JP2002513344A - フルオロポリマーブレンドを含む複合物品 - Google Patents
フルオロポリマーブレンドを含む複合物品Info
- Publication number
- JP2002513344A JP2002513344A JP50979999A JP50979999A JP2002513344A JP 2002513344 A JP2002513344 A JP 2002513344A JP 50979999 A JP50979999 A JP 50979999A JP 50979999 A JP50979999 A JP 50979999A JP 2002513344 A JP2002513344 A JP 2002513344A
- Authority
- JP
- Japan
- Prior art keywords
- composite article
- vinylidene fluoride
- monomer
- fluoropolymer
- free
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002313 fluoropolymer Polymers 0.000 title claims abstract description 140
- 239000004811 fluoropolymer Substances 0.000 title claims abstract description 128
- 239000000203 mixture Substances 0.000 title claims abstract description 80
- 239000002131 composite material Substances 0.000 title claims description 129
- 239000000463 material Substances 0.000 claims abstract description 182
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims abstract description 104
- 229920000642 polymer Polymers 0.000 claims abstract description 83
- 229920006120 non-fluorinated polymer Polymers 0.000 claims abstract description 41
- 125000003277 amino group Chemical group 0.000 claims abstract description 30
- 239000000178 monomer Substances 0.000 claims description 98
- -1 2-hydropentafluoropropylene Fluorine Chemical compound 0.000 claims description 51
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 45
- 238000000034 method Methods 0.000 claims description 42
- 229910052731 fluorine Inorganic materials 0.000 claims description 34
- 150000001336 alkenes Chemical class 0.000 claims description 32
- 239000011737 fluorine Substances 0.000 claims description 31
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 claims description 26
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 25
- 229920001577 copolymer Polymers 0.000 claims description 22
- 239000000126 substance Substances 0.000 claims description 22
- 239000003054 catalyst Substances 0.000 claims description 21
- 150000001412 amines Chemical class 0.000 claims description 20
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims description 20
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 17
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 16
- 239000004952 Polyamide Substances 0.000 claims description 16
- 229920002647 polyamide Polymers 0.000 claims description 16
- 125000001153 fluoro group Chemical group F* 0.000 claims description 15
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 14
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 13
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 13
- 229910052794 bromium Inorganic materials 0.000 claims description 13
- 229920001971 elastomer Polymers 0.000 claims description 13
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 12
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 12
- 239000000654 additive Substances 0.000 claims description 12
