IT1270973B - Processo di idroconversione in fase liquida di frazioni pesanti in presenza di un catalizzatore disperso e di un addittivo poliaromatico - Google Patents
Processo di idroconversione in fase liquida di frazioni pesanti in presenza di un catalizzatore disperso e di un addittivo poliaromaticoInfo
- Publication number
- IT1270973B IT1270973B ITMI930573A ITMI930573A IT1270973B IT 1270973 B IT1270973 B IT 1270973B IT MI930573 A ITMI930573 A IT MI930573A IT MI930573 A ITMI930573 A IT MI930573A IT 1270973 B IT1270973 B IT 1270973B
- Authority
- IT
- Italy
- Prior art keywords
- additive
- polyaromatic
- heavy fractions
- dispersed catalyst
- hydroconversion process
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/32—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions in the presence of hydrogen-generating compounds
- C10G47/34—Organic compounds, e.g. hydrogenated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Il processo riguarda l'idroconversione in fase liquida di cariche idrocarburiche contenenti frazioni pesanti e più in particolare la loro conversione profonda.Secondo l'invenzione la carica è messa in contatto con un catalizzatore disperso in presenza di un additivo poliaromatico. Il catalizzatore è costituito da un solfuro di un metallo idrogenante (come molibdeno, nichel, cobalto) prodotto in situ, a partire da un precursore. L'additivo comporta almeno tre cicli aromatici, presenta un punto di ebollizione superiore a 300°C ed è aggiunto in ragione di 5-60% in peso rispetto alla carica.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9203660A FR2689137B1 (fr) | 1992-03-26 | 1992-03-26 | Procede d'hydro conversion de fractions lourds en phase liquide en presence d'un catalyseur disperse et d'additif polyaromatique. |
Publications (3)
Publication Number | Publication Date |
---|---|
ITMI930573A0 ITMI930573A0 (it) | 1993-03-25 |
ITMI930573A1 ITMI930573A1 (it) | 1994-09-25 |
IT1270973B true IT1270973B (it) | 1997-05-26 |
Family
ID=9428109
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ITMI930573A IT1270973B (it) | 1992-03-26 | 1993-03-25 | Processo di idroconversione in fase liquida di frazioni pesanti in presenza di un catalizzatore disperso e di un addittivo poliaromatico |
Country Status (6)
Country | Link |
---|---|
US (1) | US5460714A (it) |
CA (1) | CA2092787C (it) |
DE (1) | DE4309669A1 (it) |
FR (1) | FR2689137B1 (it) |
IT (1) | IT1270973B (it) |
MX (1) | MX9301670A (it) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7645375B2 (en) * | 2003-05-16 | 2010-01-12 | Exxonmobil Research And Engineering Company | Delayed coking process for producing free-flowing coke using low molecular weight aromatic additives |
US7658838B2 (en) * | 2003-05-16 | 2010-02-09 | Exxonmobil Research And Engineering Company | Delayed coking process for producing free-flowing coke using polymeric additives |
US7303664B2 (en) * | 2003-05-16 | 2007-12-04 | Exxonmobil Research And Engineering Company | Delayed coking process for producing free-flowing coke using a metals-containing additive |
US20050279673A1 (en) * | 2003-05-16 | 2005-12-22 | Eppig Christopher P | Delayed coking process for producing free-flowing coke using an overbased metal detergent additive |
US7517446B2 (en) * | 2004-04-28 | 2009-04-14 | Headwaters Heavy Oil, Llc | Fixed bed hydroprocessing methods and systems and methods for upgrading an existing fixed bed system |
CA2855431C (en) | 2004-04-28 | 2016-08-16 | Headwaters Heavy Oil, Llc | Ebullated bed hydroprocessing methods and systems and methods of upgrading an existing ebullated bed system |
US10941353B2 (en) | 2004-04-28 | 2021-03-09 | Hydrocarbon Technology & Innovation, Llc | Methods and mixing systems for introducing catalyst precursor into heavy oil feedstock |
US20050263438A1 (en) * | 2004-05-14 | 2005-12-01 | Ramesh Varadaraj | Inhibitor enhanced thermal upgrading of heavy oils via mesophase suppression using oil soluble polynuclear aromatics |
CA2566117C (en) * | 2004-05-14 | 2012-12-04 | Exxonmobil Research And Engineering Company | Viscoelastic upgrading of heavy oil by altering its elastic modulus |
CN1954050A (zh) * | 2004-05-14 | 2007-04-25 | 埃克森美孚研究工程公司 | 在延迟焦化中从减压渣油的深拔馏分中生产基本上自由流动的焦炭 |
MXPA06012949A (es) * | 2004-05-14 | 2007-02-12 | Exxonmobil Res & Eng Co | Combinacion de materias primas de residuos para producir un coque que sea mas facil de remover de un tambor de coquizacion. |
MXPA06011752A (es) * | 2004-05-14 | 2007-01-16 | Exxonmobil Res & Eng Co | Produccion y remocion de coque de flujo libre de tambor coquizador retrasado. |
