IT8520476A0 - Catalizzatori ad alta resa e ad elevata resistenza meccanica, particolarmente adatto perl'ossidazione del metanolo a formaldeide. - Google Patents

Catalizzatori ad alta resa e ad elevata resistenza meccanica, particolarmente adatto perl'ossidazione del metanolo a formaldeide.

Info

Publication number
IT8520476A0
IT8520476A0 IT8520476A IT2047685A IT8520476A0 IT 8520476 A0 IT8520476 A0 IT 8520476A0 IT 8520476 A IT8520476 A IT 8520476A IT 2047685 A IT2047685 A IT 2047685A IT 8520476 A0 IT8520476 A0 IT 8520476A0
Authority
IT
Italy
Prior art keywords
formaldehyde
methanol
oxidation
catalyst
particularly suitable
Prior art date
Application number
IT8520476A
Other languages
English (en)
Other versions
IT1214489B (it
Inventor
Augusto Viola
Luigi Cavalli
Mario Cucchetto
Guido Petrini
Original Assignee
Ausind Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ausind Spa filed Critical Ausind Spa
Publication of IT8520476A0 publication Critical patent/IT8520476A0/it
Priority to IT8520476A priority Critical patent/IT1214489B/it
Priority to ZA862860A priority patent/ZA862860B/xx
Priority to AU56325/86A priority patent/AU578356B2/en
Priority to PT82431A priority patent/PT82431B/pt
Priority to FI861706A priority patent/FI80833C/fi
Priority to ES554255A priority patent/ES8802122A1/es
Priority to EP86105690A priority patent/EP0199359B1/en
Priority to DE8686105690T priority patent/DE3675682D1/de
Priority to BR8601855A priority patent/BR8601855A/pt
Priority to AT86105690T priority patent/ATE58491T1/de
Priority to JP61095852A priority patent/JPS6291247A/ja
Priority to DE198686105690T priority patent/DE199359T1/de
Priority to CA000507442A priority patent/CA1266041A/en
Priority to US07/175,618 priority patent/US4829042A/en
Application granted granted Critical
Publication of IT1214489B publication Critical patent/IT1214489B/it

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • B01J23/881Molybdenum and iron
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/38Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
IT8520476A 1985-04-24 1985-04-24 Catalizzatori ad alta resa e ad elevata resistenza meccanica, particolarmente adatto perl'ossidazione del metanolo a formaldeide. IT1214489B (it)

Priority Applications (14)

