IT1251708B - Procedimento per la preparazione di acidi carbossilici o loro esteri mediante scissione ossidativa di acidi grassi insaturi o loro esteri. - Google Patents

Procedimento per la preparazione di acidi carbossilici o loro esteri mediante scissione ossidativa di acidi grassi insaturi o loro esteri.

Info

Publication number
IT1251708B
IT1251708B ITTO910963A ITTO910963A IT1251708B IT 1251708 B IT1251708 B IT 1251708B IT TO910963 A ITTO910963 A IT TO910963A IT TO910963 A ITTO910963 A IT TO910963A IT 1251708 B IT1251708 B IT 1251708B
Authority
IT
Italy
Prior art keywords
esters
unsaturated fatty
procedure
preparation
fatty acids
Prior art date
Application number
ITTO910963A
Other languages
English (en)
Inventor
Andrea Gardano
Giampiero Sabarino
Marco Foa
Original Assignee
Novamont Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novamont Spa filed Critical Novamont Spa
Publication of ITTO910963A0 publication Critical patent/ITTO910963A0/it
Priority to ITTO910963A priority Critical patent/IT1251708B/it
Priority to IL92103957A priority patent/IL103957A0/xx
Priority to CA002125474A priority patent/CA2125474A1/en
Priority to DE69217388T priority patent/DE69217388T2/de
Priority to AT92924679T priority patent/ATE148686T1/de
Priority to AU30856/92A priority patent/AU658957B2/en
Priority to PCT/EP1992/002822 priority patent/WO1993012064A1/en
Priority to DK92924679.1T priority patent/DK0621861T3/da
Priority to ES92924679T priority patent/ES2097370T3/es
Priority to EP92924679A priority patent/EP0621861B1/en
Priority to BR9207023A priority patent/BR9207023A/pt
Priority to JP5510583A priority patent/JPH07502035A/ja
Priority to US07/988,671 priority patent/US5336793A/en
Priority to CN92115181A priority patent/CN1075711A/zh
Publication of ITTO910963A1 publication Critical patent/ITTO910963A1/it
Priority to FI942694A priority patent/FI106796B/fi
Priority to NO942175A priority patent/NO300321B1/no
Application granted granted Critical
Publication of IT1251708B publication Critical patent/IT1251708B/it
Priority to GR960403249T priority patent/GR3022792T3/el

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/285—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with peroxy-compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Il procedimento è condotto in un sistema bifasico acquoso-organico, in cui la fase organica contiene l'acido grasso insaturo e/o i suoi esteri e la fase acquosa contiene acqua ossigenata. La scissione ossidativa è effettuata in presenza di un sistema catalitico comprendente un catalizzatore appartenente al gruppo costituito dagli acidi tungstico, molibdico e loro sali alcalini, ed un sale di ionio, che funge da trasferitore di fase di detto catalizzatore, avente formula (R2 R3 R4 M)1 Y in cui R2, R3, R4 ed R5, rappresentano gruppi idrocarburici di cui almeno uno deve avere più di 10 atomi di carbonio,M è N o P, e Y è un anione inorganico.
ITTO910963A 1991-12-11 1991-12-11 Procedimento per la preparazione di acidi carbossilici o loro esteri mediante scissione ossidativa di acidi grassi insaturi o loro esteri. IT1251708B (it)

Priority Applications (17)

