HUE035218T2 - Fungicid kompozíció, és eljárás kártékony gombák szabályozására - Google Patents

Description

(12) EUROPEAN PATENT SPECIFICATION (45) Date of publication and mention (51) IntCI.: of the grant of the patent: A01P 3100 <2006 01> A01N 43110 <2006 01> 12.04.2017 Bulletin 2017/15 A01N 43140<2006·01> A01N 43156 <2006·01) A01N 35104 (200601) A01N 37106 (200601) (21) Application number: 08847581.9 (86) International application number: (22) Date of filing: 20.10.2008 PCT/JP2008/069392 (87) International publication number: WO 2009/060734 (14.05.2009 Gazette 2009/20)

(54) FUNGICIDAL COMPOSITION AND METHOD FOR CONTROLLING NOXIOUS FUNGI

FUNGIZIDZUSAMMENSETZUNG UND VERFAHREN ZUR BEKAMPFUNG SCHADLICHER PILZE COMPOSITION FONGICIDE ET PROCEDE DE LUTTE CONTRE LES CHAMPIGNONS NOCIFS (84) Designated Contracting States: · TSUKUDA, Shintaro AT BE BG CH CY CZ DE DK EE ES FI FR GB GR Kusatsu-shi HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT Shiga 525-0025 (JP)

ROSE SI SKTR

Designated Extension States: (74) Representative: Blodig, Wolfgang ALBAMKRS Wachtershauser &amp; Hartz

Patentanwaltspartnerschaft mbB (30) Priority: 05.11.2007 JP 2007287699 Weinstrasse 8 80333 Miinchen (DE) (43) Date of publication of application: 14.07.2010 Bulletin 2010/28 (56) References cited: WO-A-2006/016708 WO-A-2007/069777 (73) Proprietor: ISHIHARA SANGYO KAISHA, LTD. JP-A- 2007 210 924

Osaka-shi

Osaka 550-0002 (JP) Remarks:

The file contains technical information submitted after (72) Inventors: the application was filed and not included in this • MITANI, Shigeru specification

Osaka-shi

Osaka 550-0002 (JP)

Note: Within nine months of the publication of the mention of the grant of the European patent in the European Patent Bulletin, any person may give notice to the European Patent Office of opposition to that patent, in accordance with the Implementing Regulations. Notice of opposition shall not be deemed to have been filed until the opposition fee has been paid. (Art. 99(1) European Patent Convention).

Description

TECHNICAL FIELD

[0001] The present invention relates to a fungicidal composition having effects for controlling various noxious fungi remarkably improved, and a method for controlling noxious fungi.

BACKGROUND ART

[0002] Patent Documents 1,2 and 3 disclose that compounds included in the formula (I) given hereinafter are useful as fungicides, and it is disclosed that they may be used in combination or as mixed with other fungicides, as the case requires. However, it is not known that the compound of the formula (I) presents a distinctly superior fungicidal effect when it is used in combination with another specific fungicide in a synergistically effective amount. Further, Patent Documents 4 and 5 disclose that compounds included in the formula (I) given hereinafter are useful as pesticides such as nematicidal agents.

Patent Document 1: WO06/016708 Patent Document 2: WO07/069777 Patent Document 3: JP-A-2007-210924 Patent Document 4: EP1256569A Patent Document 5: EP1428817A

DISCLOSURE OF THE INVENTION

PROBLEM TO BE SOLVED BY THE INVENTION

[0003] The carboxylic acid amide derivatives of the formula (I) given hereinafter sometimes show practically no adequate controlling effects against certain diseases, such that their controlling effects are not adequate against certain noxious fungi depending upon the concentration range or the application site, the residual effects are relatively short, or the resistance against rain is weak.

MEANS TO SOLVE THE PROBLEM

[0004] The present inventors have conducted a research to solve the above problem and as a result, have found that particularly when a carboxylic acid amide derivative of the formula (I) given hereinafter and a certain specific fungicidally effective compound are used as mixed, it is possible to obtain unexpectedly excellent fungicidal activities as compared with a case where the respective compounds are used independently. Thus, the present invention has been accomplished on the basis of this discovery. Namely, the present invention provides a fungicidal composition comprising synergistically effective amounts of (a) a carboxylic acid amide derivative or a salt thereof as defined in claim 1 and (b) at least one fungicidal compound as defined in claim 1. The invention also provides methods for controlling noxious fungi as defined in claims 3 and 4. The invention further provides a use of a fungicidal composition according to claim 5.

[0005] Also described herein is a fungicidal composition comprising synergistically effective amounts of (a) a carboxylic acid amide derivative of the formula (I) or its salt:

wherein B is a heterocyclic group which may be substituted by Y; each of R1 and R2 which are independent of each other, is C1-12 alkyl; X is halogen, C1-12 alkyl or C1-12 alkoxy; Y is halogen, C1-12 alkyl or C1-12 haloalkyl; and n is an integer of from 0 to 5; and (b) at least one fungicidal compound selected from the group consisting of an azole compound, an anilinopyrimidine compound, a triazolopyrimidine compound, a strobilurin compound, an N-halogenothioalkyl compound, a pyridinamine compound, a bicarbonate, an inorganic sulfur compound, a dithiocarbamate compound, an organic chlorine compound, a dicarboxyimide compound, an amine compound, a phe- nylpyrrole compound, a benzophenone compound, a piperidine compound, a dinitrobenzene compound, a morpholine compound, a cyanoacetamide compound, a phosphorous acid compound, an organophosphorus compound, a carboxamide compound, a quinoline compound, a copper compound, a carbamate compound, an antibiotic, a guanidine compound, an oxime ether compound, a4-quinolinol derivative compound, a cyanomethylene compound, a quinazolinone compound and a benzoylpyridine compound. Further, described herein is a method for controlling noxious fungi, which comprises applying a fungicidally effective amount of such a fungicidal composition to noxious fungi or to a site where they grow. Further, the present invention provides a method for controlling noxious fungi, which comprises applying a fungicidally effective amount of (a) the carboxylic acid amide derivative of the formula (I) or its salt, and a fungicidally effective amount of (b) the fungicidal compound, to noxious fungi or to a site where they grow.

EFFECTS OF THE INVENTION

[0006] The fungicidal composition comprising synergistically effective amounts of (a) the carboxylic acid amide derivative of the formula (I) or its salt, and (b) the fungicidal compound (hereinafter referred to simply as the composition of the present invention) is capable of controlling, particularly at low dose, various fungi such as Oomycetes, Ascomycetes, Basidiomycetes or Deuteromycetes, and capable of effectively controlling various plant diseases thereby caused. Unexpectedly, their fungicidal activities exhibit an effect more than a mere additive effect of their respective individual fungicidal activities, i.e. a synergisticfungicidal activity. Thus, the composition containing synergistically effective amounts of (a) the carboxylic acid amide derivative of the formula (I) or its salt, and (b) the fungicidal compound, can be applied in a low dose as compared with a case where the respective agents are used independently, and accordingly, it is effective also to reduce the environmental load at the application site or its surroundings. Further, the fungicidal spectrum can be enlarged, and further, the fungicidal activities will last over a long period of time.

BRIEF DESCRIPTION OF DRAWINGS

[0007]

Fig. 1 is a photograph showing the results of the test on antimicrobial activity against gray mold pathogen in Test Example 7.

Fig. 2 is a view diagrammatically showing the results of the test on antimicrobial activity against gray mold pathogen in Test Example 7, wherein the four portions at which the distance from both ends of the longitudinally-placed filter paper to mycelial growth area of Botrytis cinerea was measured, are shown by arrows.

Fig. 3 is a view diagrammatically showing the results of the test on antimicrobial activity against gray mold pathogen in Test Example 7, wherein the four portions at which the distance from the portion where filter papers intersect each other to mycelial growth area of Botrytis cinerea, are shown by arrows.

BEST MODE FOR CARRYING OUT THE INVENTION

[0008] In a case where in the above formula (I), the number of substituents represented by X is more than one, such substituents may be the same or different. The substation number of Y as substituents contained in B may be one or more, and in the case of more than one, such substituents may be the same or different.

[0009] The heterocyclic moiety of the substituent represented by B in the above formula (I) is preferably a 3- to 6-membered heterocyclic ring containing from 1 to 4 atoms of at least one type selected from the group consisting of an oxygen atom, a sulfur atom and a nitrogen atom, and it may, for example, be a 3-membered heterocyclic ring such as oxiranyl; a 5-membered heterocyclic ring such as furyl, tetrahydrofuryl, thienyl, pyrrolyl, pyrrolinyl, pyrrolidinyl, dioxolanyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, imidazolyl, imidazolinyl, imidazolidinyl, pyrazolyl, pyrazolinyl, pyrazolidinyl, triazolyl, oxadiazolyl, thiadiazolyl or tetrazolyl; ora 6-membered heterocyclic ring such as pyranyl, pyridyl, piperidinyl, dioxanyl, oxazinyl, morpholinyl, thiazinyl, pyridazinyl, pyrimidinyl, pyrazinyl, piperazinyl, triazinyl, dihydrooxathiinyl, di-hydrooxooxathiinyl, dihydrodioxooxathiinyl, dihydropyranyl or dihydrothiinyl. Among them, more preferred is a 5- or 6-membered heterocyclic group containing one or two atoms of at least one type selected from the group consisting of an oxygen atom, a sulfur atom and a nitrogen atom, and most preferred is pyridyl, thienyl or pyrazolyl. Further, a specific example of the substituent represented by B may, for example, be 3-trifluoromethyl-2-pyridyl, 3-methyl-2-thienyl or 1-methyl-3-trifluoromethyl-4-pyrazolyl.

[0010] The alkyl or alkyl moiety in the above formula (I) may be C1-12 linear or branched one, such as methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, n-pentyl, 2-pentyl, n-hexyl, 2-hexyl, 3-hexyl, heptyl, octyl, nonyl, decanyl, undecanyl or dodecanyl.

[0011] The halogen or the halogen as a substituent in the above formula (I) may be an atom of fluorine, chlorine, bromine or iodine. The number of halogens as substituents, may be one or more, and in the case of more than one, such halogens may be the same or different. Further, such halogens may be substituted at any positions.

[0012] The salt of the carboxylic acid amide derivative of the above formula (I) may be any salt so long as it is agriculturally acceptable. For example, it may be an alkali metal salt such as a sodium salt ora potassium salt; an alkaline earth metal salt such as a magnesium salt or a calcium salt; an inorganic acid salt such as a hydrochloride, a perchlorate, a sulfate or a nitrate; or an organic acid salt such as an acetate or a methane sulfonate.

[0013] The carboxylic acid amide derivative of the above formula (I) has various isomers such as optical isomers or geometrical isomers, and the present invention includes both isomers and mixtures of such isomers. Further, the present invention also includes various isomers other than the above isomers within the common knowledge in the technical field concerned. Further, depending upon the types of isomers, they may have chemical structures different from the above formula (I), but they are within the scope of the present invention, since it is obvious to those skilled in the art that they are isomers.

[0014] The carboxylic acid amide derivative of the above formula (I) or its salt may be produced by the process disclosed in the above-mentioned Patent Document 1,2 or 3.

