IL166300A - Highly stereoregular polypropylene with improved properties, method for preparation and multilayer laminated articles prepared therefrom - Google Patents
Highly stereoregular polypropylene with improved properties, method for preparation and multilayer laminated articles prepared therefromInfo
- Publication number
- IL166300A IL166300A IL166300A IL16630005A IL166300A IL 166300 A IL166300 A IL 166300A IL 166300 A IL166300 A IL 166300A IL 16630005 A IL16630005 A IL 16630005A IL 166300 A IL166300 A IL 166300A
- Authority
- IL
- Israel
- Prior art keywords
- polymers
- extractable
- polymer
- electron donor
- compounds
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 27
- 229920001155 polypropylene Polymers 0.000 title claims description 20
- -1 polypropylene Polymers 0.000 title claims description 14
- 238000002360 preparation method Methods 0.000 title description 8
- 239000004743 Polypropylene Substances 0.000 title description 2
- 229920000642 polymer Polymers 0.000 claims description 47
- 150000001875 compounds Chemical class 0.000 claims description 44
- 239000000203 mixture Substances 0.000 claims description 23
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- 239000011949 solid catalyst Substances 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 14
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 12
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 9
- 238000009826 distribution Methods 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 8
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 150000003890 succinate salts Chemical class 0.000 claims description 7
- 125000003342 alkenyl group Chemical group 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 125000005842 heteroatom Chemical group 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 150000003254 radicals Chemical class 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 150000004756 silanes Chemical class 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 235000011044 succinic acid Nutrition 0.000 claims description 3
- 150000003444 succinic acids Chemical class 0.000 claims description 3
- 150000005840 aryl radicals Chemical class 0.000 claims description 2
- 229920001384 propylene homopolymer Polymers 0.000 claims 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 13
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 13
- 239000007789 gas Substances 0.000 description 12
- 238000006116 polymerization reaction Methods 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- 238000000926 separation method Methods 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- 239000011777 magnesium Substances 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- 239000010936 titanium Substances 0.000 description 8
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 5
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 5
- 238000010828 elution Methods 0.000 description 5
- 229910001629 magnesium chloride Inorganic materials 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- 239000008096 xylene Substances 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 229910003074 TiCl4 Inorganic materials 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 229940078552 o-xylene Drugs 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000006228 supernatant Substances 0.000 description 4
