JP2000017102A - 有機／無機複合高分子多孔材料及び多孔材料の製造方法 - Google Patents
有機／無機複合高分子多孔材料及び多孔材料の製造方法Info
- Publication number
- JP2000017102A JP2000017102A JP10204346A JP20434698A JP2000017102A JP 2000017102 A JP2000017102 A JP 2000017102A JP 10204346 A JP10204346 A JP 10204346A JP 20434698 A JP20434698 A JP 20434698A JP 2000017102 A JP2000017102 A JP 2000017102A
- Authority
- JP
- Japan
- Prior art keywords
- sample
- porous material
- surfactant
- organic
- pore
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011148 porous material Substances 0.000 title claims abstract description 194
- 229920000642 polymer Polymers 0.000 title claims abstract description 17
- 239000002131 composite material Substances 0.000 title claims abstract description 8
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 125000000962 organic group Chemical group 0.000 claims abstract description 62
- 125000004429 atom Chemical group 0.000 claims abstract description 59
- 229910052751 metal Inorganic materials 0.000 claims abstract description 52
- 239000002184 metal Substances 0.000 claims abstract description 52
- 238000009826 distribution Methods 0.000 claims abstract description 31
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 29
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 13
- 125000003545 alkoxy group Chemical group 0.000 claims description 11
- 125000005843 halogen group Chemical group 0.000 claims description 10
- 150000002736 metal compounds Chemical class 0.000 claims description 4
- 239000013335 mesoporous material Substances 0.000 abstract description 23
- 239000004094 surface-active agent Substances 0.000 description 75
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 57
- 239000000047 product Substances 0.000 description 45
- 238000002441 X-ray diffraction Methods 0.000 description 38
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 35
- 238000010586 diagram Methods 0.000 description 30
- 238000001179 sorption measurement Methods 0.000 description 29
- 238000006243 chemical reaction Methods 0.000 description 27
- 239000000203 mixture Substances 0.000 description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 20
- 238000003756 stirring Methods 0.000 description 19
- 229910052757 nitrogen Inorganic materials 0.000 description 17
- 239000000243 solution Substances 0.000 description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 16
- 239000002243 precursor Substances 0.000 description 16
- 239000000126 substance Substances 0.000 description 15
- 238000000034 method Methods 0.000 description 14
- 239000002244 precipitate Substances 0.000 description 14
- 125000000217 alkyl group Chemical group 0.000 description 13
- 238000006068 polycondensation reaction Methods 0.000 description 13
- 238000001228 spectrum Methods 0.000 description 11
- 239000007864 aqueous solution Substances 0.000 description 10
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 10
- 150000002902 organometallic compounds Chemical class 0.000 description 10
- 239000012265 solid product Substances 0.000 description 9
- 238000005481 NMR spectroscopy Methods 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 150000001721 carbon Chemical group 0.000 description 8
- XJWSAJYUBXQQDR-UHFFFAOYSA-M dodecyltrimethylammonium bromide Chemical compound [Br-].CCCCCCCCCCCC[N+](C)(C)C XJWSAJYUBXQQDR-UHFFFAOYSA-M 0.000 description 7
- 150000002430 hydrocarbons Chemical class 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 7
