JP2001081313A5 - - Google Patents

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Publication number

JP2001081313A5

JP2001081313A5 JP1999262447A JP26244799A JP2001081313A5 JP 2001081313 A5 JP2001081313 A5 JP 2001081313A5 JP 1999262447 A JP1999262447 A JP 1999262447A JP 26244799 A JP26244799 A JP 26244799A JP 2001081313 A5 JP2001081313 A5 JP 2001081313A5

Authority

JP

Japan

Prior art keywords

polyamide resin

parts

weight

phosphorus compound

polyamide

Prior art date

1999-09-16

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Pending

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• 239000004952 Polyamide Substances 0.000 description 67
• 229920002647 polyamide Polymers 0.000 description 67
• 239000011528 polyamide (building material) Substances 0.000 description 64
• 239000011574 phosphorus Substances 0.000 description 46
• 229910052698 phosphorus Inorganic materials 0.000 description 46
• -1 phosphorus compound Chemical class 0.000 description 40
• GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 32
• 239000011342 resin composition Substances 0.000 description 27
• 239000011347 resin Substances 0.000 description 26
• 229920005989 resin Polymers 0.000 description 26
• OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 15
• 235000010215 titanium dioxide Nutrition 0.000 description 15
• 238000002845 discoloration Methods 0.000 description 14
• 239000000203 mixture Substances 0.000 description 14
• 239000004408 titanium dioxide Substances 0.000 description 14
• 150000002903 organophosphorus compounds Chemical class 0.000 description 12
• 229920002302 Nylon 6,6 Polymers 0.000 description 9
• LOCYSVHOSYQGOV-UHFFFAOYSA-N N-hexyl-6-$l^{1}-azanyl-6-oxohexanamide Chemical compound [CH]CCCCCNC(=O)CCCCC([N])=O LOCYSVHOSYQGOV-UHFFFAOYSA-N 0.000 description 8
• 150000003839 salts Chemical class 0.000 description 8
• 239000011780 sodium chloride Substances 0.000 description 8
• QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 7
• 229910052753 mercury Inorganic materials 0.000 description 7
• 239000008188 pellet Substances 0.000 description 6
• NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
• 150000001875 compounds Chemical class 0.000 description 5
• 230000000694 effects Effects 0.000 description 5
• 229910003475 inorganic filler Inorganic materials 0.000 description 5
• 239000011256 inorganic filler Substances 0.000 description 5
• 238000004898 kneading Methods 0.000 description 5
• 238000000465 moulding Methods 0.000 description 5
• 239000002994 raw material Substances 0.000 description 5
• 239000007864 aqueous solution Substances 0.000 description 4
• 238000011156 evaluation Methods 0.000 description 4
• 229910052751 metal Inorganic materials 0.000 description 4
• 239000002184 metal Substances 0.000 description 4
• JKIJEFPNVSHHEI-UHFFFAOYSA-N tris(2,4-ditert-butylphenyl) phosphite Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 4
• GQZXNSPRSGFJLY-UHFFFAOYSA-N Hypophosphorous acid Chemical compound OP=O GQZXNSPRSGFJLY-UHFFFAOYSA-N 0.000 description 3
• 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
• 238000002347 injection Methods 0.000 description 3
• 239000007924 injection Substances 0.000 description 3
• 239000000155 melt Substances 0.000 description 3
• ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 3
• 238000006116 polymerization reaction Methods 0.000 description 3
• WNLRTRBMVRJNCN-UHFFFAOYSA-N Adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
• 239000004594 Masterbatch (MB) Substances 0.000 description 2
• 239000004677 Nylon Substances 0.000 description 2
• 229920000305 Nylon 6,10 Polymers 0.000 description 2
• AQSJGOWTSHOLKH-UHFFFAOYSA-N Phosphite Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 2
• ZGKNDXOLMOFEJH-UHFFFAOYSA-M Sodium hypophosphite Chemical compound [Na+].[O-]P=O ZGKNDXOLMOFEJH-UHFFFAOYSA-M 0.000 description 2