[0015] Among the carboxylic acid amide derivatives of the above formula (I), preferred ones will be listed below. (1) The carboxylic acid amide derivative of the above formula (I) wherein B is a 5- or 6-membered heterocyclic group which may be substituted by Y. (2) The carboxylic acid amide derivative according to the above (1), wherein the heterocyclic group for B is one containing one or two atoms of at least one type selected from the group consisting of a nitrogen atom, a sulfur atom and an oxygen atom. (3) The carboxylic acid amide derivative according to the above (1), wherein the heterocyclic group for B is pyridyl, thienyl or pyrazolyl. (4) The carboxylic acid amide derivative of the above formula (I), wherein B is 3-trifluoromethyl-2-pyridyl, 3-methyl-2-thienyl or 1-methyl-3-trifluoromethyl-4-pyrazolyl.

[0016] However, in the present invention, the at least one carboxylic acid amide derivative of the above formula (I) is selected from the group consisting N-[(3’,4’-dichloro-1,1-dimethyl)phenacyl]-3-trifluoromethyl-2-pyridinecarboxamide (Compound No. 1), N-[(3’,4’-dichloro-1,1-dimethyl)phenacyl]-3-methyl-2-thiophenecarboxamide (Compound No. 2), N-[(3’,4’-dichloro-1,1-dimethyl)phenacyl]-1-methyl-3-trifluoromethyl-4-pyrazolecarboxamide (Compound No. 3), N-[[2’-methyl-4’-(2-propyloxy)-1,1-dimethyl]phenacyl]-3-trifluoromethyl-2-pyridinecarboxamide (Compound No. 4), N-[[2’-me-thyl-4’-(2-propyloxy)-1,1-dimethyl]phenacyl]-3-methyl-2-thiophenecarboxamide (Compound No. 5), N-[[2’-methyl-4’-(2-propyloxy)-1,1-dimethyl]phenacyl]-1-methyl-3-trifluoromethyl-4-pyrazolecarboxamide (Compound No. 6), N-[[4’-(2-pro-pyloxy)-1,1-dimethyl]phenacyl]-3-trifluoromethyl-2-pyridinecarboxamide (Compound No. 7), N-[[4’-(2-propyloxy)-1,1-dimethyl]phenacyl]-3-methyl-2-thiophenecarboxamide (Compound No. 8), N-[[4’-(2-propyloxy)-1,1-dimethyl]phenacyl]-1-methyl-3-trifluoromethyl-4-pyrazolecarboxamide (Compound No. 9), N-[[2’-methyl-4’-(2-pentyloxy)-1,1-dime-thyl]phenacyl]-3-trifluoromethyl-2-pyridinecarboxamide (Compound No. 10) and N-[[4’-(2-pentyloxy)-1,1-dimethyl]phen-acyl]-3-trifluoromethyl-2-pyridinecarboxamide (Compound No. 11).

[0017] The fungicidal compound of the above (b) will be described. Among the fungicidal compounds, those having their common names already approved by ISO (International Organization for Standardization) will be represented by such common names. Other ones will be represented by chemical names, and those having their common names provisionally approved by ISO or having their common names applied to ISO for approval will be identified also by such common names.

[0018] An azole compound may, for example, be triadimefon, triflumizole, penconazole, flusilazole, myclobutanil, cyproconazole, tebuconazole, hexaconazole, N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]imidazole-1 -carboxamide (prochloraz), metconazole, epoxiconazole, prothioconazole, triadimenol, difenoconazole, fluquinconazole, eniliconazol, imazalil, bitertanol, etaconazole, propiconazole, furconazole-cis, tetraconazole, oxpoconazole fumarate, flutriafol, fen-buconazole, bromuconazole, diniconazole, tricyclazole, probenazole, simeconazole, pent-4-enyl (2RS)-2-[furfuryl(imi-dazol-1-ylcarbonyl)amino] butyrate (pefurazoate), ipconazole, imibenconazole, cyazofamid, hymexazol, amisulbrom or fuberiazole. Among them, the azole compound according to the claims is selected from triflumizole, myclobutanil, cyproconazole, tebuconazole, hexaconazole, oxpoconazole fumarate, prochloraz, metconazole, epoxiconazole, prothioconazole, difenoconazole, tetraconazole, tricyclazole, cyazofamid and hymexazol.

[0019] An anilinopyrimidine compound that is, according to the claims, selected from the group of mepanipyrim, py-rimethanil, cyprodinil and ferimzone.

[0020] A triazolopyrimidine compound that is, according to the claims, 5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine (Compound a).

[0021] A strobilurin compound may, for example, be azoxystrobin, kresoxim-methyl, metominostrobin, trifloxystrobin, picoxystrobin, (2E)-2-(methoxyimino)-2-[2-[(3E,5E,6E)-5-(methoxyimino)-4,6-dimethyl-2,8-dioxa-3,7-diazanona-3,6-di- en-1-yl]phenyl]-N-methylacetamide (orysastrobin), dimoxystrobin, pyraclostrobin, fluoxastrobin or methyl 3-methoxy-2-[2-((((1-methyl-3-(4’-chlorophenyl)-2-propenylidene)amino)oxy)-methyl)phenyl]propenoate (enestrobin). Among them, the strobilurin compound according to the claims is selected from azoxystrobin, kresoxim-methyl, trifloxystrobin, dimoxystrobin and pyraclostrobin.

[0022] An N-halogenothioalkyl compound may, for example, be captan, captafol orfolpet. Among them, the N-halog-enothioalkyl compound according to the claims is captan orfolpet.

[0023] A pyridinamine compound that is, according to the claims, fluazinam.

[0024] A bicarbonate may, for example, be sodium bicarbonate or potassium bicarbonate. Among them, potassium bicarbonate is according to the claims.

[0025] An inorganic sulfur compound may, for example, be sulfur, calcium polysulfide or zinc sulfate. Among them, sulfur is according to the claims.

[0026] A dithiocarbamate compound may, for example, be mancozeb, maneb, zineb, polycarbamate, metiram, propineb or thiram. Among them, mancozeb is according to the claims.

[0027] An organic chlorine compound may, for example, be chlorothalonil, fthalide or quintozene. Among them, chlo-rothalonil is according to the claims.

[0028] A dicarboxyimide compound may, for example, be procymidone, iprodione or vinclozolin. Among them, pro-cymidone and iprodione are according to the claims.

[0029] An amine compound may, for example, be spiroxamine ordichlofluanid. Among them, spiroxamine is according to the claims.

[0030] A phenylpyrrole compound may, for example, befludioxonil orfenpiclonil. Among them, fludioxonil is according to the claims.

[0031] A benzophenone compound that is, according to the claims, metrafenone i.e. (3’-bromo-2,3,4,6’-tetramethoxy-2’,6-dimethylbenzophenone).

[0032] A piperidine compound that is, according to the claims, fenpropidin.

[0033] A dinitrobenzene compound that is, according to the claims, meptyldinocap.

[0034] A morpholine compound may, for example, be fenpropimorph, tridemorph, dodemorph, dimethomorph or flu-morph. Among them, dimethomorph and fenpropimorph are according to the claims.

[0035] A cyanoacetamide compound that is, according to the claims, cymoxanil.

[0036] A phosphorous acid compound may, for example, be phosphorous acid, sodium phosphite, potassium phosphite or calcium phosphite. Among them, potassium phosphite is according to the claims.

[0037] An organophosphorus compound may, for example, be fosetyl-AI, tolclofos-methyl, S-benzyl O,O-diisopropyl-phosphorothioate, O-ethyl S,S-diphenylphosphorodithioate, aluminum ethyl hydrogenphosphonate, edifenphos or iprobenfos. Among them, fosetyl-AI and tolclofos-methyl are according to the claims.

[0038] A carboxamide compound may, for example, be flutolani1, 3,4-dichloro-2’-cyano-1,2-thiazole-5-carboxyanilide (isotianil), mepronil, zoxamid, tiadinil, carboxin, oxycarboxin, thifluzamide, furametpyr, penthiopyrad, boscalid, N-(3’,4’-dichloro-5-fluorobiphenyl-2-yl)-3-(difluoromethyl)-1-methylpyrazole-4-carboxamide (bixafen), N-[2-[3-chloro-5-(trifluor-omethyl)-2-pyridyl]ethyl]-a,a,a-trifluoro-o-toluamide (fluopyram), mixture of 2 syn-isomers 3-(difluoromethyl)-1-methyl-N- [(1 RS,4SR,9RS)-1,2,3,4-tetrahydro-9-isopropyl-1,4-methanonaphthalen-5-yl]pyrazole-4-carboxamide and 2 anti-iso-mers 3-(difluoromethyl)-1-methyl-/\/-[(1RS,4SR,9SR)-1,2,3,4-tetrahydro-9-isopropyl-1,4-methanonaphthalen-5-yl]pyra-zole-4-carboxamide (isopyrazam), silthiofam or fenhexamid. Among them, flutolanil and fenhexamid are according to the claims.

[0039] A quinoline compound that is, according to the claims, quinoxyfen.

[0040] A copper compound may, for example, be copper oxychloride, cupric hydroxide, copper sulfate, bordeaux mixture or oxine copper. Among them, copper oxychloride is according to the claims.

[0041] A carbamate compound may, for example, be thiophanate-methyl, benomyl, carbendazim, thiabendazole, pyribencarb, diethofencarb, propamocarb hydrochloride, iprovalicarb, methyl [S-(R,S)]-3-[(N-isopropoxycarbonylvali-nyl)amino]-3-(4-chlorophenyl)propionate (valiphenal) or benthiavalicarb-isopropyl. Among them, thiophanate-methyl, pyribencarb and propamocarb hydrochloride are according to the claims.

[0042] An antibiotic may, for example, be polyoxins, validamycin or kasugamycin. Among them, polyoxins and kas-ugamycin are according to the claims.

[0043] A guanidine compound may, for example, be iminoctadine or dodine. Among them, iminoctadine is according to the claims.

[0044] An oxime ether compound that is, according to the claims, cyflufenamid.

[0045] 4-Quinolinol derivatives may, for example, be Compound Nos. 1 to 11 disclosed on pages 8 to 14 in W02001/92231. Among them, 2,3-dimethyl-6-t-butyl-8-fluoro-4-acetylquinoline (Compound β) disclosed as Compound 2 in the same publication is according to the claims.

[0046] Cyanomethylene compounds may, for example, be Compound Nos. 1 to 236 disclosed on pages 27 to 57 in WO2001/47902. Among them, 2-(2-fluoro-5-(trifluoromethyl)phenylthio)-2-(3-(2-methoxyphenyl)thiazolidin-2-yliden)ac etonitrile (Compound γ) disclosed as Compound No. 120 in the same publication is according to the claims.

[0047] A quinazolinone compound that is, according to the claims, proquinazid.

[0048] Benzoylpyridine compounds may, for example, be compounds disclosed in Tables 1 to 18 in W02002/02527 and Tables 1 and 2 in W02004/039155. Among them, 4-(2,3,4-trimethoxy-6-methylbenzoyl)-2,5-dichloro-3-trifluorometh-ylpyridine (Compound A), 4-(2,3,4-trimethoxy-6-methylbenzoyl)-2-chloro-3-trifluoromethyl-5-methoxypyridine (Compound B), 3-(2,3,4-trimethoxy-6-methylbenzoyl)-5-bromo-4-chloro-2-methoxypyridine (Compound C) and 3-(2,3,4-tri-methoxy-6-methylbenzoyl)-5-chloro-2-methoxy-4-methylpyridine (Compound D) are according to the claims.