- 238000002411 thermogravimetry Methods 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 238000006555 catalytic reaction Methods 0.000 description 6
- 125000000524 functional group Chemical group 0.000 description 6
- 150000002894 organic compounds Chemical class 0.000 description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- 229910003902 SiCl 4 Inorganic materials 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- 238000003917 TEM image Methods 0.000 description 5
- 229910001873 dinitrogen Inorganic materials 0.000 description 5
- 238000012643 polycondensation polymerization Methods 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical group [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 4
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- DZGCGKFAPXFTNM-UHFFFAOYSA-N ethanol;hydron;chloride Chemical compound Cl.CCO DZGCGKFAPXFTNM-UHFFFAOYSA-N 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 4
- 125000004430 oxygen atom Chemical group O* 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 125000003396 thiol group Chemical group [H]S* 0.000 description 4
- -1 trimethoxysilyl group Chemical group 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000003463 adsorbent Substances 0.000 description 3
- 238000007605 air drying Methods 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 238000010894 electron beam technology Methods 0.000 description 3
- 238000000921 elemental analysis Methods 0.000 description 3
- 229910052735 hafnium Inorganic materials 0.000 description 3
- 239000002808 molecular sieve Substances 0.000 description 3
- 229910052758 niobium Inorganic materials 0.000 description 3
- 239000010955 niobium Substances 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000012044 organic layer Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000001878 scanning electron micrograph Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 3
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 3
- 229910052715 tantalum Inorganic materials 0.000 description 3
- 229910052718 tin Inorganic materials 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 229910018540 Si C Inorganic materials 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 102100031083 Uteroglobin Human genes 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000000304 alkynyl group Chemical group 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 229910052790 beryllium Inorganic materials 0.000 description 2
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000006482 condensation reaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 125000005372 silanol group Chemical group 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- WDVUXWDZTPZIIE-UHFFFAOYSA-N trichloro(2-trichlorosilylethyl)silane Chemical compound Cl[Si](Cl)(Cl)CC[Si](Cl)(Cl)Cl WDVUXWDZTPZIIE-UHFFFAOYSA-N 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- KKIGDGWHHNXWNM-UHFFFAOYSA-N 1,2,3-tripropylbenzene Chemical compound CCCC1=CC=CC(CCC)=C1CCC KKIGDGWHHNXWNM-UHFFFAOYSA-N 0.000 description 1