Application Number Priority Date Filing Date Title
ITTO910963A IT1251708B (it) 1991-12-11 1991-12-11 Procedimento per la preparazione di acidi carbossilici o loro esteri mediante scissione ossidativa di acidi grassi insaturi o loro esteri.
IL92103957A IL103957A0 (en) 1991-12-11 1992-12-03 Method of preparing carboxylic acids or esters thereof by the oxidative cleavage of unsaturated fatty acids or esters thereof
ES92924679T ES2097370T3 (es) 1991-12-11 1992-12-07 Un metodo para preparar acidos carboxilicos o sus esteres por escision oxidativa de acidos grasos insaturados o sus esteres.
JP5510583A JPH07502035A (ja) 1991-12-11 1992-12-07 不飽和脂肪酸又はそのエステルの酸化分解によるカルボン酸又はそのエステルの製造方法
AT92924679T ATE148686T1 (de) 1991-12-11 1992-12-07 Verfahren zur darstellung von carbonsauren oder ihren estern durch oxidative spaltung von ungesättigten fettsäuren oder ihren estern
AU30856/92A AU658957B2 (en) 1991-12-11 1992-12-07 A method of preparing carboxylic acids or esters thereof by the oxidative cleavage of unsaturated fatty acids or esters thereof
PCT/EP1992/002822 WO1993012064A1 (en) 1991-12-11 1992-12-07 A method of preparing carboxylic acids or esters thereof by the oxidative cleavage of unsaturated fatty acids or esters thereof
DK92924679.1T DK0621861T3 (da) 1991-12-11 1992-12-07 Fremgangsmåde til fremstilling af carboxylsyrer eller esterer deraf ved oxidativ spaltning af umættede fedtsyrer eller estere deraf
CA002125474A CA2125474A1 (en) 1991-12-11 1992-12-07 A method of preparing carboxylic acids or esters thereof by the oxidative cleavage of unsaturated fatty acids or esters thereof
EP92924679A EP0621861B1 (en) 1991-12-11 1992-12-07 A method of preparing carboxylic acids or esters thereof by the oxidative cleavage of unsaturated fatty acids or esters thereof
BR9207023A BR9207023A (pt) 1991-12-11 1992-12-07 Processo para a preparação de ácidos carboxílicos ou ésteres deles derivados pela clivagem oxidativa de ácidos graxos insaturados ou ésteres deles derivados
DE69217388T DE69217388T2 (de) 1991-12-11 1992-12-07 Verfahren zur darstellung von carbonsauren oder ihren estern durch oxidative spaltung von ungesättigten fettsäuren oder ihren estern
US07/988,671 US5336793A (en) 1991-12-11 1992-12-10 Preparing carboxylic acids or esters by oxidative cleavage of unsaturated fatty acids or esters
CN92115181A CN1075711A (zh) 1991-12-11 1992-12-10 由不饱和脂肪酸或其酯的氧化裂解制备羧酸或其酯的方法
FI942694A FI106796B (fi) 1991-12-11 1994-06-08 Menetelmä karboksyylihappojen tai niiden estereiden valmistamiseksi tyydyttymättömien rasvahappojen tai niiden estereiden hapettavalla pilkkomisella
NO942175A NO300321B1 (no) 1991-12-11 1994-06-10 Fremgangsmåte for fremstilling av karboksylsyrer eller estere av disse ved oksidativ spaltning av umettede fettsyrer eller fettsyreestere
GR960403249T GR3022792T3 (en) 1991-12-11 1997-03-12 A method of preparing carboxylic acids or esters thereof by the oxidative cleavage of unsaturated fatty acids or esters thereof.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITTO910963A IT1251708B (it) 1991-12-11 1991-12-11 Procedimento per la preparazione di acidi carbossilici o loro esteri mediante scissione ossidativa di acidi grassi insaturi o loro esteri.

Publications (3)

Publication Number Publication Date
ITTO910963A0 ITTO910963A0 (it) 1991-12-11
ITTO910963A1 ITTO910963A1 (it) 1993-06-11
IT1251708B true IT1251708B (it) 1995-05-20

Family

ID=11409772

Family Applications (1)

Application Number Title Priority Date Filing Date
ITTO910963A IT1251708B (it) 1991-12-11 1991-12-11 Procedimento per la preparazione di acidi carbossilici o loro esteri mediante scissione ossidativa di acidi grassi insaturi o loro esteri.

Country Status (17)

