GB1471589A - Desulphurisation catalyst and process - Google Patents

Desulphurisation catalyst and process

Info

Publication number
GB1471589A
GB1471589A GB4599574A GB4599574A GB1471589A GB 1471589 A GB1471589 A GB 1471589A GB 4599574 A GB4599574 A GB 4599574A GB 4599574 A GB4599574 A GB 4599574A GB 1471589 A GB1471589 A GB 1471589A
Authority
GB
United Kingdom
Prior art keywords
surface area
basal plane
plane surface
hydrodesulphurization
oct
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4599574A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP PLC
Original Assignee
BP PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP PLC filed Critical BP PLC
Priority to GB4599574A priority Critical patent/GB1471589A/en
Priority to GB4599474A priority patent/GB1471588A/en
Priority to DE19752547100 priority patent/DE2547100A1/en
Priority to JP50127290A priority patent/JPS5165089A/en
Priority to FR7532505A priority patent/FR2289237A1/en
Publication of GB1471589A publication Critical patent/GB1471589A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B01J27/049—Sulfides with chromium, molybdenum, tungsten or polonium with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1471589 Hydrodesulphurization of oils BRITISH PETROLEUM CO Ltd 9 Oct 1975 [24 Oct 1974] 45995/74 Heading C5E [Also in Division B1] Hydrocarbon feedstocks are desulphurized with H 2 in the presence of a catalyst comprising 1-50 wt. per cent of a hexagonal disulphide of a Group VIA metal (e.g. molybdenum disulphide) and a graphite-containing carbon having a basal plane surface area of at least 100 m.<SP>2</SP>/g., a ratio of BET surface area to basal plane surface area of at most 5 : 1 and a ratio of basal plane surface area to edge surface area of at least 5 : 1. The catalysts may also contain an iron-group (e.g. cobalt) component. The conversion conditions may be 150-500‹ C., 5-250 bars g., LHSV of 1-20, and H 2 flow rate 20- 2000 m.<SP>3</SP>/m.<SP>3</SP> Examples describe the formation of a mixture of butane and butene by the hydrodesulphurization of thiophen.
GB4599574A 1974-10-24 1974-10-24 Desulphurisation catalyst and process Expired GB1471589A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
GB4599574A GB1471589A (en) 1974-10-24 1974-10-24 Desulphurisation catalyst and process
GB4599474A GB1471588A (en) 1974-10-24 1975-10-09 Desulphurisation catalyst and process
DE19752547100 DE2547100A1 (en) 1974-10-24 1975-10-21 DESULFURIZATION CATALYSTS AND THEIR USE IN THE DESULFURIZATION OF HYDROCARBONS
JP50127290A JPS5165089A (en) 1974-10-24 1975-10-22 Suitendatsuryuyoshokubai
FR7532505A FR2289237A1 (en) 1974-10-24 1975-10-23 DESULFURATION CATALYST AND HYDROCARBON DESULFURATION PROCESS

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB4599574A GB1471589A (en) 1974-10-24 1974-10-24 Desulphurisation catalyst and process
GB4599474A GB1471588A (en) 1974-10-24 1975-10-09 Desulphurisation catalyst and process

Publications (1)

Publication Number Publication Date
GB1471589A true GB1471589A (en) 1977-04-27

Family

ID=26265711

Family Applications (2)

Application Number Title Priority Date Filing Date
GB4599574A Expired GB1471589A (en) 1974-10-24 1974-10-24 Desulphurisation catalyst and process
GB4599474A Expired GB1471588A (en) 1974-10-24 1975-10-09 Desulphurisation catalyst and process

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB4599474A Expired GB1471588A (en) 1974-10-24 1975-10-09 Desulphurisation catalyst and process

Country Status (3)

