IT1261700B - Procedimento per la separazione di miscugli di m- e p-diclorobenzene - Google Patents
Procedimento per la separazione di miscugli di m- e p-diclorobenzeneInfo
- Publication number
- IT1261700B IT1261700B ITRM930369A ITRM930369A IT1261700B IT 1261700 B IT1261700 B IT 1261700B IT RM930369 A ITRM930369 A IT RM930369A IT RM930369 A ITRM930369 A IT RM930369A IT 1261700 B IT1261700 B IT 1261700B
- Authority
- IT
- Italy
- Prior art keywords
- dichlorobenzene
- atoms
- pentasil
- mixtures
- cations
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/389—Separation; Purification; Stabilisation; Use of additives by adsorption on solids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
Abstract
Miscugli di m- e p-diclorobenzene possono venire separati mediante trattamento di tali miscugli nella fase liquida con una Pentasil-zeolite a 20 fino a 250°C, nel qual caso viene prelevato un filtrato arricchito in m-diclorobenzene e il p-diclorobenzene viene ottenuto mediante desorbimento della Pentasil-zeolite. Le Pentasil-zeoliti possono contenere come cationi scambiabili protoni, cationi del primo oppure del secondo gruppo principale del sistema periodico (Mendelejew), cationi dei metalli delle terre rare oppure un miscuglio di più di essi. Per la produzione della fase liquida viene impiegato insieme un solvente, il quale appartiene al gruppo degli idrocarburi saturi ciclici ocn 5 fino a 15 atomi di C, degli idrocarburi aromatici alchilsostituiti con 8 fino a 12 atomi di C e degli idrocarburi aromatici alogeno-sostituiti con 6 fino a 10 atomi di C e con 1 fino a 3 atomi di alogeno; i solventi etilbenzene, clorobenzene, p-xilene, p-C1-toluene e diclorobenzene sono esclusi. Può venire impiegato anche un miscuglio di più di questi solventi.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4218841A DE4218841A1 (de) | 1992-06-09 | 1992-06-09 | Verfahren zur Trennung von Gemischen von m- und p-Dichlorbenzol |
Publications (3)
Publication Number | Publication Date |
---|---|
ITRM930369A0 ITRM930369A0 (it) | 1993-06-03 |
ITRM930369A1 ITRM930369A1 (it) | 1994-12-03 |
IT1261700B true IT1261700B (it) | 1996-05-29 |
Family
ID=6460626
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ITRM930369A IT1261700B (it) | 1992-06-09 | 1993-06-03 | Procedimento per la separazione di miscugli di m- e p-diclorobenzene |
Country Status (5)
Country | Link |
---|---|
US (1) | US5386067A (it) |
JP (1) | JPH0656716A (it) |
DE (1) | DE4218841A1 (it) |
FR (1) | FR2691964B1 (it) |
IT (1) | IT1261700B (it) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4325484A1 (de) * | 1993-07-29 | 1995-02-02 | Bayer Ag | Verfahren zur Trennung von Gemischen von m- und p-Dichlorbenzol |
CN101891586B (zh) * | 2010-08-19 | 2012-12-26 | 江苏隆昌化工有限公司 | 一种从固废氯化苯焦油中提取高纯度间二氯苯工艺 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2855940C2 (de) * | 1978-12-23 | 1980-08-21 | Bayer Ag, 5090 Leverkusen | Verfahren zur Auftrennung von Dichlorbenzol enthaltenden Isomerengemischen unter Gewinnung von ortho-, meta- und/oder para-Dichlorbenzol |
JPS59122433A (ja) * | 1982-12-28 | 1984-07-14 | Toray Ind Inc | 3,5−キシレノ−ルの分離回収方法 |
JPS61268636A (ja) * | 1985-05-23 | 1986-11-28 | Toray Ind Inc | ジクロルベンゼン異性体の分離方法 |
JPS62175433A (ja) * | 1986-01-28 | 1987-08-01 | Hodogaya Chem Co Ltd | ジクロロベンゼン異性体の分離方法 |
JPS63196530A (ja) * | 1987-02-10 | 1988-08-15 | Hodogaya Chem Co Ltd | m−ジクロロベンゼンの選択的分離法 |
EP0334025B2 (en) * | 1988-02-26 | 1995-12-20 | Toray Industries, Inc. | Process for the separation of halogenated benzene derivatives |
US4996380A (en) * | 1989-11-08 | 1991-02-26 | Uop | Process for extracting meta-dichlorobenzene from isomer mixtures with mixed alkali metal exchanged X zeolite adsorbents |
-
1992
- 1992-06-09 DE DE4218841A patent/DE4218841A1/de not_active Withdrawn
-
1993
- 1993-06-03 IT ITRM930369A patent/IT1261700B/it active IP Right Grant
- 1993-06-03 JP JP5156319A patent/JPH0656716A/ja active Pending
- 1993-06-08 FR FR9306842A patent/FR2691964B1/fr not_active Expired - Fee Related
-
1994
- 1994-06-01 US US08/252,154 patent/US5386067A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE4218841A1 (de) | 1993-12-16 |
US5386067A (en) | 1995-01-31 |
FR2691964A1 (fr) | 1993-12-10 |
FR2691964B1 (fr) | 1995-01-06 |
ITRM930369A0 (it) | 1993-06-03 |
JPH0656716A (ja) | 1994-03-01 |
ITRM930369A1 (it) | 1994-12-03 |
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