- 229910052740 iodine Inorganic materials 0.000 claims description 12
- 239000011630 iodine Substances 0.000 claims description 12
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 12
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 12
- 239000000806 elastomer Substances 0.000 claims description 11
- 239000002861 polymer material Substances 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 11
- 229920000728 polyester Polymers 0.000 claims description 10
- 229920002635 polyurethane Polymers 0.000 claims description 10
- 239000004814 polyurethane Substances 0.000 claims description 10
- 230000000996 additive effect Effects 0.000 claims description 9
- 125000001931 aliphatic group Chemical group 0.000 claims description 9
- 229920001470 polyketone Polymers 0.000 claims description 9
- 238000006116 polymerization reaction Methods 0.000 claims description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 8
- 239000005977 Ethylene Substances 0.000 claims description 8
- 229920002396 Polyurea Polymers 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- 229920000515 polycarbonate Polymers 0.000 claims description 8
- 239000004417 polycarbonate Substances 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 7
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 claims description 7
- 229920000058 polyacrylate Polymers 0.000 claims description 7
- 229920000098 polyolefin Polymers 0.000 claims description 7
- 239000004642 Polyimide Substances 0.000 claims description 6
- 229920001721 polyimide Polymers 0.000 claims description 6
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000004793 Polystyrene Substances 0.000 claims description 5
- 229920000193 polymethacrylate Polymers 0.000 claims description 5
- 229920002223 polystyrene Polymers 0.000 claims description 5
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 claims description 5
- GVCWGFZDSIWLMO-UHFFFAOYSA-N 4-bromo-3,3,4,4-tetrafluorobut-1-ene Chemical compound FC(F)(Br)C(F)(F)C=C GVCWGFZDSIWLMO-UHFFFAOYSA-N 0.000 claims description 4
- 239000001273 butane Substances 0.000 claims description 4
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 4
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims 3
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical group FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 description 127
- 238000012360 testing method Methods 0.000 description 14
- 230000004888 barrier function Effects 0.000 description 12
- 229910052799 carbon Inorganic materials 0.000 description 12
- 229920001973 fluoroelastomer Polymers 0.000 description 11
- 239000000446 fuel Substances 0.000 description 11
- 238000002156 mixing Methods 0.000 description 11
- VHYFNPMBLIVWCW-UHFFFAOYSA-N 4-Dimethylaminopyridine Chemical compound CN(C)C1=CC=NC=C1 VHYFNPMBLIVWCW-UHFFFAOYSA-N 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 150000003141 primary amines Chemical class 0.000 description 9