[0049] Among the above-mentioned ones, (b) the fungicidal compound in the composition of the present invention is at least one member selected from the group consisting of triflumizole, myclobutanil, cyproconazole, tebuconazole, hexaconazole, N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]imidazole-1-carboxamide (prochloraz), metconazole, epox-iconazole, prothioconazole, difenoconazole, tetraconazole, tricyclazole, oxpoconazole fumarate, cyazofamid, hymexa-zol, mepanipyrim, pyrimethanil, cyprodinil, ferimzone, 5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophe-nyl)-[1,2,4]triazolo[1,5-a]pyrimidine, azoxystrobin, kresoxim-methyl, trifloxystrobin, dimoxystrobin, pyraclostrobin, captan, folpet, fluazinam, potassium bicarbonate, sulfur, mancozeb, chlorothalonil, procymidone, iprodione, spiroxamine, fludioxonil, metrafenone, fenpropidin, meptyldinocap, dimethomorph, fenpropimorph, cymoxanil, potassium phosphite, fosetyl-AI, tolclofos-methyl, flutolanil, fenhexamid, quinoxyfen, copper oxychloride, thiophanate-methyl, pyribencarb, propamocarb hydrochloride, polyoxins, kasugamycin, iminoctadine, cyflufenamid, 2,3-dimethyl-6-t-butyl-8-fluoro-4-acetylquinoline, 2-(2-fluoro-5-(trifluoro-methyl)phenylthio)-2-(3-(2-methoxyphenyl)thiazolidin-2-yliden)acetonitrile, proquinazid, 4-(2,3,4-trimethoxy-6-methylbenzoyl)-2,5-dichloro-3-trifluoromethylpyridine, 4-(2,3,4-trimethoxy-6-methylben-zoyl)-2-chloro-3-trifluoromethyl-5-methoxypyridine, 3-(2,3,4-trimethoxy-6-methylbenzoyl)-5-bromo-4-chloro-2-methox-ypyridine and 3-(2,3,4-trimethoxy-6-methylbenzoyl)-5-chloro-2-methoxy-4-methylpyridine.

[0050] The composition of the present invention is useful as a fungicidal composition capable of controlling noxious fungi at a low dose, particularly useful as an agricultural or horticultural fungicidal composition. When used as an agricultural or horticultural fungicidal composition, the composition of the present invention is capable of controlling noxious fungi such as Oomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes and particularly effective for controlling noxious fungi belonging to e.g. Ascomycetes or Deuteromycetes.

[0051] The following may be mentioned as specific examples of the above noxious fungi.

[0052] Oomycetes may, for example, be genus Phytophthora, such as potato or tomato late blight pathogen (Phy-tophthora infestans), or tomato haiiro-eki-byo pathogen (Phytophthora capsid)', genus Pseudoperonospora, such as cucumber downy mildew pathogen (Pseudoperonospora cubensis)', genus Plasmopara, such as grape downy mildew pathogen (Plasmopara viticola)', and genus Pythium, such as rice seedling blight pathogen (Pythium graminicola), or wheat browning root rot pathogen (Pythium iwayamai).

[0053] Ascomycetes may, for example, be genus Claviceps such as false smut of rice (Claviceps virens)', genus Erysiphe, such as wheat powdery mildew pathogen (Erysiphe graminis)', genus Sphaerotheca, such as cucumber powdery mildew pathogen (Sphaerotheca fuliginea), or strawberry powdery mildew pathogen (Sphaerotheca humuli)', genus Uncinula, such as grape powdery mildew pathogen (Uncinula necator)', genus Podosphaera, such as apple powdery mildew pathogen (Podosphaera leucotricha); genus Mycosphaerella, such as garden pea Mycosphaerella blight pathogen (Mycosphaerella pinodes), apple fruit spot pathogen (Mycosphaerella pomi), banana black sigatoka pathogen (Mycosphaerella musicola), persimmons circular leaf spot pathogen (Mycosphaerella nawae), or strawberry leaf spot pathogen (Mycosphaerella fragariae) ; genus Venturia, such as apple scab pathogen (Venturia inaequalis), or pear scab pathogen (Venturia nashicola); genus Pyrenophora, such as barley net blotch pathogen (Pyrenophora teres), or barley stripe pathogen (Pyrenophora graminea); genus Sclerotinia, such as various Sclerotinia disease pathogen (Sclerotinia Sclerotiorum) such as kidney bean stem rot pathogen, cucumber Sclerotinia rot pathogen, cabbage Sclerotinia rot pathogen, Chinese cabbage Sclerotinia rot pathogen, red pepper Sclerotinia rot pathogen, sweet pepper Sclerotinia rot pathogen, onion watery soft rot pathogen, or rapeseed rot pathogen, wheat Sclerotinia snow blight pathogen (Sclerotinia borealis), tomato syoryu-kinkaku pathogen (Sclerotinia minor), or alfalfa Sclerotinia rot and crown rot pathogen (Sclerotinia trifoliorum); genus Botryolinia, such as peanut small Sclerotinia rot pathogen (Botryolinia arachidis); genus Co-chliobolus, such as rice brown spot pathogen (Cochliobolus miyabeanus); genus Didymella, such as cucumber gummy stem blight pathogen (Didymella bryoniae); genus Gibberella, such as wheat Fusarium blight pathogen (Gibberella zeae); genus Elsinoe, such as grape anthracnose pathogen (Elsinoe ampelina), or citrus scab pathogen (Elsinoe fawcet-tii); genus Diaporthe, such as citrus melanose pathogen (Diaporthe citri), or grape swelling arm pathogen (Diaporthe sp.); genus Guinardia, such as grape blackspot pathogen (Guignardia bidwellii); genus Monilinia, such as apple blossom blight pathogen (Monilinia mali), or peach brown rot pathogen (Monilinia fructicola); and genus Glomerella, such as grape ripe rot pathogen (Glomerella cingulata).

[0054] Basidiomycetes may, for example, be genus Rhizoctonia, such as rice sheath blight pathogen (Rhizoctonia solani); genus Ustilago, such as wheat loose smut pathogen (Ustilago nuda); genus Puccinia, such as oat crown rust pathogen (Puccinia coronata), wheat brown rust pathogen (Puccinia recondita), or wheat stripe rust pathogen (Puccinia striiformis); and genus Typhula, such as wheat or barley Typhula snow blight pathogen (Typhula incarnata, Typhula ishikariensisis).

[0055] Deuteromycetes may, for example, be genus Septoria, such as wheat glume blotch pathogen (Septoria nodo-rum), wheat speckled leaf blotch (Septoria tritici)', genus Botrytis, such as various gray mold pathogen (Botrytis cinerea) such as grape gray mold pathogen, citrus gray mold pathogen, cucumber gray mold pathogen, tomato gray mold pathogen, strawberry gray mold pathogen, eggplant gray mold pathogen, kidney bean gray mold pathogen, adzuki bean gray mold pathogen, garden pea gray mold pathogen, peanut gray mold pathogen, red pepper gray mold pathogen, sweet pepper gray mold pathogen, lettuce gray mold pathogen, onion gray mold pathogen, statice gray mold pathogen, carnation gray mold pathogen, rose Botrytis blight pathogen, garden pansy gray mold pathogen, or sunflower gray mold pathogen, onion gray mold neck rot pathogen (Botrytis allii), or onion Botrytis hagare-syo (Botrytis squamosa, Botrytis byssoidea, Botrytis tulipae)', genus Pyricularia, such as rice blast pathogen (Pyricularia oryzae); genus Cercospora, such as sugar beet Cercospora leaf spot pathogen (Cercospora beticola), or persimmons Cercospora leaf spot pathogen (Cercospora kakivola); genus Colletotrichum, such as cucumber anthracnose pathogen (Colletotrichum orbiculare); genus Alternaria, such as apple Alternaria leaf spot pathogen (Alternaria alternata apple pathotype), pear black spot pathogen (Alternaria alternata Japanese pear pathotype), potato or tomato early blight pathogen (Alternaria solani), cabbage or Chinese cabbage Alternaria leaf spot pathogen (Alternaria brassicae), cabbage Alternaria sooty spot pathogen (Alternaria brassicola), onion or Welsh onion Alternaria leaf spot pathogen (Alternaria porri), Alternaria padwickii; genus Pseudocercosporella, such as wheat eye spot pathogen (Pseudocercosporella herpotrichoides); genus Pseu-docercospora, such as grape leaf spot pathogen (Pseudocercospora vitis); genus Rhynchosporium, such as barley scald pathogen (Rhynchosporium secalis); genus Cladosporium, such as peach scab pathogen (Cladosporium car-pophilum); genus Phomopsis, such as peach Phomopsis rot pathogen (Phomopsis sp.); genus Gloeosporium, such as persimmons anthracnose pathogen (Gloeosporium kaki); genus Fulvia, such as tomato leaf mold pathogen (Fulvia fulva); genus Corynespora, such as cucumber Corynespora leaf spot pathogen (Corynespora cassiicola); genus Curvularia such as Curvularia intermedia, Curvularia clavata, Curvularia inaequalis, Curvularia ovoidea; genus Epicoccum such as Epicoccum purpurascens.

[0056] The composition of the present invention is capable of controlling the above various noxious fungi and thus capable of preventively or curatively controlling various diseases. Particularly, the composition of the present invention is effective for controlling various diseases which are problematic in the agricultural and horticultural field, such as blast, brown spot, sheath blight or damping-off of rice (Oryza sativa, etc.); powdery mildew, scab, brown rust, stripe rust, net blotch, stripe, snow mold, snow blight, loose smut, eye spot, scald, leaf spot orglume blotch of cereals (Hordeum vulgare, Tricum aestivum, etc.); melanose or scab of citrus (Citrus spp., etc.); blossom blight, powdery mildew, melanose, Alternaria leaf spot or scab of apple (Malus pumila); scab or black spot of pear (Pyrus serotina, Pyrus ussuriensis, Pyrus communis)', brown rot, scab or Phomopsis rot of peach (Prunus persica, etc.); anthracnose, ripe rot, leaf spot, swelling arm, powdery mildew or downy mildew of grape (Vitis vinifera spp., etc.); anthracnose, circular leaf spot or Cercospora leafspot of Japanese persimmon (Diospyros kaki, etc.); anthracnose, powdery mildew, gummy stem blight, corynespora leaf spot or downy mildew of cucurbit (Cucumis melo, etc.); early blight, haiiro-eki-byo, leaf mold or late blight of tomato (Lycopersicon esculentum); black sigatoka of banana (Musa sapientum, etc.); Cercospora leaf spot of sugar beet (Beta vulgaris var. saccharifera, etc.); Mycosphaerella blight of garden pea (Pisum sativum)', various Alternaria disease pathogens of cruciferous vegetables (Brassica sp., Raphanus sp., etc); late blight or early blight of potato (Solanum tuberosum)', powdery mildew or leaf spot of strawberry (Fragaria, etc.); and gray mold or disease caused by Sclerotinia of various crops such as beans, vegetables, fruits or flowers. Among them, it is particularly effective against various gray mold or disease caused by Sclerotinia of cucumber (Cucumis sativus), kidney bean (Phaseolus vulgaris), adzuki bean (Vigna angularis), soybean (Glycine max), garden pea, peanut (Arachis hypogaea), tomato, strawberry, eggplant (Solanum melongena), red pepper (Capsicum annuum), sweet pepper (Capsicum annuum), lettuce (Lactuca sativa), onion (Allium cepa), grape, citrus, statice (Limonium spp.), carnation (Dianthus spp.), rose (Rosa spp.), garden pansy (Viola, etc.) or sunflower (Helianthus annuus).

