IE35681B1 - An improved catalyst for producing oxirane compounds by epoxidizing olefins with hydroperoxides - Google Patents
An improved catalyst for producing oxirane compounds by epoxidizing olefins with hydroperoxidesInfo
- Publication number
- IE35681B1 IE35681B1 IE1219/71A IE121971A IE35681B1 IE 35681 B1 IE35681 B1 IE 35681B1 IE 1219/71 A IE1219/71 A IE 1219/71A IE 121971 A IE121971 A IE 121971A IE 35681 B1 IE35681 B1 IE 35681B1
- Authority
- IE
- Ireland
- Prior art keywords
- hydroperoxides
- oxirane compounds
- improved catalyst
- olefins
- epoxidizing olefins
- Prior art date
Links
- 150000002924 oxiranes Chemical class 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title abstract 2
- 150000002432 hydroperoxides Chemical class 0.000 title abstract 2
- GQNOPVSQPBUJKQ-UHFFFAOYSA-N 1-hydroperoxyethylbenzene Chemical compound OOC(C)C1=CC=CC=C1 GQNOPVSQPBUJKQ-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052810 boron oxide Inorganic materials 0.000 abstract 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 abstract 1
- 238000006735 epoxidation reaction Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 150000001282 organosilanes Chemical class 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0231—Halogen-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0254—Nitrogen containing compounds on mineral substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
- B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
- B01J31/0275—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 also containing elements or functional groups covered by B01J31/0201 - B01J31/0269
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0209—Impregnation involving a reaction between the support and a fluid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
- B01J2231/72—Epoxidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/617—500-1000 m2/g
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Tubes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7738570A | 1970-10-01 | 1970-10-01 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE35681L IE35681L (en) | 1972-04-01 |
| IE35681B1 true IE35681B1 (en) | 1976-04-28 |
Family
ID=22137754
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE1219/71A IE35681B1 (en) | 1970-10-01 | 1971-09-29 | An improved catalyst for producing oxirane compounds by epoxidizing olefins with hydroperoxides |
Country Status (16)
| Country | Link |
|---|---|
| JP (1) | JPS5440526B1 (xx) |
| AT (1) | AT315135B (xx) |
| BE (1) | BE773363A (xx) |
| CA (1) | CA1002056A (xx) |
| CH (1) | CH568792A5 (xx) |
| DE (1) | DE2148637C3 (xx) |
| DK (1) | DK150592C (xx) |
| ES (1) | ES395527A1 (xx) |
| FR (1) | FR2109867A5 (xx) |
| GB (1) | GB1339309A (xx) |
| IE (1) | IE35681B1 (xx) |
| IT (1) | IT938878B (xx) |
| NL (1) | NL153872C (xx) |
| NO (2) | NO129888B (xx) |
| SE (1) | SE377525B (xx) |
| ZA (1) | ZA716592B (xx) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK151016C (da) * | 1972-03-13 | 1988-06-27 | Shell Int Research | Fremgangsmaade til fremstilling af oxiranforbindelser ved omsaetning af en olefinisk umaettet forbindelse med et organisk hydroperoxid i naervaerelse af en katalysator |
| DE3734138A1 (de) * | 1987-10-09 | 1989-04-20 | Scharmer Klaus Dr Ing | Saurer katalysator und verfahren zum herstellen des katalysators |
| CA2002341A1 (en) * | 1988-11-09 | 1990-05-09 | Takehisa Nakanishi | Method for preparing epichlorohydrins |
| US5081267A (en) * | 1989-10-05 | 1992-01-14 | Arco Chemical Technology, Inc. | Epoxidation process |
| US5319114A (en) * | 1993-09-23 | 1994-06-07 | Arco Chemical Technology, L. P. | Olefin epoxidation using a carbon molecular sieve impregnated with a transition metal |