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 4
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 4
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- IPKKHRVROFYTEK-UHFFFAOYSA-N dipentyl phthalate Chemical compound CCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCC IPKKHRVROFYTEK-UHFFFAOYSA-N 0.000 description 3
- 239000008246 gaseous mixture Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 3
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- 235000007586 terpenes Nutrition 0.000 description 3
- 150000003609 titanium compounds Chemical class 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KCXZNSGUUQJJTR-UHFFFAOYSA-N Di-n-hexyl phthalate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCC KCXZNSGUUQJJTR-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- FHUODBDRWMIBQP-UHFFFAOYSA-N Ethyl p-anisate Chemical compound CCOC(=O)C1=CC=C(OC)C=C1 FHUODBDRWMIBQP-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910010165 TiCu Inorganic materials 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- XSIFPSYPOVKYCO-UHFFFAOYSA-N butyl benzoate Chemical compound CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- MQHNKCZKNAJROC-UHFFFAOYSA-N dipropyl phthalate Chemical compound CCCOC(=O)C1=CC=CC=C1C(=O)OCCC MQHNKCZKNAJROC-UHFFFAOYSA-N 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000005243 fluidization Methods 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 150000002690 malonic acid derivatives Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 150000003505 terpenes Chemical class 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- POXXQVSKWJPZNO-UHFFFAOYSA-N 1-o-ethyl 2-o-(2-methylpropyl) benzene-1,2-dicarboxylate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC(C)C POXXQVSKWJPZNO-UHFFFAOYSA-N 0.000 description 1
- ABYCGAKJMGFSPY-UHFFFAOYSA-N 2-hexan-3-yloxycarbonylbenzoic acid Chemical compound CCCC(CC)OC(=O)C1=CC=CC=C1C(O)=O ABYCGAKJMGFSPY-UHFFFAOYSA-N 0.000 description 1
- DUAYDERMVQWIJD-UHFFFAOYSA-N 2-n,2-n,6-trimethyl-1,3,5-triazine-2,4-diamine Chemical compound CN(C)C1=NC(C)=NC(N)=N1 DUAYDERMVQWIJD-UHFFFAOYSA-N 0.000 description 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
- HRAQMGWTPNOILP-UHFFFAOYSA-N 4-Ethoxy ethylbenzoate Chemical compound CCOC(=O)C1=CC=C(OCC)C=C1 HRAQMGWTPNOILP-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 229910010066 TiC14 Inorganic materials 0.000 description 1
- 229910010062 TiCl3 Inorganic materials 0.000 description 1
- 238000002083 X-ray spectrum Methods 0.000 description 1
- 238000006653 Ziegler-Natta catalysis Methods 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000007860 aryl ester derivatives Chemical class 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- KYZHGEFMXZOSJN-UHFFFAOYSA-N benzoic acid isobutyl ester Natural products CC(C)COC(=O)C1=CC=CC=C1 KYZHGEFMXZOSJN-UHFFFAOYSA-N 0.000 description 1
- 150000001559 benzoic acids Chemical class 0.000 description 1
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 1
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 1
- WNVMVIYFKFGESM-UHFFFAOYSA-N bis(2-methylpropyl) 2,3-di(propan-2-yl)butanedioate Chemical compound CC(C)COC(=O)C(C(C)C)C(C(C)C)C(=O)OCC(C)C WNVMVIYFKFGESM-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 1