- 239000010408 film Substances 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 7
- 229930195733 hydrocarbon Natural products 0.000 description 7
- 150000003335 secondary amines Chemical group 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 150000008064 anhydrides Chemical class 0.000 description 5
- 229920000768 polyamine Polymers 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 4
- 229920000459 Nitrile rubber Polymers 0.000 description 4
- 229920000299 Nylon 12 Polymers 0.000 description 4
- 239000000370 acceptor Substances 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 238000010526 radical polymerization reaction Methods 0.000 description 4
- 229920001897 terpolymer Polymers 0.000 description 4
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 229920002292 Nylon 6 Polymers 0.000 description 3
- 239000005062 Polybutadiene Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 125000003710 aryl alkyl group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 3
- 239000000920 calcium hydroxide Substances 0.000 description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000005796 dehydrofluorination reaction Methods 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical class C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 230000001737 promoting effect Effects 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229920004142 LEXAN™ Polymers 0.000 description 2
- 239000004418 Lexan Substances 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 229920000571 Nylon 11 Polymers 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical class C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000002828 fuel tank Substances 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- DOUHZFSGSXMPIE-UHFFFAOYSA-N hydroxidooxidosulfur(.) Chemical compound [O]SO DOUHZFSGSXMPIE-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 150000003949 imides Chemical class 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000005673 monoalkenes Chemical class 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 150000004010 onium ions Chemical class 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- RXZBMPWDPOLZGW-XMRMVWPWSA-N (E)-roxithromycin Chemical compound O([C@@H]1[C@@H](C)C(=O)O[C@@H]([C@@]([C@H](O)[C@@H](C)C(=N/OCOCCOC)/[C@H](C)C[C@@](C)(O)[C@H](O[C@H]2[C@@H]([C@H](C[C@@H](C)O2)N(C)C)O)[C@H]1C)(C)O)CC)[C@H]1C[C@@](C)(OC)[C@@H](O)[C@H](C)O1 RXZBMPWDPOLZGW-XMRMVWPWSA-N 0.000 description 1
- LGPPATCNSOSOQH-UHFFFAOYSA-N 1,1,2,3,4,4-hexafluorobuta-1,3-diene Chemical compound FC(F)=C(F)C(F)=C(F)F LGPPATCNSOSOQH-UHFFFAOYSA-N 0.000 description 1
- QAERDLQYXMEHEB-UHFFFAOYSA-N 1,1,3,3,3-pentafluoroprop-1-ene Chemical group FC(F)=CC(F)(F)F QAERDLQYXMEHEB-UHFFFAOYSA-N 0.000 description 1
- OQMIRQSWHKCKNJ-UHFFFAOYSA-N 1,1-difluoroethene;1,1,2,3,3,3-hexafluoroprop-1-ene Chemical group FC(F)=C.FC(F)=C(F)C(F)(F)F OQMIRQSWHKCKNJ-UHFFFAOYSA-N 0.000 description 1
- RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 description 1
- AYCANDRGVPTASA-UHFFFAOYSA-N 1-bromo-1,2,2-trifluoroethene Chemical group FC(F)=C(F)Br AYCANDRGVPTASA-UHFFFAOYSA-N 0.000 description 1
- VJGCZWVJDRIHNC-UHFFFAOYSA-N 1-fluoroprop-1-ene Chemical compound CC=CF VJGCZWVJDRIHNC-UHFFFAOYSA-N 0.000 description 1
- YTCHAEAIYHLXBK-UHFFFAOYSA-N 2-chloro-1,1,3,3,3-pentafluoroprop-1-ene Chemical compound FC(F)=C(Cl)C(F)(F)F YTCHAEAIYHLXBK-UHFFFAOYSA-N 0.000 description 1
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 229920003313 Bynel® Polymers 0.000 description 1
- 239000004970 Chain extender Substances 0.000 description 1
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical group [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 229920006368 Hylar Polymers 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 229920007478 Kynar® 740 Polymers 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 241001676573 Minium Species 0.000 description 1
- OKIZCWYLBDKLSU-UHFFFAOYSA-M N,N,N-Trimethylmethanaminium chloride Chemical compound [Cl-].C[N+](C)(C)C OKIZCWYLBDKLSU-UHFFFAOYSA-M 0.000 description 1
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N N-phenyl amine Natural products NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229920001007 Nylon 4 Polymers 0.000 description 1
- 229920003189 Nylon 4,6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 229920002614 Polyether block amide Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2327/00—Polyvinylhalogenides
- B32B2327/12—Polyvinylhalogenides containing fluorine
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2597/00—Tubular articles, e.g. hoses, pipes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
- Y10T428/1393—Multilayer [continuous layer]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31507—Of polycarbonate
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
- Y10T428/31544—Addition polymer is perhalogenated
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. (a)(i) ビニリデンフルオリド含有フルオロポリマー、及び (ii)第1の実質的にビニリデンフルオリドを含有しないフルオロポリマーを 含む、第1及び第2の表面を有するブレンド材料と、 (b)(i)1つ以上のペンダント第一または第二アミン基を有すると共に、 (ii)露出面を有する、該ブレンド材料の該第1の表面に付着した実質的にフ ッ素化されていないポリマー材料と、を含む複合物品。 2. 材料(a)の前記ビニリデンフルオリド含有フルオロポリマーが、ビニリデ ンフルオリドの共重合単位または重合時に重合したビニリデンフルオリドに似た ポリマー微細構造配列を形成する他のモノマーの共重合単位を含む請求項1に記 載の複合物品。 3. 材料(a)の前記ビニリデンフルオリド含有フルオロポリマーが、(i)ビニ リデンフルオリド、トリフルオロエチレン、1−ヒドロペンタフルオロプロピレ ン、2−ヒドロペンタフルオロプロピレンの群から選択される少なくとも1つの フッ素含有モノマー、及び、任意に、(ii)それらと共重合することができる少 なくとも1つのモノマーから誘導される共重合単位のフルオロポリマーを含む請 求項1に記載の複合物品。 4. 前記モノマー(ii)が、フッ素含有モノマー、フッ素を含まない不飽和オレ フィンモノマー、ヨウ素または臭素含有不飽和オレフィンモノマー、またはそれ らの組合せから選択される請求項3に記載の複合物品。 5. (a)前記フッ素含有モノマーが、ヘキサフルオロプロピレン、テトラフル オロエチレン、クロロトリフルオロエチレン、フッ素化ビニルエーテル、及びフ ッ素含有ジオレフィンから選択され、 (b)前記フッ素を含まない不飽和オレフィンモノマーが、エチレン、プロピレ ン、及びブタジエンから選択され、及び (c)前記ヨウ素または臭素含有不飽和オレフィンモノマーが、ブロモジフルオ ロエチレン、ブロモトリフルオロエチレン、ヨードトリフルオロエチレン、及び 4−ブロモ−3,3,4,4−テトラフルオロ−1−ブテンから選択される請求 項4に記載の複合物品。 6. 