| EP0752916B1 (en) * | 1994-03-31 | 1999-12-08 | Infineum USA L.P. | Polymerisation reactions with supported lewis acid catalysts |
| DE19545042A1 (de) * | 1995-12-02 | 1997-06-05 | Studiengesellschaft Kohle Mbh | Amorphe mikroporöse Mischoxidkatalysatoren mit kontrollierter Oberflächenpolarität für die selektive heterogene Katalyse Adsorption und Stofftrennung |
| DE19743165A1 (de) * | 1997-09-30 | 1999-04-01 | Studiengesellschaft Kohle Mbh | Selektive Alkylierung von Aromaten mit oberflächenmodifizierten mikroporösen Mischoxiden |
| WO1999043431A1 (fr) * | 1998-02-24 | 1999-09-02 | Japan As Represented By Director-General Of Agency Of Industrial Science And Technology | Catalyseur d'oxydation partielle d'hydrocarbure insature |
| SG82626A1 (en) | 1998-08-04 | 2001-08-21 | Sumitomo Chemical Co | Titanium-containing silicon oxide catalyst |
| SG73663A1 (en) * | 1998-08-04 | 2000-06-20 | Sumitomo Chemical Co | A process for producing propylene oxide |
| JP2000279809A (ja) * | 1999-03-30 | 2000-10-10 | Nippon Shokubai Co Ltd | エポキシド製造用触媒及びエポキシドの製法 |
| DE19925926A1 (de) * | 1999-06-08 | 2000-12-14 | Bayer Ag | Katalysatoren auf Basis Titan-haltiger, organisch-anorganischer Hybridmaterialien zur selektiven Oxidation von Kohlenwasserstoffen |
| JP4694712B2 (ja) * | 2001-01-15 | 2011-06-08 | 丸善石油化学株式会社 | チタン含有固体触媒及びこれを用いたエポキシ化合物の製造法 |
| JP6634179B1 (ja) * | 2018-07-30 | 2020-01-22 | 花王株式会社 | エポキシアルカンの製造方法、及び固体酸化触媒 |
| WO2021142635A1 (zh) * | 2020-01-14 | 2021-07-22 | 万华化学集团股份有限公司 | 一种丙烯环氧化催化剂的制备方法及其用途 |
| CN113181961B (zh) * | 2020-01-14 | 2022-09-20 | 万华化学集团股份有限公司 | 一种丙烯环氧化催化剂的制备方法及其用途 |
-
1971
- 1971-09-29 AT AT842471A patent/AT315135B/de not_active IP Right Cessation
- 1971-09-29 FR FR7135035A patent/FR2109867A5/fr not_active Expired
- 1971-09-29 NL NL7113338.A patent/NL153872C/xx not_active IP Right Cessation
- 1971-09-29 CH CH1421871A patent/CH568792A5/xx not_active IP Right Cessation
- 1971-09-29 JP JP7551671A patent/JPS5440526B1/ja active Pending
- 1971-09-29 IT IT29294/71A patent/IT938878B/it active
- 1971-09-29 CA CA124,017A patent/CA1002056A/en not_active Expired
- 1971-09-29 DK DK474171A patent/DK150592C/da active
- 1971-09-29 ES ES395527A patent/ES395527A1/es not_active Expired
- 1971-09-29 SE SE7112339A patent/SE377525B/xx unknown
- 1971-09-29 IE IE1219/71A patent/IE35681B1/xx unknown
- 1971-09-29 GB GB4535271A patent/GB1339309A/en not_active Expired
- 1971-09-29 NO NO03587/71A patent/NO129888B/no unknown
- 1971-09-29 DE DE2148637A patent/DE2148637C3/de not_active Expired
- 1971-09-30 BE BE773363A patent/BE773363A/nl not_active IP Right Cessation
- 1971-10-01 ZA ZA716592A patent/ZA716592B/xx unknown
-
1973
- 1973-12-18 NO NO734842A patent/NO138883C/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NO138883B (no) | 1978-08-21 |
| GB1339309A (en) | 1973-12-05 |
| DE2148637C3 (de) | 1982-04-22 |
| NL153872B (nl) | 1977-07-15 |
| CH568792A5 (xx) | 1975-11-14 |
| NO129888B (xx) | 1974-06-10 |
| IT938878B (it) | 1973-02-10 |
| IE35681L (en) | 1972-04-01 |
| DK150592B (da) | 1987-04-06 |
| ES395527A1 (es) | 1973-12-16 |
| NL153872C (nl) | 1981-07-16 |
| BE773363A (nl) | 1972-03-30 |
| CA1002056A (en) | 1976-12-21 |
| JPS5440526B1 (xx) | 1979-12-04 |
| DE2148637B2 (de) | 1981-02-26 |
| ZA716592B (en) | 1972-06-28 |
| AU3399671A (en) | 1973-04-19 |
| FR2109867A5 (xx) | 1972-05-26 |
| AT315135B (de) | 1974-05-10 |
| DE2148637A1 (de) | 1972-04-06 |
| DK150592C (da) | 1987-10-05 |
| NO138883C (no) | 1978-11-29 |
| SE377525B (xx) | 1975-07-14 |
| NL7113338A (xx) | 1972-04-05 |
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