reworking adhesively bonded liquid crystal displays |
| BRPI0906732A2 (pt) * | 2008-01-29 | 2015-07-07 | Lanxess Deutschland Gmbh | Borrachas nitrílicas que contêm opcionalmente grupos terminais alquiltio e que são opcionalmente hidrogenadas |
| EP2147721A1 (de) * | 2008-07-08 | 2010-01-27 | Lanxess Deutschland GmbH | Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen |
| EP2143489A1 (de) * | 2008-07-08 | 2010-01-13 | Lanxess Deutschland GmbH | Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen |
| KR101409075B1 (ko) | 2008-09-12 | 2014-06-23 | 란세스 인크. | 향상된 내열성, 압축영구변형률, 및 가공성을 가지는 신규 엘라스토머 조성물 |
| EP2289622A1 (en) | 2009-08-31 | 2011-03-02 | LANXESS Deutschland GmbH | Ruthenium based catalysts for the metathesis of nitrile rubbers |
| EP2289623A1 (en) | 2009-08-31 | 2011-03-02 | LANXESS Deutschland GmbH | Metathesis of nitrile rubbers in the presence of transition metal catalysts |
| EP2289621A1 (en) * | 2009-08-31 | 2011-03-02 | LANXESS Deutschland GmbH | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
| EP2473279B1 (en) * | 2009-08-31 | 2014-04-02 | LANXESS Deutschland GmbH | Metathesis of a nitrile rubber in the presence of a transition metal catalyst |
| WO2011079439A1 (en) | 2009-12-30 | 2011-07-07 | Zannan Scitech Co., Ltd. | Highly active metathesis catalysts selective for romp and rcm reactions |
| EP2418225A1 (de) | 2010-08-09 | 2012-02-15 | LANXESS Deutschland GmbH | Teilhydrierte Nitrilkautschuke |
| RU2482915C2 (ru) * | 2010-08-13 | 2013-05-27 | Открытое акционерное общество "СИБУР Холдинг"(ОАО "СИБУР Холдинг") | Рутениевый катализатор селективного гидрирования ненасыщенных полимеров и способ гидрирования ненасыщенных полимеров |
| EP2423238A1 (de) * | 2010-08-31 | 2012-02-29 | LANXESS Deutschland GmbH | Verfahren zur Herstellung von Nitrilkautschuken in organischen Lösungsmitteln |
| EP2484700B1 (de) | 2011-02-04 | 2013-10-09 | LANXESS Deutschland GmbH | Funktionalisierte Nitrilkautschuke und ihre Herstellung |
| RU2492193C2 (ru) * | 2011-03-12 | 2013-09-10 | Открытое акционерное общество "Беларусьрезинотехника" | Композиционный материал на основе гидрированного бутадиен-нитрильного и акрилатного каучуков |
| WO2013056463A1 (en) * | 2011-10-21 | 2013-04-25 | Lanxess Deutschland Gmbh | Catalyst compositions and their use for hydrogenation of nitrile rubber |
| WO2013056459A1 (en) * | 2011-10-21 | 2013-04-25 | Lanxess Deutschland Gmbh | Catalyst compositions and their use for hydrogenation of nitrile rubber |
| WO2013098056A1 (en) | 2011-12-28 | 2013-07-04 | Lanxess Deutschland Gmbh | Purification of optionally hydrogenated nitrile rubber |
| CN104271607B (zh) * | 2012-04-28 | 2017-05-24 | 阿朗新科德国有限责任公司 | 丁腈橡胶的氢化 |
| CN105622783B (zh) * | 2014-10-29 | 2017-06-30 | 中国石油化工股份有限公司 | 一种共聚物的制备方法 |
| TWI566835B (zh) | 2014-12-25 | 2017-01-21 | 財團法人工業技術研究院 | 烯烴複分解觸媒及低分子量丁腈橡膠之製備方法 |
| MX2017014732A (es) * | 2015-05-26 | 2018-08-01 | Zeon Corp | Caucho de copolimero altamente saturado que contiene grupo nitrilo. |
| CN107540765B (zh) * | 2016-06-24 | 2020-06-09 | 中国石油天然气股份有限公司 | 一种丁腈橡胶用阻燃型增塑剂的制备方法 |
| JP6957868B2 (ja) * | 2016-11-24 | 2021-11-02 | 株式会社ブリヂストン | ホース用ゴム組成物及びホース |
| US11692051B2 (en) * | 2017-09-28 | 2023-07-04 | Zeon Corporation | Method for producing nitrile group-containing copolymer rubber |
