HUE028596T2 - Polietilén gyanta habosított részecskék, öntõformában öntött polietilén gyanta hab cikkek, és eljárás polietilén gyanta habosított részecskék elõállítására - Google Patents
Polietilén gyanta habosított részecskék, öntõformában öntött polietilén gyanta hab cikkek, és eljárás polietilén gyanta habosított részecskék elõállítására Download PDFInfo
- Publication number
- HUE028596T2 HUE028596T2 HUE12754382A HUE12754382A HUE028596T2 HU E028596 T2 HUE028596 T2 HU E028596T2 HU E12754382 A HUE12754382 A HU E12754382A HU E12754382 A HUE12754382 A HU E12754382A HU E028596 T2 HUE028596 T2 HU E028596T2
- Authority
- HU
- Hungary
- Prior art keywords
- polyethylene resin
- particles
- foamed particles
- ppm
- less
- Prior art date
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- 239000002245 particle Substances 0.000 title claims description 421
- 239000006260 foam Substances 0.000 title claims description 109
- 238000004519 manufacturing process Methods 0.000 title claims description 28
- 239000003963 antioxidant agent Substances 0.000 claims description 164
- 229920005989 resin Polymers 0.000 claims description 141
- 239000011347 resin Substances 0.000 claims description 141
- 230000003078 antioxidant effect Effects 0.000 claims description 136
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 101
- -1 polyethylene Polymers 0.000 claims description 76
- 238000005187 foaming Methods 0.000 claims description 73
- 239000011342 resin composition Substances 0.000 claims description 71
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 69
- 229910052698 phosphorus Inorganic materials 0.000 claims description 60
- 239000011574 phosphorus Substances 0.000 claims description 60
- 238000002844 melting Methods 0.000 claims description 54
- 230000008018 melting Effects 0.000 claims description 54
- 239000000126 substance Substances 0.000 claims description 51
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical group O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 49
- 238000000034 method Methods 0.000 claims description 49
- 239000004088 foaming agent Substances 0.000 claims description 41
- 239000000203 mixture Substances 0.000 claims description 36
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- 239000002612 dispersion medium Substances 0.000 claims description 22
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 22
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 20
- 238000010438 heat treatment Methods 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 229910001872 inorganic gas Inorganic materials 0.000 claims description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 4
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- 239000008188 pellet Substances 0.000 claims description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 2
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- 235000006708 antioxidants Nutrition 0.000 claims 8
- 229920000573 polyethylene Polymers 0.000 claims 8
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- 150000004291 polyenes Chemical class 0.000 claims 2
- SGTNSNPWRIOYBX-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-{[2-(3,4-dimethoxyphenyl)ethyl](methyl)amino}-2-(propan-2-yl)pentanenitrile Chemical compound C1=C(OC)C(OC)=CC=C1CCN(C)CCCC(C#N)(C(C)C)C1=CC=C(OC)C(OC)=C1 SGTNSNPWRIOYBX-UHFFFAOYSA-N 0.000 claims 1
- 241000195940 Bryophyta Species 0.000 claims 1
- HEFNNWSXXWATRW-UHFFFAOYSA-N Ibuprofen Chemical compound CC(C)CC1=CC=C(C(C)C(O)=O)C=C1 HEFNNWSXXWATRW-UHFFFAOYSA-N 0.000 claims 1
- 241000406668 Loxodonta cyclotis Species 0.000 claims 1
- 241000699670 Mus sp. Species 0.000 claims 1
- 206010030113 Oedema Diseases 0.000 claims 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims 1
- 235000011613 Pinus brutia Nutrition 0.000 claims 1
- 241000018646 Pinus brutia Species 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- BMCCWMIUYHAWDU-UHFFFAOYSA-N [Si+4].[O-][Si]([O-])([O-])[O-] Chemical compound [Si+4].[O-][Si]([O-])([O-])[O-] BMCCWMIUYHAWDU-UHFFFAOYSA-N 0.000 claims 1
- 239000003146 anticoagulant agent Substances 0.000 claims 1
- 229940127219 anticoagulant drug Drugs 0.000 claims 1
- 229910052785 arsenic Inorganic materials 0.000 claims 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims 1
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- RBNPZEHAODHBPZ-UHFFFAOYSA-M dihydroxyaluminium Chemical compound O.O.NCC(=O)O[Al] RBNPZEHAODHBPZ-UHFFFAOYSA-M 0.000 claims 1
- 239000011888 foil Substances 0.000 claims 1
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- 238000009987 spinning Methods 0.000 claims 1
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- 238000011144 upstream manufacturing Methods 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
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- 210000004027 cell Anatomy 0.000 description 76
