JP2003514923A - 開始剤／アミジン錯体、その錯体を含んでなる系、およびそれによる重合組成物 - Google Patents
開始剤／アミジン錯体、その錯体を含んでなる系、およびそれによる重合組成物Info
- Publication number
- JP2003514923A JP2003514923A JP2001535415A JP2001535415A JP2003514923A JP 2003514923 A JP2003514923 A JP 2003514923A JP 2001535415 A JP2001535415 A JP 2001535415A JP 2001535415 A JP2001535415 A JP 2001535415A JP 2003514923 A JP2003514923 A JP 2003514923A
- Authority
- JP
- Japan
- Prior art keywords
- initiator
- amidine
- composition
- complex
- initiator system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
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- 239000003999 initiator Substances 0.000 title claims abstract description 112
- 150000001409 amidines Chemical class 0.000 title claims abstract description 59
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 31
- 238000010668 complexation reaction Methods 0.000 title 1
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- 239000000178 monomer Substances 0.000 claims abstract description 35
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- 239000000463 material Substances 0.000 claims description 20
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- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- GQHTUMJGOHRCHB-UHFFFAOYSA-N 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine Chemical compound C1CCCCN2CCCN=C21 GQHTUMJGOHRCHB-UHFFFAOYSA-N 0.000 claims description 6
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- 125000002947 alkylene group Chemical group 0.000 claims description 6
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- 125000002524 organometallic group Chemical group 0.000 claims description 4
- KYVBNYUBXIEUFW-UHFFFAOYSA-N 1,1,3,3-tetramethylguanidine Chemical group CN(C)C(=N)N(C)C KYVBNYUBXIEUFW-UHFFFAOYSA-N 0.000 claims description 3
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- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 2
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- 229960000549 4-dimethylaminophenol Drugs 0.000 description 2
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- 239000004971 Cross linker Substances 0.000 description 2
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- 239000002841 Lewis acid Substances 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 2
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- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical compound C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001490 poly(butyl methacrylate) polymer Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920005547 polycyclic aromatic hydrocarbon Chemical group 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 238000011417 postcuring Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
- ZTKBVWUYLHTIBB-UHFFFAOYSA-N tri(propan-2-yl)borane Chemical compound CC(C)B(C(C)C)C(C)C ZTKBVWUYLHTIBB-UHFFFAOYSA-N 0.000 description 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- WXRGABKACDFXMG-UHFFFAOYSA-N trimethylborane Chemical compound CB(C)C WXRGABKACDFXMG-UHFFFAOYSA-N 0.000 description 1
- ZMPKTELQGVLZTD-UHFFFAOYSA-N tripropylborane Chemical compound CCCB(CCC)CCC ZMPKTELQGVLZTD-UHFFFAOYSA-N 0.000 description 1
- XDSSGQHOYWGIKC-UHFFFAOYSA-N tris(2-methylpropyl)borane Chemical compound CC(C)CB(CC(C)C)CC(C)C XDSSGQHOYWGIKC-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24843—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] with heat sealable or heat releasable adhesive layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polymerization Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/433,236 US6410667B1 (en) | 1999-11-04 | 1999-11-04 | Initiator/amidine complexes, systems comprising the complexes, and polymerized compositions made therewith |
