FR3100809B1 - Procédé de coupure oxydante d'oléfines utilisant comme catalyseur un halooxodiperoxométallate - Google Patents

Procédé de coupure oxydante d'oléfines utilisant comme catalyseur un halooxodiperoxométallate Download PDF

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Publication number
FR3100809B1
FR3100809B1 FR1910191A FR1910191A FR3100809B1 FR 3100809 B1 FR3100809 B1 FR 3100809B1 FR 1910191 A FR1910191 A FR 1910191A FR 1910191 A FR1910191 A FR 1910191A FR 3100809 B1 FR3100809 B1 FR 3100809B1
Authority
FR
France
Prior art keywords
halooxodiperoxometallate
catalyst
oxidative cleavage
olefins
functionalized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1910191A
Other languages
English (en)
Other versions
FR3100809A1 (fr
Inventor
Corentin Bordier
Vincent Escande
Christophe Darcel
Frédéric Caijo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DEMETA, FR
Universite De Rennes Fr
Original Assignee
Universite de Rennes 1
Demeta SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universite de Rennes 1, Demeta SAS filed Critical Universite de Rennes 1
Priority to FR1910191A priority Critical patent/FR3100809B1/fr
Priority to US17/642,248 priority patent/US20220315517A1/en
Priority to EP20781051.6A priority patent/EP4031554A1/fr
Priority to CN202080064444.5A priority patent/CN114787172A/zh
Priority to PCT/FR2020/051585 priority patent/WO2021053289A1/fr
Publication of FR3100809A1 publication Critical patent/FR3100809A1/fr
Application granted granted Critical
Publication of FR3100809B1 publication Critical patent/FR3100809B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Procédé de coupure oxydante d'oléfines utilisant comme catalyseur un halooxodiperoxométallate La présente invention concerne un procédé de coupure oxydante d'un substrat constitué d'au moins une oléfine linéaire fonctionnalisée ou non fonctionnalisée, notamment d'un acide carboxylique aliphatique mono- ou polyinsaturé, ou l'un de ses esters, ou d'au moins une oléfine cyclique non fonctionnalisée, à l'aide de peroxyde d'hydrogène, en présence d'un catalyseur métallique, qui est constitué d'au moins un halooxodiperoxométallate d'onium. Elle a encore pour objet un nouveau catalyseur constitué d'un halooxodiperoxométallate d'onium particulier qui peut notamment être mis en œuvre dans ce procédé.
FR1910191A 2019-09-16 2019-09-16 Procédé de coupure oxydante d'oléfines utilisant comme catalyseur un halooxodiperoxométallate Active FR3100809B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1910191A FR3100809B1 (fr) 2019-09-16 2019-09-16 Procédé de coupure oxydante d'oléfines utilisant comme catalyseur un halooxodiperoxométallate
US17/642,248 US20220315517A1 (en) 2019-09-16 2020-09-14 Method for oxidative cleavage of olefins using a halooxodiperoxometallate as a catalyst
EP20781051.6A EP4031554A1 (fr) 2019-09-16 2020-09-14 Procede de coupure oxydante d'olefines utilisant comme catalyseur un halooxodiperoxometallate
CN202080064444.5A CN114787172A (zh) 2019-09-16 2020-09-14 使用卤代氧代二过氧金属酸盐作为催化剂的烯烃氧化裂解方法
PCT/FR2020/051585 WO2021053289A1 (fr) 2019-09-16 2020-09-14 Procede de coupure oxydante d'olefines utilisant comme catalyseur un halooxodiperoxometallate

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1910191A FR3100809B1 (fr) 2019-09-16 2019-09-16 Procédé de coupure oxydante d'oléfines utilisant comme catalyseur un halooxodiperoxométallate
FR1910191 2019-09-16

Publications (2)

Publication Number Publication Date
FR3100809A1 FR3100809A1 (fr) 2021-03-19
FR3100809B1 true FR3100809B1 (fr) 2023-06-02

Family

ID=68501833

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1910191A Active FR3100809B1 (fr) 2019-09-16 2019-09-16 Procédé de coupure oxydante d'oléfines utilisant comme catalyseur un halooxodiperoxométallate

Country Status (5)

Country Link
US (1) US20220315517A1 (fr)
EP (1) EP4031554A1 (fr)
CN (1) CN114787172A (fr)
FR (1) FR3100809B1 (fr)
WO (1) WO2021053289A1 (fr)

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1200002B (it) 1983-04-15 1989-01-05 Montedison Spa Procedimento per la preparazione di acidi carbossilici a partire da olefine o diidrossicomposti vicinali
IT1251708B (it) 1991-12-11 1995-05-20 Novamont Spa Procedimento per la preparazione di acidi carbossilici o loro esteri mediante scissione ossidativa di acidi grassi insaturi o loro esteri.
FR2984887B1 (fr) 2011-12-22 2014-01-03 Toulouse Inst Nat Polytech Procede de scission moleculaire oxydative d'un compose gras
JP5801727B2 (ja) * 2012-01-16 2015-10-28 株式会社日本触媒 ペルオキソ錯体
FR2994178B1 (fr) 2012-07-31 2015-08-07 Interoleagineuse D Assistance Et De Dev S I A Soc Procede de preparation d'un acide carboxylique ou d'un aldehyde

Also Published As

Publication number Publication date
CN114787172A (zh) 2022-07-22
EP4031554A1 (fr) 2022-07-27
WO2021053289A1 (fr) 2021-03-25
US20220315517A1 (en) 2022-10-06
FR3100809A1 (fr) 2021-03-19

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