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- 238000010097 foam moulding Methods 0.000 description 32
- 238000004383 yellowing Methods 0.000 description 30
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 27
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- 238000000113 differential scanning calorimetry Methods 0.000 description 22
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- 238000005259 measurement Methods 0.000 description 20
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 17
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
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- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 8
- 239000005977 Ethylene Substances 0.000 description 8
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 8
- 230000004927 fusion Effects 0.000 description 8
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000002202 Polyethylene glycol Substances 0.000 description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 6
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- 239000002667 nucleating agent Substances 0.000 description 5
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 5
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- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 4
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- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
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- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 3
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
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- GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 description 2
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- YAGPRJYCDKGWJR-UHFFFAOYSA-N 2-(2,4,8,10-tetratert-butylbenzo[d][1,3,2]benzodioxaphosphepin-6-yl)oxy-n,n-bis[2-(2,4,8,10-tetratert-butylbenzo[d][1,3,2]benzodioxaphosphepin-6-yl)oxyethyl]ethanamine Chemical compound O1C2=C(C(C)(C)C)C=C(C(C)(C)C)C=C2C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP1OCCN(CCOP1OC2=C(C=C(C=C2C=2C=C(C=C(C=2O1)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C)CCOP(OC1=C(C=C(C=C11)C(C)(C)C)C(C)(C)C)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C YAGPRJYCDKGWJR-UHFFFAOYSA-N 0.000 description 2
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 description 2
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- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 2
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- 239000002253 acid Substances 0.000 description 2
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- 125000004122 cyclic group Chemical group 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
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- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
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- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 2
- 229910000400 magnesium phosphate tribasic Inorganic materials 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
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- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
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- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 1
- 229960000367 inositol Drugs 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- KZAUOCCYDRDERY-UHFFFAOYSA-N oxamyl Chemical compound CNC(=O)ON=C(SC)C(=O)N(C)C KZAUOCCYDRDERY-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- DGBWPZSGHAXYGK-UHFFFAOYSA-N perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000447 polyanionic polymer Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- VLCLHFYFMCKBRP-UHFFFAOYSA-N tricalcium;diborate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]B([O-])[O-].[O-]B([O-])[O-] VLCLHFYFMCKBRP-UHFFFAOYSA-N 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- NFMWFGXCDDYTEG-UHFFFAOYSA-N trimagnesium;diborate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]B([O-])[O-].[O-]B([O-])[O-] NFMWFGXCDDYTEG-UHFFFAOYSA-N 0.000 description 1
- 229940113165 trimethylolpropane Drugs 0.000 description 1
- JZNDMMGBXUYFNQ-UHFFFAOYSA-N tris(dodecylsulfanyl)phosphane Chemical compound CCCCCCCCCCCCSP(SCCCCCCCCCCCC)SCCCCCCCCCCCC JZNDMMGBXUYFNQ-UHFFFAOYSA-N 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0004—Use of compounding ingredients, the chemical constitution of which is unknown, broadly defined, or irrelevant
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
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- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0095—Mixtures of at least two compounding ingredients belonging to different one-dot groups
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- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
- C08J9/18—Making expandable particles by impregnating polymer particles with the blowing agent
