IL29642A - Process for fabricating porous sintered amalgamated zinc structures - Google Patents
Process for fabricating porous sintered amalgamated zinc structuresInfo
- Publication number
- IL29642A IL29642A IL29642A IL2964268A IL29642A IL 29642 A IL29642 A IL 29642A IL 29642 A IL29642 A IL 29642A IL 2964268 A IL2964268 A IL 2964268A IL 29642 A IL29642 A IL 29642A
- Authority
- IL
- Israel
- Prior art keywords
- zinc
- amalgamated
- oxide film
- sintering
- particles
- Prior art date
Links
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims description 140
- 238000000034 method Methods 0.000 title claims description 38
- 229910052725 zinc Inorganic materials 0.000 claims description 81
- 239000011701 zinc Substances 0.000 claims description 80
- 238000005245 sintering Methods 0.000 claims description 68
- 239000002245 particle Substances 0.000 claims description 49
- 239000003795 chemical substances by application Substances 0.000 claims description 47
- 239000012535 impurity Substances 0.000 claims description 41
- 238000006243 chemical reaction Methods 0.000 claims description 39
- 239000000203 mixture Substances 0.000 claims description 31
- 229960002523 mercuric chloride Drugs 0.000 claims description 27
- LWJROJCJINYWOX-UHFFFAOYSA-L mercury dichloride Chemical compound Cl[Hg]Cl LWJROJCJINYWOX-UHFFFAOYSA-L 0.000 claims description 27
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 13
- BIVUUOPIAYRCAP-UHFFFAOYSA-N aminoazanium;chloride Chemical compound Cl.NN BIVUUOPIAYRCAP-UHFFFAOYSA-N 0.000 claims description 12
- AJGPQPPJQDDCDA-UHFFFAOYSA-N azanium;hydron;oxalate Chemical compound N.OC(=O)C(O)=O AJGPQPPJQDDCDA-UHFFFAOYSA-N 0.000 claims description 9
- 238000011065 in-situ storage Methods 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 7
- 239000007795 chemical reaction product Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 229910021529 ammonia Inorganic materials 0.000 claims description 6
- 238000000859 sublimation Methods 0.000 claims description 6
- 230000008022 sublimation Effects 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 5
- 150000004820 halides Chemical class 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- -1 halide salts Chemical class 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 230000000977 initiatory effect Effects 0.000 claims 3
- 239000011787 zinc oxide Substances 0.000 claims 3
- 239000002253 acid Substances 0.000 claims 2
- 238000003487 electrochemical reaction Methods 0.000 claims 1
- 238000002386 leaching Methods 0.000 claims 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 48
- 235000019270 ammonium chloride Nutrition 0.000 description 24
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 14
- 238000005260 corrosion Methods 0.000 description 12
- 230000007797 corrosion Effects 0.000 description 12
- 239000000843 powder Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 7
- 229910052753 mercury Inorganic materials 0.000 description 7
- 239000000945 filler Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000013043 chemical agent Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 239000002923 metal particle Substances 0.000 description 4
- OVARTBFNCCXQKS-UHFFFAOYSA-N propan-2-one;hydrate Chemical compound O.CC(C)=O OVARTBFNCCXQKS-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 235000005074 zinc chloride Nutrition 0.000 description 2
- 239000011592 zinc chloride Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- KYARBIJYVGJZLB-UHFFFAOYSA-N 7-amino-4-hydroxy-2-naphthalenesulfonic acid Chemical compound OC1=CC(S(O)(=O)=O)=CC2=CC(N)=CC=C21 KYARBIJYVGJZLB-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- HEFNNWSXXWATRW-UHFFFAOYSA-N Ibuprofen Chemical compound CC(C)CC1=CC=C(C(C)C(O)=O)C=C1 HEFNNWSXXWATRW-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 101150015779 act3 gene Proteins 0.000 description 1
- 238000001994 activation Methods 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 238000005267 amalgamation Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/11—Making porous workpieces or articles