Country Link
DE (1) DE2547100A1 (en)
FR (1) FR2289237A1 (en)
GB (2) GB1471589A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4288422A (en) 1979-02-23 1981-09-08 Exxon Research & Engineering Co. Method of preparing chalcogenides of group VIII by low temperature precipitation from monaqueous solution, the products produced by said method and their use as catalysts
US4299892A (en) 1975-12-17 1981-11-10 Exxon Research & Engineering Co. Amorphous and sheet dichalcogenides of Group IVb, Vb, molybdenum and tungsten
US4308171A (en) 1977-05-16 1981-12-29 Exxon Research & Engineering Co. Method of preparing di and poly chalcogenides of group VIIb by low temperature precipitation from nonaqueous solution and small crystallite size stoichiometric layered dichalcogenides of rhenium and technetium
US4313852A (en) 1979-08-10 1982-02-02 Coal Industry (Patents) Limited Catalysts
US4323480A (en) 1975-12-17 1982-04-06 Exxon Research & Engineering Co. Method of preparing di and poly chalcogenides of group IVb, Vb, molybdenum and tungsten transition metals by low temperature precipitation from non-aqueous solution and the product obtained by said method
US4390514A (en) 1977-05-16 1983-06-28 Exxon Research And Engineering Co. Method of preparing chalocogenides of group VIII by low temperature precipitation from nonaqueous solution, the products produced by said method and their use as catalysts
DE102012012510A1 (en) * 2012-06-22 2013-12-24 Clariant International Ag Graphite-containing catalyst molding

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1565074A (en) * 1976-11-03 1980-04-16 British Petroleum Co Process for the production of ammonia
GB1601715A (en) * 1977-03-03 1981-11-04 Engelhard Min & Chem Method of preparing activated graphite and catalysts based thereon
GB2056478B (en) * 1979-08-10 1983-03-02 Coal Ind Coal liquefaction process
DE3172380D1 (en) * 1980-12-11 1985-10-24 Exxon Research Engineering Co Compositions comprising highly dispersed metal on a graphite support
DE3430484A1 (en) * 1984-08-18 1986-02-27 Basf Ag, 6700 Ludwigshafen METHOD FOR THE OXIDATIVE CLEANING OF SEWAGE
US5186818A (en) * 1991-08-12 1993-02-16 Exxon Research And Engineering Company Catalytic processes
DE69315636D1 (en) * 1992-07-27 1998-01-22 Texaco Development Corp Hydra treatment of crack naphta
WO2018004461A1 (en) * 2016-06-28 2018-01-04 Nanyang Technological University One-step approach to 2,5-diformylfuran from carbohydrates by a molybdenum-based catalyst

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4299892A (en) 1975-12-17 1981-11-10 Exxon Research & Engineering Co. Amorphous and sheet dichalcogenides of Group IVb, Vb, molybdenum and tungsten
US4323480A (en) 1975-12-17 1982-04-06 Exxon Research & Engineering Co. Method of preparing di and poly chalcogenides of group IVb, Vb, molybdenum and tungsten transition metals by low temperature precipitation from non-aqueous solution and the product obtained by said method
US4308171A (en) 1977-05-16 1981-12-29 Exxon Research & Engineering Co. Method of preparing di and poly chalcogenides of group VIIb by low temperature precipitation from nonaqueous solution and small crystallite size stoichiometric layered dichalcogenides of rhenium and technetium
US4390514A (en) 1977-05-16 1983-06-28 Exxon Research And Engineering Co. Method of preparing chalocogenides of group VIII by low temperature precipitation from nonaqueous solution, the products produced by said method and their use as catalysts
US4288422A (en) 1979-02-23 1981-09-08 Exxon Research & Engineering Co. Method of preparing chalcogenides of group VIII by low temperature precipitation from monaqueous solution, the products produced by said method and their use as catalysts
US4313852A (en) 1979-08-10 1982-02-02 Coal Industry (Patents) Limited Catalysts
DE102012012510A1 (en) * 2012-06-22 2013-12-24 Clariant International Ag Graphite-containing catalyst molding
DE102012012510B4 (en) * 2012-06-22 2018-12-06 Clariant International Ltd. Graphite-containing shaped catalyst body, its production method and use

Also Published As

Publication number Publication date
DE2547100A1 (en) 1976-04-29
GB1471588A (en) 1977-04-27
FR2289237B3 (en) 1978-07-28
FR2289237A1 (en) 1976-05-28

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee