JP2003186208A

JP2003186208A - 平版印刷版の再生方法

平版印刷版の再生方法

Info

Publication number: JP2003186208A
Authority: JP; Japan
Prior art keywords: group; printing plate; lithographic printing; acid; meth
Prior art date: 2001-12-14
Legal status : Pending

Application number

JP2001382284A

Other languages

English (en)

Japanese (ja)

Other versions

JP2003186208A5 (https=

Inventor

Toshiyoshi Urano

年由浦野

Takuya Uematsu

卓也植松

Yuuji Mizuho

右二瑞穂

Current Assignee

Mitsubishi Chemical Corp

Mitsubishi Heavy Industries Ltd

Original Assignee

Mitsubishi Chemical Corp

Mitsubishi Heavy Industries Ltd

Priority date

2001-12-14

Filing date

2001-12-14

Publication date

2003-07-03

2001-12-14 Application filed by Mitsubishi Chemical Corp, Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Chemical Corp

2001-12-14 Priority to JP2001382284A priority Critical patent/JP2003186208A/ja

2003-07-03 Publication of JP2003186208A publication Critical patent/JP2003186208A/ja

2005-08-04 Publication of JP2003186208A5 publication Critical patent/JP2003186208A5/ja

Status Pending legal-status Critical Current

Links

238000007639 printing Methods 0.000 title claims abstract description 212
229910052782 aluminium Inorganic materials 0.000 claims abstract description 69
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 69
238000000034 method Methods 0.000 claims abstract description 64
239000003795 chemical substances by application Substances 0.000 claims abstract description 35
239000007864 aqueous solution Substances 0.000 claims abstract description 30
230000001172 regenerating effect Effects 0.000 claims abstract description 10
150000001875 compounds Chemical class 0.000 claims description 98
239000000126 substance Substances 0.000 claims description 67
239000000203 mixture Substances 0.000 claims description 66
229920005989 resin Polymers 0.000 claims description 34
239000011347 resin Substances 0.000 claims description 34
229920005596 polymer binder Polymers 0.000 claims description 16
239000002491 polymer binding agent Substances 0.000 claims description 16
238000006243 chemical reaction Methods 0.000 claims description 15
239000003945 anionic surfactant Substances 0.000 claims description 13
239000003999 initiator Substances 0.000 claims description 13
239000003960 organic solvent Substances 0.000 claims description 12
229920003986 novolac Polymers 0.000 claims description 11
239000002280 amphoteric surfactant Substances 0.000 claims description 6
125000005842 heteroatom Chemical group 0.000 claims description 6
125000000129 anionic group Chemical group 0.000 claims description 4
239000000463 material Substances 0.000 claims description 4
238000004064 recycling Methods 0.000 claims description 4
238000010521 absorption reaction Methods 0.000 claims description 3
238000004519 manufacturing process Methods 0.000 claims 1
230000007935 neutral effect Effects 0.000 claims 1
239000000758 substrate Substances 0.000 abstract description 2
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125000001424 substituent group Chemical group 0.000 description 107
239000000975 dye Substances 0.000 description 74
125000000217 alkyl group Chemical group 0.000 description 67
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 65
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 50
125000004432 carbon atom Chemical group C* 0.000 description 49
229920003171 Poly (ethylene oxide) Polymers 0.000 description 39
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 34
238000000576 coating method Methods 0.000 description 30
239000002253 acid Substances 0.000 description 28
229910052799 carbon Inorganic materials 0.000 description 28
125000005843 halogen group Chemical group 0.000 description 28
239000011248 coating agent Substances 0.000 description 27
SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 26
239000000243 solution Substances 0.000 description 26
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 25
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 25
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 24
IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 24
125000003545 alkoxy group Chemical group 0.000 description 23
SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 22
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235000014113 dietary fatty acids Nutrition 0.000 description 18
239000000194 fatty acid Substances 0.000 description 18
229930195729 fatty acid Natural products 0.000 description 18
239000004094 surface-active agent Substances 0.000 description 18
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 17
150000001450 anions Chemical class 0.000 description 17
125000003118 aryl group Chemical group 0.000 description 17
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 16
125000003342 alkenyl group Chemical group 0.000 description 16
125000000623 heterocyclic group Chemical group 0.000 description 16
230000035945 sensitivity Effects 0.000 description 16
QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 14
150000001252 acrylic acid derivatives Chemical class 0.000 description 14
125000003277 amino group Chemical group 0.000 description 14
125000002887 hydroxy group Chemical group [H]O* 0.000 description 14
RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 14
IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 14
WVIICGIFSIBFOG-UHFFFAOYSA-N pyrylium Chemical compound C1=CC=[O+]C=C1 WVIICGIFSIBFOG-UHFFFAOYSA-N 0.000 description 14
OKYDCMQQLGECPI-UHFFFAOYSA-N thiopyrylium Chemical compound C1=CC=[S+]C=C1 OKYDCMQQLGECPI-UHFFFAOYSA-N 0.000 description 14
239000010408 film Substances 0.000 description 13
125000004435 hydrogen atom Chemical group [H]* 0.000 description 13
PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 13
RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 13
229920000642 polymer Polymers 0.000 description 13
150000003839 salts Chemical class 0.000 description 13
125000000304 alkynyl group Chemical group 0.000 description 12
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 12
238000011161 development Methods 0.000 description 12
230000018109 developmental process Effects 0.000 description 12
150000002148 esters Chemical class 0.000 description 12
239000007788 liquid Substances 0.000 description 12
230000007246 mechanism Effects 0.000 description 12
239000002736 nonionic surfactant Substances 0.000 description 12
229920001223 polyethylene glycol Polymers 0.000 description 12
239000002904 solvent Substances 0.000 description 12
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 11
235000011187 glycerol Nutrition 0.000 description 11
230000008569 process Effects 0.000 description 11
229910052717 sulfur Inorganic materials 0.000 description 11
125000004434 sulfur atom Chemical group 0.000 description 11
TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 10
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
239000007795 chemical reaction product Substances 0.000 description 10
229920001577 copolymer Polymers 0.000 description 10
150000001925 cycloalkenes Chemical group 0.000 description 10
JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 10
PESYEWKSBIWTAK-UHFFFAOYSA-N cyclopenta-1,3-diene;titanium(2+) Chemical class [Ti+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 PESYEWKSBIWTAK-UHFFFAOYSA-N 0.000 description 10
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 10
239000001301 oxygen Substances 0.000 description 10
229910052760 oxygen Inorganic materials 0.000 description 10
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 10
GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 10
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 9
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
239000002202 Polyethylene glycol Substances 0.000 description 9
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
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238000001035 drying Methods 0.000 description 9
239000011734 sodium Substances 0.000 description 9
229910052708 sodium Inorganic materials 0.000 description 9
125000004182 2-chlorophenyl group Chemical group [H]C1=C([H])C(Cl)=C(*)C([H])=C1[H] 0.000 description 8
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VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
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PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
230000004888 barrier function Effects 0.000 description 8
150000001735 carboxylic acids Chemical class 0.000 description 8
SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 8
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 8
125000004430 oxygen atom Chemical group O* 0.000 description 8
150000002989 phenols Chemical class 0.000 description 8
WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 8
239000000600 sorbitol Substances 0.000 description 8
229910019142 PO4 Inorganic materials 0.000 description 7
239000004115 Sodium Silicate Substances 0.000 description 7
150000005215 alkyl ethers Chemical class 0.000 description 7
238000002156 mixing Methods 0.000 description 7
235000021317 phosphate Nutrition 0.000 description 7
239000000049 pigment Substances 0.000 description 7
239000004065 semiconductor Substances 0.000 description 7
159000000000 sodium salts Chemical class 0.000 description 7
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 7
229910052911 sodium silicate Inorganic materials 0.000 description 7
229920003169 water-soluble polymer Polymers 0.000 description 7
NKTOLZVEWDHZMU-UHFFFAOYSA-N 2,5-xylenol Chemical compound CC1=CC=C(C)C(O)=C1 NKTOLZVEWDHZMU-UHFFFAOYSA-N 0.000 description 6
ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 6
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
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125000001931 aliphatic group Chemical group 0.000 description 6
150000003973 alkyl amines Chemical class 0.000 description 6
125000003282 alkyl amino group Chemical group 0.000 description 6
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
150000001642 boronic acid derivatives Chemical class 0.000 description 6
UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 6
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 6
239000003112 inhibitor Substances 0.000 description 6
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239000005011 phenolic resin Substances 0.000 description 6
150000003013 phosphoric acid derivatives Chemical class 0.000 description 6
239000005056 polyisocyanate Substances 0.000 description 6