- B22F3/1121—Making porous workpieces or articles by using decomposable, meltable or sublimatable fillers
- B22F3/1134—Inorganic fillers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/11—Making porous workpieces or articles
- B22F3/1143—Making porous workpieces or articles involving an oxidation, reduction or reaction step
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/06—Electrodes for primary cells
- H01M4/08—Processes of manufacture
- H01M4/12—Processes of manufacture of consumable metal or alloy electrodes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Powder Metallurgy (AREA)
- Inert Electrodes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US624034A US3337336A (en) | 1967-03-17 | 1967-03-17 | Addition agents for sintering purposes |
| US669325A US3413116A (en) | 1967-03-17 | 1967-06-21 | Addition agents for sintering purposes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IL29642A true IL29642A (en) | 1972-01-27 |
Family
ID=27089579
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL29642A IL29642A (en) | 1967-03-17 | 1968-03-14 | Process for fabricating porous sintered amalgamated zinc structures |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3413116A (en:Method) |
| BE (1) | BE712303A (en:Method) |
| CH (1) | CH503378A (en:Method) |
| DE (1) | DE1671856B2 (en:Method) |
| DK (1) | DK127989B (en:Method) |
| ES (1) | ES351695A1 (en:Method) |
| FR (1) | FR1574748A (en:Method) |
| GB (1) | GB1211403A (en:Method) |
| IL (1) | IL29642A (en:Method) |
| NL (1) | NL6803810A (en:Method) |
| SE (1) | SE347843B (en:Method) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3655447A (en) * | 1969-09-08 | 1972-04-11 | Mallory & Co Inc P R | Means and method for making porous bodies of integral structure |
| JPS5539601B1 (en:Method) * | 1970-05-12 | 1980-10-13 | ||
| US3645793A (en) * | 1970-06-01 | 1972-02-29 | Esb Inc | Method for producing porous metal battery electrode structure |
| US4460543A (en) * | 1982-04-10 | 1984-07-17 | Grillo-Werke Ag | Process for preparation of zinc powder for alkaline batteries by amalgamation of zinc powder |
| DE3416728A1 (de) * | 1984-05-07 | 1985-11-07 | Varta Batterie Ag, 3000 Hannover | Poroese zinkelektrode fuer alkali-mangan-zellen |
| US6410160B1 (en) * | 1998-05-04 | 2002-06-25 | Colorado School Of Mines | Porous metal-containing materials, method of manufacture and products incorporating or made from the materials |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE583869C (de) * | 1929-02-23 | 1933-09-11 | I G Farbenindustrie Akt Ges | Verfahren zur Herstellung von Elektroden fuer Akkumulatoren durch Druck- und bzw. oder Waermebehandlung von zweckmaessig aus Metallcarbonyl gewonnenen Metallpulvern |
| US3322535A (en) * | 1965-06-01 | 1967-05-30 | Mallory & Co Inc P R | Addition agents for exothermic sintering processes |
-
1967
- 1967-06-21 US US669325A patent/US3413116A/en not_active Expired - Lifetime
-
1968
- 1968-03-14 IL IL29642A patent/IL29642A/en unknown
- 1968-03-15 CH CH385868A patent/CH503378A/de not_active IP Right Cessation
- 1968-03-15 SE SE03485/68A patent/SE347843B/xx unknown
- 1968-03-15 BE BE712303D patent/BE712303A/xx unknown
- 1968-03-15 FR FR1574748D patent/FR1574748A/fr not_active Expired
- 1968-03-15 DK DK110968AA patent/DK127989B/da unknown
- 1968-03-16 DE DE1968M0077616 patent/DE1671856B2/de active Granted
- 1968-03-18 NL NL6803810A patent/NL6803810A/xx unknown
- 1968-03-18 GB GB03063/68A patent/GB1211403A/en not_active Expired
-
1969
- 1969-03-16 ES ES351695A patent/ES351695A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR1574748A (en:Method) | 1969-07-18 |
| CH503378A (de) | 1971-02-15 |
| DE1671856B2 (de) | 1977-04-28 |
| BE712303A (en:Method) | 1968-09-16 |
| US3413116A (en) | 1968-11-26 |
| SE347843B (en:Method) | 1972-08-14 |
| DK127989B (da) | 1974-02-11 |
| GB1211403A (en) | 1970-11-04 |
| ES351695A1 (es) | 1969-12-01 |
| NL6803810A (en:Method) | 1968-09-18 |
| DE1671856A1 (de) | 1971-12-23 |
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