材料(a)の前記第1の実質的にビニリデンフルオリドを含有しないフルオ ロポリマーが、(i)ビニリデンフルオリドモノマーの共重合単位、または(ii) 重合したビニリデンフルオリドに似た微細構造配列を形成する他のモノマーの共 重合単位を実質的に含まない請求項1に記載の複合物品。 7. 材料(a)の前記第1の実質的にビニリデンフルオリドを含有しないフルオ ロポリマーが、(i)ヘキサフルオロプロピレン、テトラフルオロエチレン、ク ロロトリフルオロエチレン、フッ素化ビニルエーテル、及びそれらの組合せから 選択されるフッ素含有モノマーと、任意に、(ii)フッ素を含まない不飽和オレ フィンコモノマーと、所望により、(iii)ヨウ素または臭素含有不飽和オレフ ィンモノマーと、の共重合単位から形成される請求項1に記載の複合物品。 8. 前記フッ素を含まない不飽和オレフィンモノマーが、エチレン、プロピレ ン、及びブタジエンから選択され、前記ヨウ素または臭素含有不飽和オレフィン モノマーが、ブロモジフルオロエチレン、ブロモトリフルオロエチレン、ヨード トリフルオロエチレン、及び4−ブロモ−3,3,4,4−テトラフルオロ−1 −ブテンから選択される請求項7に記載の複合物品。 9. 材料(a)の前記第1の実質的にビニリデンフルオリドを含有しないフルオ ロポリマーが、テトラフルオロエチレンと、ヘキサフルオロプロピレン、フッ素 化ビニルエーテル、エチレン、及びプロピレンから選択される少なくとも1つの 他のモノマーとの共重合単位から形成される請求項7に記載の複合物品。 10.前記材料(b)が、フッ素原子で置換されたそれらの炭素に結合した水素原 子10%未満を含有する請求項1に記載の複合物品。 11.前記材料(b)が、ポリアミド、ポリイミド、ポリウレタン、ポリオレフィ ン、ポリスチレン、ポリエステル、ポリカーボネート、ポリケトン、ポリ尿素、 ポリアクリレート、及びポリメタクリレートから選択される請求項1に記載の複 合物品。 12.前記材料(b)がエラストマーである請求項1に記載の複合物品。 13.前記ペンダントアミン基が第一アミン基である請求項1に記載の複合物品 。 14.材料(b)が触媒を更に含む請求項1に記載の複合物品。 15.前記触媒が、オルガノ−オニウム化合物と酸受容体との組合せを含む請求 項14に記載の複合物品。 16.前記触媒が、脂肪族、アリール、またはアミジンアミン化合物から選択さ れるアミン化合物を含む請求項14に記載の複合物品。 17.前記ブレンド材料が、前記ビニリデンフルオリド含有フルオリポリマー約 5%〜約75%、前記第1の実質的にビニリデンフルオリドを含有しないフルオ リポリマー約25%〜約95%を含む請求項1に記載の複合物品。 18.前記ブレンド材料が、前記ビニリデンフルオリド含有フルオリポリマー約 10%〜約75%、前記第1の実質的にビニリデンフルオリドを含有しないフル オリポリマー約25%〜約90%を含む請求項1に記載の複合物品。 19.前記ブレンド材料が、前記ビニリデンフルオリド含有フルオリポリマー約 10%〜約50%、前記第1の実質的にビニリデンフルオリドを含有しないフル オリポリマー約50%〜約90%を含む請求項1に記載の複合物品。 20.成形された請求項1に記載の複合物品。 21.ワイヤー被覆、チューブ、容器、シート、ケーブルジャケット、及びフィ ルムの群から選択される請求項20に記載の複合物品。 22.前記材料(b)の前記露出面に付着した第2の実質的にフッ素化されていな いポリマー材料(c)を更に含む請求項1に記載の複合物品。 23.前記材料(c)が、ポリアミド、ポリイミド、ポリウレタン、ポリオレフィ ン、ポリスチレン、ポリエステル、ポリカーボネート、ポリケトン、ポリ尿素、 ポリアクリレート、及びポリメタクリレートから選択される請求項22に記載の 複合物品。 24.前記材料(c)がエラストマーである請求項22に記載の複合物品。 25.前記材料(c)がポリアミドである請求項22に記載の複合物品。 26.前記ブレンド材料(a)の前記第2の表面に付着した第2の実質的にビニリ デンフルオリドを含有しないフルオロポリマーを含む第4の材料(d)を更に含む 複合物品であって、該ブレンド材料(a)と前記材料(b)との間の剥離強度値が、該 材料(d)と該材料(b)との間の剥離強度値より大きい請求項1に記載の複合物品。 27.材料(d)の前記第2の実質的にビニリデンフルオリドを含有しないフルオ ロポリマーが、ビニリデンフルオリドの共重合単位(i)、または重合したビニリ デンフルオリドに本質的に似た微細構造配列を形成する他のモノマーの共重合単 位(ii)を実質的に含まない請求項26に記載の複合物品。。 28.材料(d)の前記第2の実質的にビニリデンフルオリドを含有しないフルオ ロポリマーが、(i)ヘキサフルオロプロピレン、テトラフルオロエチレン、ク ロロトリフルオロエチレン、フッ素化ビニルエーテル、及びそれらの組合せから 選択されるフッ素含有モノマーと、(ii)フッ素を含まない不飽和オレフィンコ モノマーと、任意に、(iii)ヨウ素または臭素含有オレフィンモノマーと、の 共重合単位から形成される請求項26に記載の複合物品。 29.前記フッ素を含まない不飽和オレフィンモノマーが、エチレン、プロピレ ン、及びブタジエンから選択され、前記ヨウ素または臭素含有不飽和オレフィン モノマーが、ブロモジフルオロエチレン、ブロモトリフルオロエチレン、ヨード トリフルオロエチレン、及び4−ブロモ−3,3,4,4−テトラフルオロ−1 −ブテンから選択される請求項28に記載の複合物品。 30.材料(d)の前記第2の実質的にビニリデンフルオリドを含有しないフルオ ロポリマーが、テトラフルオロエチレンと、ヘキサフルオロプロピレン、フッ素 化ビニルエーテル、エチレン、及びプロピレンから選択される少なくとも1つの 他のモノマーとの共重合単位から形成される請求項28に記載の複合物品。 31.前記第1及び第2の実質的にビニリデンフルオリドを含有しないフルオロ ポリマーが、同一または互いに似ている請求項26に記載の複合物品。 32.前記材料(b)の前記露出面に付着した第2の実質的にフッ素化されていな いポリマー材料(c)を更に含む請求項26に記載の複合物品。 33.実質的にフッ素化されていないポリマーをフルオロポリマーに付着させる 方法であって、(A)該フッ素化されていないポリマー、(B)(i)ビニリデンフル オリド含有フルオロポリマーと、(ii)第1の実質的にビニリデンフルオリドを 含有しないフルオロポリマーとのブレンド、及び(C)1つ以上のペンダント第一 または第二アミン基を有する実質的にフッ素化されていないポリマーを提供する 工程と、 遂次にまたは同時に、該ブレンド材料(B)を該ペンダントアミン材料(C)に付着さ せる工程と、 該フッ素化されていないポリマー材料(A)を該ペンダントアミン材料(C)に付着さ せる工程と、を含む方法。 