| US09/433,236 | 1999-11-04 | ||
| PCT/US2000/005090 WO2001032717A2 (en) | 1999-11-04 | 2000-02-25 | Initiator/amidine complexes, systems comprising the complexes, and polymerized compositions made therewith |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2003514923A true JP2003514923A (ja) | 2003-04-22 |
| JP2003514923A5 JP2003514923A5 (enExample) | 2007-04-26 |
Family
ID=23719368
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001535415A Withdrawn JP2003514923A (ja) | 1999-11-04 | 2000-02-25 | 開始剤／アミジン錯体、その錯体を含んでなる系、およびそれによる重合組成物 |
Country Status (6)
| Country | Link |
|---|---|
| US (3) | US6410667B1 (enExample) |
| EP (1) | EP1261647B1 (enExample) |
| JP (1) | JP2003514923A (enExample) |
| AU (1) | AU3710000A (enExample) |
| DE (1) | DE60010761T2 (enExample) |
| WO (1) | WO2001032717A2 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005507969A (ja) * | 2001-10-30 | 2005-03-24 | ダウ グローバル テクノロジーズ インコーポレイティド | 有機ボラン・アミン錯体重合開始剤および重合性組成物 |
| JP2005272817A (ja) * | 2004-02-27 | 2005-10-06 | Hideo Nagashima | ラジカル重合開始剤およびそれを用いる重合体の製造方法 |
| WO2026088859A1 (ja) * | 2024-10-22 | 2026-04-30 | 株式会社レゾナック | トリアルキルボラン－アミン錯体及びアミン化合物の組み合わせの選定方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6806330B1 (en) * | 1999-12-17 | 2004-10-19 | Dow Global Technologies Inc. | Amine organoborane complex polymerization initiators and polymerizable compositions |
| EP1201722A1 (en) | 2000-10-23 | 2002-05-02 | Loctite (R & D) Limited | Polymerisation initiators, polymerisable compositions, and uses thereof |
| IE20020293A1 (en) | 2002-04-23 | 2003-10-29 | Loctite R & D Ltd | Initiator systems, polymerisable compositions, and uses thereof for bonding low surface energy substrates |
| US6630555B2 (en) | 2001-11-06 | 2003-10-07 | Lord Corporation | Internally blocked organoborate initiators and adhesives therefrom |
| US6849569B2 (en) * | 2001-12-31 | 2005-02-01 | 3M Innovative Properties Company | Initiator systems comprising β-ketone compounds |
| US6734268B2 (en) | 2001-12-31 | 2004-05-11 | 3M Innovative Properties Company | Metal salt modifiers for bonding compositions |
| WO2003089536A2 (en) | 2002-04-19 | 2003-10-30 | Loctite (R & D) Limited | Polymerisation initiators based on ammonium tetraalkyl boranes, polymerisable compositions, and uses thereof for bonding low surface energy substrates |
| US7098279B2 (en) | 2002-10-22 | 2006-08-29 | Loctite (R&D) Limited | Non-flammable and non-combustible adhesive bonding systems having adherence to low energy surfaces |
| US20040242817A1 (en) * | 2003-05-29 | 2004-12-02 | Lord Corporation | Internally coordinated organoboranes |
| RU2358992C2 (ru) * | 2003-06-09 | 2009-06-20 | Дау Глобал Текнолоджиз Инк. | Стабилизированные органоборановые инициаторы полимеризации и способные к полимеризации композиции |
| US7273531B2 (en) * | 2003-11-05 | 2007-09-25 | 3M Innovative Properties Company | Method of modifying a fluoropolymeric substrate and composite articles thereby |
| CN1898082B (zh) * | 2003-12-22 | 2010-09-29 | 陶氏环球技术公司 | 促进的有机硼烷胺络合物引发的可聚合组合物 |
| US8501886B2 (en) * | 2003-12-22 | 2013-08-06 | Dow Global Technologies Llc | Accelerated organoborane amine complex initiated polymerizable compositions |
| US7485729B2 (en) * | 2004-08-12 | 2009-02-03 | King Industries, Inc. | Organometallic compositions and coating compositions |
| US7408012B1 (en) | 2005-04-18 | 2008-08-05 | Loctite (R&D) Limited | Adhesive bonding systems having adherence to low energy surfaces |