[0057] Further, the composition of the present invention is effective also for preventive or curative control of soil diseases caused by plant pathogens such as Fusarium, Pythium, Rhizoctonia, Verticillium and Plasmodiophora.

[0058] Still further, the composition of the present invention is effective also to control various pathogens resistant to fungicides such as benzimidazoles, strobilurins, dicarboximides, phenylamides and ergosterol biosynthesis inhibitors. [0059] Furthermore, the composition of the present invention has an excellent penetrative migration property, and when a pesticide containing the composition of the present invention is applied to soil, it is possible to control noxious fungi on stems and leaves at the same time as controlling noxious fungi in soil.

[0060] The composition of the present invention, is usually formulated by mixing above mentioned (a) the carboxylic acid amide derivative as defined in claim 1 or a salt thereof (hereinafter referred to simply as component (a)), and (b) the fungicidal compound defined in claim 1 (hereinafterreferred to simply as component (b)), each of which may separately be mixed with various agricultural adjuvants in the same manner as conventional agricultural chemicals, and used in the form of a formulation such as a dust, granules, water-dispersible granules, a wettable powder, a water-based suspension concentrate, an oil-based suspension concentrate, water soluble granules, an emulsifiable concentrate, a soluble concentrate, a paste, an aerosol or an ultra low-volume formulation. However, so long as it is suitable for the purpose of the present invention, it may be formulated into any type of formulation which is commonly used in this field. Such agricultural adjuvants include solid carriers such as diatomaceous earth, slaked lime, calcium carbonate, talc, white carbon, kaoline, bentonite, kaolinite, sericite, clay, sodium carbonate, sodium bicarbonate, mirabilite, zeolite and starch; solvents such as water, toluene, xylene, solvent naphtha, dioxane, acetone, isophorone, methyl isobutyl ketone, chlorobenzene, cyclohexane, dimethylsulfoxide, Ν,Ν-dimethylformamide, dimethylacetamide, N-methyl-2-pyrrolidone, and alcohol; anionic surfactants and spreaders such as a salt of fatty acid, a benzoate, an alkylsulfosuccinate, a dialkylsul-fosuccinate, a polycarboxylate, a salt of alkylsulfuric acid ester, an alkyl sulfate, an alkylaryl sulfate, an alkyl diglycol ether sulfate, a salt of alcohol sulfuric acid ester, an alkyl sulfonate, an alkylaryl sulfonate, an aryl sulfonate, a lignin sulfonate, an alkyldiphenyI ether disulfonate, a polystyrene sulfonate, a salt of alkylphosphoric acid ester, an alkylaryl phosphate, a styrylaryl phosphate, a salt of polyoxyethylene alkyl ether sulfuric acid ester, a polyoxyethylene alkylaryl ether sulfate, a salt of polyoxyethylene alkylaryl ether sulfuric acid ester, a polyoxyethylene alkyl ether phosphate, a salt of polyoxyethylene alkylaryl phosphoric acid ester, and a salt of a condensate of naphthalene sulfonate with formalin; nonionic surfactants and spreaders such as asorbitan fatty acid ester, a glycerin fatty acid ester, a fatty acid polyglyceride, a fatty acid alcohol polyglycol ether, acetylene glycol, acetylene alcohol, an oxyalkylene block polymer, a polyoxyethylene alkyl ether, a polyoxyethylene alkylaryl ether, a polyoxyethylene styrylaryl ether, a polyoxyethylene glycol alkyl ether, a polyoxyethylene fatty acid ester, a polyoxyethylene sorbitan fatty acid ester, a polyoxyethylene glycerin fatty acid ester, a polyoxyethylene hydrogenated castoroil, and a polyoxypropylene fatty acid ester; and vegetable and mineral oils such as olive oil, kapok oil, castoroil, palm oil, camellia oil, coconut oil, sesame oil, corn oil, rice bran oil, peanut oil, cottonseed oil, soybean oil, rapeseed oil, linseed oil, tung oil, and liquid paraffins. Such adjuvants may be selected for use among these known in this field, so long as such selection does not depart from the purpose of the present invention. Further, it is possible to use commonly employed various additives such as a filler, a thickener, an anti-settling agent, an antifreezing agent, a dispersion stabilizer, a phytotoxicity reducing agent, an anti-mold agent, etc. The blend ratio of the components (a) and (b) as active components to various additives is usually from 0.005:99.995 to 95:5, preferably from 0.2:99.8 to 90:10. In actual use of such a formulation, it may be used as it is, or it may be diluted with a diluting agent such as water to a predetermined concentration, and as a case requires, various extenders may be added.

[0061] In the composition of the present invention, a proper blend weight ratio of component (a) to component (b) varies by a difference in weather conditions, crop plants concerned, the method of use, the formulation, etc., and can not simply be defined, but it is usually from 1:70,000 to 70,000:1, preferably from 1:1,000 to 70,000:1. Further, a more preferred blend weight ratio of component (a) to component (b) may be mentioned with respect to each fungicidal compound of component (b). Namely, for example, in a case where component (b) is an azole compound, it is from 1:100 to 70,000:1; in a case where component (b) is an anilinopyrimidine compound, it is from 1:100 to 500:1; in a case where component (b) is at least one fungicidal compound selected from the group consisting of an N-halogenothioalkyl compound, a pyridinamine compound, a bicarbonate, an inorganic sulfur compound, a dithiocarbamate compound, a dicarboxyimide compound, a morpholine compound, a cyanoacetamide compound, a phosphorous acid compound, a carboxamide compound and an antibiotic, it is from 1:500 to 200:1; in a case where component (b) is a copper compound and/or a carbamate compound, it is from 1:1,000 to 200:1; in a case where component (b) is a benzophenone compound, it is from 1:100 to 40,000:1; in a case where component (b) is a quinoline compound and/or a benzoylpyridine compound, it is from 1:100 to 5,000:1; and in the case of other compounds, it is from 1:100 to 200:1.

[0062] The composition of the present invention may be applied by an application method which is commonly used, such as spreading (spreading, spraying, misting, atomizing, grain diffusing or application on water surface), soil application (such as mixing or irrigation) or surface application (such as coating, dust coating or covering). Further, it may be applied also by so-called ultra low volume. In this method, the formulation may contain 100% of the active ingredient. In its application, it is possible to optionally select an application to noxious fungi or to a site where they grow (the application may be pre-emergence or post-emergence of such noxious fungi). Further, the components (a) and (b) may be separately formulated, and at the time of application, they may be mixed and applied. Otherwise, they may be formulated together and applied. The formulation may be applied as it is or after being diluted with e.g. water.

[0063] The dose of the composition of the present invention varies depending upon the weather conditions, crop plants, method of use, formulation, etc. and can not be generally defined. However, in the case of foliage treatment, it is applied so that the total amount of components (a) and (b) as active ingredients will be at a concentration of usually from 0.1 to 10,000 ppm, preferably from 1 to 4,000 ppm, more preferably from 1 to 2,000 ppm, and in the case of soil treatment, it is applied so that the total amount of components (a) and (b) as active ingredients will be usually from 10 to 100,000 g/ha, preferably from 200 to 20,000 g/ha.

[0064] Additionally, the composition of the present invention may be mixed with or may be used in combination with other agricultural chemicals, fertilizers or phytotoxicity-reducing agents, whereby synergistic effects or activities may sometimes be obtained. Such other agricultural chemicals may, for example, be a fungicide, an insecticide, a miticide, a nematicide, a herbicide, an antivirus agent, an attractant, a plant hormone and a plant growth regulating agent. [0065] The active ingredient compounds (common names; including some which are under application, or test code of the Japan Plant Protection Association) of the fungicides in such other agricultural chemicals, may, for example, be: a phenylamide compound such as metalaxyl, metalaxyl-M, mefenoxam, oxadixyl, ofurace, benalaxyl, benalaxyl-M (another name: kiralaxyl or chiralaxyl), furalaxyl or cyprofuram; a piperazine compound such as triforine; a pyridine compound such as pyrifenox; a carbinol compound such asfenarimol orflutriafol; an oxazolidinone compound such as famoxadone; a thiazole carboxamide compound such as ethaboxam; an imidazolidine compound such as fenamidone a benzenesulfoneamide compound such as flusulfamid; an oxime ether compound such as cyflufenamid; a phenoxy amide compound such as fenoxanil; an anthraquinone compound; a crotonic acid compound; an azole compound such as triadimefon, triflumizole, penconazole, flusilazole, myclobutanil, cyproconazole, tebu-conazole, hexaconazole, N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]imidazole-1-carboxamide (prochloraz), met-conazole, epoxiconazole, prothioconazole, triadimenol, difenoconazole, fluquinconazole, eniliconazol, imazalil, bit-ertanol, etaconazole, propiconazole, furconazole-cis, tetraconazole, oxpoconazole fumarate, flutriafol, fenbucona-zole, bromuconazole, diniconazole, tricyclazole, probenazole, simeconazole, pent-4-enyl (2RS)-2-[furfuryl(imidazol- 1- ylcarbonyl)amino]butyrate (pefurazoate), ipconazole, imibenconazole, cyazofamid, hymexazol, amisulbrom or fuberiazole; an anilinopyrimidine compound such as mepanipyrim, pyrimethanil, cyprodinil orferimzone; a triazolopyrimidine compound such as 5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazo-lo[1,5-a]pyrimidine; astrobilurin compound such asazoxystrobin, kresoxim-methyl, metominostrobin, trifloxystrobin, picoxystrobin, (2E)- 2- (methoxyimino)-2-[2-[(3E,5E,6E)-5-(methoxyimino)-4,6-dimethyl-2,8-dioxa-3,7-diazanona-3,6-dien-1-yl]phe-nyl]-N-methylacetamide (orysastrobin), dimoxystrobin, pyraclostrobin, fluoxastrobin, or methyl 3-methoxy-2-[2-((((1-methyl-3-(4’-chlorophenyl)-2-propenylidene)amino)oxy)-methyl)phenyl]propenoate (enestrobin); an N-halogenothioalkyl compound such as captan, captafol orfolpet; a pyridinamine compound such as fluazinam; a bicarbonate such as sodium bicarbonate or potassium bicarbonate; an inorganic sulfur compound such as sulfur, calcium polysulfide or zinc sulfate; a dithiocarbamate compound such as mancozeb, maneb, zineb, polycarbamate, metiram, propineb orthiram; an organic chlorine compound such as chlorothalonil, fthalide or quintozene; a dicarboxyimide compound such as procymidone, iprodione or vinclozolin; an amine compound such as spiroxamine or dichlofluanid; a phenylpyrrole compound such as fludioxonil or fenpiclonil; a benzophenone compound such as metrafenone (3’-bromo-2,3,4,6’-tetramethoxy-2’,6-dimethylbenzophenone); a dinitrobenzene compound such as meptyldinocap; a piperidine compound such as fenpropidin; a morpholine compound such as fenpropimorph, tridemorph, dodemorph, dimethomorph orflumorph; a cyanoacetamide compound such as cymoxanil; a phosphorous acid compound such as phosphorus acid, sodium primary phosphite, potassium primary phosphite, calcium primary phosphite, sodium secondary phosphite, potassium secondary phosphite or calcium secondary phosphite; an organophosphorus compound such as fosetyl-AI, tolcofos-methyl, S-benzyl Ο,Ο-diisopropyl phosphorothioate, O-ethyl S,S-diphenyl phosphorodithioate, aluminum ethyl hydrogenphosphonate, edifenphos or iprobenfos; a carboxamide compound such asflutolanil, 3,4-dichloro-2’-cyano-1,2-thiazole-5-carboxyanilide (isotianil), mepronil, zoxamid, tiadinil, carboxin, oxycarboxin, thifluzamide, furametpyr, penthiopyrad, boscalid, N-(3’,4’-dichloro-5-fluor-obiphenyl-2-yl)-3-(difluoromethyl)-1-methylpyrazole-4-carboxamide (bixafen), N-[2-[3-chloro-5-(trifluoromethyl)-2-pyridyl]ethyl]-a,a,a-trifluoro-o-toluamide (fluopyram), mixture of 2 syn-isomers 3-(difluoromethyl)-1-methyl-/\/-[(1RS,4SR,9RS)-1,2,3,4-tetrahydro-9-isopropyl-1,4-methanonaphthalen-5-yl]pyrazole-4-carboxamide and 2 anti-isomers 3-(difluoromethyl)-1-methyl-/\/-[(1RS,4SR,9SR)-1,2,3,4-tetrahydro-9-isopropyl-1,4-methanonaphthalen-5-yl]pyrazole-4-carboxamide (isopyrazam), silthiofam or fenhexamid; a quinoline compound such as quinoxyfen; a copper compound such as copper oxychloride, cupric hydroxide, coppersulfate, bordeaux mixture oroxine copper; a carbamate compound such as thiophanate-methyl, benomyl, carbendazim, thiabendazole, pyribencarb, diethofen-