| JP2021532208A (ja) | 2018-07-23 | 2021-11-25 | アランセオ・ドイチュランド・ゲーエムベーハー | 水素化ニトリルゴムを製造するための方法及びそのｈｎｂｒ組成物 |
| US11673130B2 (en) | 2018-12-12 | 2023-06-13 | Arlanxeo Deutschland Gmbh | Catalyst system containing a metathesis catalyst and at least one phenolic compound and a process for metathesis of nitrile-butadiene rubber (NBR) using the catalyst system |
| CN110283454A (zh) * | 2019-05-29 | 2019-09-27 | 周宁东 | 一种低烟阻燃电缆料及其制备方法 |
| KR102923904B1 (ko) * | 2020-10-16 | 2026-02-04 | 주식회사 엘지화학 | 디엔계 중합체의 분해 방법 |
| CN114797991B (zh) * | 2022-03-24 | 2023-09-01 | 北京化工大学 | 一种橡胶加氢催化剂及其制备方法、回收方法和应用 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5869213A (ja) * | 1981-09-21 | 1983-04-25 | Daikin Ind Ltd | 含フツ素共重合体 |
| DE3920466A1 (de) * | 1989-06-22 | 1991-01-03 | Bayer Ag | Hitzebestaendige kautschukmassen auf basis von hydriertem nitrilkautschuk |
| JPH0616872A (ja) * | 1992-07-03 | 1994-01-25 | Nippon Zeon Co Ltd | ゴム組成物 |
| US5446102A (en) * | 1994-08-10 | 1995-08-29 | Bridgeston, Corporation | Olefin metathesis catalysts for degelling polymerization reactors |
| DE69506885T2 (de) * | 1994-08-29 | 1999-05-12 | Nippon Zeon Co., Ltd., Tokio/Tokyo | Ungesättigtes nitrilkonjugiertes diencopolymer, verfahren zu dessen herstellung und vulkanisierbare kautschukzusammensetzung |
| JPH08134271A (ja) * | 1994-11-14 | 1996-05-28 | Sumitomo Wiring Syst Ltd | 防水ゴム栓用ゴム組成物 |
| IT1272863B (it) * | 1995-01-04 | 1997-07-01 | Ausimont Spa | Copolimeri termoprocessabili del tetrafluoroetilene |
| EP1152029A4 (en) * | 1998-11-04 | 2002-11-20 | Nippon Zeon Co | MULTIPLE MIX COMPOSITION, CROSSLINKED OBJECT AND GASOLINE HOSE |
| US6187867B1 (en) * | 1999-03-26 | 2001-02-13 | Zeon Chemicals L.P. | Hydrogenated nitrile rubber compositions containing thermoplastic polyolefins |
| CA2304501A1 (en) * | 2000-04-10 | 2001-10-10 | Bayer Inc. | Process for hydrogenating carboxylated nitrile rubber, the hydrogenated rubber and its uses |
| JP2002020541A (ja) * | 2000-07-06 | 2002-01-23 | Matsushita Electric Ind Co Ltd | Ｎｂｒ組成物 |
| DE10061174A1 (de) * | 2000-12-07 | 2002-06-20 | Bayer Ag | NBR-Gele in Butylkautschukcompounds |
| CA2350280A1 (en) * | 2001-06-12 | 2002-12-12 | Bayer Inc. | Low molecular weight hydrogenated nitrile rubber |
| US6673881B2 (en) | 2001-06-12 | 2004-01-06 | Bayer Inc. | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
| US6841623B2 (en) * | 2001-06-29 | 2005-01-11 | Bayer Inc. | Low molecular weight nitrile rubber |
-
2002
- 2002-12-05 CA CA002413607A patent/CA2413607A1/en not_active Abandoned
-
2003
- 2003-11-25 DE DE60319325T patent/DE60319325T2/de not_active Expired - Lifetime
- 2003-11-25 EP EP05023925A patent/EP1621577A3/en not_active Withdrawn
- 2003-11-25 EP EP03026918A patent/EP1426383B1/en not_active Expired - Lifetime
- 2003-12-04 RU RU2003135265/04A patent/RU2356913C9/ru not_active IP Right Cessation
- 2003-12-04 EP EP03027956A patent/EP1426384A1/en not_active Withdrawn
- 2003-12-04 US US10/728,029 patent/US7381781B2/en not_active Expired - Lifetime
- 2003-12-05 CN CNA2007100840038A patent/CN101016349A/zh active Pending
- 2003-12-05 CN CNA2007100051319A patent/CN100999595A/zh active Pending
- 2003-12-05 CN CNB2003101240894A patent/CN100558772C/zh not_active Expired - Lifetime
- 2003-12-05 JP JP2003406953A patent/JP4667738B2/ja not_active Expired - Fee Related
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