IE52180B1 - Efficiently rechargeable totally inorganic non-aqueous li/so2 cell with halogallate electrolyte salt - Google Patents
Efficiently rechargeable totally inorganic non-aqueous li/so2 cell with halogallate electrolyte saltInfo
- Publication number
- IE52180B1 IE52180B1 IE1958/81A IE195881A IE52180B1 IE 52180 B1 IE52180 B1 IE 52180B1 IE 1958/81 A IE1958/81 A IE 1958/81A IE 195881 A IE195881 A IE 195881A IE 52180 B1 IE52180 B1 IE 52180B1
- Authority
- IE
- Ireland
- Prior art keywords
- cell
- lithium
- anode
- rechargeable
- metal
- Prior art date
Links
- 239000003792 electrolyte Substances 0.000 title claims abstract description 41
- 150000003839 salts Chemical class 0.000 title claims abstract description 32
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 83
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 81
- 239000002904 solvent Substances 0.000 claims abstract description 34
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910052751 metal Inorganic materials 0.000 claims abstract description 25
- 239000002184 metal Substances 0.000 claims abstract description 25
- 150000001768 cations Chemical class 0.000 claims abstract description 7
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 6
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000010269 sulphur dioxide Nutrition 0.000 claims abstract 4
- 239000004291 sulphur dioxide Substances 0.000 claims abstract 3
- 239000000758 substrate Substances 0.000 claims description 13
- 230000002441 reversible effect Effects 0.000 claims description 12
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 6
- 239000000956 alloy Substances 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 150000001450 anions Chemical class 0.000 claims description 4
- 239000011888 foil Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 2
- 229910000423 chromium oxide Inorganic materials 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 230000002687 intercalation Effects 0.000 claims description 2
- 238000009830 intercalation Methods 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 229910000733 Li alloy Inorganic materials 0.000 abstract 1
- 229910010937 LiGaCl4 Inorganic materials 0.000 abstract 1
- 210000004027 cell Anatomy 0.000 description 70
- 239000007795 chemical reaction product Substances 0.000 description 11
- 230000001351 cycling effect Effects 0.000 description 11
- 238000007747 plating Methods 0.000 description 11
- -1 lithium cations Chemical class 0.000 description 10
- 239000003960 organic solvent Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 8
- 210000001787 dendrite Anatomy 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 150000002258 gallium Chemical class 0.000 description 5
- 230000002427 irreversible effect Effects 0.000 description 5
- 238000004064 recycling Methods 0.000 description 5
- 239000006184 cosolvent Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000000151 deposition Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 239000008151 electrolyte solution Substances 0.000 description 3
- 229940021013 electrolyte solution Drugs 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- XRZCZQUCDBWELQ-UHFFFAOYSA-L [Li+].[Li+].[O-]S(=O)S([O-])=O Chemical compound [Li+].[Li+].[O-]S(=O)S([O-])=O XRZCZQUCDBWELQ-UHFFFAOYSA-L 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000010405 anode material Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000011889 copper foil Substances 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000003049 inorganic solvent Substances 0.000 description 2
- 229910001867 inorganic solvent Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 2
- 229910052808 lithium carbonate Inorganic materials 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
- 159000000002 lithium salts Chemical class 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 239000005486 organic electrolyte Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 1
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical group CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- WGZCUXZFISUUPR-UHFFFAOYSA-N acetonitrile;oxolane Chemical compound CC#N.C1CCOC1 WGZCUXZFISUUPR-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-YPZZEJLDSA-N carbon-10 atom Chemical compound [10C] OKTJSMMVPCPJKN-YPZZEJLDSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- XOYLJNJLGBYDTH-UHFFFAOYSA-M chlorogallium Chemical compound [Ga]Cl XOYLJNJLGBYDTH-UHFFFAOYSA-M 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002999 depolarising effect Effects 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229940006487 lithium cation Drugs 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 229910001537 lithium tetrachloroaluminate Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920001521 polyalkylene glycol ether Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000011536 re-plating Methods 0.000 description 1
- 230000036647 reaction Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 229910001538 sodium tetrachloroaluminate Inorganic materials 0.000 description 1