carb, propamocarb hydrochloride, iprovalicarb, methyl [S-(R,S)]-3-[(N-isopropoxycarbonylvalinyl)-amino]-3-(4-chlo-rophenyl)propanoate (valiphenal) or benthiavalicarb-isopropyl; an antibiotic such as polyoxins, validamycin or kasugamycin; a guanidine compound such as iminoctadine or dodine; a 4-quinolinol derivative compound such as 2,3-dimethyl-6-t-butyl-8-fluoro-4-acetylquinoline; a cyanomethylene compound such as 2-(2-fluoro-5-(trifluoromethyl)phenylthio)-2-(3-(2-methoxyphenyl)thiazolidin- 2-ylidene)acetonitrile; a benzoylpyridine compound such as 4-(2,3,4-trimethoxy-6-methylbenzoyl)-2,5-dichloro-3-trifluoromethylpyridine, 4-(2,3,4-trimethoxy-6-methylbenzoyl)-2-chloro-3-trifluoromethyl-5-methoxypyridine, 3-(2,3,4-trimethoxy-6-methyl-benzoyl)-5-bromo-4-chloro-2-methoxypyridine or 3-(2,3,4-trimethoxy-6-methylbenzoyl)-5-chloro-2-methoxy-4-methylpyridine; or other compounds, such as proquinazid, isoprothiolane, pyroquilon, diclomezine, chloropicrin, dazomet, metam-sodium, UBF-307, diclocymet, Syngenta 446510 (mandipropamid, dipromandamid), fluopicolide, carpropamid, BCF051, BCM061 and BCM062.

Now, among the above fungicidal compositions, a combination not described above will be exemplified.

[0066] Afungicidal composition comprising synergistically effective amounts of (a) the carboxylic acid amide derivative of the above formula (I) or its salt, and (b) at least one fungicidal compound selected from the group consisting of cyproconazole, tebuconazole, N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]imidazole-1 -carboxamide, metconazole, epoxiconazole, prothioconazole, difenoconazole, tetraconazole, oxpoconazolefumarate, cyazofamid, mepanipyrim, py-rimethanil, cyprodinil, azoxystrobin, kresoxim-methyl, trifloxystrobin, pyraclostrobin, captan,folpet.fluazinam, mancozeb, chlorothalonil, procymidone, iprodione, spiroxamine, fludioxonil, metrafenone, fenpropidin, fenpropimorph, cymoxanil, fosetyl-AI, flutolanil, fenhexamid, quinoxyfen, copper oxychloride, thiophanate-methyl, pyribencarb, polyoxins, iminoctadine, 4-(2,3,4-trimethoxy-6-methylbenzoyl)-2,5-dichloro-3-trifluoromethylpyridine, 4-(2,3,4-trimethoxy-6-methylben-zoyl)-2-chloro-3-trifluoromethyl-5-methoxypyridine, 3-(2,3,4-trimethoxy-6-methylbenzoyl)-5-bromo-4-chloro-2-methox-ypyridine and 3-(2,3,4-trimethoxy-6-methylbenzoyl)-5-chloro-2-methoxy-4-methylpyridine.

[0067] Now, Test Examples of the present invention will be described. Compound No. in each Test Example corresponds to Compound No. shown in the above exemplification of the carboxylic acid amide derivative of the formula (I). TEST EXAMPLE 1: Test on Preventive Effect Against Wheat Powdery Mildew [0068] Wheat (cultivar: Norin-61-go) was cultivated in a plastic pot having a diameter of 7.5 cm, and when it reached 1,5-leaf stage, a mixed chemical solution having the respective test compounds adjusted to prescribed concentrations, was applied by a spray gun in an amount of 10 ml per seedling. After the chemical solution dried, conidia of Erysiphe graminis were dusted and inoculated and maintained in a constant temperature chamber at 20°C. From 7 to 8 days after the inoculation, the area of sporulation was investigated, and the diseased area ratio to non-treated section was obtained by the following equation. The results are shown in Tables 1-1 to 1-101.

Diseased area ratio to non-treated section = (a/b)xl00 a: Average area of sporulation in treated section b: Average area of sporulation in non-treated ection [0069] Further, the theoretical value was calculated by a Colby’s formula and shown in brackets () in Tables 1-1 to 1-101. Since the diseased area ratio to non-treated section (experimental value) is lower than the theoretical value, the composition of the present invention can be said to have a synergistic effect. TABLE 1-1

TABLE 1-2

TABLE 1-7

TABLE 1-12

TABLE 1-17

TABLE 1-22

TABLE 1-27

TABLE 1-32

TABLE 1-37

TABLE 1-42

(continued)

TABLE 1-53

TABLE 1-58

TABLE 1-63

TABLE 1-69

(continued)

(continued)

(continued)

TABLE 1-89

TABLE 1-94

TABLE 1-99

TEST EXAMPLE 2: Test on Preventive Effect Against Cucumber Powdery Mildew [0070] Cucumber (cultivar: Suyo) was cultivated in a plastic pot having a diameter of 7.5 cm, and when it reached 1.5-leaf stage, a mixed chemical solution having the respective sample compounds adjusted to prescribed concentrations, was applied by a spray gun in an amount of 10 ml per seed ling. After the chemical solution dried, a suspension of conidia of Sphaerotheca fuliginea was sprayed and inoculated and maintained in a constant temperature chamber at 20°C. From 7 to 12 days after the inoculation, the area of sporulation was investigated, and the diseased area ratio to non-treated section was obtained in the same manner as in Test Example 1. The results are shown in Tables 2-1 to 2-112. [0071] Further, the theoretical value was calculated by a Colby’s formula and shown in brackets () in Tables 2-1 to 2-112. Since the diseased area ratio to non-treated section (experimental value) is lower than the theoretical value, the composition of the present invention can be said to have a synergistic effect. TABLE 2-1

TABLE 2-2

TABLE 2-7

TABLE 2-12

TABLE 2-17

TABLE 2-22

TABLE 2-28

TABLE 2-33

(continued)

(continued)

TABLE 2-48

TABLE 2-53

TABLE 2-58

TABLE 2-64

TABLE 2-69

TABLE 2-74

TABLE 2-80

TABLE 2-85

(continued)

TABLE 2-96

TABLE 2-102

(continued)

TABLE 2-112

TEST EXAMPLE 3: Test on Preventive Effect Against Wheat Glum Bloth [0072] Wheat (cultivar: Norin-61-go) was cultivated in a plastic pot having a diameter of 7.5 cm, and when it reached 1,5-leaf stage, a mixed chemical solution having the respective sample compounds adjusted to prescribed concentrations, was applied by a spray gun in an amount of 10 ml per seed ling. After the chemical solution dried, a suspension of conidia of Septoria nodorum was sprayed and inoculated and maintained at 20°C for 7 days (for the first 3 days maintained under high humidity condition). Thereafter, the area of lesions was investigated, and the diseased area ratio to non-treated section was obtained by the following equation. The results are shown in Tables 3-1 to 3-14.

Diseased area ratio to non-treated section = (a/b)xl00 a: Average area of lesions in treated section b: Average area of lesions in non-treated section [0073] Further, the theoretical value was calculated by a Colby’s formula and shown in brackets () in Tables 3-1 to 3-14. Since the diseased area ratio to non-treated section (experimental value) is lower than the theoretical value, the composition of the present invention can be said to have a synergistic effect. TABLE 3-1

TABLE 3-2

TABLE 3-3

(continued)

(continued)

TABLE 3-14

TEST EXAMPLE 4: Test on Preventive Effect Against Kidney Bean Gray Mold [0074] Kidney bean (cultivar: Taisyou Kintoki) was cultivated in a plastic pot having a diameter of 12.0 cm, and when it reached 2.5-leaf stage, a mixed chemical solution having the respective test compounds adjusted to prescribed concentrations, was applied by a spray gun in an amount of 10 ml per seedling. After the chemical solution dried, the leaf was cut out, and a filter paper disk (8 mm in diameter) was placed on the leaf. Then, 120 μΙ of a suspension of spores of Botrytis cinerea (1.0X106 spores/ml) was dropped thereon and inoculated. The system was maintained under a humidity condition at 20°C for three days, whereupon the area of lesions was investigated, and the diseased area ratio to non-treated section was obtained in the same manner as in Test Example 3. The results are shown in Tables 4-1 to 4-19. Further, the theoretical value was calculated by a Colby’s formula and shown in brackets () in Tables 4-1 to 4-19. Since the diseased area ratio to non-treated section (experimental value) is lower than the theoretical value, the composition of the present invention can be said to have a synergistic effect. TABLE 4-1

TABLE 4-2

TABLE 4-3

TABLE 4-8

TABLE 4-13

TABLE 4-18

TEST EXAMPLE 5: Test on Antifungal Activity Against Rice Blast Pathogen [0075] Mycelial growth of Phyicularia oryzae preliminarily obtained by cultivation was punched out by a cork borer having a diameter of 4 mm and transplanted on a potato sucrose agar medium containing mixed chemical agents adjusted to prescribed concentrations. The system was left to stand at 25°C for 3 days for cultivation, and thereafter, the diameter of mycelial growth was measured. The incidence to non-treated section was obtained by the following equation, and the results are shown in Table 5-1 to 5-3.

Incidence to non-treated section = (a/b)xlOO a: Average diameter (mm) of mycelial growth in treated section b: Average diameter (mm) of mycelial growth in non-treated section.

[0076] Further, the theoretical value was calculated by a Colby’s formula and shown in brackets () in Tables 5-1 to 5-3. Since the incidence to non-treated section is lowerthan the theoretical value, the composition ofthe present invention can be said to have a synergistic effect. TABLE 5-1

TABLE 5-3

TEST EXAMPLE 6: Test on Antifungal Activity Against Gray Mold Pathogen [0077] Mycelial growth of Botrytis cinerea preliminarily obtained by cultivation was punched out by a cork borer having a diameter of 4 mm and transplanted on a potato sucrose agar medium containing mixed chemical agents adjusted to prescribed concentrations. The system was left to stand at 25°C for 3 days for cultivation, whereupon the diameter of mycelial growth was measured. The incidence to non-treated section was obtained in the same manner as the above Test Example 5, and the results are shown in Table 6-1 to 6-3.