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/228—Forming foamed products
- C08J9/232—Forming foamed products by sintering expandable particles
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- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/034—Post-expanding of foam beads or sheets
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- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/06—CO2, N2 or noble gases
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- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
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- C08J2205/00—Foams characterised by their properties
- C08J2205/04—Foams characterised by their properties characterised by the foam pores
- C08J2205/046—Unimodal pore distribution
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- C08J2205/00—Foams characterised by their properties
- C08J2205/04—Foams characterised by their properties characterised by the foam pores
- C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
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- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
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- Polymers & Plastics (AREA)
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- General Chemical & Material Sciences (AREA)
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- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Claims (8)
- POLIETILÉN GYANTA HABOSÍTOTT iSClfc ÖNTŐFÖRtóBAN ONTOTT POLIETILÉN GYANTA HAB CINKEK, ÉS BLÄÄS POLÍETILÉN GYANTA HABOSÍTOTT RÉSZECSKÉK ELŐÁLLÍTÁSÁRA SZABADALMI IGÉNYPONTOK 1 Reliefén gyanta istóíiöS.ifen^íl részecskék, gmélyek alternate terasznak egy peÉsü$a :|püe icemptfcit ától :ez ferfeimaz - ûm^méàm mennyislgbem smeíy nem leveséit^ mint föSO ppm. de tstm ®í% mH 4000 ppm -egy vagy tsöö Olyan |anyagst: fppmpo»«% mâ$ S következők közi ÄS2ti*$ö· ë: sntiöxldáíisék, léPA^tolfek és szervetlen vagyöletek fanpgok fssbsíancss);, ahei a polietilén gyanta habosított részecskék ä koveisM tulajdonságokká! ttMi: 2-átíagos (E-average) molekulatömegük, ahogyan ez a leírásáéi összhangban meg vsa határozva. nem kisebb, mist 40.1 OY de bem nagyobb, mint 70; Wt atisges septméíbjit (oeit iameferí, ahogyan m. a teirássalYsszhSbghsn meg van hé&üm, nm UM&, mtotiSöiprm de asm nagyobb, mihi 450 gm, Is nyílt éela hányadosak (opemestí ratio), ahogyan ez s leírással összhangban meg kan határozva. nem több, mint 1¾.
- 2. Az 1 Igénypont szedné pelieNén gyanta habosított részecskék, ahol a Evéiiágbs mptokuiatomeg nam kisebb, mint#1öt; de nerr: nagyobb, mint 60.1 DA
- 3. Az I vagy 2 igénypont szerinti polietilén: gprsia habösísett résaeeskék, ahol g poíieSsn gyanta kompozieiô Összességében olyan mennyiségben: tartaimazZá az égy vagytöbb vegyietet (asf agoí| amely nem kisebb, mint iőSD ppm, be nem nagyobb, mintSTÚö ppm.
- 4. Az 1 -3. igénypontok feémfelyle szerinti pólóién gyanta habosított részecskék, ahol - a polietilén gyan ta kompozíció tartalmaz antioxtoánseket amelyek magúkban foglalnak feszfciapú anáoxidérssokaf és kmoi-alapé ÂsrldàbSOkat; és - a következő (sí) és |a2) feltételek ktsfegrtese szükséges: (sí) a polietilén gyanta kompozícióban tartózkodó foszfor-alapú antfoaíeáos mennyisbe nem lehet kisebb, mint 500 ppm, és nem leheT nagyobb, mint 1530 ppm: és (s2) a foszfor-aiapo antioxidáns mennyiségének hányadosa a fenol-alapú antioxidáns mennyiségéhez a polietilén gyanta kommozleiébsn (vagyis a foszfor-alapú aníkaddáns mennyisége / a fenol-alapú antioxidáns mennyisége) nem lehet kisebb, mint 2,0, de nem iahet nagyobb, mmt 7,ö. 5. A 4, Igénypont szerinti plietilen gyahta habosított részecskék, ahol: a Äyados nem kisebb, mint 2,§, de nem nagyobb, : mint 5.Ö. 8, ;Az: 14 igénypontok hérmslpe szerinti peleién gyanta habosított részecskék, ahol á böifotiíéfi gyarite ksmpozfoiőbats: tartózkodó foszfor-aiapu antiox-dáns és fenol-alapú antioxldáns összesítet! mennyisége nem kisebb, mint 800 ppm, de nem nagyobb, mint: 1900 ppm
- 7. AZ: 14 igénypontok bármelyike szerinti posai Ér gyanta habosított részecskék, ehöl ä peleién gyanta kompezíeié tartstmaz egyíém-sztearátet, mégpedig olyan mennyiségben., amely nem kisebb, mint 200 ppm, de nem nagyobb. mmiTOOppm
- 8. Az 1-7. Igénypontok bármelyike szerírríi piietitèh: gyanta behosltstt részecskék, almi a piietilüt gyahfe kompozíció tartalmaz egyszéfvetlén: anyagot, mégpedig olyan mennyiségben, amely nem kisebb, mint 300 ppm, m nem nagyobb, mint SOOpgfo. Sl Az T-b. Igérwppntek bámieíylé polfeíén gyanta habosított részecskék, ahol az átlagos ssjfetofero nem kisebb, mint Wë pm, de: nem nagyobb,. mfetéOÖ pm. :!0;. Az 1-S. IgérrypontOk ibérmeiyiike szerirdi poiielén gyanta hebösttett részecskék, ahol a poíistlsén gyama s poliétiimi gyanta kompozictóban tartalmaz iegaiábbegy knsáris kis-sOröségű (linear iow-^sfty) poliahlén gyantát.