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- ILYPBNJZPIUWFJ-UHFFFAOYSA-N 3-methoxysulfanylpropylsilane Chemical compound COSCCC[SiH3] ILYPBNJZPIUWFJ-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910018516 Al—O Inorganic materials 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 101000777301 Homo sapiens Uteroglobin Proteins 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- 102220500397 Neutral and basic amino acid transport protein rBAT_M41T_mutation Human genes 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- 229910020923 Sn-O Inorganic materials 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 108090000203 Uteroglobin Proteins 0.000 description 1
- 229910007746 Zr—O Inorganic materials 0.000 description 1
- NURCXSUYOXAANP-UHFFFAOYSA-N [Br-].C(C1=CC=CC=C1)[NH3+].[Cl-].C(C1=CC=CC=C1)[NH3+] Chemical compound [Br-].C(C1=CC=CC=C1)[NH3+].[Cl-].C(C1=CC=CC=C1)[NH3+] NURCXSUYOXAANP-UHFFFAOYSA-N 0.000 description 1
- XTUNVEMVWFXFGV-UHFFFAOYSA-N [C].CCO Chemical compound [C].CCO XTUNVEMVWFXFGV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002156 adsorbate Substances 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- CBVJWBYNOWIOFJ-UHFFFAOYSA-N chloro(trimethoxy)silane Chemical compound CO[Si](Cl)(OC)OC CBVJWBYNOWIOFJ-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002003 electron diffraction Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 150000002500 ions Chemical group 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000001819 mass spectrum Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 238000000371 solid-state nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- 238000012916 structural analysis Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- JCGDCINCKDQXDX-UHFFFAOYSA-N trimethoxy(2-trimethoxysilylethyl)silane Chemical compound CO[Si](OC)(OC)CC[Si](OC)(OC)OC JCGDCINCKDQXDX-UHFFFAOYSA-N 0.000 description 1
- AQZSPJRLCJSOED-UHFFFAOYSA-M trimethyl(octyl)azanium;chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(C)C AQZSPJRLCJSOED-UHFFFAOYSA-M 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Landscapes
- Catalysts (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Silicon Polymers (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10204346A JP2000017102A (ja) | 1998-07-03 | 1998-07-03 | 有機／無機複合高分子多孔材料及び多孔材料の製造方法 |
| JP20807499A JP3899733B2 (ja) | 1998-07-03 | 1999-06-16 | 多孔材料及び多孔材料の製造方法 |
| US09/347,005 US6248686B1 (en) | 1998-07-03 | 1999-07-02 | Organic/inorganic complex porous materials |
| DE19930944A DE19930944B4 (de) | 1998-07-03 | 1999-07-05 | Organische/anorganische Materialien umfassende Komplexe eines porösen Materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10204346A JP2000017102A (ja) | 1998-07-03 | 1998-07-03 | 有機／無機複合高分子多孔材料及び多孔材料の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2000017102A true JP2000017102A (ja) | 2000-01-18 |
| JP2000017102A6 JP2000017102A6 (enExample) | 2005-06-09 |
Family
ID=16488988
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10204346A Pending JP2000017102A (ja) | 1998-07-03 | 1998-07-03 | 有機／無機複合高分子多孔材料及び多孔材料の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2000017102A (enExample) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003106565A1 (ja) | 2002-06-03 | 2003-12-24 | 三洋化成工業株式会社 | ミセル含有有機ポリマー、有機ポリマー多孔体及び多孔炭素材料 |
| JP2006504854A (ja) * | 2002-10-30 | 2006-02-09 | ウオーターズ・インベストメンツ・リミテツド | 多孔性無機／有機ハイブリッド材料およびその調製 |
| JP2006070139A (ja) * | 2004-09-01 | 2006-03-16 | Toyota Central Res & Dev Lab Inc | シリカ系メソ構造体及びその製造方法 |
| JP2006152263A (ja) * | 2004-10-27 | 2006-06-15 | Tokyo Institute Of Technology | 有機−無機ハイブリッド型メソポーラス材料、その製造方法及び固体触媒 |
| JP2006519287A (ja) * | 2003-01-23 | 2006-08-24 | コミツサリア タ レネルジー アトミーク | 無機メソポーラス相および有機相を含む有機−無機ハイブリッド材料、膜および燃料電池 |