[0078] Further, the theoretical value was calculated by a Colby’s formula and shown in brackets () in Tables 6-1 to 6-3. Since the incidence to non-treated section is lowerthan the theoretical value, the composition ofthe present invention can be said to have a synergistic effect. TABLE 6-1

TEST EXAMPLE 7: Test on Antifungal Activity Against Gray Mold Pathogen [0079] On a potato sucrose agar medium in a Petri dish, a suspension of spores of Botrytis cinerea (spore concentration: 2X106 spores/ml) was spread in an amount of 300 μΙ per Petri dish and dried. Thereon, filter paper immersed in a chemical solution (30 ppm) of Compound No. 2 and a filter paper immersed in a chemical solution (30 ppm) of fluazinam were placed to intersect each other (the respective filter papers were air-dried ones of 0.7 cm X 8 cm). The system was left to stand at 20°C for 4 days, and then, mycelial growth of Botrytis cinerea was observed (photograph in Fig. 1). In

Fig. 1, the transversely-placed filter paper is one immersed in Compound No. 2, and the longitudinally-placed filter paper is one immersed in fluazinam. The white turbid portion is a portion where Botrytis cinerea proliferated.

[0080] Both end portions of the transversely-placed filter paper are in contact with mycelial growth area of Botrytis cinerea, thus indicating that by the single use of Compound No. 2 (30 ppm), no adequate controlling effect can be obtained. Whereas, both end portions of the longitudinally-placed filter paper, are not in contact with mycelial growth area of Botrytis cinerea, thus indicating that by the single use of fluazinam (30 ppm), a certain controlling effect is obtained. Whereas, in the vicinity of the intersection of filter papers, the filter papers are not in contact with mycelial growth area of Botrytis cinerea over a wide range, thus indicating that when Compound No. 2 and fluazinam are used in combination, an excellent controlling effect can be obtained.

[0081] This controlling effect was numerically represented. Namely, the distance from both ends of the longitudinally-placed filter paper corresponding to a single use section of fluazinam to the mycelial growth area of Botrytis cinerea was measured at four portions (arrow portions in Fig. 2), and averaged to obtain 5 mm. On the other hand, the distance from the portion where the filter papers intersect each other, corresponding to a mixed use section of Compound No. 2 and fluazinam to mycelial growth area of Botrytis cinerea was measured at four portions (arrow portions in Fig. 3) and averaged to obtain 17 mm. TEST EXAMPLE 8: Test on Antifungal Activity Against Gray Mold Pathogen [0082] The test was carried out in the same manner as in Test Example 7 except that 30 ppm of fluazinam was changed to 30 ppm of oxpoconazole fumarate. As a result, the distance (average value) from both ends of the longitudinally-placed filter paper corresponding to the single use section of oxpoconazole fumarate to mycelial growth area of Botrytis cinerea, was 7.5 mm. Whereas, the distance (average value) from the portion where the filter papers intersect each other corresponding to a mixed use section of Compound No. 2 and oxpoconazole fumarate to mycelial growth area of Botrytis cinerea was 13.3 mm.

[0083] Now, Formulation Examples of the composition of the present invention will be described, but it should be understood that the blend components, blend ratio, type of formulation, etc. in the present invention are not limited to the following examples. FORMULATION EXAMPLE 1 (a) Kaolin 78 parts by weight (b) Condensate of β-naphthalenesulfonic acid sodium salt with formalin 2 parts by weight (c) Polyoxyethylene alkylaryl ether sulfate 5 parts by weight (d) Hydrated amorphous silicon dioxide 15 parts by weight [0084] A mixture of the above components, a compound of the formula (I) and epoxiconazole are mixed in a weight ratio of 8:1:1 to obtain a wettable powder. FORMULATION EXAMPLE 2 (a) Compound of the formula (I) 0.5 part by weight (b) Epoxiconazole 0.5 part by weight (c) Bentonite 20 parts by weight (d) Kaolin 74 parts by weight (e) Sodium lignin sulfonate 5 parts by weight [0085] To the above components, a suitable amount of water required for granulation is added, followed by mixing and granulation to obtain granules. FORMULATION EXAMPLE 3 (a) Compound of the formula (I) 2 parts by weight (b) Epoxiconazole 3 parts by weight (c) Talc 95 parts by weight [0086] The above components are uniformly mixed to obtain a dust.

Claims 1. A fungicidal composition comprising synergistically effective amounts of (a) a carboxylic acid amide derivative, or its salt, that is at least one compound selected from the group consisting of N-[(3’,4’-dichloro-1,1-dimethyl)phenacyl]- 3- trifluoromethyl-2-pyridinecarboxamide, N-[(3’,4’-dichloro-1,1-dimethyl)phenacyl]-3-methyl-2-thiophenecarboxa-mide, N-[(3’,4’-dichloro-1,1-dimethyl)phenacyl]-1-methyl-3-trifluoromethyl-4-pyrazolecarboxamide, N-[[2’-methyl-4’-(2-propyloxy)-1,1-dimethyl]phenacyl]-3-trifluoromethyl-2-pyridinecarboxamide, N-[[2’-methyl-4’-(2-propyloxy)- 1,1-dimethyl]phenacyl]-3-methyl-2-thiophenecarboxamide, N-[[2’-methyl-4’-(2-propyloxy)-1,1-dimethyl]phenacyl]-1-methyl-3-trifluoromethyl-4-pyrazolecarboxamide, N-[[4’-(2-propyloxy)-1,1-dimethyl]phenacyl]-3-trifluoromethyl-2-pyridinecarboxamide, N-[[4’-(2-propyloxy)-1,1-dimethyl]phenacyl]-3-methyl-2-thiophenecarboxamide, N-[[4’-(2-propyloxy)-1,1-dimethyl]phenacyl]-1-methyl-3-trifluoromethyl-4-pyrazolecarboxamide, N-[[2’-methyl-4’-(2-penty-loxy)-1,1-dimethyl]phenacyl]-3-trifluoromethyl-2-pyridinecarboxamide and N-[[4’-(2-pentyloxy)-1,1-dimethyl]phena-cyl]-3-trifluoromethyl-2-pyridinecarboxamide; and (b) at least one fungicidal compound selected from the group consisting of an azole compound, an anilinopyrimidine compound, a triazolopyrimidine compound, a strobilurin compound, an N-halogenothioalkyl compound, a pyridi-namine compound, a bicarbonate, an inorganic sulfur compound, a dithiocarbamate compound, an organic chlorine compound, a dicarboxyimide compound, an amine compound, a phenylpyrrole compound, a benzophenone compound, a piperidine compound, a dinitrobenzene compound, a morpholine compound, a cyanoacetamide compound, a phosphorous acid compound, an organophosphorus compound, a carboxamide compound, a quinoline compound, a copper compound, a carbamate compound, an antibiotic, a guanidine compound, an oxime ether compound, a 4- quinolinol derivative compound, a cyanomethylene compound, a quinazolinone compound and a benzoylpyridine compound, wherein the azole compound is selected from the group consisting of triflumizole, myclobutanil, cyproconazole, tebuconazole, hexaconazole, N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]imidazole-1 -carboxamide, metconazole, epoxicona-zole, prothioconazole, difenoconazole, tetraconazole, tricyclazole, oxpoconazolefumarate, cyazofamid, and hymex-azol, the anilinopyrimidine compound is selected from the group consisting of mepanipyrim, pyrimethanil, cyprodinil, and ferimzone, the triazolopyrimidine compound is 5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2, 4]triazolo[1,5-a]pyrimidine, the strobilurin compound is selected from the group consisting of azoxystrobin, kresoxim-methyl, trifloxystrobin, dimoxystrobin, and pyraclostrobin, the N-halogenothioalkyl compound is selected from captan and folpet, the pyridinamine compound is fluazinam, the bicarbonate is potassium bicarbonate, the inorganic sulfur compound is sulfur, the dithiocarbamate compound is mancozeb, the organic chlorine compound is chlorothalonil, the dicarboxyimide compound is selected from procymidone and iprodione, the amine compound is spiroxamine, the phenylpyrrole compound is fludioxonil, the benzophenone compound is metrafenone, the piperidine compound is fenpropidin, the dinitrobenzene compound is meptyldinocap, the morpholine compound is selected from dimethomorph and fenpropimorph, the cyanoacetamide compound is cymoxanil, the phosphorous acid compound is potassium phosphite, the organophosphorus compound is selected from the group consisting of fosetyl-AI and tolclofos-methyl, the carboxamide compound is selected from the group consisting of flutolanil and fenhexamid, the quinoline compound is quinoxyfen, the copper compound is copper oxychloride, the carbamate compound is selected from the group consisting of thiophanate-methyl, pyribencarb and propamocarb hydrochloride, the antibiotic is selected from the group consisting of polyoxins and kasugamycin, the guanidine compound is iminoctadine, the oxime ether compound is cyflufenamid, the 4-quinolinol derivative compound is 2,3-dimethyl-6-t-butyl-8-fluoro-4-acetylquinoline, the cyanomethylene compound is 2-(2-fluoro-5-(trifluoromethyl)phenylthio)-2-(3-(2-methoxyphenyl)thiazolidin-2-yli-den)acetonitrile, the quinazolinone compound is proquinazid, the benzoylpyridine compound is selected from the group consisting of 4-(2,3,4-trimethoxy-6-methylbenzoyl)-2,5-dichloro-3-trifluoromethylpyridine, 4-(2,3,4-trimethoxy-6-methylbenzoyl)-2-chloro-3-trifluoromethyl-5-methoxypyri-dine, 3-(2,3,4-trimethoxy-6-methylbenzoyl)-5-bromo-4-chloro-2-methoxypyridine and 3-(2,3,4-trimethoxy-6-methyl-benzoyl)-5-chloro-2-methoxy-4-methylpyridine. 2. The fungicidal composition according to Claim 1, wherein the blend weight ratio of (a) the carboxylic acid amide derivative or its salt to (b) the fungicidal compound is from 1:70,000 to 70,000:1. 3. A method for controlling noxious fungi, which comprises applying the composition as defined in Claim 1 to noxious fungi or to a site where they grow. 4. A method for controlling noxious fungi, which comprises applying (a) the carboxylic acid amide derivative or its salt, and (b) the fungicidal compound, as defined in Claim 1, to noxious fungi or to a site where they grow. 5. Use of a fungicidal composition, as defined in claim 1, for exhibiting a synergistic fungicidal activity in the control of noxious fungi.