- 11. Ontőimmában őötötí p-moplpl potiebi&ï gyÄ hab cÄek, ameipk az 1v%. igènypentpk bimfetyikéPes hemststotf polietilén Qÿanta habesitött ösbosttotöniése révén vannak kisíasitva.
- 12, Eljárás poíietlién részecskék előállítására, ahoi a polietilén gyanta habosított mszeoskék a követező: ioíldoaságokkeí: irendeileznek; Milages fZ-average) mölekpiáÉrnegOk, ahogyan «*· a leírással összhangban meg 'm fta!áro2vá,aenil<ísg5)b, min! 40.10*. ds^nagy^M^ 70, i$; átlagos sé)!á!®éíöjűk: (œil diameter}, ahogyan ez a leírással összhángfesn megvan határozva, nem kisebb, mihi; 1S0 pm, de nem nágybbb; Inin? 450 am, és nyílnia hányadosuk (opse-deil: ratio), ahogyan ez a ieirássál összhangban mepsh öátározusé nemiig. mintlli:; az spits táríáimázzs az|f első sipdlornh NM lépési: (Ä-slage föárning step), vagyis a HsPöséanPé pöüeüíén gyanta részecskék diszpergáiását egy vizéé diszperziós közegben egy: zári edényben posed vesse!): együtt ep habképző anyaggal ifeaming agent); a habositandó pbliáíén gyanta resaMék mágukban fö^nak égy pteién gyanta kompozíciót, amely tanaimaz - olyan mennyiségben, amely összességéin nem ktasbb, mint ISO® pprn, é$m® nagyobb, naht 4l0ö ppft - egy vagy 'Ä yegyüietei jaoyagöt (comseunb)j. amely a következők közű! válaszható Ír sntioxidáosok, fém-Mearaick és szervetlen anyagok substances); és §! nyomás alá betyezzök (pressurize) és félmeiegiek a habosttsndo poiieién gyanta részecskék legymási homérséktetére (ssítaaing tembiZsrs| vagy a £p;; majd (¾ :kiboesát{ök a haboshandó polietilén gyanta; részecskéket egy olyan zónába, amelynek nyomása kisebb, mint a zárt edény beíss! nyomása. 13: A12. igénypont szerinti eljárás polietilén gyanta bábesitott részecskék eiilásárá,, almi az: èpràs a kivetkőzi lépéseket: tarlaknszzs: - az eísö stádlumó bsbcsté tépés égre hegy poiieién gyanta: habosított részecskék keletkezzenek, ahoi a habosltó szer széndioxid; és - a második siádiumö habosltó lépés (second-stage foaming step), amely szerint b; azetsö stádiumé habosltó lépésben kapott polietilén gpnta habosíistt részecskéket behelyezzük egy ayomásáiiő edénybe (pmsscre-resistant vessel); fit) tmpíégná|bk a polietilén; gyanta habosított részecskéM: egy szervetlen gázzal, amely tartalmaz legalább egy ttpusö gázt, ahol ez a kivetkezők közül választható ki: levegő, nitrogén és szén-dloz:® bogy hozzélesszlk a belső nyomást a poireíiién gyanta habosított részecskékhez; mid pl) tovább habosfdak a poletiin gyanta habosított részecskéket melegítés révén. Μ. Λ12. vagy 13, Igénypont szerinti epràs, ahol > a polietilén gyanta kemppzfcto tartalmaz aniioxldlnsökäf. amelyek magukban: tégláinak tósztór-áiapé sntroxldánsskat és fenol·· alapú anfeidán sokai: és < á következő (all) és (a2) íehétslek kielégítése szükséges:: (ál): a póiieiiién gyanta kompozícióban tartózkodó foszfor-alapú ántlöxidáne mennyiségé nem lehéf kisebb, mint öOö ppm, és nem lehet nagyobb, mint 1500 pprn; és |á2):. a fpszfoí'alapú: arrtíoxiaáns mennyiségének lányaié sa a ferrobaiepg antioxibáns mennyiségéhez a poiieién gyanta kómpoziölóbsn (vagyis a fbszfor-alapú anüoxidárié rherinyiséga f a fenol-alapú antioxidsns mennyiségét nem lehet kisebb, miré 2,0. da nem lehet nagyobb, mint 7.5 15; A12-14, igénypoihek bármstyöm szÄti epás. ából a Äoskandö poiieién gyanta részecskéket olvasztás: fmsíting) és györás (kneadmg) révén kapjuk meg ΰψ» 0âM3?ÂtoèfdeHésteà!^an, amely nem kisebo. mint 2§D€, de ne® nagyobb, mint mint SSPC.