34.第2の実質的にビニリデンフルオリドを含有しないフルオロポリマー材料 (D)を前記材料(B)に付着させる工程を更に含む方法であって、ブレンド材料(B) と前記ペンダントアミン材料(C)との間の剥離強度値が、該材料(D)と該ペンダン トアミン材料(C)との間の剥離強度値より大きい請求項33に記載の方法。 35.前記材料の少なくとも1つに添加剤を更に含む請求項32に記載の複合物 品。 36.実質的にビニリデンフルオリドを含有しないフルオロポリマーの第1の層 と、 (i) ビニリデンフルオリド含有フルオロポリマー、及び (ii) 実質的にビニリデンフルオリドを含有しないフルオロポリマーのブレン ドを含む第2の層と、 1つ以上のペンダント第一または第二アミン基を有する実質的にフッ素化されて いないポリマーを含む第3の層と、 実質的にフッ素化されていないポリマーを含む第4の層と、を順に含む多層ポリ マー物品であって、該第2の層と該第3の層との間の剥離強度が、該第1の層と 該第3の層との間の剥離強度より大きい多層ポリマー物品。 37.請求項36に記載の成形された複合物品。 38.シート、ホース、チューブ、ワイヤー被覆、ケーブルジャケット、及び容 器から選択される請求項37に記載の成形された物品。 39.前記材料の少なくとも1つに添加剤を更に含む請求項26に記載の複合物 品。 40.前記材料の少なくとも1つに添加剤を更に含む請求項22に記載の複合物 品。 41.前記フッ素含有モノマーがヘキサフルオロプロピレンである請求項5に記 載の複合物品。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US08/884,057 US6117508A (en) | 1997-06-27 | 1997-06-27 | Composite articles including a fluoropolymer blend |
US08/884,057 | 1997-06-27 | ||
PCT/US1998/011870 WO1999000249A1 (en) | 1997-06-27 | 1998-06-08 | Composite articles including a fluoropolymer blend |
Publications (3)
Publication Number | Publication Date |
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JP2002513344A true JP2002513344A (ja) | 2002-05-08 |
JP2002513344A5 JP2002513344A5 (ja) | 2005-12-02 |
JP4281927B2 JP4281927B2 (ja) | 2009-06-17 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP50979999A Expired - Fee Related JP4281927B2 (ja) | 1997-06-27 | 1998-06-08 | フルオロポリマーブレンドを含む複合物品 |
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Country | Link |
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US (2) | US6117508A (ja) |
EP (2) | EP1454953A1 (ja) |
JP (1) | JP4281927B2 (ja) |
AU (1) | AU8139898A (ja) |
CA (1) | CA2294509A1 (ja) |
DE (1) | DE69823353T2 (ja) |
WO (1) | WO1999000249A1 (ja) |
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-
1997
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-
1998
- 1998-06-08 JP JP50979999A patent/JP4281927B2/ja not_active Expired - Fee Related
- 1998-06-08 EP EP20040009001 patent/EP1454953A1/en not_active Withdrawn
- 1998-06-08 AU AU81398/98A patent/AU8139898A/en not_active Abandoned
- 1998-06-08 EP EP98931221A patent/EP0991519B1/en not_active Expired - Lifetime
- 1998-06-08 DE DE1998623353 patent/DE69823353T2/de not_active Expired - Lifetime
- 1998-06-08 CA CA 2294509 patent/CA2294509A1/en not_active Abandoned
- 1998-06-08 WO PCT/US1998/011870 patent/WO1999000249A1/en active IP Right Grant
-
2002
- 2002-09-11 US US10/241,660 patent/USRE40516E1/en not_active Expired - Lifetime
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US6117508A (en) | 2000-09-12 |
CA2294509A1 (en) | 1999-01-07 |
WO1999000249A1 (en) | 1999-01-07 |
USRE40516E1 (en) | 2008-09-23 |
AU8139898A (en) | 1999-01-19 |
DE69823353T2 (de) | 2005-05-04 |
JP4281927B2 (ja) | 2009-06-17 |
DE69823353D1 (de) | 2004-05-27 |
EP0991519B1 (en) | 2004-04-21 |
EP1454953A1 (en) | 2004-09-08 |
EP0991519A1 (en) | 2000-04-12 |
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