- 238000007614 solvation Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- CFJRPNFOLVDFMJ-UHFFFAOYSA-N titanium disulfide Chemical compound S=[Ti]=S CFJRPNFOLVDFMJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0563—Liquid materials, e.g. for Li-SOCl2 cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US18686880A | 1980-09-12 | 1980-09-12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE811958L IE811958L (en) | 1982-03-12 |
| IE52180B1 true IE52180B1 (en) | 1987-08-05 |
Family
ID=22686596
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE1958/81A IE52180B1 (en) | 1980-09-12 | 1981-08-27 | Efficiently rechargeable totally inorganic non-aqueous li/so2 cell with halogallate electrolyte salt |
Country Status (23)
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4513067A (en) * | 1983-06-30 | 1985-04-23 | Duracell Inc. | Inorganic non-aqueous cell |
| EP0269855A3 (en) * | 1986-12-01 | 1988-09-07 | Whittaker Technical Products, Inc. | Rechargeable electrochemical cell |
| DE3826812A1 (de) * | 1988-08-06 | 1990-02-08 | Heitbaum Joachim | Nichtwaessriges, wiederaufladbares galvanisches lithiumelement mit anorganischer elektrolytloesung |
| US20050100786A1 (en) * | 2003-09-19 | 2005-05-12 | Ryu Duk H. | Nonaqueous lithium secondary battery with cyclability and/or high temperature safety improved |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3493433A (en) * | 1964-10-13 | 1970-02-03 | American Cyanamid Co | Electrodeposition of alkali metals from nonaqueous solvents |
| NL6511298A (enrdf_load_stackoverflow) * | 1964-10-13 | 1966-04-14 | ||
| FR1556247A (enrdf_load_stackoverflow) * | 1967-11-15 | 1969-02-07 | ||
| GB1258498A (enrdf_load_stackoverflow) * | 1968-06-11 | 1971-12-30 | ||
| US3764385A (en) * | 1970-12-22 | 1973-10-09 | Exxon Research Engineering Co | Electric battery using complexed inorganic lithium salts as charge transfer agent |
| IL41154A0 (en) * | 1971-12-27 | 1973-02-28 | Gte Laboratories Inc | Electrochemical cell |
| US4091152A (en) * | 1973-08-16 | 1978-05-23 | P.R. Mallory & Co. Inc. | Lithium SO2 cell |
| US3953302A (en) * | 1973-08-16 | 1976-04-27 | P. R. Mallory & Co. Inc. | Prevention of dendritic plating of lithium |
| US3928067A (en) * | 1974-09-06 | 1975-12-23 | Bell Telephone Labor Inc | Polyalkylene glycol ethers in rechargeable lithium nonaqueous batteries |
| US4009052A (en) * | 1975-02-24 | 1977-02-22 | Exxon Research And Engineering Company | Chalcogenide battery |
| US4002492A (en) * | 1975-07-01 | 1977-01-11 | Exxon Research And Engineering Company | Rechargeable lithium-aluminum anode |
| JPS526446A (en) * | 1975-07-04 | 1977-01-18 | Mitsubishi Electric Corp | Unipole antenna |
| US4020240A (en) * | 1975-09-03 | 1977-04-26 | P. R. Mallory & Co., Inc. | Electrochemical cell with clovoborate salt in electrolyte and method of operation and composition of matter |
| US4154902A (en) * | 1976-09-13 | 1979-05-15 | American Energizer Corporation | Electric battery cell, system and method |
| US4075397A (en) * | 1977-03-01 | 1978-02-21 | Exxon Research & Engineering Co. | Cell having chalcogenide cathode and solvated alkali metal salt electrolyte |
| US4139681A (en) * | 1978-03-02 | 1979-02-13 | Exxon Research & Engineering Co. | Electrochemical cells having alkali metal anodes and electrolyte salt complex compositions including haloorganometallic alkali metal salt complexes |
| US4177329A (en) * | 1978-11-02 | 1979-12-04 | P. R. Mallory & Co. Inc. | Electrolyte salts for non aqueous electrochemical cells |
| US4238552A (en) * | 1979-07-03 | 1980-12-09 | P. R. Mallory & Co. Inc. | Electrolyte salt for non-aqueous electrochemical cells |
| IL60238A (en) * | 1980-06-05 | 1983-07-31 | Tadiran Israel Elect Ind Ltd | Cathode and electric cell containing same |
-
1981
- 1981-08-06 IL IL63515A patent/IL63515A/xx not_active IP Right Cessation
- 1981-08-07 AU AU73876/81A patent/AU543584B2/en not_active Ceased
- 1981-08-07 ZA ZA815453A patent/ZA815453B/xx unknown
- 1981-08-19 GR GR65822A patent/GR74676B/el unknown
- 1981-08-21 DE DE19813133211 patent/DE3133211A1/de active Granted
- 1981-08-25 GB GB8125832A patent/GB2083942B/en not_active Expired
- 1981-08-26 BE BE0/205779A patent/BE890101A/fr not_active IP Right Cessation
- 1981-08-27 IE IE1958/81A patent/IE52180B1/en not_active IP Right Cessation
- 1981-08-31 BR BR8105538A patent/BR8105538A/pt unknown
- 1981-09-01 ES ES505098A patent/ES505098A0/es active Granted
- 1981-09-02 NL NL8104075A patent/NL8104075A/nl not_active Application Discontinuation
- 1981-09-02 CA CA000385027A patent/CA1158305A/en not_active Expired
- 1981-09-03 FR FR8116765A patent/FR2490407A1/fr active Granted
- 1981-09-09 IT IT23853/81A patent/IT1138588B/it active
- 1981-09-09 KR KR1019810003362A patent/KR830008419A/ko not_active Withdrawn
- 1981-09-11 DD DD81233230A patent/DD202081A5/de unknown
- 1981-09-11 NO NO813104A patent/NO813104L/no unknown
- 1981-09-11 PL PL23299381A patent/PL232993A1/xx unknown
- 1981-09-11 DK DK404081A patent/DK404081A/da not_active Application Discontinuation
- 1981-09-11 SE SE8105426A patent/SE8105426L/xx not_active Application Discontinuation
- 1981-09-11 JP JP56143713A patent/JPS57107576A/ja active Granted
- 1981-10-12 IN IN654/DEL/81A patent/IN157369B/en unknown
-
1989
- 1989-07-20 HK HK579/89A patent/HK57989A/xx unknown
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Patent lapsed |