| BRPI0617591A2 (pt) * | 2005-10-07 | 2011-08-02 | Dow Global Technologies Inc | sistemas para iniciar polimerização via radical livre, composição polimerizável de duas partes, método de polimerização, método para ligar dois ou mais substratos entre si, método para modificar a superfìcie de um polìmero de baixa energia superficial, método para revestir um substrato, composição de revestimento e laminado |
| KR101409252B1 (ko) * | 2006-05-23 | 2014-07-03 | 다우 코닝 코포레이션 | 아마이드 작용성 중합체와의 보레인 촉매 착물 및 이로부터제조된 경화성 조성물 |
| US7524907B2 (en) * | 2006-10-12 | 2009-04-28 | Dow Global Technologies, Inc. | Accelerated organoborane initiated polymerizable compositions |
| US20080103274A1 (en) * | 2006-10-12 | 2008-05-01 | Jialanella Gary L | Accelerated organoborane initiated polymerizable compositions |
| US8501887B2 (en) | 2008-07-28 | 2013-08-06 | Dow Corning Corporation | Radical polymerizable composition |
| WO2012122098A1 (en) * | 2011-03-06 | 2012-09-13 | King Industries, Inc. | Compositions of a metal amidine complex and second compound, coating compositions comprising same |
| US9006336B2 (en) | 2011-12-29 | 2015-04-14 | 3M Innovative Properties Company | Curable polysiloxane coating composition |
| CN104470983A (zh) | 2011-12-29 | 2015-03-25 | 3M创新有限公司 | 可固化聚硅氧烷组合物 |
| WO2013101742A1 (en) | 2011-12-29 | 2013-07-04 | 3M Innovative Properties Company | Curable-on-demand polysiloxane coating composition |
| KR102335364B1 (ko) | 2014-03-27 | 2021-12-06 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 오가노보란-함유 조성물, 및 그의 사용 방법 |
| EP3218442B1 (en) | 2014-11-14 | 2018-09-05 | 3M Innovative Properties Company | Two-part adhesive composition and method of making an adhesive composition |
| KR101919293B1 (ko) | 2015-09-10 | 2018-11-15 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 중합성 조성물, 중합된 조성물, 및 그의 제조 및 사용 방법 |
| CN111094398B (zh) | 2017-09-26 | 2023-02-14 | 3M创新有限公司 | 可固化的密封剂组合物、密封帽以及它们的制备和使用方法 |
| CN112262014A (zh) | 2018-06-15 | 2021-01-22 | 3M创新有限公司 | 组件和制备垫片的方法 |
| EP3856849A1 (en) | 2018-09-27 | 2021-08-04 | 3M Innovative Properties Company | Composition including amino-functional silanes and method of applying a sealant to a substrate |
| EP3877449A1 (en) | 2018-11-09 | 2021-09-15 | 3M Innovative Properties Company | Curable sealant compositions, seal cap, and methods of making and using the same |
| WO2020202076A1 (en) | 2019-04-04 | 2020-10-08 | 3M Innovative Properties Company | Method of irradiating a composition through a substrate |
| US20220258848A1 (en) | 2019-07-25 | 2022-08-18 | 3M Innovative Properties Company | Methods of shimming an assembly |
| WO2022254369A1 (en) | 2021-06-02 | 2022-12-08 | 3M Innovative Properties Company | Composition including cyclic imide-containing monomer and organoborane complex and related articles and methods |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2434185A1 (de) * | 1974-07-16 | 1976-02-05 | Bayer Ag | Verfahren zur herstellung von amidin-metall-komplexen |
| US4538920A (en) | 1983-03-03 | 1985-09-03 | Minnesota Mining And Manufacturing Company | Static mixing device |
| ZA867551B (en) | 1985-10-07 | 1987-05-27 | Lord Corp | Structural adhesive formulations |
| US5082147A (en) | 1988-02-29 | 1992-01-21 | Richard Jacobs | Composition dispensing system |
| US5106928A (en) * | 1991-04-29 | 1992-04-21 | National Starch And Chemical Investment Holding Corporation | Acrylic adhesive composition and organoboron initiator system |
| JP2728106B2 (ja) | 1991-09-05 | 1998-03-18 | インターナショナル・ビジネス・マシーンズ・コーポレイション | 電子パッケージングにおける除去可能なデバイス保護のための開裂性ジエポキシド |