- AIXMJTYHQHQJLU-UHFFFAOYSA-N chembl210858 Chemical compound O1C(CC(=O)OC)CC(C=2C=CC(O)=CC=2)=N1 AIXMJTYHQHQJLU-UHFFFAOYSA-N 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- YCYHZGIPKZHEEL-UHFFFAOYSA-N diethyl 2,3-bis(2,2-dimethylpropyl)butanedioate Chemical compound CCOC(=O)C(CC(C)(C)C)C(CC(C)(C)C)C(=O)OCC YCYHZGIPKZHEEL-UHFFFAOYSA-N 0.000 description 1
- ZEKAIFREAFGGIC-UHFFFAOYSA-N diethyl 2,3-bis(2-ethylbutyl)butanedioate Chemical compound CCOC(=O)C(CC(CC)CC)C(CC(CC)CC)C(=O)OCC ZEKAIFREAFGGIC-UHFFFAOYSA-N 0.000 description 1
- AVLHXEDOBYYTGV-UHFFFAOYSA-N diethyl 2,3-bis(2-methylpropyl)butanedioate Chemical compound CCOC(=O)C(CC(C)C)C(CC(C)C)C(=O)OCC AVLHXEDOBYYTGV-UHFFFAOYSA-N 0.000 description 1
- FITPXUCDWCINLG-UHFFFAOYSA-N diethyl 2,3-bis(cyclohexylmethyl)butanedioate Chemical compound C1CCCCC1CC(C(=O)OCC)C(C(=O)OCC)CC1CCCCC1 FITPXUCDWCINLG-UHFFFAOYSA-N 0.000 description 1
- OTUNNRWESSPIBH-UHFFFAOYSA-N diethyl 2,3-bis(trimethylsilyl)butanedioate Chemical compound CCOC(=O)C([Si](C)(C)C)C([Si](C)(C)C)C(=O)OCC OTUNNRWESSPIBH-UHFFFAOYSA-N 0.000 description 1
- WGFNXLQURMLAGC-UHFFFAOYSA-N diethyl 2,3-di(propan-2-yl)butanedioate Chemical compound CCOC(=O)C(C(C)C)C(C(C)C)C(=O)OCC WGFNXLQURMLAGC-UHFFFAOYSA-N 0.000 description 1
- UIZHEHICSUOPQL-UHFFFAOYSA-N diethyl 2,3-dibenzylbutanedioate Chemical compound C=1C=CC=CC=1CC(C(=O)OCC)C(C(=O)OCC)CC1=CC=CC=C1 UIZHEHICSUOPQL-UHFFFAOYSA-N 0.000 description 1
- CXKANZAMPQTLBJ-UHFFFAOYSA-N diethyl 2,3-dicyclohexylbutanedioate Chemical compound C1CCCCC1C(C(=O)OCC)C(C(=O)OCC)C1CCCCC1 CXKANZAMPQTLBJ-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- VHPUZTHRFWIGAW-UHFFFAOYSA-N dimethoxy-di(propan-2-yl)silane Chemical compound CO[Si](OC)(C(C)C)C(C)C VHPUZTHRFWIGAW-UHFFFAOYSA-N 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- NWPWRAWAUYIELB-UHFFFAOYSA-N ethyl 4-methylbenzoate Chemical compound CCOC(=O)C1=CC=C(C)C=C1 NWPWRAWAUYIELB-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000003538 pentan-3-yl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 150000003022 phthalic acids Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- JAYPHJBLPAEMEX-UHFFFAOYSA-N trimethoxy(2-methylpentan-2-yl)silane Chemical compound CCCC(C)(C)[Si](OC)(OC)OC JAYPHJBLPAEMEX-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/651—Pretreating with non-metals or metal-free compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02017287 | 2002-08-01 | ||
| US41699102P | 2002-10-08 | 2002-10-08 | |
| PCT/EP2003/008491 WO2004013193A2 (en) | 2002-08-01 | 2003-07-30 | Highly stereoregular polypropylene with improved properties |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL166300A0 IL166300A0 (en) | 2006-01-15 |
| IL166300A true IL166300A (en) | 2008-12-29 |
Family
ID=31497088
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL166300A IL166300A (en) | 2002-08-01 | 2005-01-13 | Highly stereoregular polypropylene with improved properties, method for preparation and multilayer laminated articles prepared therefrom |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US7112642B2 (pl) |
| EP (1) | EP1527106A2 (pl) |
| JP (1) | JP2005534761A (pl) |
| KR (1) | KR20050033639A (pl) |
| CN (1) | CN100564399C (pl) |
| AU (1) | AU2003250201B2 (pl) |
| BR (1) | BR0306195B1 (pl) |
| CA (1) | CA2492939A1 (pl) |
| IL (1) | IL166300A (pl) |
| PL (1) | PL374508A1 (pl) |
| RU (1) | RU2325404C2 (pl) |
| WO (1) | WO2004013193A2 (pl) |