• 238000006243 chemical reaction Methods 0.000 description 2
• 239000003795 chemical substances by application Substances 0.000 description 2
• 230000000052 comparative effect Effects 0.000 description 2
• 239000000945 filler Substances 0.000 description 2
• 238000001746 injection moulding Methods 0.000 description 2
• XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
• 229910052748 manganese Inorganic materials 0.000 description 2
• 239000011572 manganese Substances 0.000 description 2
• 238000002156 mixing Methods 0.000 description 2
• 229920001778 nylon Polymers 0.000 description 2
• 150000003018 phosphorus compounds Chemical class 0.000 description 2
• 239000000843 powder Substances 0.000 description 2
• 229910001379 sodium hypophosphite Inorganic materials 0.000 description 2
• AGGHKNBCHLWKHY-UHFFFAOYSA-N sodium triacetoxyborohydride Substances [Na+].CC(=O)O[B-](OC(C)=O)OC(C)=O AGGHKNBCHLWKHY-UHFFFAOYSA-N 0.000 description 2
• 239000003381 stabilizer Substances 0.000 description 2
• 239000000126 substance Substances 0.000 description 2
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
• LCJRHAPPMIUHLH-UHFFFAOYSA-N 1-$l^{1}-azanylhexan-1-one Chemical compound [CH]CCCCC([N])=O LCJRHAPPMIUHLH-UHFFFAOYSA-N 0.000 description 1
• YAGPRJYCDKGWJR-UHFFFAOYSA-N 2-(2,4,8,10-tetratert-butylbenzo[d][1,3,2]benzodioxaphosphepin-6-yl)oxy-N,N-bis[2-(2,4,8,10-tetratert-butylbenzo[d][1,3,2]benzodioxaphosphepin-6-yl)oxyethyl]ethanamine Chemical compound O1C2=C(C(C)(C)C)C=C(C(C)(C)C)C=C2C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP1OCCN(CCOP1OC2=C(C=C(C=C2C=2C=C(C=C(C=2O1)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C)CCOP(OC1=C(C=C(C=C11)C(C)(C)C)C(C)(C)C)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C YAGPRJYCDKGWJR-UHFFFAOYSA-N 0.000 description 1
• RVUBSBSILFNFCY-UHFFFAOYSA-N CCCCCCCCOP([O-])[O-] Chemical compound CCCCCCCCOP([O-])[O-] RVUBSBSILFNFCY-UHFFFAOYSA-N 0.000 description 1
• 239000005749 Copper compound Substances 0.000 description 1
• NAQMVNRVTILPCV-UHFFFAOYSA-N Hexamethylenediamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 1
• 229920002292 Nylon 6 Polymers 0.000 description 1
• FRCLQKLLFQYUJJ-UHFFFAOYSA-N P(O)(O)O.P(O)(O)O.C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1C(C)(C)C)C)C(C)(C)C Chemical compound P(O)(O)O.P(O)(O)O.C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1C(C)(C)C)C)C(C)(C)C FRCLQKLLFQYUJJ-UHFFFAOYSA-N 0.000 description 1
• GIATZHZBSIMOEE-UHFFFAOYSA-N P(O)(O)O.P(O)(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1)C(C)(C)C)C(C)(C)C Chemical compound P(O)(O)O.P(O)(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1)C(C)(C)C)C(C)(C)C GIATZHZBSIMOEE-UHFFFAOYSA-N 0.000 description 1
• 239000004743 Polypropylene Substances 0.000 description 1
• OGIDPMRJRNCKJF-UHFFFAOYSA-N TiO Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
• 229910010413 TiO 2 Inorganic materials 0.000 description 1
• DQWPFSLDHJDLRL-UHFFFAOYSA-N Triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
• BDZBKCUKTQZUTL-UHFFFAOYSA-N Triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 1
• WVLBCYQITXONBZ-UHFFFAOYSA-N Trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
• CYTQBVOFDCPGCX-UHFFFAOYSA-N Trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 description 1
• HVLLSGMXQDNUAL-UHFFFAOYSA-N Triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 1
• IRUFUJRSEXVACB-UHFFFAOYSA-N [2-(dihydroxyphosphanyloxymethyl)-2-(hydroxymethyl)-3-octadecoxyhenicosyl] dihydrogen phosphite Chemical compound CCCCCCCCCCCCCCCCCCOC(C(CO)(COP(O)O)COP(O)O)CCCCCCCCCCCCCCCCCC IRUFUJRSEXVACB-UHFFFAOYSA-N 0.000 description 1
• 239000001361 adipic acid Substances 0.000 description 1
• 235000011037 adipic acid Nutrition 0.000 description 1
• 229910052783 alkali metal Inorganic materials 0.000 description 1
• 150000001340 alkali metals Chemical class 0.000 description 1
• 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
