CN1107684C - 生产丙烯/1－戊烯共聚物的气相聚合方法 - Google Patents

生产丙烯/1－戊烯共聚物的气相聚合方法 Download PDF

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Publication number
CN1107684C
CN1107684C CN98808505A CN98808505A CN1107684C CN 1107684 C CN1107684 C CN 1107684C CN 98808505 A CN98808505 A CN 98808505A CN 98808505 A CN98808505 A CN 98808505A CN 1107684 C CN1107684 C CN 1107684C
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CN
China
Prior art keywords
propylene
reaction
reaction zone
amylene
magnesium chloride
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Expired - Fee Related
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CN98808505A
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English (en)
Chinese (zh)
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CN1268145A (zh
Inventor
伊万·廷卡尔
伊格内修斯·亨德里克·布特吉耶特尔
戴维·约翰内斯·朱伯特
安东尼·赫尔曼纳斯·布特吉耶特尔
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Sastech Pty Ltd
Sasol Technology Pty Ltd
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Sastech Pty Ltd
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Publication of CN1268145A publication Critical patent/CN1268145A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
CN98808505A 1997-07-04 1998-07-03 生产丙烯/1－戊烯共聚物的气相聚合方法 Expired - Fee Related CN1107684C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ZA975997 1997-07-04
ZA97/5997 1997-07-04

Publications (2)

Publication Number Publication Date
CN1268145A CN1268145A (zh) 2000-09-27
CN1107684C true CN1107684C (zh) 2003-05-07

Family

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CN98808505A Expired - Fee Related CN1107684C (zh) 1997-07-04 1998-07-03 生产丙烯/1－戊烯共聚物的气相聚合方法

Country Status (16)

Country Link
US (1) US6391987B1 (hu)
EP (1) EP0993474B1 (hu)
JP (1) JP2002508019A (hu)
KR (1) KR20010021512A (hu)
CN (1) CN1107684C (hu)
AT (1) ATE249484T1 (hu)
AU (1) AU755262B2 (hu)
BR (1) BR9810982A (hu)
CA (1) CA2294798A1 (hu)
DE (1) DE69818056T2 (hu)
HK (1) HK1028054A1 (hu)
HU (1) HUP0002365A2 (hu)
ID (1) ID23869A (hu)
IL (1) IL133738A0 (hu)
PL (1) PL337968A1 (hu)
WO (1) WO1999001485A1 (hu)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6921794B2 (en) 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
DE69935815T2 (de) 1998-07-01 2007-12-27 Exxonmobil Chemical Patents Inc., Baytown Elastische Mischung mit Kristallpolymeren und kristallisierbaren Polymeren des Propens
US20030008988A1 (en) * 2001-01-29 2003-01-09 Sasol Technology (Proprietary) Limited Polymerization
US20030225224A1 (en) * 2002-05-28 2003-12-04 Sasol Technology (Proprietary) Limited Polymerization
WO2011009704A1 (en) 2009-07-21 2011-01-27 Basell Poliolefine Italia S.R.L. Fibres made from copolymers of propylene and 1-pentene
WO2017001474A1 (en) * 2015-06-30 2017-01-05 Borealis Ag Process for preparing propylene polymer compositions
US10836846B2 (en) 2015-10-12 2020-11-17 Institute Of Chemistry, Chinese Academy Of Sciences Olefin polymerization catalyst, preparation method thereof, olefin polymerization catalyst system, use thereof, and method of preparing polyolefin resin
CN106565870B (zh) * 2015-10-12 2019-07-05 中国科学院化学研究所 烯烃聚合催化剂及其制备方法和烯烃聚合催化剂体系及其应用以及聚烯烃树脂的制备方法
CN106565883B (zh) * 2015-10-12 2019-07-05 中国科学院化学研究所 一种有机硅烷的应用以及聚烯烃树脂及其制备方法
JP7045312B2 (ja) 2015-10-12 2022-03-31 中国科学院化学研究所 ポリオレフィン樹脂及びその製造方法
EP3363825B1 (en) * 2015-10-12 2021-04-14 Institute Of Chemistry, Chinese Academy Of Sciences Use of organic siloxane, and polyolefin in-reactor alloy and preparation method thereof
CN110144022B (zh) * 2019-05-28 2020-02-21 国家能源集团宁夏煤业有限责任公司 Ziegler-Natta催化剂的工业制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1043508A (zh) * 1988-12-16 1990-07-04 波利萨有限公司 新型乙烯-丙烯共聚物
US5618895A (en) * 1990-04-06 1997-04-08 Basf Aktiengesellschaft Process for preparing copolymers of propylene with other 1-alkenes

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1988002379A1 (en) * 1986-10-02 1988-04-07 Bp Chemicals Limited Process for polymerizing one or more 1-olefins in the gas phase in the presence of pulverulent inorganic material
ZA96626B (en) * 1995-02-09 1996-08-15 Sastech Pty Ltd Copolymerization

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1043508A (zh) * 1988-12-16 1990-07-04 波利萨有限公司 新型乙烯-丙烯共聚物
US5618895A (en) * 1990-04-06 1997-04-08 Basf Aktiengesellschaft Process for preparing copolymers of propylene with other 1-alkenes

Also Published As

Publication number Publication date
ATE249484T1 (de) 2003-09-15
BR9810982A (pt) 2000-08-08
CA2294798A1 (en) 1999-01-14
HUP0002365A2 (hu) 2000-11-28
US6391987B1 (en) 2002-05-21
DE69818056T2 (de) 2004-04-08
KR20010021512A (ko) 2001-03-15
EP0993474B1 (en) 2003-09-10
HK1028054A1 (en) 2001-02-02
CN1268145A (zh) 2000-09-27
AU8230498A (en) 1999-01-25
WO1999001485A1 (en) 1999-01-14
PL337968A1 (en) 2000-09-11
JP2002508019A (ja) 2002-03-12
ID23869A (id) 2000-05-25
EP0993474A1 (en) 2000-04-19
IL133738A0 (en) 2001-04-30
DE69818056D1 (de) 2003-10-16
AU755262B2 (en) 2002-12-05

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