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| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| BR0315341B1 (pt) | 2002-10-15 | 2014-02-18 | Adesivos compreendendo poliolefina. | |
| AU2005291326A1 (en) * | 2004-10-04 | 2006-04-13 | Basell Poliolefine Italia S.R.L. | Elastomeric polyolefin compositions |
| US8513366B2 (en) * | 2005-03-17 | 2013-08-20 | University Of Maryland, College Park | Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby |
| EP1726603A1 (en) * | 2005-05-27 | 2006-11-29 | Borealis Technology Oy | Propylene polymer with high crystallinity |
| EP1726602A1 (en) * | 2005-05-27 | 2006-11-29 | Borealis Technology Oy | Propylene polymer with high crystallinity |
| ATE421760T1 (de) * | 2006-07-10 | 2009-02-15 | Borealis Tech Oy | Elektrischer isolierfilm |
| PT2208749E (pt) | 2006-07-10 | 2016-03-04 | Borealis Tech Oy | Películas de polipropileno orientadas biaxialmente |
| EP1967547A1 (en) | 2006-08-25 | 2008-09-10 | Borealis Technology OY | Extrusion coated substrate |
| ATE427330T1 (de) | 2006-08-25 | 2009-04-15 | Borealis Tech Oy | Polypropylenschaumstoff |
| EP1903579B1 (en) | 2006-09-25 | 2010-03-24 | Borealis Technology Oy | Coaxial cable |
| ATE424424T1 (de) | 2006-12-28 | 2009-03-15 | Borealis Tech Oy | Verfahren zur herstellung von verzweigtem polypropylen |
| MX2009003471A (es) * | 2006-12-29 | 2009-04-15 | Fina Technology | Sistema de catalizador de polimerizacion que contiene succinato usando n-butilmetildimeto-xisilano para la preparacion de resinas de grado de pelicula de polipropileno. |
| EP1964948A1 (en) * | 2007-02-28 | 2008-09-03 | Total Petrochemicals Research Feluy | Polypropylene fibers and spunbond nonwoven with improved properties. |
| RU2457290C2 (ru) * | 2007-03-26 | 2012-07-27 | Курарей Ко., Лтд. | Полипропиленовые волокна, способы их получения и их применение |
| MX2011001970A (es) * | 2008-08-21 | 2011-08-12 | Dow Global Technologies Llc | Composicion de catalizador con agente de control de selectividad mezclado y metodo de polimerizacion que la usa. |
| EP2194070B1 (en) * | 2008-12-03 | 2012-08-22 | Süd-Chemie IP GmbH & Co. KG | Electron donor composition for a solid catalyst, solid catalyst composition used in the polymerisation of alpha-olefins, and process for the production of a polymer consisting of alpha-olefin units using the solid catalyst composition |
| US9068028B2 (en) | 2009-06-19 | 2015-06-30 | Basell Poliolefine Italia S.R.L. | Process for the preparation of impact resistant propylene polymer compositions |
| MY148239A (en) * | 2009-08-13 | 2013-03-29 | China Petroleum & Chemical | A catalyst component for olefin polymerization and a catalyst comprising the same |
| CN102372797A (zh) * | 2010-08-12 | 2012-03-14 | 中国石油化工股份有限公司 | 用于烯烃聚合反应的催化剂组分及其催化剂 |
| WO2013004507A1 (en) | 2011-07-01 | 2013-01-10 | Basell Poliolefine Italia S.R.L. | Polypropylene films and sheets |
| JP6076328B2 (ja) * | 2012-02-20 | 2017-02-08 | サンアロマー株式会社 | シート成形用ポリプロピレン系樹脂組成物 |
| EP2914649B1 (en) | 2012-10-31 | 2017-11-29 | ExxonMobil Chemical Patents Inc. | Articles comprising broad molecular weight distribution polypropylene resins |
| EP2914637B1 (en) | 2012-10-31 | 2017-12-13 | ExxonMobil Chemical Patents Inc. | Broad molecular weight distribution polypropylene resins |