US7871510B2 (en) * | 2007-08-28 | 2011-01-18 | Exxonmobil Research & Engineering Co. | Production of an enhanced resid coker feed using ultrafiltration |
US8034232B2 (en) | 2007-10-31 | 2011-10-11 | Headwaters Technology Innovation, Llc | Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker |
US8142645B2 (en) | 2008-01-03 | 2012-03-27 | Headwaters Technology Innovation, Llc | Process for increasing the mono-aromatic content of polynuclear-aromatic-containing feedstocks |
US7794587B2 (en) * | 2008-01-22 | 2010-09-14 | Exxonmobil Research And Engineering Company | Method to alter coke morphology using metal salts of aromatic sulfonic acids and/or polysulfonic acids |
US7951747B1 (en) * | 2009-04-03 | 2011-05-31 | Sandia Corporation | Single-layer transition metal sulfide catalysts |
CN103228355A (zh) | 2010-12-20 | 2013-07-31 | 雪佛龙美国公司 | 加氢加工催化剂及其制备方法 |
US9790440B2 (en) | 2011-09-23 | 2017-10-17 | Headwaters Technology Innovation Group, Inc. | Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker |
US9644157B2 (en) | 2012-07-30 | 2017-05-09 | Headwaters Heavy Oil, Llc | Methods and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking |
EP2888342B1 (en) | 2012-08-24 | 2020-06-17 | Saudi Arabian Oil Company | Hydrovisbreaking process for feedstock containing dissolved hydrogen |
US11414607B2 (en) | 2015-09-22 | 2022-08-16 | Hydrocarbon Technology & Innovation, Llc | Upgraded ebullated bed reactor with increased production rate of converted products |
US11414608B2 (en) | 2015-09-22 | 2022-08-16 | Hydrocarbon Technology & Innovation, Llc | Upgraded ebullated bed reactor used with opportunity feedstocks |
US11421164B2 (en) | 2016-06-08 | 2022-08-23 | Hydrocarbon Technology & Innovation, Llc | Dual catalyst system for ebullated bed upgrading to produce improved quality vacuum residue product |
KR101988571B1 (ko) | 2016-07-20 | 2019-06-12 | 한국에너지기술연구원 | 아로마틱 성분 및 레진 성분이 포함된 첨가제 및 이를 활용한 수첨전환 방법 |
US11118119B2 (en) | 2017-03-02 | 2021-09-14 | Hydrocarbon Technology & Innovation, Llc | Upgraded ebullated bed reactor with less fouling sediment |
US11732203B2 (en) | 2017-03-02 | 2023-08-22 | Hydrocarbon Technology & Innovation, Llc | Ebullated bed reactor upgraded to produce sediment that causes less equipment fouling |
KR102433701B1 (ko) | 2017-11-29 | 2022-08-18 | 한국에너지기술연구원 | 중질유분 전환 및 경질유분 수율 향상을 위한 수첨전환 방법 |
CA3057131C (en) | 2018-10-17 | 2024-04-23 | Hydrocarbon Technology And Innovation, Llc | Upgraded ebullated bed reactor with no recycle buildup of asphaltenes in vacuum bottoms |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1031914B (de) * | 1954-02-15 | 1958-06-12 | Exxon Research Engineering Co | Verfahren zur Gewinnung wertvoller Produkte, wie Gasoele, Heizoele und Benzine, aus asphalthaltigen OElen |
US4066530A (en) * | 1976-07-02 | 1978-01-03 | Exxon Research & Engineering Co. | Hydroconversion of heavy hydrocarbons |
US4244839A (en) * | 1978-10-30 | 1981-01-13 | Exxon Research & Engineering Co. | High surface area catalysts |
US4292168A (en) * | 1979-12-28 | 1981-09-29 | Mobil Oil Corporation | Upgrading heavy oils by non-catalytic treatment with hydrogen and hydrogen transfer solvent |
US4485004A (en) * | 1982-09-07 | 1984-11-27 | Gulf Canada Limited | Catalytic hydrocracking in the presence of hydrogen donor |
CA1291057C (en) * | 1986-12-19 | 1991-10-22 | Junichi Kubo | Method for hydrocracking heavy fraction oils |
JPS63243196A (ja) * | 1987-03-30 | 1988-10-11 | Nippon Oil Co Ltd | 重質油の軽質化法 |
JPH03503743A (ja) * | 1988-11-22 | 1991-08-22 | シェブロン リサーチ アンド テクノロジー カンパニー | 重質かつ不反応性油の水素化処理に対するスラリー触媒 |
-
1992
- 1992-03-26 FR FR9203660A patent/FR2689137B1/fr not_active Expired - Lifetime
-
1993
- 1993-03-25 MX MX9301670A patent/MX9301670A/es unknown
- 1993-03-25 US US08/037,111 patent/US5460714A/en not_active Expired - Lifetime
- 1993-03-25 IT ITMI930573A patent/IT1270973B/it active IP Right Grant
- 1993-03-26 CA CA002092787A patent/CA2092787C/fr not_active Expired - Lifetime
- 1993-03-26 DE DE4309669A patent/DE4309669A1/de not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
CA2092787C (fr) | 2003-07-29 |
DE4309669A1 (de) | 1993-09-30 |
ITMI930573A1 (it) | 1994-09-25 |
US5460714A (en) | 1995-10-24 |
FR2689137B1 (fr) | 1994-05-27 |
FR2689137A1 (fr) | 1993-10-01 |
CA2092787A1 (fr) | 1993-09-27 |
ITMI930573A0 (it) | 1993-03-25 |
MX9301670A (es) | 1994-05-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
0001 | Granted | ||
TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19970326 |