| US5286821A (en) | 1992-03-17 | 1994-02-15 | National Starch And Chemical Investment Holding Corporation | Acrylic adhesive composition and organoboron initiator system |
| US5310835A (en) | 1993-09-30 | 1994-05-10 | National Starch And Chemical Investment Holding Corporation | Transparent two-part acrylic adhesive composition and the method of use thereof |
| EP0746573B1 (en) | 1994-02-22 | 2001-06-06 | Minnesota Mining And Manufacturing Company | Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes |
| US5621143A (en) | 1995-04-14 | 1997-04-15 | Minnesota Mining And Manufacturing Company | Organoborane polyoxyalkylenepolyamine complexes and adhesive compositions made therewith |
| US5616796A (en) | 1995-04-14 | 1997-04-01 | Minnesota Mining And Manufacturing Company | Organoborane polyamine complexes and adhesive composition made therewith |
| US5686544A (en) | 1995-08-11 | 1997-11-11 | Minnesota Mining And Manufacturing Company | Organoborane polyamine complex initiator systems and polymerizable compositions made therewith |
| WO1997007171A1 (en) | 1995-08-11 | 1997-02-27 | Minnesota Mining And Manufacturing Company | Initiator system and adhesive composition made therewith |
| CA2236939A1 (en) | 1995-11-07 | 1997-05-15 | E. John Deviny | Initiator system and adhesive composition made therewith |
| WO1998012295A1 (en) | 1996-09-19 | 1998-03-26 | The Procter & Gamble Company | Color care compositions |
| US5935711A (en) | 1996-10-23 | 1999-08-10 | 3M Innovative Properties Company | Organoborane amine complex initiator systems and polymerizable compositions made therewith |
| US5792821A (en) | 1997-01-06 | 1998-08-11 | American Dental Association Health Foundation | Polymerizable cyclodextrin derivatives |
| US5833208A (en) | 1997-09-15 | 1998-11-10 | Jm Clipper Corporation | Inner seal for ram-type blowout preventer |
| KR100629832B1 (ko) | 1998-06-12 | 2006-09-29 | 미네소타 마이닝 앤드 매뉴팩춰링 캄파니 | 표면 에너지가 낮은 기재를 접착시키기에 유용한 저취중합성 조성물 |
| DE69823562T2 (de) | 1998-06-12 | 2005-04-21 | Minnesota Mining & Mfg | Initiatorsystem sowie damit hergestellte polymerisierbare zusammensetzungen |
-
1999
- 1999-11-04 US US09/433,236 patent/US6410667B1/en not_active Expired - Fee Related
-
2000
- 2000-02-25 JP JP2001535415A patent/JP2003514923A/ja not_active Withdrawn
- 2000-02-25 WO PCT/US2000/005090 patent/WO2001032717A2/en not_active Ceased
- 2000-02-25 EP EP00915911A patent/EP1261647B1/en not_active Expired - Lifetime
- 2000-02-25 DE DE2000610761 patent/DE60010761T2/de not_active Expired - Lifetime
- 2000-02-25 AU AU37100/00A patent/AU3710000A/en not_active Abandoned
-
2002
- 2002-05-03 US US10/138,757 patent/US6762256B2/en not_active Expired - Fee Related
-
2003
- 2003-02-14 US US10/365,849 patent/US6740717B2/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005507969A (ja) * | 2001-10-30 | 2005-03-24 | ダウ グローバル テクノロジーズ インコーポレイティド | 有機ボラン・アミン錯体重合開始剤および重合性組成物 |
| JP2005272817A (ja) * | 2004-02-27 | 2005-10-06 | Hideo Nagashima | ラジカル重合開始剤およびそれを用いる重合体の製造方法 |
| WO2026088859A1 (ja) * | 2024-10-22 | 2026-04-30 | 株式会社レゾナック | トリアルキルボラン－アミン錯体及びアミン化合物の組み合わせの選定方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US6762256B2 (en) | 2004-07-13 |
| AU3710000A (en) | 2001-05-14 |
| EP1261647B1 (en) | 2004-05-12 |
| EP1261647A2 (en) | 2002-12-04 |
| DE60010761T2 (de) | 2005-05-25 |
| US20030176607A1 (en) | 2003-09-18 |
| US20020182425A1 (en) | 2002-12-05 |
| US6410667B1 (en) | 2002-06-25 |
| WO2001032717A3 (en) | 2002-09-26 |
| DE60010761D1 (de) | 2004-06-17 |
| WO2001032717A2 (en) | 2001-05-10 |
| US6740717B2 (en) | 2004-05-25 |
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