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238000012545 processing Methods 0.000 description 6
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229960001755 resorcinol Drugs 0.000 description 6
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 6
JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical class C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 description 5
YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 5
YKXVZTWMMZZVRA-UHFFFAOYSA-N CC1(C=CC=C1)[Ti]C1(C=CC=C1)C Chemical compound CC1(C=CC=C1)[Ti]C1(C=CC=C1)C YKXVZTWMMZZVRA-UHFFFAOYSA-N 0.000 description 5
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 5
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 5
239000004372 Polyvinyl alcohol Substances 0.000 description 5
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 5
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 5
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
239000003513 alkali Substances 0.000 description 5
150000001412 amines Chemical class 0.000 description 5
150000001768 cations Chemical class 0.000 description 5
238000007796 conventional method Methods 0.000 description 5
125000004663 dialkyl amino group Chemical group 0.000 description 5
ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 5
238000007598 dipping method Methods 0.000 description 5
238000004090 dissolution Methods 0.000 description 5
235000019256 formaldehyde Nutrition 0.000 description 5
150000002576 ketones Chemical class 0.000 description 5
MXHTZQSKTCCMFG-UHFFFAOYSA-N n,n-dibenzyl-1-phenylmethanamine Chemical compound C=1C=CC=CC=1CN(CC=1C=CC=CC=1)CC1=CC=CC=C1 MXHTZQSKTCCMFG-UHFFFAOYSA-N 0.000 description 5
150000007524 organic acids Chemical class 0.000 description 5
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 5
238000005498 polishing Methods 0.000 description 5
229920002451 polyvinyl alcohol Polymers 0.000 description 5
229910052913 potassium silicate Inorganic materials 0.000 description 5
235000019353 potassium silicate Nutrition 0.000 description 5
238000005507 spraying Methods 0.000 description 5
VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 4
QRHHZFRCJDAUNA-UHFFFAOYSA-N 2-(4-methoxyphenyl)-4,6-bis(trichloromethyl)-1,3,5-triazine Chemical compound C1=CC(OC)=CC=C1C1=NC(C(Cl)(Cl)Cl)=NC(C(Cl)(Cl)Cl)=N1 QRHHZFRCJDAUNA-UHFFFAOYSA-N 0.000 description 4
XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 4
QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 4
TUAMRELNJMMDMT-UHFFFAOYSA-N 3,5-xylenol Chemical compound CC1=CC(C)=CC(O)=C1 TUAMRELNJMMDMT-UHFFFAOYSA-N 0.000 description 4
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DPTGFYXXFXSRIR-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-ylmethyl prop-2-enoate Chemical compound C1C(COC(=O)C=C)CCC2OC21 DPTGFYXXFXSRIR-UHFFFAOYSA-N 0.000 description 4
VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 description 4
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239000004593 Epoxy Substances 0.000 description 4
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OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 4
BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 4
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical class CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 4
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
239000007983 Tris buffer Substances 0.000 description 4
150000001447 alkali salts Chemical class 0.000 description 4
150000008064 anhydrides Chemical class 0.000 description 4
238000007743 anodising Methods 0.000 description 4
125000001769 aryl amino group Chemical group 0.000 description 4
125000004104 aryloxy group Chemical group 0.000 description 4
PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 4
HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 4
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
XUPYJHCZDLZNFP-UHFFFAOYSA-N butyl butanoate Chemical compound CCCCOC(=O)CCC XUPYJHCZDLZNFP-UHFFFAOYSA-N 0.000 description 4
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
239000000460 chlorine Substances 0.000 description 4
ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 4
LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 4
230000006870 function Effects 0.000 description 4
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FTUYQIPAPWPHNC-UHFFFAOYSA-M sodium;4-[[4-[benzyl(ethyl)amino]phenyl]-[4-[benzyl(ethyl)azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]benzene-1,3-disulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=CC=CC=2)C=2C(=CC(=CC=2)S([O-])(=O)=O)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC=C1 FTUYQIPAPWPHNC-UHFFFAOYSA-M 0.000 description 1
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125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
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125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 1
125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
AMJYHMCHKZQLAY-UHFFFAOYSA-N tris(2-isocyanatophenoxy)-sulfanylidene-$l^{5}-phosphane Chemical class O=C=NC1=CC=CC=C1OP(=S)(OC=1C(=CC=CC=1)N=C=O)OC1=CC=CC=C1N=C=O AMJYHMCHKZQLAY-UHFFFAOYSA-N 0.000 description 1
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