Application Number Priority Date Filing Date Title
IT8520476A IT1214489B (it) 1985-04-24 1985-04-24 Catalizzatori ad alta resa e ad elevata resistenza meccanica, particolarmente adatto perl'ossidazione del metanolo a formaldeide.
ZA862860A ZA862860B (en) 1985-04-24 1986-04-16 High yield,high resistance catalyst,particularly suitable for the oxidation of methyl alcohol to formaldehyde
AU56325/86A AU578356B2 (en) 1985-04-24 1986-04-17 Iron-molybdenum catatyst
PT82431A PT82431B (pt) 1985-04-24 1986-04-21 Processo de preparacao de catalisador de alto rendimento e de alta resistencia e processo de oxidacao do alcool metilico a formaldeido com aquele
FI861706A FI80833C (fi) 1985-04-24 1986-04-23 Synnerligen bestaendig katalyt med hoegt utbyte, laemplig speciellt foer oxidation av metylakohol till formaldehyd, och foerfarande foer framstaellning av den.
ES554255A ES8802122A1 (es) 1985-04-24 1986-04-23 Un metodo para la preparacion de un catalizador de alto rendimiento alta resistencia particularmente apropiado para la oxidacion del alcohol metilico a formaldehido
EP86105690A EP0199359B1 (en) 1985-04-24 1986-04-24 High yield, high resistance catalyst, particularly suitable for the oxidation of methyl alcohol to formaldehyde
DE8686105690T DE3675682D1 (de) 1985-04-24 1986-04-24 Sehr widerstandsfaehiger katalysator mit hoher ausbeute, der besonders fuer die oxidation von methanol zu formaldehyd geeignet ist.
BR8601855A BR8601855A (pt) 1985-04-24 1986-04-24 Catalisador de alto rendimento e de alta resistencia mecanica particularmente adequado para a oxidacao do alcool metilico a formaldeido e processo de preparacao do catalisador
AT86105690T ATE58491T1 (de) 1985-04-24 1986-04-24 Sehr widerstandsfaehiger katalysator mit hoher ausbeute, der besonders fuer die oxidation von methanol zu formaldehyd geeignet ist.
JP61095852A JPS6291247A (ja) 1985-04-24 1986-04-24 メチルアルコールからホルムアルデヒドへの酸化に用いられる、高収率かつ高耐性な触媒
DE198686105690T DE199359T1 (de) 1985-04-24 1986-04-24 Sehr widerstandsfaehiger katalysator mit hoher ausbeute, der besonders fuer die oxidation von methanol zu formaldehyd geeignet ist.
CA000507442A CA1266041A (en) 1985-04-24 1986-04-24 High yield, high resistance catalyst, particularly suitable for the oxidation of methyl alcohol to formaldehyde
US07/175,618 US4829042A (en) 1985-04-24 1988-03-29 Catalyst suitable for the oxidation of methyl alcohol to formaldehyde and method for preparing the catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT8520476A IT1214489B (it) 1985-04-24 1985-04-24 Catalizzatori ad alta resa e ad elevata resistenza meccanica, particolarmente adatto perl'ossidazione del metanolo a formaldeide.

Publications (2)

Publication Number Publication Date
IT8520476A0 true IT8520476A0 (it) 1985-04-24
IT1214489B IT1214489B (it) 1990-01-18

Family

ID=11167517

Family Applications (1)

Application Number Title Priority Date Filing Date
IT8520476A IT1214489B (it) 1985-04-24 1985-04-24 Catalizzatori ad alta resa e ad elevata resistenza meccanica, particolarmente adatto perl'ossidazione del metanolo a formaldeide.

Country Status (13)