| US9522968B2 (en) | 2012-11-26 | 2016-12-20 | Lummus Novolen Technology Gmbh | High performance Ziegler-Natta catalyst systems, process for producing such MgCl2 based catalysts and use thereof |
| WO2014152692A1 (en) | 2013-03-15 | 2014-09-25 | Braskem America, Inc. | Propylene polymer resins |
| JP6235805B2 (ja) * | 2013-06-17 | 2017-11-22 | サンアロマー株式会社 | 二軸延伸フィルム用ポリプロピレン樹脂組成物 |
| ES2651456T3 (es) | 2013-08-14 | 2018-01-26 | Borealis Ag | Composición de propileno con mejor resistencia al impacto a baja temperatura |
| JP6190961B2 (ja) | 2013-08-21 | 2017-08-30 | ボレアリス・アクチェンゲゼルシャフトＢｏｒｅａｌｉｓ Ａｇ | 高い剛性および靭性を有する高流動ポリオレフィン組成物 |
| BR112016002682A8 (pt) | 2013-08-21 | 2020-01-28 | Borealis Ag | composição de poliolefina de alto fluxo com alta rigidez e tenacidade |
| PT2853563T (pt) | 2013-09-27 | 2016-07-14 | Borealis Ag | Filmes adequados para processamento de bopp a partir de polímeros com xs elevada e tm elevado |
| EP2860031B1 (en) | 2013-10-11 | 2016-03-30 | Borealis AG | Machine direction oriented film for labels |
| EP3060589B9 (en) | 2013-10-24 | 2018-04-18 | Borealis AG | Low melting pp homopolymer with high content of regioerrors and high molecular weight |
| MX368147B (es) | 2013-11-22 | 2019-09-20 | Borealis Ag | Homopolímero de propileno de baja emisión con alto flujo de masa fundida. |
| MX366147B (es) | 2013-11-22 | 2019-06-28 | Borealis Ag | Homopolimero de propileno de baja emision. |
| BR112016011829B1 (pt) | 2013-12-04 | 2022-01-18 | Borealis Ag | Composição de polipropileno, fibra e trama soprada em fusão, artigo e uso da composição de polipropileno |
| US9637602B2 (en) | 2013-12-18 | 2017-05-02 | Borealis Ag | BOPP film with improved stiffness/toughness balance |
| EP3083778B1 (en) * | 2013-12-18 | 2020-11-11 | Borealis AG | Bopp film having low shrinkage |
| CN105829364B (zh) | 2014-01-17 | 2017-11-10 | 博里利斯股份公司 | 用于制备丙烯/1‑丁烯共聚物的方法 |
| PL3102634T3 (pl) | 2014-02-06 | 2020-11-16 | Borealis Ag | Miękkie i przezroczyste kopolimery odporne na uderzenia |
| WO2015117958A1 (en) | 2014-02-06 | 2015-08-13 | Borealis Ag | Soft copolymers with high impact strength |
| EP2907841A1 (en) | 2014-02-14 | 2015-08-19 | Borealis AG | Polypropylene composite |
| ES2659731T3 (es) | 2014-05-20 | 2018-03-19 | Borealis Ag | Composición de polipropileno para aplicaciones en interiores de automóviles |
| JP6655030B2 (ja) | 2014-06-25 | 2020-02-26 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 高溶融強度ポリプロピレンおよび溶融強度を保持するための押出方法 |
| EP3309183A1 (en) | 2016-10-14 | 2018-04-18 | SABIC Global Technologies B.V. | Polypropylene for use in bopp applications |
| KR102420733B1 (ko) | 2017-07-13 | 2022-07-15 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 변형률 경화된 폴리프로필렌의 제조 방법 |
| JP7780918B2 (ja) * | 2021-11-05 | 2025-12-05 | 住友化学株式会社 | プロピレン系重合体組成物、プロピレン系重合体組成物の製造方法、および、二軸延伸フィルム |
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| IT1096661B (it) | 1978-06-13 | 1985-08-26 | Montedison Spa | Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente |
| IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| US4820772A (en) * | 1987-04-20 | 1989-04-11 | Chisso Corporation | Polyolefin composition |
| IT1246614B (it) * | 1991-06-03 | 1994-11-24 | Himont Inc | Procedimento per la polimerizzazione in fase gas delle olefine |
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| US5286791A (en) * | 1992-05-29 | 1994-02-15 | Himont Incorporated | Impact modified graft copolymer compositions containing broad molecular weight distribution polypropylene |