Patentansprüche 1. Fungizide Zusammensetzung umfassend synergistisch wirksame Mengen an (a) einem Carbonsäureamidderivat oder dessen Salz, das mindestens eine Verbindung ist ausgewählt aus der Gruppe bestehend aus N-[(3’,4’-Dichlor-1,1-dimethyl)phenacyl]-3-trifluormethyl-2-pyridincarboxamid, N-[(3’,4’-Dichlor-1,1-dimethyl)phenacyl]-3-methyl-2-thiophencarboxamid, N-[(3’,4’-Dichlor-1,1-dimethyl)phenacyl]-1-methyl-3-trifluormethyl-4-pyrazolcarboxamid, N-[[2’-Methyl-4’-(2-propyloxy)-1,1-dimethyl]phenacyl]-3-triffuormethyl-2-pyridincarboxamid, N-[[2’-Methyl-4’-(2-pro-pyloxy)-1,1-dimethyl]phenacyl]-3-methyl-2-thiophencarboxamid, N-[[2’-Methyt-4’-(2-propyloxy)-1,1-dimethyl]phe-nacyl]-1-methyl-3-trifluormethyl-4-pyrazolcarboxamid, N-[[4’-(2-Propyloxy)-1,1-dimethyl]phenacyl]-3-trifluormethyl-2-pyridincarboxamid, N-[[4’-(2-Propyloxy)-1,1-dimethyl]phenacyl]-3-methyl-2-thiophencarboxamid, N-[[4’-(2-Propy-loxy)-1,1-dimethyl]phenacyl]-1-methyl-3-trifluormethyl-4-pyrazolcarboxamid, N-[[2’-Methyl-4’-(2-pentyloxy)-1,1-di-methyl]phenacyl]-3-trifluormethyl-2-pyridincarboxamid und N-[[4’-(2-Pentyloxy)-1,1-dimethyl]phenacyl]-3-trifluor-methyl-2-pyridincarboxamid; und (b) mindestens einer fungiziden Verbindung ausgewählt aus der Gruppe bestehend aus einer Azolverbindung, einer Anilinopyrimidinverbindung; einer Triazolopyrimidinverbindung, einer Strobilurinverbindung, einer N-Halogenthio-alkylverbindung, einer Pyridinaminverbindung, einem Bicarbonat, einer anorganischen Schwefelverbindung, einer Dithiocarbamatverbindung, einer organischen Chlorinverbindung, einer Dicarboxyimidverbindung, einer Aminverbindung, einer Phenylpyrrolverbindung, einer Benzophenonverbindung, einer Piperidinverbindung, einer Dinitrobenzenverbindung, einer Morpholinverbindung, einer Cyanoacetamidverbindung, einer Phosphonsäureverbindung, einer Organophosphorverbindung, einer Carboxamidverbindung, einer Chinolinverbindung, einer Kupferverbindung, einer Carbamatverbindung, einem Antibiotikum, einerGuanidinverbindung, einer Oximetherverbindung, einer 4-Chinolinolderivatverbindung, einer Cyanomethylenverbindung, a Chinazolinonverbindung und einer Benzaylpyridinverbindung, wobei die Azolverbindung ausgewählt ist aus der Gruppe bestehend aus Triflumizol, Myclobutanil, Cyproconazol, Tebu-conazol, Hexaconazol, N-Propyl-N-[2-(2,4,6-trichlorphenoxy)ethyl]imidazol-1-carboxamid, Metconazol, Epoxicona-zol, Prothioconazol, Difenoconazol, Tetraconazol, Tricyclazol, Oxpoconazolfumarat, Cyazofamid und Hymexazol, die Anilinopyrimidinverbindung ausgewählt ist aus der Gruppe bestehend aus Mepanipyrim, Pyrimethanil, Cyprodinil und Ferimzon, die Triazolopyrimidinverbindung 5-Chlor-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorphenyl)-[1,2,4]triazolo[1,5-a]pyri-midin ist, die Strobilurinverbindung ausgewählt ist aus der Gruppe bestehend aus Azoxystrobin, Kresoxim-methyl, Trifloxys-trobin, Dimoxystrobin und Pyraclostrobin, die N-Halogenthioalkylverbindung ausgewählt ist aus Captan und Folpet, die Pyridinaminverbindung Fluazinam ist, das Bicarbonat Kaliumbicarbonat ist, die anorganische Schwefelverbindung Schwefel ist, die Dithiocarbamatverbindung Mancozeb ist, die organische Chlorinverbindung Chlorothalonil ist, die Dicarboxyimidverbindung ausgewählt ist aus Procymidon und Iprodion, die Aminverbindung Spiroxamin ist, die Phenylpyrrolverbindung Fludioxonil ist, die Benzophenonverbindung Metrafenon ist, die Piperidinverbindung Fenpropidin ist, die Dinitrobenzenverbindung Meptyldinocap ist, die Morpholinverbindung ausgewählt ist aus Dimethomorph und Fenpropimorph, die Cyanoacetamideverbindung Cymoxanil ist, die Phosphonsäureverbindung Kaliumphosphit ist, die Organophosphorverbindung ausgewählt ist aus der Gruppe bestehend aus Fosetyl-Al und Tolclofos-methyl, die Carboxamidverbindung ausgewählt ist aus der Gruppe bestehend aus Flutolanil und Fenhexamid, die Chinolinverbindung Ouinoxyfen ist, die Kupferverbindung Kupferoxychlorid ist, die Carbamatverbindung ausgewählt ist aus der Gruppe bestehend aus Thiophanat-methyl, Pyribencarb und Pro-pamocarb hydrochlorid, das Antibiotikum ausgewählt ist aus der Gruppe bestehend aus Polyoxinen und Kasugamycin, die Guanidinverbindung Iminoctadin ist, die Oximetherverbindung Cyflufenamid ist, die 4-Chinolinolderivatverbindung 2,3-dimethyl-6-t-butyl-8-fluor-4-acetylchinolin ist, die Cyanomethylenverbindung 2-(2-Fluoro-5-(trifluormethyl)phenylthio)-2-(3-(2-methoxyphenyl)thiazolidin-2-yli-den)acetanitril ist, die Chinazolinonverbindung Proquinazid ist, die Benzoylpyridinverbindung ausgewählt ist aus der Gruppe bestehend aus4-(2,3,4-Trimethoxy-6-methylbenzoyl)-2,5-dichlor-3-trifluormethylpyridin, 4-(2,3,4-Trimethoxy-6-methylbenzoyl)-2-chlor-3-trifluormethyl-5-methoxypyri-din, 3-(2,3,4-Trimethoxy-6-methylbenzoyl)-5-brom-4-chlor-2-methoxypyridin und 3-(2,3,4-Trimethoxy-6-methylben-zoyl)-5-chlor-2-methoxy-4-methylpyridin. 2. Die fungizide Zusammensetzung gemäß Anspruch 1, wobei das Mischungsgewichtsverhältnis von (a) des Carbonsäureamidderivats oder dessen Salz zu (b) der fungiziden Verbindung von 1:70,000 bis 70,000:1 beträgt. 3. Methode zur Kontrolle schädlicher Pilze, umfassend Anwenden der Zusammensetzung wie in Anspruch 1 definiert auf schädliche Pilze oder an eine Stelle, wo diese wachsen. 4. Methode zur Kontrolle schädlicher Pilze, umfassend Anwenden (a) des Carbonsäureamidderivats oderdessen Salz und (b) der fungiziden Verbindung, wie in Anspruch 1 definiert, auf schädliche Pilze oder an eine Stelle, wo diese wachsen. 5. Verwendung einer fungiziden Zusammensetzung wie in Anspruch 1 definiert, um eine synergistische fungizide Aktivität bei der Kontrolle schädlicher Pilze zu zeigen.

Revendications 1. Composition fongicide comprenant des quantités efficaces de façon synergique de (a) un dérivé amide d’acide carboxylique, ou son sel, qui est au moins un composé choisi dans l’ensemble constitué par le N-[(3’,4’-dichloro-1,1-diméthyl)phénacyl]-3-trifluorométhyl-2-pyridinecarboxamide, le N-[(3’,4’-dichloro-1,1-diméthyl)phénacyl]-3-mé-thyl-2-thiophènecarboxamide, le N-[(3’,4’-dichloro-1,1-diméthyl)phénacyl]-1-méthyl-3-trifluorométhyl-4-pyrazole-carboxamide, le N-[[2’-méthyl-4’-(2-propyloxy)-1,1-diméthyl]phénacyl]-3-trifluorométhyl-2-pyridinecarboxamide, le N-[[2’-méthyl-4’-(2-propyloxy)-1,1-diméthyl]phénacyl]-3-méthyl-2-thiophènecarboxamide, le N-[[2’-méthyl-4’-(2-propyloxy)-1,1-diméthyl]phénacyl]-1-méthyl-3-trifluorométhyl-4-pyrazolecarboxamide, le N-[[4’-(2-propyloxy)-1,1-diméthyl]phénacyl]-3-trifluorométhyl-2-pyridinecarboxamide, le N-[[4’-(2-propyloxy)-1,1-diméthyl]phénacyl]-3-mé-thyl-2-thiophènecarboxamide, le N-[[4’-(2-propyloxy)-1,1-diméthyl]phénacyl]-1-méthyl-3-trifluorométhyl-4-pyrazole-carboxamide, le N-[[2’-méthyl-4’-(2-pentyloxy)-1,1-diméthyl]phénacyl]-3-trifluorométhyl-2-pyridinecarboxamideet le N-[[4’-(2-pentyloxy)-1,1-diméthyl]phénacyl]-3-trifluorométhyl-2-pyridinecarboxamide ; et (b) au moins un composé fongicide choisi dans l’ensemble constitué par un composé azole, un composé anilinopyrimidine, un composé triazolopyrimidine, un composé strobilurine, un composé N-halogénothioalkyle, un composé pyridinamine, un bicarbonate, un composé soufré inorganique, un composé dithiocarbamate, un composé chloré organique, un composé dicarboxyimide, un composé amine, un composé phénylpyrrole, un composé benzophénone, un composé pipéridine, un composé dinitrobenzène, un composé morpholine, un composé cyanoacétamide, un composé acide phosphoreux, un composé phosphoré organique, un composé carboxamide, un composé quinoline, un composé du cuivre, un composé carbamate, un antibiotique, un composé guanidine, un composé oxime-éther, un composé dérivé de 4-quinolinol, un composé cyanométhylène, un composé quinazolinone et un composé benzoylpyridine, dans laquelle le composé azole est choisi dans l’ensemble constitué par le triflumizole, le myclobutanil, le cyproconazole, le tébuconazole, l’hexaconazole, le N-propyl-N-[2-(2,4,6-trichlorophénoxy)éthyl]imidazole-1-carboxamide, le metco-nazole, l’époxiconazole, le prothioconazole, le difénoconazole, le tétraconazole, le tricyclazole, lefumarate d’oxpo-conazole, le cyazofamid, et l’hymexazol, le composé anilinopyrimidine est choisi dans l’ensemble constitué par le mépanipyrim, le pyriméthanil, le cyprodinil, et la férimzone, le composé triazolopyrimidine est le 5-chloro-7-(4-méthylpipéridin-1-yl)-6-(2,4,6-trifluorophényl)-[1,2,4]triazolo[1,5-a]pyrimidine, le composé strobilurine est choisi dans l’ensemble constitué par l’azoxystrobine, le krésoxim-méthyl, la trifloxystro-bine, la dimoxystrobine, et la pyraclostrobine, le composé N-halogénothioalkyle est choisi parmi le captan et le folpet, le composé pyridinamine est le fluazinam, le bicarbonate est le bicarbonate de potassium, le composé inorganique soufré est le soufre, le composé dithiocarbamate est le mancozeb, le composé chloré organique est le chlorothalonil, le composé dicarboxyimide est choisi parmi la procymidone et l’iprodione, le composé amine est la spiroxamine, le composé phénylpyrrole est le fludioxonil, le composé benzophénone est la métrafénone, le composé pipéridine est la fenpropidine, le composé dinitrobenzène est le meptyldinocap, le composé morpholine est choisi parmi le diméthomorph et le fenpropimorph, le composé cyanoacétamide est le cymoxanil, le composé acide phosphoreux est le phosphite de potassium, le composé phosphoré organique est choisi dans l’ensemble constitué par le fosétyl-AI et le tolclofos-méthyl, le composé carboxamide est choisi dans l’ensemble constitué par le flutolanil et le fenhexamid, le composé quinoline est le quinoxyfène, le composé du cuivre est l’oxychlorure de cuivre, le composé carbamate est choisi dans l’ensemble constitué par le thiophanate-méthyl, le pyribencarb et le chlorhydrate de propamocarb, l’antibiotique est choisi dans l’ensemble constitué par les polyoxines et la kasugamycine, le composé guanidine est l’iminoctadine, le composé oxime-éther est le cyflufénamid, le dérivé de 4-quinolinol est le 2,3-diméthyl-6-t-butyl-8-fluoro-4-acétylquinoline, le composé cyanométhylène est le 2-(2-fluoro-5-(trifluorométhyl)phénylthio)-2-(3-(2-méthoxyphényl)thiazolidin-2-ylidène)acétonitrile, le composé quinazolinone est le proquinazid, le composé benzoylpyridine est choisi dans l’ensemble constitué par la 4-(2,3,4-triméthoxy-6-méthylbenzoyl)-2,5-dichloro-3-trifluorométhylpyridine, la 4-(2,3,4-triméthoxy-6-méthylbenzoyl)-2-chloro-3-trifluorométhyl-5-méthoxypy-ridine, la 3-(2,3,4-triméthoxy-6-méthylbenzoyl)-5-bromo-4-chloro-2-méthoxypyridine et la 3-(2,3,4-triméthoxy-6-mé-thylbenzoyl)-5-chloro-2-méthoxy-4-méthylpyridine. 2. Composition fongicide selon la revendication 1, dans laquelle le rapport de mélange en poids de (a) le dérivé amide d’acide carboxylique ou son sel sur (b) le composé fongicide est de 1/70 000 à 70 000/1. 3. Procédé pour lutter contre des champignons néfastes, qui comprend l’application de la composition telle que définie dans la revendication 1 à des champignons néfastes ou sur un site où ils poussent. 4. Procédé pour lutter contre des champignons néfastes, qui comprend l’application de (a) le dérivé amide d’acide carboxylique ou son sel, et (b) le composé fongicide, comme défini dans la revendication 1, à des champignons néfastes ou sur un site où ils poussent. 5. Utilisation d’une composition fongicide telle que definie dans la revendication 1 de sorte qu’elle presente une activite fongicide synergique dans la lutte contre les champignons nefastes.