Country Link
US (1) US5336793A (it)
EP (1) EP0621861B1 (it)
JP (1) JPH07502035A (it)
CN (1) CN1075711A (it)
AT (1) ATE148686T1 (it)
AU (1) AU658957B2 (it)
BR (1) BR9207023A (it)
CA (1) CA2125474A1 (it)
DE (1) DE69217388T2 (it)
DK (1) DK0621861T3 (it)
ES (1) ES2097370T3 (it)
FI (1) FI106796B (it)
GR (1) GR3022792T3 (it)
IL (1) IL103957A0 (it)
IT (1) IT1251708B (it)
NO (1) NO300321B1 (it)
WO (1) WO1993012064A1 (it)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1256989B (it) * 1992-10-29 1995-12-27 Novamont Spa Procedimento per la preparazione di acidi carbossilici o loro esteri mediante scissione ossidativa di acidi grassi insaturi o loro esteri.
GB9313080D0 (en) * 1993-06-25 1993-08-11 Solvay Interox Ltd Oxidative cleavage of alkenes
US5596111A (en) * 1995-06-05 1997-01-21 North Dakota State University Method for preparation of carboxylic acids
US6051725A (en) * 1998-12-28 2000-04-18 Caschem, Inc. Epoxidation of ricinic compounds using a phase-transfer catalyst
US6414168B1 (en) 1998-12-28 2002-07-02 Caschem, Inc. Epoxidation of ricinic compounds using a phase-transfer catalyst
DE19922643A1 (de) * 1999-05-18 2000-11-23 Bayer Ag Herstellung von aliphatischen alpha,omega-Dicarbonsäuren
CN1087012C (zh) * 1999-09-29 2002-07-03 中国科学院兰州化学物理研究所 清洁催化氧化合成己二酸的方法
US8043273B2 (en) * 2002-12-19 2011-10-25 Kimberly-Clark Worldwide, Inc. Disposable undergarment with a stretchable absorbent insert and method for the use thereof
CN100415707C (zh) * 2004-09-17 2008-09-03 中国科学院新疆理化技术研究所 一种用微波反应制备壬二酸的方法
ITMI20070953A1 (it) * 2007-05-10 2008-11-11 Novamont Spa Processo di scissione catalitica di oli vegetali
US8513287B2 (en) 2007-12-27 2013-08-20 Eisai R&D Management Co., Ltd. Heterocyclic ring and phosphonoxymethyl group substituted pyridine derivatives and antifungal agent containing same
CN102333755B (zh) * 2008-12-31 2016-02-24 巴特尔纪念研究院 通过初始的脂肪酸氧化分解后的酯化反应制备酯和多元醇
JP5448036B2 (ja) * 2009-02-18 2014-03-19 トヨタ自動車株式会社 カルボン酸の製造方法
CN101811954B (zh) * 2010-04-23 2012-12-26 浙江华诺化工有限公司 油酸催化氧化制备壬二酸的方法
FR2970252B1 (fr) 2011-01-10 2013-11-15 Arkema France Procede de production de composes nitrile-acide gras
FI123683B (en) * 2011-11-28 2013-09-13 Teknologian Tutkimuskeskus Vtt Process for catalytic oxidation of a natural composition comprising unsaturated fatty acids and / or esters thereof and use of a mixture obtained therefrom to produce mono-, oligo- and / or polyesters
FR2984887B1 (fr) * 2011-12-22 2014-01-03 Toulouse Inst Nat Polytech Procede de scission moleculaire oxydative d'un compose gras
CN110117223A (zh) * 2018-02-05 2019-08-13 北京先锋创新科技发展有限公司 一种臭氧氧化法制备并分离提纯壬二酸的方法
CN109467684B (zh) * 2018-12-17 2020-11-24 南开大学 一种氧化蓖麻油酸聚合酯制备方法
FR3100809B1 (fr) 2019-09-16 2023-06-02 Demeta Procédé de coupure oxydante d'oléfines utilisant comme catalyseur un halooxodiperoxométallate

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3855257A (en) * 1970-06-29 1974-12-17 Procter & Gamble Preparation of carboxylic acids by the oxidation of vicinal glycols
GB1324763A (en) * 1971-03-19 1973-07-25 Continental Oil Co Phase transfer catalysis of heterogeneous reactions by quaternary salts
IT1200002B (it) * 1983-04-15 1989-01-05 Montedison Spa Procedimento per la preparazione di acidi carbossilici a partire da olefine o diidrossicomposti vicinali
JPH0761972B2 (ja) * 1986-10-08 1995-07-05 新日本理化株式会社 カルボン酸の製造法

Also Published As

Publication number Publication date
US5336793A (en) 1994-08-09
IL103957A0 (en) 1993-05-13
NO300321B1 (no) 1997-05-12
ITTO910963A1 (it) 1993-06-11
AU3085692A (en) 1993-07-19
FI942694A (fi) 1994-06-08
ITTO910963A0 (it) 1991-12-11
CA2125474A1 (en) 1993-06-24
WO1993012064A1 (en) 1993-06-24
FI942694A0 (fi) 1994-06-08
CN1075711A (zh) 1993-09-01
NO942175L (it) 1994-06-10
NO942175D0 (no) 1994-06-10
EP0621861B1 (en) 1997-02-05
DE69217388T2 (de) 1997-05-22
ATE148686T1 (de) 1997-02-15
DK0621861T3 (da) 1997-07-28
ES2097370T3 (es) 1997-04-01
DE69217388D1 (de) 1997-03-20
GR3022792T3 (en) 1997-06-30
AU658957B2 (en) 1995-05-04
FI106796B (fi) 2001-04-12
EP0621861A1 (en) 1994-11-02
BR9207023A (pt) 1995-12-19
JPH07502035A (ja) 1995-03-02

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