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| US20150240043A1 (en) * | 2012-09-12 | 2015-08-27 | Kaneka Corporation | Polyethylene-based resin foamed particles, polyethylene-based resin in-mold-foam-molded body, and method for producing polyethylene-based resin foamed particles |
| WO2014099335A2 (en) * | 2012-12-21 | 2014-06-26 | Dow Global Technologies Llc | Polyolefin-based cable compound formulation for improved foamability and enhanced processability |
| US9988511B2 (en) * | 2014-03-12 | 2018-06-05 | Sekisui Plastics Co., Ltd. | Composite resin particles, foamable particles, pre-foamed particles, and foam molded body |
| JP6701501B2 (ja) * | 2014-12-22 | 2020-05-27 | キョーラク株式会社 | 発泡ブロー成形方法 |
| WO2016158686A1 (ja) * | 2015-03-27 | 2016-10-06 | 株式会社カネカ | ポリエチレン系樹脂発泡成形体の製造方法 |
| EP3438173B1 (en) * | 2016-03-30 | 2021-12-29 | Kaneka Corporation | Process for producing expanded polyethylene-based resin beads and process for producing polyethylene-based molded resin object by in-mold foaming |
| CN107325324B (zh) * | 2016-04-28 | 2019-08-20 | 中国石油化工股份有限公司 | 阻燃剂、阻燃防静电组合物和阻燃防静电聚丙烯发泡珠粒 |
| JP6838940B2 (ja) * | 2016-11-11 | 2021-03-03 | 株式会社ジェイエスピー | 発泡粒子成形体及びソール部材 |
| CN107383636B (zh) * | 2017-08-22 | 2021-03-19 | 中国科学院长春应用化学研究所 | 一种低导热系数发泡粒子及其制备方法 |
| KR101933322B1 (ko) * | 2017-12-06 | 2018-12-27 | 한화토탈 주식회사 | 발포체용 폴리에틸렌 수지 및 이로부터 제조된 성형품 |
| JP7767214B2 (ja) * | 2022-03-30 | 2025-11-11 | 株式会社ジェイエスピー | 発泡粒子及び発泡粒子成形体 |
| JP7767213B2 (ja) * | 2022-03-30 | 2025-11-11 | 株式会社ジェイエスピー | 発泡粒子及び発泡粒子成形体 |
| EP4502023A1 (en) * | 2022-03-30 | 2025-02-05 | JSP Corporation | Expanded beads, and expanded bead molded body |
| WO2025129162A1 (en) * | 2023-12-15 | 2025-06-19 | Si Group, Inc. | Foamed antioxidant masterbatch and method of making the same |
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| JP2603858B2 (ja) | 1988-08-16 | 1997-04-23 | 株式会社ジェイエスピー | 球状ポリエチレン発泡粒子の製造法 |
| US5110837A (en) | 1990-11-26 | 1992-05-05 | Basf Corporation | Process for making molded polymeric product with multipass expansion of polymer bead with low blowing agent content |
| US5086078A (en) | 1990-11-26 | 1992-02-04 | Basf Corporation | Process for making expanded polymeric product with low level of emission of blowing agent |
| US5110836A (en) | 1990-11-26 | 1992-05-05 | Basf Corporation | Time-efficient process for making expanded polymeric products with multipass expansion of polystyrene bead |
| AU643851B2 (en) | 1990-11-26 | 1993-11-25 | Basf Corporation | Process for making molded polymeric expansion of polymer bead with low blowing agent content |
| US5110524A (en) | 1990-11-26 | 1992-05-05 | Basf Corporation | Process for making molded polymeric product with multipass expansion of polymer bead with low blowing agent content |