• 150000001342 alkaline earth metals Chemical class 0.000 description 1
• 229910052782 aluminium Inorganic materials 0.000 description 1
• 150000001412 amines Chemical class 0.000 description 1
• 230000003712 anti-aging Effects 0.000 description 1
• 230000003078 antioxidant Effects 0.000 description 1
• 239000003963 antioxidant agent Substances 0.000 description 1
• OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
• 239000011575 calcium Substances 0.000 description 1
• 229910052791 calcium Inorganic materials 0.000 description 1
• 239000003086 colorant Substances 0.000 description 1
• 238000004040 coloring Methods 0.000 description 1
• 150000001880 copper compounds Chemical class 0.000 description 1
• LROMFDHROPKFSO-UHFFFAOYSA-N dioxidophosphane Chemical class [O-]P[O-] LROMFDHROPKFSO-UHFFFAOYSA-N 0.000 description 1
• FEICCOFQXMKGRC-UHFFFAOYSA-M disodium;dioxido(oxo)phosphanium;pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].[O-][P+]([O-])=O FEICCOFQXMKGRC-UHFFFAOYSA-M 0.000 description 1
• 239000003365 glass fiber Substances 0.000 description 1
• 238000010438 heat treatment Methods 0.000 description 1
• 230000001771 impaired Effects 0.000 description 1
• 150000002484 inorganic compounds Chemical class 0.000 description 1
• 229910052500 inorganic mineral Inorganic materials 0.000 description 1
• 229910052742 iron Inorganic materials 0.000 description 1
• 150000003951 lactams Chemical class 0.000 description 1
• 239000000314 lubricant Substances 0.000 description 1
• FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
• 239000011777 magnesium Substances 0.000 description 1
• 229910052749 magnesium Inorganic materials 0.000 description 1
• PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
• 150000002697 manganese compounds Chemical class 0.000 description 1
• 238000004519 manufacturing process Methods 0.000 description 1
• 239000000463 material Substances 0.000 description 1
• 238000000034 method Methods 0.000 description 1
• 239000011707 mineral Substances 0.000 description 1
• 229910052757 nitrogen Inorganic materials 0.000 description 1
• IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
• QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
• 150000002894 organic compounds Chemical class 0.000 description 1
• SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
• 239000002245 particle Substances 0.000 description 1
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
• 239000002530 phenolic antioxidant Substances 0.000 description 1
• MLCHBQKMVKNBOV-UHFFFAOYSA-N phenylphosphinic acid Chemical compound OP(=O)C1=CC=CC=C1 MLCHBQKMVKNBOV-UHFFFAOYSA-N 0.000 description 1
• QLZHNIAADXEJJP-UHFFFAOYSA-N phenylphosphonic acid Chemical compound OP(O)(=O)C1=CC=CC=C1 QLZHNIAADXEJJP-UHFFFAOYSA-N 0.000 description 1
• 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
• 239000004033 plastic Substances 0.000 description 1
• 229920000642 polymer Polymers 0.000 description 1
• 229920001155 polypropylene Polymers 0.000 description 1
• ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
• 239000011591 potassium Substances 0.000 description 1
• 229910052700 potassium Inorganic materials 0.000 description 1
• 238000002360 preparation method Methods 0.000 description 1
• 230000003014 reinforcing Effects 0.000 description 1
• KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
• 239000011734 sodium Substances 0.000 description 1
• 229910052708 sodium Inorganic materials 0.000 description 1
• 241000894007 species Species 0.000 description 1
• NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
• 239000011593 sulfur Substances 0.000 description 1
• 229910052717 sulfur Inorganic materials 0.000 description 1
• 229910001929 titanium oxide Inorganic materials 0.000 description 1
• 238000004383 yellowing Methods 0.000 description 1
• 229910052725 zinc Inorganic materials 0.000 description 1