| JP2007527312A (ja) * | 2003-07-16 | 2007-09-27 | シュトゥディエンゲゼルシャフト・コーレ・ミット・ベシュレンクテル・ハフツング | 多孔性マトリックス中にカプセル化された水素可逆吸蔵用材料 |
| JP2008508516A (ja) * | 2004-07-30 | 2008-03-21 | ウオーターズ・インベストメンツ・リミテツド | クロマトグラフィー分離用の秩序領域を有する多孔質無機／有機のハイブリッド材料およびこれらの調製方法 |
| JP2013066888A (ja) * | 1999-09-20 | 2013-04-18 | Toyota Central R&D Labs Inc | 多孔体及びその製造方法 |
-
1998
- 1998-07-03 JP JP10204346A patent/JP2000017102A/ja active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013066888A (ja) * | 1999-09-20 | 2013-04-18 | Toyota Central R&D Labs Inc | 多孔体及びその製造方法 |
| WO2003106565A1 (ja) | 2002-06-03 | 2003-12-24 | 三洋化成工業株式会社 | ミセル含有有機ポリマー、有機ポリマー多孔体及び多孔炭素材料 |
| JP2006504854A (ja) * | 2002-10-30 | 2006-02-09 | ウオーターズ・インベストメンツ・リミテツド | 多孔性無機／有機ハイブリッド材料およびその調製 |
| JP2006519287A (ja) * | 2003-01-23 | 2006-08-24 | コミツサリア タ レネルジー アトミーク | 無機メソポーラス相および有機相を含む有機−無機ハイブリッド材料、膜および燃料電池 |
| JP2007527312A (ja) * | 2003-07-16 | 2007-09-27 | シュトゥディエンゲゼルシャフト・コーレ・ミット・ベシュレンクテル・ハフツング | 多孔性マトリックス中にカプセル化された水素可逆吸蔵用材料 |
| JP2008508516A (ja) * | 2004-07-30 | 2008-03-21 | ウオーターズ・インベストメンツ・リミテツド | クロマトグラフィー分離用の秩序領域を有する多孔質無機／有機のハイブリッド材料およびこれらの調製方法 |
| JP2013210382A (ja) * | 2004-07-30 | 2013-10-10 | Waters Technologies Corp | クロマトグラフィー分離用の秩序領域を有する多孔質無機／有機のハイブリッド材料およびこれらの調製方法 |
| JP2015111120A (ja) * | 2004-07-30 | 2015-06-18 | ウオーターズ・テクノロジーズ・コーポレイシヨン | クロマトグラフィー分離用の秩序領域を有する多孔質無機／有機のハイブリッド材料およびこれらの調製方法 |
| JP2006070139A (ja) * | 2004-09-01 | 2006-03-16 | Toyota Central Res & Dev Lab Inc | シリカ系メソ構造体及びその製造方法 |
| JP2006152263A (ja) * | 2004-10-27 | 2006-06-15 | Tokyo Institute Of Technology | 有機−無機ハイブリッド型メソポーラス材料、その製造方法及び固体触媒 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3899733B2 (ja) | 多孔材料及び多孔材料の製造方法 | |
| KR100624648B1 (ko) | 메소구조의 무기 산화물을 제조하기 위한 블록 중합체 공정 | |
| US6346140B2 (en) | Porous solid for gas adsorption separation and gas adsorption separation process employing it | |
| US7947799B2 (en) | High organic group content-periodic mesoporous organosilicas (HO-PMO's) | |
| Sasidharan et al. | Incorporation of tin in different types of pores in SBA-15: synthesis, characterization and catalytic activity | |
| Hunks et al. | Single‐Source Precursors For Synthesizing Bifunctional Periodic Mesoporous Organosilicas | |
| JP4026884B2 (ja) | メソポア分子ふるい、およびその製造方法 | |
| JP4482298B2 (ja) | ジェミニ型界面活性剤、およびこれを用いたメソポーラス物質の製造方法 | |
| JP2000281331A (ja) | メソ多孔体及びその製造方法 | |
| JP2000017102A (ja) | 有機／無機複合高分子多孔材料及び多孔材料の製造方法 | |
| WO2003037511A1 (en) | Method of preparing highly ordered mesoporous molecular sieves | |
| JP4925086B2 (ja) | 薄板状もしくは繊維状の有機無機多孔質シリカ粒子とその製造方法 | |
| Zhang et al. | Super-microporous organosilicas synthesized from well-defined nanobuilding units | |
| KR100900919B1 (ko) | 제올라이트 골격을 갖는 메조포러스 물질의 제조방법 | |
| JP4534279B2 (ja) | 有機無機複合材料からなる多孔質粒子 | |
| Xia et al. | Preparation of bifunctionalized phenylene-bridged periodic mesoporous organosilica for solid-phase microextraction | |
| US20090186226A1 (en) | Mesostructured organic-inorganic hybrid material | |
| JP4544411B2 (ja) | 有機シリカ複合材料の製造方法 | |
| US8415403B2 (en) | Mesoporous materials and reactants for preparing them | |
| JP2001116737A (ja) | 多孔質粒子を用いた吸着分離方法 | |
| KR100941930B1 (ko) | 유기-무기 혼성 중간세공 분자체 및 그 제조 방법 | |
| JP3980397B2 (ja) | 有機無機複合材料を含有する触媒組成物および有機化合物の転化方法 | |
| JP5057021B2 (ja) | 球状シリカ系メソ多孔体及びその製造方法、並びにそれを用いた塩基性色素吸着材 | |
| JP2008145190A (ja) | マイクロカプセル、液体クロマトグラフ用充填剤及びそれを用いた液体クロマトグラフ用カラム | |
| JP2003146625A (ja) | 非シリカ系メソ構造体及びその製造方法 |