REFERENCES CITED IN THE DESCRIPTION

This list of references cited by the applicant is for the reader’s convenience only. It does not form part of the European patent document. Even though great care has been taken in compiling the references, errors or omissions cannot be excluded and the EPO disclaims all liability in this regard.

Patent documents cited in the description • WO 06016708 A [0002] · WO 200192231 A [0045] • WO 07069777 A [0002] · WO 200147902 A [0046] • JP 2007210924 A [0002] · WO 200202527 A [0048] • EP 1256569 A [0002] · WO 2004039155 A [0048] • EP 1428817 A [0002]

Claims (5)

1. FUNGICÍD KOMPOZÍCIÓ, ÉS ELJÁRÁS KÁRTÉKONY GOMBÁK SZABÁLYOZÁSÁRA SZABADALMI IGÉNyPÖNTÖK

   1, Faégictá kompozíció, amely tartalmazza a következők vaiaa^eíylkének szinergikcsan (synsfgettásííy; hatébny mennyiségét (a) kafboesavamiö származék vagy sója, amely legalább egyik® az aisbbiak közül kíválaszthető vagya léteknek; N-^ALdíkióF’ 1(1-őirneíii)-feniStáéii)-3-iflííüöMnetlí-2-píriÜÍn'-karböxamid, N-{í3’,4‘-diklőr-1,1-éime®)-tenÍí-acliÍ-3-meíll-24iPÍén^karljöxarntá. N-ÍÍB'A’-diklóíM ,1-Ci'néíil)“léiÍil-acílrt-'metií’3'lrifisot'me{li4-pií3ZQÍ-karboxamtá, Ν-{:(2ΑηοϋΙ-4-{2-ρίόρΙΙ-βΧίί4,1-0ίίη0ίίΟ-ΐ0ηΙί'3θΙ)-S-tKfeof'-metik^tíöi^WböXArh^, N-{$‘-m»íMM24Wii"ö»H <1-őimetii)-fenil-aeii)-3-metll-2-ticfén-karfeoxamtá. N-tlZ’-metil-A-(2>ρΓορ!ΐ>0Χ!)-1,1-0ί^6ϋί)-ί8ηίΙ-3αί}>:1-ηΐδ1ίί-3-0ΐί!θο^ο1.ίί-4-ρίΓ®ζοί-·2δΓ0βΧ8η'ίΐΟ, N-44:-(2-píepll-axi)-1.1-dimetHi-fenil-acll}-3-táficQr-metii-S-piíiőtá-katböxafntá, N-{Í4!-(2-propjkoxi)-1,i-dmtáíiíLfgn!kacil)-3-metil-2-tiotén-karböxamSd, N4Í4'42-pröpil'Oxí)-1,1-dimetiibfenibaellJ-lerietÍl-MIfíüor-meíÍLd-pírazol’karboxamid, N-flS'-rnsSil-A'-íZ-poclil-oxi)-1.'i-diingtlli-ienAsc!l}-3-triíkior-m8l!i-2-piriőtá-katboxamid, ás N-{[4--í2-pent|i-öxl)-1,1-dímetii}«fenií-acíí)-3-tfiííeör--mettá2-plbdin-kafböx8tnld: és (P) legalább egy fongicid vegyöiet- amely a következők közül választható ki: azöi végyöletek, snlltno-piriraidln vegyüietek, triszol-plrífbidin vegyüietek, strebitüűn vegyüietek, N-isaiögéa-íieaikil vegyüietek, táírtáin-amin vegyüietek, bikarbónátok, szervetlen kénvegyületek, ditlokarbaraat vegyüietek, szerves kiőrvegyüSeték, dikarööxí-imid vegyüietek, amin vegyüietek, ténit-pifröí vegyülték, benzöfesion vegyületsk, pipettáin vegyüietek, dlnitrö^bénzöl vegyölétsk, swfelin vegyüietek. eianö-seatamid vegyüietek, ávszforessav vegyöiatek, szerves föszfervegyöletek, karboxamtá vegyüietak, klaelin vegyüietek,: rezvegyülgték, karbaraát vegyüietek, antíbiotikmbek, oxim-éter vegyüietek, -i-kinoiinol származék vegyüietek, ciano-metiién vegyüietek, kinazölinon vegyüietek, és benzoil-piddln vegyüietek, shöi az ázol vegyüietek a kővetkezők közül válastábtáök Rí: trifnmízol, mikiöbutanü, ciprokönazoi, tebnkenazái, üexskönszoi, N-prepli-N-íg-iZÁ.S-Mkiön-ienöxü-étin-itntáazökAkafbekaíniü. metkcnazöl. epexíköiiazel, prötiokenezöi, dlfetiökonazol, teírakenazol, tncikiazel, expokénszei fúrásiét, clazefsíPid és bimexszöl, az anilifio-pirlmtáin vagy öletek a kővetkezők közül választhatók ki: mepanipirim, pldmetaniL clprodtnll és ferlrnzon, a iriazQi-c!riR!Ídín vegyölet 5-kíőí-7-(4-Ípetil-pipertáift-1-ii)>S-i2,4,6-írillyor-fenli-H,2i4]triazotá[t5a)öi,i'!niitiiói a: sirohslurin vegyület a kővetkezők közül váiaszthatö ki; azexiströbiü, krezoxini-metik trltloxiströbin. dímcxístföbtá és píraklostrobín, ez N-helegénAíaalkil vegyüiét a kővetkezők közöl választható ki; kaptán és telpet, a píridin-amín vegyület iföazkiáni. a bikarbónát káiiufs-bikarbonát; a szervetlen kénvegyület kén, a díliökafbarnát vegyület mankezeb, s szerves klörvegyölet kíórtalönil. sdlkartoí-lmtá vegyület a következők közűi vátászthatö ki: preeíraiöen és iprodion, az amin vegyület spnoxamin. a TeniLpirroí vegyület itedloxiníl, a benzofenen vegyület metrafenon, a pipettáin vegyület fenpreptáin, a öiíittíö-benze! vegyület meptildinökap, a moriöfin vegyület :a kővetkezők közül választásíó ki: dímetomorf és fenpropimetá a claníeacetamiő vegyidet cimoxanil, a foszforossav vegyidet kálíöm-toszlit, a szarvas foszfetvagyülai a következők közei válászthátö ki; foszetlhAl és tölklőíesznneül, a karboxamid vegyidet a kővetkezők kőzlii választható ki: flptolani! és fenhexamld, a k ióölín v sg y ü tel kinözífén, a rézvegyület réz-oxiklorlö, a karhamát vegyidet a következők közöl választható ki: ilöíánábmetlt, pirlbenkarb és propamokárb, az antibiotikum a következők közül választható ki: poiloxinok és kaszügarniöln, a guanióin vegyötét tmlnoktadin. az exim-éter vagy ötét oídutepamlci, 4-klnolinoi származék vegyidet Ζ,ΟΌΙιηδίίί-δ^όηίΙΕδΊΙοοΜ^ί^ηΐ^ίηοΙίη, s ölanö-metiiáh vegyöiéti2-(2-tSüor'-§"(tfidyor"aM>l!l)-féfdi-tiö>2-l3-'t*kaietöxi-:featldtíazeltdiö-2-t!idéa}:-sc:atonitfiS: a klnazöiinöh vágyaiét prokinazid, a benzöii-piridin vegyidet a kővetkezők közöl választható ki: 4^2,3,A-fhmetöXdő^meiil-benZöiíj^jS-őfkfór-SdnttuoometíhpiÍidin, 4« (2,3,4-tfimeloxi'6-metll"b8nzollh2"klór*3,killuofmi8til-Smtetökl-piridin, 3^2,3,44rimetQxí>6-metii'benzofíj"ő'-bröm'4-kléf-2'metoxi' piriőlfi és 3-(2.3,4-40316^1-0^181100002010-0^10^240813^-4-1^6111-010010,
2. 2. Az 1. igénypont szerinti fungieid köínpözfeiő, ahol az (a) karbensavamid származéknak vagy sójának keverék-tömegaránya (blenő weight táti©) a (bj fürigicidvegyüleihez az 1 : ?ÖOÖÖ és a 70000:1 közötti tartományban van,
3. 3, Síjárás kártékony inoxleas) gombák szabályozására, amely eljárás: tartalmazza egy az i, igénypont szerint megbáláfozéit kompozlolö felvitelét a kártékony gombákra vagy arra a: helyre, ahol ezek növekednek,
4. 4, Eljárás kártékony gombák szabályozására, amely eljárás tartalmazza az (aj karhőrsssvsmid származéknak vagy sójának és (bt a íártgisid komoozielönak. ahogyan ezek meg vannak határozva az 1. igénypontban, felvitelét a kértékony gömbákra vagy arra a helyre, éltől szék növekednek.
5. 5. Álkáknazásá egy. az i Igénypontban meghatározott fengfeld kömpoziolónak, hogy sztneígikus fengtoid aktivitást matasson kártékony gombák szabályozásában.