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| IT1271420B (it) * | 1993-08-30 | 1997-05-28 | Himont Inc | Composizioni poliolefiniche aventi un elevato bilancio di rigidita' e resilienza |
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| US7049377B1 (en) * | 1995-02-21 | 2006-05-23 | Basell Poliolefine Italia S.R.L. | 1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers |
| IT1275573B (it) * | 1995-07-20 | 1997-08-07 | Spherilene Spa | Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine |
| EP0916701B1 (en) * | 1997-04-24 | 2004-02-25 | Mitsui Chemicals, Inc. | Crystalline polypropylene resin composition |
| US6204335B1 (en) * | 1997-09-12 | 2001-03-20 | Eastman Chemical Company | Compositions of linear ultra low density polyethylene and propylene polymers and films therefrom |
| JP4864176B2 (ja) * | 1999-02-19 | 2012-02-01 | トータル・ペトロケミカルズ・リサーチ・フエリユイ | ポリオレフィン製造 |
| CA2334743C (en) * | 1999-04-15 | 2010-01-12 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
| WO2001057099A1 (en) | 2000-02-02 | 2001-08-09 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
| PL355609A1 (pl) * | 2000-10-13 | 2004-05-04 | Basell Poliolefine Italia S.P.A. | Składniki katalizatora do polimeryzacji olefin |
| JP4206645B2 (ja) | 2001-03-27 | 2009-01-14 | 株式会社プライムポリマー | 結晶性ポリプロピレン樹脂組成物およびそれから製造されるシート |
| US7067690B2 (en) | 2001-12-24 | 2006-06-27 | Basell Poliolefine Italia S.P.A. | Separation of diastereoisomers |
-
2003
- 2003-07-30 PL PL37450803A patent/PL374508A1/pl unknown
- 2003-07-30 KR KR1020057001697A patent/KR20050033639A/ko not_active Ceased
- 2003-07-30 RU RU2005105593A patent/RU2325404C2/ru not_active IP Right Cessation
- 2003-07-30 CA CA 2492939 patent/CA2492939A1/en not_active Abandoned
- 2003-07-30 CN CNB038185423A patent/CN100564399C/zh not_active Expired - Fee Related
- 2003-07-30 US US10/522,957 patent/US7112642B2/en not_active Expired - Lifetime
- 2003-07-30 JP JP2004525402A patent/JP2005534761A/ja not_active Withdrawn
- 2003-07-30 EP EP20030766382 patent/EP1527106A2/en not_active Ceased
- 2003-07-30 AU AU2003250201A patent/AU2003250201B2/en not_active Expired - Fee Related
- 2003-07-30 BR BR0306195A patent/BR0306195B1/pt active IP Right Grant
- 2003-07-30 WO PCT/EP2003/008491 patent/WO2004013193A2/en not_active Ceased
-
2005
- 2005-01-13 IL IL166300A patent/IL166300A/en not_active IP Right Cessation
-
2006
- 2006-08-01 US US11/496,924 patent/US7772346B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| BR0306195A (pt) | 2004-10-19 |
| EP1527106A2 (en) | 2005-05-04 |
| CA2492939A1 (en) | 2004-02-12 |
| WO2004013193A2 (en) | 2004-02-12 |
| KR20050033639A (ko) | 2005-04-12 |
| RU2325404C2 (ru) | 2008-05-27 |
| CN100564399C (zh) | 2009-12-02 |
| BR0306195B1 (pt) | 2012-12-25 |
| RU2005105593A (ru) | 2005-07-20 |
| IL166300A0 (en) | 2006-01-15 |
| JP2005534761A (ja) | 2005-11-17 |
| CN1675254A (zh) | 2005-09-28 |
| AU2003250201B2 (en) | 2008-12-11 |
| WO2004013193A3 (en) | 2004-03-25 |
| US7112642B2 (en) | 2006-09-26 |
| AU2003250201A1 (en) | 2004-02-23 |
| US7772346B2 (en) | 2010-08-10 |
| US20060264585A1 (en) | 2006-11-23 |
| US20060009594A1 (en) | 2006-01-12 |
| PL374508A1 (pl) | 2005-10-31 |
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| MM9K | Patent not in force due to non-payment of renewal fees |