Country Link
US (1) US4829042A (it)
EP (1) EP0199359B1 (it)
JP (1) JPS6291247A (it)
AT (1) ATE58491T1 (it)
AU (1) AU578356B2 (it)
BR (1) BR8601855A (it)
CA (1) CA1266041A (it)
DE (2) DE3675682D1 (it)
ES (1) ES8802122A1 (it)
FI (1) FI80833C (it)
IT (1) IT1214489B (it)
PT (1) PT82431B (it)
ZA (1) ZA862860B (it)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SK496890A3 (en) * 1989-10-16 1998-10-07 Haldor Topsoe As Catalyst for preparing aldehydes
CN1044339C (zh) * 1993-09-24 1999-07-28 化学工业部北京化工研究院 用于甲醇氧化制甲醛的催化剂的制法
US6037290A (en) * 1998-04-15 2000-03-14 Lehigh University In situ regeneration of metal-molybdate catalysts for methanol oxidation to formaldehyde
US6331503B1 (en) * 1998-04-15 2001-12-18 Lehigh University In-situ formation of metal-molybdate catalysts
ATE499987T1 (de) * 2000-07-12 2011-03-15 Albemarle Netherlands Bv Ein auf einem brennbaren bindemittel basierender mischmetallkatalysator
WO2002022539A2 (en) * 2000-09-14 2002-03-21 Lehigh University Metal molybdate/iron-molybdate dual catalyst bed system and process using the same for methanol oxidation to formaldehyde
WO2002022540A2 (en) 2000-09-14 2002-03-21 Lehigh University Dual catalyst bed reactor for methanol oxidation
US6552233B2 (en) 2000-09-14 2003-04-22 Lehigh University Vanadia-titania/metal-molybdate dual catalyst bed system and process using the same for methanol oxidation to formaldehyde
ITMI20042456A1 (it) * 2004-12-22 2005-03-22 Sued Chemie Mt Srl Catalizzatori per l'ossidazione del metanolo a formaldeide
ITMI20042500A1 (it) * 2004-12-23 2005-03-23 Sued Chemie Mt Srl Processo per la preparazione di un catalizzatore per l'ossidazione del metanolo a formaldeide
DE102010040921A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Methanol und Essigsäure
DE102010040923A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Ethanol und Formaldehyd
DE102011083079A1 (de) 2011-09-20 2013-03-21 Wacker Chemie Ag Vanadium-Antimon-Mischoxid Katalysator seine Herstellung und Verfahren zur Partialoxidation von Alkoholen zu Aldehyden
KR101303061B1 (ko) 2012-09-25 2013-09-03 금호석유화학 주식회사 다중벽 탄소나노튜브 제조용 촉매조성물
US20140121403A1 (en) 2012-10-31 2014-05-01 Celanese International Corporation Integrated Process for the Production of Acrylic Acids and Acrylates
US9120743B2 (en) 2013-06-27 2015-09-01 Celanese International Corporation Integrated process for the production of acrylic acids and acrylates
DE102014204628A1 (de) 2014-03-13 2015-09-17 Technische Universität Darmstadt Vanadium-Antimon-Mischoxid Katalysator seine Herstellung und Verfahren zur Partialoxidation von Alkoholen zu Aldehyden
CN109806881A (zh) * 2017-11-20 2019-05-28 中国科学院大连化学物理研究所 一种用于甲醇氧化制甲醛的铁钼催化剂及其制备方法
CN113019386B (zh) * 2019-12-09 2022-06-14 中国科学院大连化学物理研究所 甲醇氧化制甲醛铁钼催化剂及制备和应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2812308A (en) * 1954-08-27 1957-11-05 Reichhold Chemicals Inc Method for producing supported catalyst for oxidation of alcohols to aldehydes
LU39911A1 (it) * 1958-10-28
US3408309A (en) * 1964-11-16 1968-10-29 Lummus Co Fe, mo, co, and w mixed oxides as oxidation catalysts
GB1191143A (en) * 1966-05-30 1970-05-06 Ceskoslovenska Akademie Ved Method of Preparing Catalysts for a Catalytic Oxidising Conversion of Methanol into Formaldehydes
FR2082444A5 (it) * 1970-03-16 1971-12-10 Inst Francais Du Petrole
US3978136A (en) * 1971-09-14 1976-08-31 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Process for the production of a catalyst suitable for the oxidation of methanol to formaldehyde
GB2069859B (en) * 1979-12-19 1983-06-22 Euteco Impianti Spa Process for preparing catalysts based on polybdenum and iron oxide
US4425260A (en) * 1982-09-30 1984-01-10 Monsanto Company Catalysts for the oxidation and ammoxidation of alcohols

Also Published As

Publication number Publication date
PT82431B (pt) 1988-05-27
FI861706A (fi) 1986-10-25
FI80833C (fi) 1990-08-10
EP0199359B1 (en) 1990-11-22
ES554255A0 (es) 1988-04-16
EP0199359A3 (en) 1987-06-24
FI80833B (fi) 1990-04-30
CA1266041A (en) 1990-02-20
AU5632586A (en) 1986-10-30
ES8802122A1 (es) 1988-04-16
DE3675682D1 (de) 1991-01-03
PT82431A (en) 1986-05-01
DE199359T1 (de) 1987-03-19
EP0199359A2 (en) 1986-10-29
ZA862860B (en) 1987-03-25
BR8601855A (pt) 1986-12-30
IT1214489B (it) 1990-01-18
AU578356B2 (en) 1988-10-20
FI861706A0 (fi) 1986-04-23
US4829042A (en) 1989-05-09
JPH0550342B2 (it) 1993-07-28
ATE58491T1 (de) 1990-12-15
JPS6291247A (ja) 1987-04-25

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TA Fee payment date (situation as of event date), data collected since 19931001

Effective date: 19970421