| US5240657A (en) | 1990-11-26 | 1993-08-31 | Basf Corporation | Process for making expanded polymeric product with low level of emission of blowing agent |
| US5114640A (en) | 1990-11-26 | 1992-05-19 | Basf Corporation | Time-efficient process for making expanded polymeric products with multipass expansion of polystyrene bead |
| JP3537001B2 (ja) | 1995-03-27 | 2004-06-14 | 株式会社ジェイエスピー | ポリプロピレン系樹脂発泡粒子及びその製造方法 |
| JPH10176077A (ja) | 1996-12-19 | 1998-06-30 | Kanegafuchi Chem Ind Co Ltd | ポリオレフィン系樹脂予備発泡粒子およびその製法 |
| JPH10204203A (ja) | 1997-01-21 | 1998-08-04 | Kanegafuchi Chem Ind Co Ltd | ポリエチレン系樹脂予備発泡粒子の製法 |
| JPH10202720A (ja) | 1997-01-22 | 1998-08-04 | Mitsui Chem Inc | 押出ポリプロピレンフィルム |
| JPH10237211A (ja) | 1997-02-26 | 1998-09-08 | Kanegafuchi Chem Ind Co Ltd | 無架橋ポリエチレン系樹脂予備発泡粒子の製造方法 |
| US6114025A (en) * | 1998-06-15 | 2000-09-05 | Tenneco Protective Packaging, Inc. | Foam and film/foam laminates using linear low density polyethylene |
| JP4138949B2 (ja) * | 1998-07-02 | 2008-08-27 | 株式会社ジェイエスピー | 無架橋ポリエチレン系樹脂発泡粒子及びその成型体 |
| EP1043359A4 (en) | 1998-10-23 | 2004-09-08 | Mitsui Chemicals Inc | ETHYLENE COPOLYMERS AND METHOD FOR THE PRODUCTION, RESIN COMPOSITION THEREFOR AND THE USE THEREOF |
| JP4157206B2 (ja) | 1998-10-29 | 2008-10-01 | 株式会社ジェイエスピー | ポリプロピレン系樹脂発泡粒子及びポリプロピレン系樹脂発泡粒子成形体 |
| US7335716B1 (en) | 1999-06-17 | 2008-02-26 | Mitsui Chemicals, Inc. | Ethylene (co)polymers and uses thereof |
| JP2001172438A (ja) | 1999-12-17 | 2001-06-26 | Toyo Ink Mfg Co Ltd | ポリオレフィン樹脂組成物 |
| JP2009173798A (ja) | 2008-01-25 | 2009-08-06 | Mitsui Chemicals Inc | エチレン系重合体、該エチレン系重合体を含む熱可塑性樹脂組成物およびこれらから得られる成形体 |
| US8513317B2 (en) | 2007-12-11 | 2013-08-20 | Kaneka Corporation | Process for producing expanded polyolefin resin particles and expanded polyolefin resin particles |
| JP2009197226A (ja) | 2008-01-25 | 2009-09-03 | Mitsui Chemicals Inc | エチレン共重合体、該エチレン共重合体を含む熱可塑性樹脂組成物およびこれらから得られる成形体 |
| US20120123006A1 (en) | 2009-05-29 | 2012-05-17 | Sumitomo Chemical Company, Limited | Resin composition for crosslinking/foam molding, crosslinked molded foam, member for footwear, and footwear |
| JP2011099091A (ja) | 2009-09-30 | 2011-05-19 | Sumitomo Chemical Co Ltd | エチレン系重合体の製造方法 |
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| US9309384B2 (en) | 2016-04-12 |
| EP2684910A1 (en) | 2014-01-15 |
| CN103443176A (zh) | 2013-12-11 |
| JPWO2012121163A1 (ja) | 2014-07-17 |
| CN103443176B (zh) | 2015-09-16 |
| EP2684910A4 (en) | 2014-08-20 |
| EP2684910B1 (en) | 2016-02-24 |
| WO2012121163A1 (ja) | 2012-09-13 |
| US20130338246A1 (en) | 2013-12-19 |
| JP5813749B2 (ja) | 2015-11-17 |
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