HUP0002365A2 - Gázfázisú polimerizációs eljárás propilén/1-pentén kopolimerek előállítására - Google Patents

Gázfázisú polimerizációs eljárás propilén/1-pentén kopolimerek előállítására

Info

Publication number
HUP0002365A2
HUP0002365A2 HU0002365A HUP0002365A HUP0002365A2 HU P0002365 A2 HUP0002365 A2 HU P0002365A2 HU 0002365 A HU0002365 A HU 0002365A HU P0002365 A HUP0002365 A HU P0002365A HU P0002365 A2 HUP0002365 A2 HU P0002365A2
Authority
HU
Hungary
Prior art keywords
reaction space
reaction
vapor phase
monomer
reactants
Prior art date
Application number
HU0002365A
Other languages
English (en)
Inventor
Dawid Johannes Joubert
Antonie Hermanus Potgieter
Ignatius Hendrik Potgieter
Ioan Tincul
Original Assignee
Sasol Technology (Proprietary) Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sasol Technology (Proprietary) Limited filed Critical Sasol Technology (Proprietary) Limited
Publication of HUP0002365A2 publication Critical patent/HUP0002365A2/hu

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium

Abstract

A találmány tárgya eljárás propilén/1-pentén polimer előállításáraZiegler-Natta katalizátor vagy Ziegler-Natta katalizátort és koka-talizátort tartalmazó katalizátorrendszer jelenlétében oly módon, hogya reagensek a reakció alatt a reakciótérben gőzfázisban vannak, és areakciótérben a reakció alatt nincs jelen folyadékkomponens és mindkétmonomer reagenst külön-külön előmelegítik a gőzfázis biztosítására, ésa monomer reagenseket egymástól elkülönítve vezetik gőzfázisban areakciótérbe; vagy legalább az egyik monomer reagenst részbengőzfázisban vezetik be a reakciótérbe, és a monomernek azt a részét,amit a reakciótérbe folyadékfázisban vezetnek be, ezzel a résszel areakciótérben elpárologtatják a reakció alatt mindkét monomer reagensgőzfázisának biztosítására; vagy a propilént gázfázisban vezetik be areakciótérbe, míg az 1-pentént folyadékfázisban vezetik areakciótérbe, olyan mennyiségben, hogy a reakciótérben gyorsanelpárologjon és így szintén gőzfázisban legyen, biztosítva ezáltal,hogy a reakció alatt mindkét monomer reagens gőzfázisban van. Ó
HU0002365A 1997-07-04 1998-07-03 Gázfázisú polimerizációs eljárás propilén/1-pentén kopolimerek előállítására HUP0002365A2 (hu)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ZA975997 1997-07-04

Publications (1)

Publication Number Publication Date
HUP0002365A2 true HUP0002365A2 (hu) 2000-11-28

Family

ID=25586472

Family Applications (1)

Application Number Title Priority Date Filing Date
HU0002365A HUP0002365A2 (hu) 1997-07-04 1998-07-03 Gázfázisú polimerizációs eljárás propilén/1-pentén kopolimerek előállítására

Country Status (16)

Country Link
US (1) US6391987B1 (hu)
EP (1) EP0993474B1 (hu)
JP (1) JP2002508019A (hu)
KR (1) KR20010021512A (hu)
CN (1) CN1107684C (hu)
AT (1) ATE249484T1 (hu)
AU (1) AU755262B2 (hu)
BR (1) BR9810982A (hu)
CA (1) CA2294798A1 (hu)
DE (1) DE69818056T2 (hu)
HK (1) HK1028054A1 (hu)
HU (1) HUP0002365A2 (hu)
ID (1) ID23869A (hu)
IL (1) IL133738A0 (hu)
PL (1) PL337968A1 (hu)
WO (1) WO1999001485A1 (hu)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6921794B2 (en) 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
JP2002519497A (ja) 1998-07-01 2002-07-02 エクソンモービル・ケミカル・パテンツ・インク 結晶性プロピレンポリマーと結晶化可能プロピレンポリマーとを含んでなる弾性ブレンド
US20030008988A1 (en) * 2001-01-29 2003-01-09 Sasol Technology (Proprietary) Limited Polymerization
US20030225224A1 (en) * 2002-05-28 2003-12-04 Sasol Technology (Proprietary) Limited Polymerization
WO2011009704A1 (en) 2009-07-21 2011-01-27 Basell Poliolefine Italia S.R.L. Fibres made from copolymers of propylene and 1-pentene
CN109071722B (zh) * 2015-06-30 2021-08-27 博里利斯股份公司 用于制备丙烯聚合物组合物的方法
CN106565883B (zh) * 2015-10-12 2019-07-05 中国科学院化学研究所 一种有机硅烷的应用以及聚烯烃树脂及其制备方法
WO2017063116A1 (zh) * 2015-10-12 2017-04-20 中国科学院化学研究所 一种有机硅烷的应用以及聚烯烃树脂及其制备方法
US10836846B2 (en) 2015-10-12 2020-11-17 Institute Of Chemistry, Chinese Academy Of Sciences Olefin polymerization catalyst, preparation method thereof, olefin polymerization catalyst system, use thereof, and method of preparing polyolefin resin
CN106565870B (zh) * 2015-10-12 2019-07-05 中国科学院化学研究所 烯烃聚合催化剂及其制备方法和烯烃聚合催化剂体系及其应用以及聚烯烃树脂的制备方法
JP6745339B2 (ja) * 2015-10-12 2020-08-26 中国科学院化学研究所Ｉｎｓｔｉｔｕｔｅ Ｏｆ Ｃｈｅｍｉｓｔｒｙ， Ｃｈｉｎｅｓｅ Ａｃａｄｅｍｙ Ｏｆ Ｓｃｉｅｎｃｅｓ 有機シランの使用、並びにポリオレフィン釜内アロイ及びその製造方法
CN110144022B (zh) * 2019-05-28 2020-02-21 国家能源集团宁夏煤业有限责任公司 Ziegler-Natta催化剂的工业制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0266074B1 (en) * 1986-10-02 1991-08-14 BP Chemicals Limited Process for polymerising one or more 1-olefins in the gas phase in the presence of pulverulent inorganic material
KR900009719A (ko) * 1988-12-16 1990-07-05 엠. 데이비드 레오나이드 신규 에틸렌-프로필렌 공중합체
US5618895A (en) * 1990-04-06 1997-04-08 Basf Aktiengesellschaft Process for preparing copolymers of propylene with other 1-alkenes
ZA96626B (en) * 1995-02-09 1996-08-15 Sastech Pty Ltd Copolymerization

Also Published As

Publication number Publication date
ID23869A (id) 2000-05-25
AU755262B2 (en) 2002-12-05
BR9810982A (pt) 2000-08-08
CN1268145A (zh) 2000-09-27
US6391987B1 (en) 2002-05-21
IL133738A0 (en) 2001-04-30
DE69818056D1 (de) 2003-10-16
EP0993474B1 (en) 2003-09-10
CN1107684C (zh) 2003-05-07
WO1999001485A1 (en) 1999-01-14
HK1028054A1 (en) 2001-02-02
ATE249484T1 (de) 2003-09-15
KR20010021512A (ko) 2001-03-15
AU8230498A (en) 1999-01-25
PL337968A1 (en) 2000-09-11
JP2002508019A (ja) 2002-03-12
EP0993474A1 (en) 2000-04-19
CA2294798A1 (en) 1999-01-14
DE69818056T2 (de) 2004-04-08

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